• Proceedings of the Korean Fiber Society Conference
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• 1996.10a
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• pp.443-449
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• 1996

• Journal of the Korean Chemical Society
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• v.50 no.1
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• pp.65-78
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• 2006

study identified secondary school chemistry major teachers' perceptions of sublimation related to the drying phenomenon of frozen wash and representation of the phenomenon on phase diagram. The subjects were 53 teachers for the questionnaire developed for this study, and interviews. The two professors who majored physical chemistry and one professor who majored analytical chemistry at teacher's college were interviewed for teacher educators' perceptions of sublimation. The results showed that forty one teachers among fifty three teachers thought that the drying phenomenon was sublimation. The most teachers who thought that the phenomenon was sublimation responded as a reason that solid state changes to gas state. The teachers who thought that the phenomenon was not sublimation responded as a reason that the 1 atm of air pressure was not the condition of sublimation. Seventeen teachers thought that the drying phenomenon of frozen wash could be represented on phase diagram, but thirty four teachers thought that it could not. But most teachers confused the scientific representation of the phenomenon, and felt difficulties to teach the contents to students.

• Korean Chemical Engineering Research
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• v.57 no.1
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• pp.78-84
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• 2019

Recently, bio-butanol is being promoted as environmentally friendly sustainable energy. However, some problems are still obstacle for commercialization of bio-butanol: the development of cheap biomass and enhancement of fermentation ratio and preparation of economical separation process for fermented products. In the conventional ABE biobutanol fermentation process, organic acids with acetone, butanol, and ethanol are produced. Therefore, it is necessary to study phase equilibrium data and mixture properties for the design and operation of separation process. However, there is lack of design data for organic acids except acetic acid contained system. In this study, therefore, binary solid-liquid equilibria (SLE) and mixture properties: the excess molar volumes ($V^E$), molar refraction deviation (${\Delta}R$) and deviation of viscosity (${\Delta}v$) at 298.15 for $C_3-C_6$ organic acid were reported. The experimental SLE data were correlated with the NRTL and UNIQUAC activity coefficient model with less than 0.5 K of root mean square deviation (RMSD). In addition, $V^E$, ${\Delta}R$ and ${\Delta}v$ for the same binary systems were satisfactorily fitted using the Redlich-Kister polynomial with less than ca. 0.004 standard deviation.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.710-710
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• 2009

$SF_6$ 가스는 높은 절연 특성으로 인해 산업공정에서 순수 또는 $N_2$ 나 $CO_2$ 가스를 혼합시켜 광범위하게 사용되고 있다. 그러나 $SF_6$ 가스의 지구온난화지수는 $CO_2$ 대비 23,900배로 환경에 치명적인 영향을 줄 수 있으므로, $SF_6$ 가스에 대한 분리 및 처리에 관한 연구가 필요하다. 본 연구에서는 조성에 따른 $SF_6-N_2$ 혼합기체의 3상평형(물-하이드레이트-기체)점을 측정하였다. 측정결과 $N_2$가 더 많이 첨가된 혼합기체일수록 순수 $SF_6$의 상평형 조건보다 더 높은 압력, 더 낮은 온도에서 형성됨을 알 수 있었고 라만분석으로 실제 만들어진 하이드레이트 내에 혼합기체를 확인하였다. 또한 하이드레이트 형성속도 및 회수기체의 조성을 측정하여 분리 및 회수의 효율을 살펴보았다. 본 실험에서 얻어진 결과는 $SF_6$ 혼합기체의 분리 및 처리에 관한 연구의 중요한 기초 자료가 될 것이다.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.150-150
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• 2013

Organic Light Emitting Diode (OLED)에 사용되는 유기발광재료 9,10-di(2-naphthyl)anthracene (ADN)의 상평형 특성을 저진공에서 고진공 조건에 따라 연구하였다. ADN재료의 지속적인 가열과 압력제어가 가능한 진공시스템에서 진공도를 변화시키면서 ADN재료의 온도변화에 따른 상전이 현상을 확인하였다. 본 연구장비의 신뢰성평가를 위하여 상압에서 기존의 Differential Scanning Calorimetry (DSC) 열분석으로 측정한 ADN의 melting point와 비교하였고 각각의 진공조건에서 3회 반복 측정하여 장비신뢰성을 검증하였다. 연구결과, 0.1 Torr에서부터는 상압의 경우와 달리 ADN이 승화하는 것을 확인하였고, 예상대로 진공도가 높아질수록 상전이가 시작되는 온도가 낮아지는 것을 알 수 있었다. 이러한 결과는 기존의 DSC열분석으로는 확인할 수 없었던 고진공에서의 유기재료의 상전이 현상을 관측하였다는데 큰 의미가 있다. 향후, 이러한 방법을 활용한 고진공에서의 유기재료의 상전이 특성 관측은 유기재료를 이용한 진공 증착공정방법의 최적화와, 다양한 유기재료의 열안정성 특성 파악에 도움이 될 것으로 기대가 된다.

• Proceedings of the Korean Society of Computer Information Conference
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• 2019.01a
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• pp.319-321
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• 2019

본 논문에서는 수학교육용 소프트웨어에서 확률적 현상을 경험한 이후 과학 그래프 해석에 있어 확률론적 관점을 도입하여 해석하는 학습자의 관점의 변화를 제시한다. 이 연구에서 11명의 고등학교 1학년 학생은 수학교육용 소프트웨어인 지오지브라(GeoGebra)를 활용하여 학습자가 평면 상에서 수직선이나 반원 위에 점을 찍는 활동을 통하여 기하학적 확률을 경험하였으며 이와 같은 경험을 토대로 물의 상평형 그래프를 해석하였다. 물의 상평형 그래프에 나타나는 얼음(고체), 물(액체), 수증기(기체)의 상태 변화에 대하여 각 상태가 나타나는 온도-압력의 영역 간의 경계에 대하여 학습자는 기하학적 확률을 적용하여 해석하려고 하였으나 경계선 위의 온도-압력의 물의 미시적 구조를 표현하는 과정에서 4명의 학생만 확률론적 관점으로 해석하고 그렇지 못한 학생들은 상태의 공존을 물질적 관점이나 과정적 관점으로 이해하였다.

• Journal of the Korean Chemical Society
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• v.52 no.1
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• pp.84-95
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• 2008

In this study, preconceptions held by chemistry major secondary school science teachers were searched in relation to explanations of water evaporation phenomena with phase equilibrium diagrams. 25 chemistry major science teachers were selected to complete questionnaires developed in this study and 6 among of them were selected to participate in follow-up interviews. Among these, 10 participants were selected for an evaluation of the change of their preconceptions through lessons developed in this study. From the results, it was found that many teachers believed that the phase equilibrium diagram could not explain water evaporation phenomena. They also thought that there was no relation between vapor pressure and the vertical axis of the phase equilibrium diagram. However, after the lessons in earth science, they recognized that the vapor pressure curve of the phase equilibrium diagram could be explained by adopting a saturated vapor curve. Because they had known the process of application the conceptions of saturated situation, nonsaturated situation, process of equilibrium movement in saturated vapor curve. They could understand natural phenomena such as evaporation with the phase equilibrium diagram through a change in their conceptions as guided from science lessons integrating earth science and chemistry.

• Clean Technology
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• v.15 no.4
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• pp.258-264
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• 2009

Thermodynamic measurements were performed to show the possibility of recovering $CO_2$ from fuel gas (the mixture of $CO_2$ and $H_2$) by forming gas hydrates with water where water was dispersed in the pores of silica gel particles having nominal 100 nm of pore diameter. The hydrate-phase equilibria for the ternary $CO_2+H_2$+water in pores were measured and $CO_2$ concentrations in vapor and hydrate phase were determined under the hydrate-vapor two phase region at constant 274.15 K. It was shown that the inhibition effect appeared due to silica gel pores, and the corresponding equilibrium dissociation pressures became higher than those of bulk water hydrates at a specific temperature. In addition, direct measurement of $CO_2$ content in the hydrate phase showed that the retrieved gas from the dissociation of hydrate contained more than 95 mol% of $CO_2$ when 42 mol% of $CO_2$ and balanced Hz mixture was applied. Compared with data obtained in case of bulk water hydrates, which showed just 83 mol% of $CO_2$ where 2-stage hydrate slurry reactor was intended to utilize this property, the hydrate formation in porous silica gel has enhanced the feasibility of $CO_2$ separation process. Hydrate formation as not for slurry but solid particle makes it possible to used fixed bed reactor, and can be a merit of well-understood technologies in the industrial field.

• Korean Chemical Engineering Research
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• v.56 no.2
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• pp.222-228
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• 2018

Benzene is one of the most widely used basic materials in the petrochemical industry. Generally, benzene exists as a mixture with alcohols rather than as a pure substance. Further, the alcohols-added mixtures usually exhibit an azeotropic composition. In this context, knowledge of the phase equilibrium behavior of the mixture is essential for its separation and purification. In this study, the vapor-liquid equilibrium data were measured in favor of a recirculating VLE apparatus under constant pressure for the 1 - propanol / benzene system. The measured vapor - liquid equilibrium data were also correlated by using the UNIQUAC and WILSON models and the thermodynamic consistency test based on the Gibbs/Duhem equation was followed. The results of the phase equilibrium experiment revealed RMSEs (Root Mean Square Error) and AADs (Average Absolute Deviation) of less than 0.05 for both models, indicating a good agreement between the experimental value and the calculated value. The results of the thermodynamic consistency test also confirmed through the residual term within ${\pm}0.2$.

• 기계와재료
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• v.11 no.1 s.39
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• pp.88-98
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• 1999