• Journal of the Korea Organic Resources Recycling Association
• /
• v.21 no.3
• /
• pp.82-92
• /
• 2013

The Intermittent Aeration MBR systems have the advantage of controlling reaction time by changing aeration period and are one of economic BNR systems since these processes do not require MLSS recirculation that demands capital and operation costs. In this study, two intermittent aeration MBR systems were studied by computer simulation: an intermittent aeration MBR system that had both 1hr/1hr and 4hr/4hr aeration/unaeration periods at intermittent reactor and NEW INTERMITTENT-process that was an energy saving process and certified as a new process by Korean government. Since DO concentration reached only at 0.23mg/L at intermittent reactor when it was aerated, the Intermittent aeration MBR system having 1hr/1hr aeration/unaeration period showed simultaneous nitrification/denitrification and had the highest nitrogen and phosphorus removal efficiencies that were 57% and 55%, respectively. Since this study was based on the constant influent flow and characteristics, more studies are needed to define the operational characteristics of intermittent aeration MBR systems under dynamic influent conditions.

• Journal of Wetlands Research
• /
• v.7 no.4
• /
• pp.43-50
• /
• 2005

Wetlands can transform or remove pollutants from water body, such as nitrogen, phosphate, and organics. Many researches were conducted in relation to uptake process by aquatic plants in wetlands. However, water purification processes in wetlands are the results of physical, chemical and biological, especially microbiological reactions. As such, understanding on microbial processes is of great importance. In this study, we used pondor marsh-type wetland microcosms for investigating the water purification capacity and microbial functions, namely, extracellular enzyme activities, nitrification and denitrification. In a pond system, removal efficiencies of $NO_3{^-}$ and $PO{_4}^{3-}$ were 96% and 100 % respectively, while those in a marsh system were 94%, 100% respectively. These high removal efficiencies appeared to be caused by high adsorption ability to soils and microbial functions in wetland.

• Clean Technology
• /
• v.8 no.2
• /
• pp.77-83
• /
• 2002

The purpose of this study is to develop the efficient nutrient removal process and to verify operation and design parameters in domestic sewage. Endogenous nitrate respiration (ENR) was used for denitrification of nitrate in return sludge without additional organic carbon source. ENR reactor before the anaerobic tank enable to reduce nitrate below 3 mg/L and increase phosphate release at anaerobic reaction. Primary effluent during pilot scale plant were shown as TCOD/TP ratio of 40~60 and TCOD/TKN ratio of 5~7. Effluent concentrations were 10 to 12mg/L as TN and 1mg/L as TP respectively. In lab scale experiments endogenous denitrification rate of ENR reactor ranges from 0.042 to $0.057gNO_3-N/gMv.d.$ $SP_{rel}/SCOD_{rm}$ was shown as from 0.13 to 0.17 in anaerobic reaction. These kinetic parameters are expected to be available for BNR(Biological Nutrient Removal) plant design and ENR reaction is available for nutrient removal in low strength wastewater.

• Korean Chemical Engineering Research
• /
• v.46 no.5
• /
• pp.971-976
• /
• 2008

Water pollution by ammonium ion and nitrate is a common and growing problem in the ecosystem. Process of biological removal consists of nitrification and denitrification by bacteria. Ammonium is oxidized generally to nitrate by nitrification and nitrate is reduced to dinitrogen gas in the subsequent denitrification process. Although natural zeolite is well known for its ability to preferentially remove ammonium, it is not sufficiently removing ammonium ion and nitrate by adsorption. In order to overcome this problem, a method of biological removal with zeolite is used for simultaneous removal of ammonium and nitrate. As a result, in case of shaking culture with 1% seed and passing through zeolite column, the process revealed that ammonium ion could be removed completely after 14 hours. The removal of nitrate using columns with naturally adsorbed bacteria onto zeolite reached approximately 100% after 4 hours.

• Journal of Korean Society of Water and Wastewater
• /
• v.19 no.4
• /
• pp.446-454
• /
• 2005

An economic treatment method to remove oxidized nitrogen from wastewater is biological denitrification with organic matters. Several organics can be used, however, methanol is commonly used. When methanol is provided, M:N (Methanol to Nitrogen) ratio is used to define methanol demand for denitrification. In this study, two artificial wastewaters were provided to a biological system to evaluate denitrification performance. Differences of influent total CODcr from effluent soluble CODcr were converted to methanol equivalent and oxidized nitrogen difference between influent and effluent were converted to nitrate equivalent to define M:N ratios. Modes I, II, III, I-1 and IV showed 5.1, 2.7, 3.3, 2.3 and 2.6 of M:N ratios, respectively. Since denitrifying microorganisms had to build a new metabolic system for methanol and influent organics, initial operation mode, Mode I, required more methanol and this resulted in high M:N ratios compared with later operation mode, Mode I-1. Salt in influent did not show inhibitory effects on denitrfication, although this was believed to increase effluent SS and soluble CODcr concentrations in Mode III, I-1 and IV, respectively. The concentrations of effluent soluble $COD_{Mn}$ did not changed much with influent salt.

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.3
• /
• pp.302-308
• /
• 2005

Nitrate is one of common contaminants frequently found in the bank filtrate. Biological autotrophic denitrification into permeable reactive barrier(PRB) system to reduce nitrate concentration in bank filtrate was implanted. The objectives of research are to investigate effect of inoculation, to evaluate alternative alkalinity sources, and to determine effect of hydraulic characteristics, such as retention time, flow rate on the performance of semi-pilot PRB system. Semi-pilot scale biological PRB system was installed using elemental sulfur and limestone/oyster shell as reactive materials near Nakdong River in Kyoungnam province, Korea. Nitrate concentration in bank filtrate was reduced by indigenous microorganisms in oyster shell as welt as by inoculating microorganisms isolated from the sludge of an anaerobic digester in a wastewater treatment plant. Oyster shell as well as limestone can be used as an alkalinity source. However, oyster shell resulted in suspended solids of effluent. As the flow rate in the system increased from 66 to 132 mL/min and accordingly the residence time decreased from 15 to 7.5 hours, nitrate concentration in effluent increased and nitrate removal efficiencies decreased from 75 to 58% at the fixed thickness of 80 cm of PRB.

• Journal of Korean Society of Environmental Engineers
• /
• v.35 no.10
• /
• pp.724-729
• /
• 2013

Simultaneous nitrification and denitrification (SND) occurs concurrently in the same reactor under micro dissolved oxygen (DO) conditions. Anaerobic zone was applied for phosphorus release prior to an aerated membrane bio-reactor (MBR), and anoxic zone was installed by placing a baffle in the MBR for enhancing denitrification even in high DO concentration in the MBR. Phosphorus removal was tested by alum coagulation in the anaerobic reactor preceding to MBR. DO concentration were 2.0, 1.5, 1.0, 0.75 mg/L in the MBR at different operating stages for finding optimum DO concentration in MBR for nitrogen removal by SND. pH was maintained at 7.0~8.0 without addition of alkaline solution even with alum addition due to high alkalinity in the raw sewage. Both TCODcr and $NH_4^+$-N removal efficiency were over 90% at all DO concentration. TN removal efficiencies were 50, 51, 54, 66% at DO concentration of 2.0, 1.5, 1.0, 0.75 mg/L, respectively. At DO concentration of 0.75 mg/L with addition of alum, TN removal efficiency decreased to 54%. TP removal efficiency increased from 29% to 95% by adding alum to anaerobic reactor. The period of chemical backwashing of the membrane module increased from 15~20 days to 40~50 days after addition of alum.

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.11
• /
• pp.1198-1204
• /
• 2005

The objectives of this study were to isolate and culture methanotrophs and to apply them for biological removal of nitrogen and phosphorous. Methanotrophs (dominant species: Methylomonas methanica) were isolated from a landfill cover soil, cultured in a NMS medium, and analyzed to reveal their characteristics of growth and nutrient removal. The methanotrophs themselves can produce substantial amount of organic substances(as COD) including methanol, formaldehyde, and formate, as carbon sources required for denitrification. For instance, the production rate for methanol was $8\;mg/L{\cdot}hr$. Moreover, the analysis of nitrogen and phosphorous in the sludge suggested that the methanotrophs assimilate nitrogen and phosphorous as growth substances.

• Resources Recycling
• /
• v.16 no.6
• /
• pp.52-60
• /
• 2007

Denitrification from aqueous solution was investigated through patent analysis and electrochemical denitrification experiment. Among several candidates, biological treatment and oxidation/reduction method are mainly discussed. Recently, patent pending concerning to electrochemical treatment is increasing. Based on basic electrochemical study, total nitrogen was removed up 47% by 1-hour galvanostatic electrolysis with Fe cathode and Pt anode. More applicable technique to industry could be mentioned combination of two or more technologies suitable to waste water characteristics. In the case of small and concentrate effluent, combination of chemical and electrochemical treatment would be recommendable because nitrate could be easily converted to nitrite by chemical treatment, and in that case denitrification by electrolysis becomes more efficient and metal ions from chemical treatment can be recovered during electrolysis.

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.7
• /
• pp.719-725
• /
• 2005

Anaerobic fill time and feeding pattern in SBR operation were investigated to find way of minimizing poor nitrogen removal efficiency in BNR process without external carbon addition. The three types of the modified SBR operations that were CO-SBR, IA-SBR, and SF-SBR were tested by lab-scale and pilot-scale SBR processes($2\;m^3/day$). In addition, practical equation for biological nitrogen removal was suggested and the equation considered the effect of ratio of fill volume over whole SBR volume and the ratio of step-feed in SBR. The denitrification efficiency of the SF-SBR was best among the three SBRs and followed by IA-SBR, and CO-SBR. The efficiency was 95%, 61%, and 19%, respectively. Looking at the change of sludge floc density by the length of anaerobic fill time, the density of sludge floc at 1 hour and 2 hours of anaerobic fill time were greater than 3 hours of one. The floc size distributions were $100{\sim}300\;{\mu}m$ and $200{\sim}400\;{\mu}m$ with respect to anaerobic fill time 2 hours and 3 hours, respectively.