• Journal of the Korean Geotechnical Society
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• v.30 no.1
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• pp.37-47
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• 2014

Unsaturated hydraulic conductivity (HC) is integrated theoretically from soil water retention curves (SWRC) by Mualem capillary model, but the prediction of HC is extremely sensitive to small variation of matric suction near saturation. Near saturation, the Mualem HC based on smooth SWRC decreases abruptly and has problems in the reliability of hydraulic behavior and the stability of numerical solutions. To improve van Genuchten-Mualem (VGM) HC, the van Genuchten SWRC model is modified within range of low matric suction (arbitrary air entry pressure). At an arbitrary air entry pressure, the VG SWRC is linearized in log scale until full saturation. The modified VG SWRC does not affect the fit of actual retention behavior and either the parameters of original VG SWRC fit. Using the modified VG SWRC, the VGM HC is modified to integrate for each interval decomposed by arbitrary air entry pressure. An analytical solution on modified VGM HC is proposed each interval, to protect the rapid change in HC near saturation. For silty soils, VGM models of HC function underestimate the unsaturated permeability characteristics and especially show rapid reduction near saturation. The modified VGM model predicts more accurate HC functions for Korean weathered soils. Furthermore, near saturation, the saturated HC is conserved by the modified VGM model. After 2-D infiltration analysis of an actual slope, the hydraulic behaviors are compared for VGM and the modified models. The prediction by the proposed model conserved the convergence of solutions on various rainfall conditions. However, the solution by VGM model did not converge since the conductivity near saturation reduced abruptly for heavy rainfall condition. Using VGM model, the factor of safety is overestimated in both initial and final stage during heavy rainfall. Stability analysis based on infiltration analysis could simulate the actual slope failure by the proposed model on HC.

• Economic and Environmental Geology
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• v.42 no.5
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• pp.479-486
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• 2009

In natural environments, manganese (Mn) exists in the valence of +2, +3, and +4 and plays a pivotal role as a strong oxidant or reductant in the geochemical cycles of elements. Especially, Mn forms varying (oxyhydr)oxides. The oxidation state of structural Mn is characteristic to each oxide and is one of the most important factors controlling its geochemical behaviors such as solubility, sorption capacity, and redox potential. Therefore, it is important to elucidate processes governing Mn oxidation state in predicting the fate and transport of many redox sensitive elements in the environment. X-ray photoelectron spectroscopy (XPS) is a very useful method to determine the oxidation state of various elements in solid phases. In this study, the oxidation states of structural Mn in MnO, $Mn_2O_3$, $MnO_2$ were assessed based on the binding energy spectra of $Mn2p_{3/2}$ and Mn3s using XPS and were compared with those reported elsewhere. $Mn2p_{3/2}$ binding energies were determined as 640.9, 641.5, 641.8 eV for MnO, $Mn_2O_3$, $MnO_2$, respectively, which indicates that the binding energy increased with increasing Mn oxidation state. It was also noted that Ar etching may cause changes in electronic structure configuration on surface of the original sample.

• Korean Chemical Engineering Research
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• v.54 no.5
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• pp.612-620
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• 2016

Aqueous mineral carbonation process, in which $CO_2$ is captured through the reaction with aqueous calcium oxide (CaO) solution, is one of CCU technology enabling the stable sequestration of $CO_2$ as well as economic value creation from its products. In order to enhance the carbon capture efficiency, it is required to maximize the dissolution rate of solid reactants, CaO. For this purpose, the proper design of a reactor, which can achieve the uniform distribution of solid reactants throughout the whole reactor, is essential. In this paper, the effect of internal reactor designs on the solid dispersion quality is studied by using CFD (computational fluid dynamics) techniques for the pilot-scale reactor which can handle 40 ton of $CO_2$ per day. Various combination cases consisting of different internal design variables, such as types, numbers, diameters, clearances and speed of impellers and length and width of baffles are analyzed for the stirred tank reactor with a fixed tank geometry. By conducting sensitivity analysis, we could distinguish critical variables and their impacts on solid distribution. At the same time, the reactor design which can produce solid distribution profile with a standard deviation value of 0.001 is proposed.

• Korean Journal of Remote Sensing
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• v.34 no.6_1
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• pp.1055-1066
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• 2018

Vegetation indices on the basis of optical characteristics of vegetation can represent various conditions such as canopy biomass and physiological activity. Those have been mostly developed with the large-scaled applications of multi-band optical sensors on-board satellites. However, the sensitivity of vegetation indices for detecting vegetation features will be different depending on the spatial scales. Therefore, in this study, the investigation of photochemical reflectance index (PRI), known as one of useful vegetation indices for detecting photosynthetic ability and vegetation stress, under the three spatial scales was conducted using multi-spectral camera installed in unmanned aerial vehicle (UAV),field spectrometer, and leaf reflectometer. In the leaf scale, diurnal PRI had minimum values at different local-time according to the compass direction of leaf face. It meant that each leaf in some moment had the different degree of light use efficiency (LUE). In early growth stage of crop, $PRI_{leaf}$ was higher than $PRI_{stands}$ and $PRI_{canopy}$ because the leaf scale is completely not governed by the vegetation cover fraction.In the stands and canopy scales, PRI showed a large spatial variability unlike normalized difference vegetation index (NDVI). However, the bias for the relationship between $PRI_{stands}$ and $PRI_{canopy}$ is lower than that in $NDVI_{stands}$ and $NDVI_{canopy}$. Our results will help to understand and utilize PRIs observed at different spatial scales.

• Journal of Korea Water Resources Association
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• v.55 no.10
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• pp.785-799
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• 2022

The aim of this study was to characterize the emission pathways and the footprint of greenhouse gases (GHG) in Daecheong Reservoir using the G-res Tool, and to evaluate the GHG emission intensity (EI) compared to other energy sources. In addition, the change in GHG emissions was assessed in response to the total phosphorus (TP) concentration. The GHG flux in post-impoundment was found to be 262 gCO₂eq/m²/yr, of which CO₂ and CH₄ were 45.7% and 54.2%, respectively. Diffusion of CO₂ contributed the most, followed by diffusion, degassing, and bubbling of CH₄. The net GHG flux increased to 510 gCO₂eq/m²/yr because the forest (as CO₂ sink) was lost after dam construction. The EI of Daecheong Reservoir was 86.8 gCO₂eq/kWh, which is 3.7 times higher than the global EI of hydroelectric power, due to its low power density. However, it was remarkable to highlight the value to be 9.5 times less than that of coal, a fossil fuel. We also found that a decrease in TP concentration in the reservoir leads to a decrease in GHG emissions. The results can be used to improve understanding of the GHG emission characteristics and to reduce uncertainty of the national GHG inventory of dam reservoirs.

• Journal of the Korean Ceramic Society
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• v.41 no.9
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• pp.696-702
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• 2004

Lifetime of excited electronic states inside the 4f configuration of rare-earth elements embedded in chalcogenide glasses is very sensitive to medium-range structural changes of the host glasses. We have measured lifetimes of the 1.6$\mu\textrm{m}$ emission originating from Pr$\^$3+/ : ($^3$F$_3$, $^3$F$_4$)\longrightarrow$^3$H$_4$ transition in amorphous chalcogenide samples consisting of Ge, Sb, and Se elements. The measured lifetimes fumed out to have their maximum at the mean coordination number of -2.67, which arises accordingly from structural changes of the host glasses from 2 dimensional layers to 3 dimensional networks. This new finding supports that the so-called topological structure model together with chemically ordered network model is adequate to explain relationship between the emission properties of rare-earth elements and the medium-range structures of amorphous chalcogenide hosts with a large covalent bond nature. Thus, it is validated to predict site distribution and lifetime of rare-earth elements doped in chalcogenide glasses simply based on their mean coordination number.

• KSBB Journal
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• v.10 no.1
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• pp.46-54
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• 1995

The physiological characteristics of carrot hairy roots and suspension cells were examined based on their nutritional requirements. Inorganic nutrient (phosphorous and ammonium) requirements of carrot hairy roots were similar to those of suspension cells. Optimal sucrose concentration for the growth of hairy roods (7%) was different from that of suspension cells (3%). Since suspension cells were move easily affected by the environmental condition, e.g., osmotic stress, than hairy roofs which made the suitable growth condition for cells, it can be understood that optimal sucrose concentration for the growth of hairy roots was higher than that for the growth of the suspension cells. To investigate the roles of sucrose on the growth of hairy roots, the effects of sucrose on the fresh weight and dry weight was analysed by the addition of mannitol as an osmolicum. Sucrose acts also as an energy source for hairy roots rather than as an osmotic regulator, since the increase of dry weight was higher than that of fresh weight at the given sucrose concentration.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.626-626
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• 2013

P-N 접합에 의해 절연된 게이트를 통해 전류 통로를 제어하는 접합형 전계효과 트랜지스터(Junction Field Effect Transistors; JFETs)는, 입력 임피던스가 크고, 온도에 덜 민감하며, 제조가 간편하여 집적회로(IC) 제조가 용이하고, 동작의 해석이 단순하다는 장점을 가지고 있다. 특히 JFET는 선형적인 전류의 증폭 특성을 가지고 있으며, 잡음이작기 때문에, 감도가 우수한 음향 센서의 증폭회로, 선형성이 우수한 증폭회로, 입력 계측 증폭 회로 등에 주로 사용되고 있다. 기존에 사용되는 JFET 소자는 구조와 제조 공정에 따라서, 컷 오프 전압($V_{cut-off}$)과 드레인-소스 포화 전류($I_{DSS}$)의 변화가 심하게 발생하여, 소자의 전기적 특성 제어가 어렵고, 소자의 수율이 낮다는 문제점이 있다. 본 연구에서는 TCAD 시뮬레이션을 통해 게이트 전압에 의해 채널이 형성되는 채널 층의 상하부에 각각 $Si_xGe_{1-x}$로 이루어진 상부 및 하부 확산 저지층을 삽입한 JFET 소자 형성하여, 게이트 접합부의 접합 영역 확산을 저지하고, 상기 게이트 접합부가 계면에서 날카로운 농도 구배를 갖도록 함으로써, 공정 변화에 따른 전기적 특성의 편차가 작아지는 JFET 소자 구조를 만들어 전기적 특성을 개선하였다. JFET은 채널층에 삽입된 $Si_xGe_{1-x}$ 층의 두께, Ge 함유량 및 n채널층의 두께를 변화하였을 때, off 상태의 게이트-소스 전압이 감소한 반면에 드레인-소스 포화 전류($I_{DSS}$)와 컨덕턴스(gm) 값이 증가하였다. 삽입된 $Si_xGe_{1-x}$층이 Boron이 밖으로 확산되는 현상이 감소하여 채널이 좁아지는 현상을 막아 소자의 전기적 특성을 개선함으로써 제조공정의 변화에 관계없이 컷오프 전압을 정확하고 안정되게 제어할 수 있고 이를 통해 소자의 수율을 높일 수 있을 것으로 기대된다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.36 no.3
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• pp.279-284
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• 2008

Propellant pressurization system in liquid rocket propulsion system plays a role in supplying pressurant gas at a controlled pressure into the ullage space of propellant tanks. The most important design parameter for such propellant pressurization system is the temperature of pressurant gas fed from pressurant tank, which is placed inside of cryogenic propellant tank. Such pressurant is gaseous state, of which density is very sensitive to the temperature of pressurant. Previous investigation dealt with thermal correlation of pressurant and external fluid at room temperature. This study investigates the temperature variation of cryogenic pressurant (GHe) at the time when the pressurant is coming out of pressurant tank, which is submerged in a liquid oxygen, experimentally as well as numerically.

• Tunnel and Underground Space
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• v.8 no.3
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• pp.184-193
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• 1998

In order to dispose radioactive wastes safely, it is needed to understand the mechanical, thermal, fluid behavior of rockmass and physico-chemical interactions between rockmass and water. Also, the knowledge about mechanical and hydraulic properties of rocks is required to predict and to model many conditions of geological structure, underground in-situ stress, folding, hot water interaction, intrusion of magma, plate tectonics etc. This study is based on researches about rock mechanics issues associated with a waste disposal in deep rockmass. This paper includes the mechanical and hydraulic behavior of rocks in varying temperature conditions, thermo-hydro-mechanical coupling analysis in rock mass and deformation behavior of discontinuous rocks. The mechanical properties were measured with Interaken rock mechanics testing systems and hydraulic properties were measured with transient pulse permeability measuring systems. In all results, rock properties were sensitive to temperature variation.