• Title/Summary/Keyword: 상자성 큐리 온도

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Magnetic Susceptibility of the Single Crystal MnF2(1.5% EuF3) (단결정 MnF2(1.5% EuF3)의 자기 감수율)

  • Lee, Jun-Young;Nahm, Kyun;Kim, Chul-Koo
    • Journal of the Korean Magnetics Society
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    • v.16 no.5
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    • pp.261-263
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    • 2006
  • In order to investigate the magnetic properties of Eu ions in the single crystal $MnF_2$, the temperature dependent magnetic susceptibilities of the antiferromagnetic $MnF_2$ and the single crystal $MnF_2$(1.5% $EuF_3$) with the rutile structures were measured in the temperature range from 4K to 300K. The detailed analysis of the measured susceptibilities showed that the magnetic susceptibility by the doping of the small amount $EuF_3$ in the antiferromagnetic single crystal $MnF_2$ follows the antiferromagnetic Curie-Weiss law with the negative paramagnetic Curie temperature similarly as in $MnF_2$. It was also found that Eu ion has +3 valence. This solves the long standing discrepancy on this problem.

A Study on the Conducting Behavior of La-Ca-Mn-O in the vicinity of Phase Transition Temperature (임계점 부근에서 LCMO의 전도 특성에 대하여)

  • 송하정;김우진;권순주
    • Journal of the Korean Magnetics Society
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    • v.8 no.4
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    • pp.179-184
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    • 1998
  • Colossal magnetoresistance is closely related to (but is not) the abrupt change of electrical resistivity in the vicinity of Curie temperature, which is caused by the temperature dependent paramagnetic-ferromagnetic phase transition and concurrent change of electrical conducting mechanism. A resistivity-temperature equation is presented to fully describe the overall behavior, especially the abrupt change. The main ingredients of the equation are a simple effective media theory and a function for the temperature dependent fraction of ferromagnetic phase. The model fits very well to the measured resistivity-temperature curve of $La_{0.7}Ca_{0.3}MnO_3$.

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Temperature Dependence of Magnetic Properties of YIG films Grown by Solid Phase Epitaxy (고상에피택시 YIG 박막의 온도에 따른 자기특성)

  • Jang, Pyug-Woo;Kim, Jong-Ryul
    • Journal of the Korean Magnetics Society
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    • v.15 no.1
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    • pp.25-29
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    • 2005
  • Magnetic properties of YIG films grown by solid phase epitaxy (SPE) was measured as a function of temperature with focus on magneto-crystalline and perpendicular magnetic anisotropy. Perpendicular magnetic anisotropy was not induced in the SPE YIG films annealed at low temperature by relaxing residual stress through formation of dislocation. On the contrary the films annealed at high temperature showed perpendicular magnetic anisotropy which shows very low density of dislocation. Perpendicular magnetic anisotropy field decreased linearly up to a high temperature of $230^{\circ}C$ above which magneto-crystalline anisotropy disappeared. Coercivity also decreased linearly with temperature up 세 $230^{\circ}C$. Magneto-crystalline anisotropy of perpendicular anisotropy induced epitaxial (111) YIG films can be measured using $H_k=4K_1/3M_s$. Temperature behavior of initial susceptibility can be successfully explained by Hopkinson effects. Curie temperature of YIG films grown on GGG substrate with high paramagnetic susceptibility can be easily measured using the results.

Studies on Crystallographic and Magnetic Properties of the Sn0.9957Fe0.01O2 (Sn0.9957Fe0.01O2의 결정학적 및 자기적 성질에 관한 연구)

  • Li, Yong-Hui;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.20 no.5
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    • pp.187-190
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    • 2010
  • $Sn_{0.99}{^{57}Fe}_{0.01}O_2$ prepared by a sol-gel method, and studied by x-ray diffractometer, vibrating magnetometer, Superconducting quantum interference devices and M$\ddot{o}$ssbauer spectroscopy. the crystal structure were found to be a rutile tetragonal structure with space group $P4_2$/mnm, and oxygen deficiency are 5.6 % by Rietveld refinement. magnetization value were $M_s=1.95{\times}10^{-2}{\mu}_B/Fe$ at room temperature, and Curri-weiss temperature were and ${\theta}_{cw}$ = 18 k, measurement of VSM and SQUID, respectively. Mssbauer spectra of $Sn_{0.99}{^{57}Fe}_{0.01}O_2$ have been Sextet taken at various temperatures ranging from 4.2 K to RT, and isomer shift value $\delta$ = 0.18~0.36 mm/s of $^{57}Fe$ ion site all of the temperature range the state shows ferric.

First Principles Calculations on Electronic Structure and Magnetism of Transition Metal Doped ZnO (전이금속이 도핑된 ZnO의 전자구조와 자성에 대한 제일원리계산)

  • Yun, Sun-Young;Cha, Gi-Beom;Hong, Sun-C.
    • Journal of the Korean Magnetics Society
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    • v.15 no.1
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    • pp.1-6
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    • 2005
  • In this study we investigate the electronic structure and magnetism of transition metal (TM = Ti, Cr, Mn, Fe, Co, Ni, Ru, Pd, Ag ) deped ZnO($TM_{0.25}Zn_{0.75}O$), which are expected to have Curie temperature. Full-potential Linearized Augmented Plane Wave(FLAPW) metod is adopted with exchange-correlation potential expressed as general gradient approximation(GGA). The calculated magnetic moments of ($TM_{0.25}Zn_{0.75}O$) are 0.83, 3.03, 4.03, 3.48, 2.47, 1.56, 0.43, 0.75, 0.01 ${\mu}_B$ for TM = Ti, Cr, Mn, Fe, Co, Ni, Ru, Pd, Ag, respectively. The nearest neighbor O atom to the transition metal is calculated to have a significant magnetic moment of about 0.1${\mu}_B$, ?? 새 strong hybridization between O-p and TM-d bands. As the results, the systems may have larger magnetic moments in total, compared to the corresponding isolated atoms. The 3d TM doped systems exhibit the half-metallic character except Co, wheres the 4d TM doped systems behave like normal metals and low spin polarization at the Fermi levels.