• Clean Technology
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• v.25 no.3
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• pp.198-205
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• 2019

The adsorption equilibrium, kinetic, and thermodynamic parameters of brilliant green adsorbed by coconut based granular activated carbon were determined from various initial concentrations ($300{\sim}500mg\;L^{-1}$), contact time (1 ~ 12 h), and adsorption temperature (303 ~ 323 K) through batch experiments. The equilibrium adsorption data were analyzed by Langmuir, Freundlich, Temkin, Harkins-Jura, and Elovich isotherm models. The estimated Langmuir dimensionless separation factor ($R_L=0.018{\sim}0.040$) and Freundlich constant ($n^{-1}=0.176{\sim}0.206$) show that adsorption of brilliant green by activated carbon is an effective treatment process. Adsorption heat constants ($B=12.43{\sim}17.15J\;mol^{-1}$) estimated by the Temkin equation corresponded to physical adsorption. The isothermal parameter ($A_{HJ}$) by the Harkins-Jura equation showed that the heterogeneous pore distribution increased with increasing temperature. The maximum adsorption capacity by the Elovich equation was found to be much smaller than the experimental value. The adsorption process was best described by the pseudo second order model, and intraparticle diffusion was a rate limiting step in the adsorption process. The intraparticle diffusion rate constant increased because the dye activity increased with increases in the initial concentration. Also, as the initial concentration increased, the influence of the boundary layer also increased. Negative Gibbs free energy ($-10.3{\sim}-11.4kJ\;mol^{-1}$), positive enthalpy change ($18.63kJ\;mol^{-1}$), and activation energy ($26.28kJ\;mol^{-1}$) indicate respectively that the adsorption process is spontaneous, endothermic, and physical adsorption.

• (The)Study of the Eastern Classic
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• no.33
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• pp.7-29
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• 2008

Jang, Hyeon-Guang is one of the representative natural philosophers of Joseon Korea. This article aims to investigate the meaning of the factors of Xiangshuxue(象數學) contained in his cosmology. Xiangshuxue applies Image(Xiang), Numeral(Shu) and In-Yang to present the distinctions, inter-relations and time-series orders of things. Jang's cosmology, combined with Xiangshuxue, insisted that Li(Principle) is infinite in time and space, the cosmos is finite on the other side. This assures that the moral principle is absolute and eternal. Jang emphasized the book I-ching as the criterion and the model in understanding the nature. This restrained the objectivizm of Shaoyong and made his concept 'natural law' difficult to change itself as the experience and the knowledge expand. None the less, his cosmology is appraised in that it strengthened natural philosophical basis of neo-confucianism and preceded the cosmological investigations since mid-Joseon dynasty.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.186.2-186.2
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• 2014

최근 친환경 에너지에 대한 관심이 증폭되면서 리튬이차전지에 대한 연구가 활발히 진행되고 있다. 특히 음극(anode) 물질의 경우 기존의 흑연(graphite)보다 이론적 용량이 약 10배 이상 높은 실리콘(Silicon)에 대한 관심이 매우 높다. 하지만 Si의 경우 리튬 충전거동 시 400% 이상의 부피팽창으로 몇 번의 충전/방전 싸이클(cycle)에 전극이 파괴되는 문제점을 지니고 있다. 이를 극복하기 위해 Si 나노선이 고려되고 있다. 우수한 전극특성을 갖는 Si 소재를 개발하기 위해서는 원자단위에서 Si 나노선의 리튬 충전 메커니즘을 살펴보는 것이 매우 중요하다. 하지만 기존의 시뮬레이션 기법으로는 Si 나노선의 볼륨팽창에 관한 메커니즘과 리튬 충전과정에서의 상변화(결정질에서 비정질) 과정을 설명하기는 기술적으로 매우 힘들다. 고전적인 분자동역학 방법의 경우 실제 나노스케일을 고려할 수 있지만, empirical potential로는 원자들간의 화학반응을 제대로 묘사할 수 없다. 한편 양자역학에 기반을 둔 제일원리방법의 경우 계산의 복잡성으로 현재의 컴퓨터 환경에서는 나노스케일에서 원자들의 동역학적인 거동을 연구하기 매우 힘들다. 우리는 이러한 문제를 해결하기 위해 실제 나노스케일에서 원자간 화학반응을 예측할 수 있는 Si-Li 시스템의 Reactive force field를 개발하였고, 분자동역학 계산방법을 이용하여 Si 나노선의 Li 충전 메커니즘을 규명하였다.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.11a
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• pp.68-75
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• 2008

화재시뮬레이션용 소프트웨어인 FDS (Fire Dynamics Simulator)의 수직벽 화재 시뮬레이션에 있어서의 문제점을 파악하기 위해, 수직벽 프로필렌 화재에 대한 시뮬레이션을 수행하였다. 성능기반설계 등에 널리 사용되고 있는 이 전산유체역학 모델에 포함되어있는 주요 매개변수의 기본값을 사용한 경우, 수직벽 화재에서는 정확도가 매우 낮음을 확인하였다. 프로필렌 연소율 $10.08g/m^2$-s과 $29.29g/m^2$-s에 대한 주요 매개변수의 조사를 수행한 결과, 스마고린스키 상수(Smagorinsky constant)가 기본값인 0.2에서 수직벽에 형성된 경계층이 층류로 예측되었다. 스마고린스키 상수가 0.1일 때 온도분포가 실험과 비교적 잘 일치하였으나 벽면에서의 열유속에는 큰 오차가 있음을 확인하였다.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.134-134
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• 2011

3차원 난류 부력젵의 혼합을 큰 와 모의(large-eddy simulation) 기법을 이용하여 수치모의 한다. 개발된 수치모형은 3차원 열동수역학 모형을 이용하여 부력젵의 퍼짐, 자기 보존 그리고 주변류의 연행 등을 포함하는 난류젵의 동적 특성을 분석할 수 있다. 수치해석에서 하부격자규모 (subgrid scale, SGS) 난류 응력은 부력항을 수정한 Smagorinsky 모형을 이용한다. 여과된 엔탈피 수송방정식에서 하부격자규모의 스칼라 플럭스는 상수의 SGS Prandtl 수를 가지는 단순 경사수송 가설에 근거하여 모의한다. 계산된 결과를 실험결과와 비교하며, 결과는 양호하게 일치함을 보여준다. 계산결과에 따르면 부력항의 수정이나 SGS 난류 Prandtl 수는 결과에 큰 영향을 미치지 않지만 SGS 모형 상수인 Cs 값은 부력젵 확산 예측에 중요한 영향을 미치는 것으로 나타났다.

• Journal of the Mineralogical Society of Korea
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• v.29 no.4
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• pp.209-220
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• 2016

Clay minerals are a major player to determine geochemical cycles of trace metals and carbon in the critical zone which covers the atmosphere down to groundwater aquifers. Molecular dynamics (MD) simulations can examine the Earth materials at an atomic level and, therefore, provide detailed fundamental-level insights related to physicochemical properties of clay minerals. In the current study, we have applied classical MD simulations with clayFF force field to dioctahedral clay minerals (i.e., gibbsite, kaolinite, and pyrophyllite) to analyze and compare structural parameters (lattice parameter, atomic pair distance) with experiments. We further calculated vibrational power spectra for the hydroxyls of the minerals by using the MD simulations results. The MD simulations predicted lattice parameters and interatomic distances respectively deviated less than 0.1~3.7% and 5% from the experimental results. The stretching vibrational wavenumber of the hydroxyl groups were calculated $200-300cm^{-1}$ higher than experiment. However, the trends in the frequencies among different surface hydroxyl groups of each mineral was consistent with experimental results. The angle formed by the surface hydroxyl group with the (001) plane and hydrogen bond distances of the surface hydroxyls were consistent with experimental result trends. The inner hydroxyls, however, showed results somewhat deviated from reported data in the literature. These results indicate that molecular dynamics simulations with clayFF can be a useful method in elucidating the roles of surface hydroxyl groups in the adsorption of metal ions to clay minerals.

• The Journal of Engineering Geology
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• v.15 no.3
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• pp.337-348
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• 2005

Jurassic granite from Pocheon area were tested to investigate the effect of microcracks on mechanical properties of the granite. Three oriented core specimens were used for uniaxial compressive tests and each core specimen are perpendicular to the axes'R'(rift plane),'c'(grain plane) and'H'(hardway plane), respectively Among vacious elastic constants, the variation of Poisson's ratio as function of the directions was examined. From the related chart between ratio of failure strength and Poisson's ratio, H-specimen shows the highest range in Poisson's ratio and Poisson's ratio decreases in the order of C-specimen and R-specimen. The curve pattern is nearly linear in stage $I\simIII$ but the slope increases abruptly in stage H-3. As shown in the related chart, diverging point of a curve is formed when ratio of failure strength is $0.92\sim0.96$ Stage IV -3 is out of elastic region. The behaviour of rock in the four fracturing stages was analyzed in term of the stress-volumetric strain me. From the stress increment-volumetric strain equations governing the behaviour of rock, characteristic material constants, a, n, Q, m and $\varepsilon_v^{mcf}$, were determined. Among these, inherent microcrack porosity$(a, 10^{-3})$ and compaction exponent(n) in the microcrack closure region(stage I ) show an order of $a^R(3.82)>a^G(3.38)>a^H(2.32)\;and\;n^R(3.69)>n^G(2.79)>n^H(1.99)4, respectively. Especially, critical volumetric microcrack strain($\varepsilon_v^{mcf}$) in the stage W is highest in the H-specimen, normal to the hardway plane. These results indicate a strong correlation between two major sets of microcracks and mechanical properties such as Poisson's ratio and material constants. Correlation of strength anisotropy with microcrack orientation can have important application in rock fracture studies.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.600-604
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• 2001

The relation between the aerodynamic diameter and some morphological parameters was studied for flame-generated aggregates. $SiO_{2}$ aggregates were generated from $SiCl_{4}$ in premixed methane/air flames. These aggregates were sampled and classified according to their aerodynamic diameter by a cascade impactor; moreover, computer program was developed and tested to find the equivalent area diameter and the fractal dimension of the aggregates. We calculated the parameters from the digitized images of the aggregate TEM micrographs. The aerodynamic diameters of the sampled aggregates were larger than $0.4{\mu}m$ in this experiment. In most cases, fractal dimension of their projection image was very close to 2.0 for these large aggregates. It was found that the equivalent area diameter of these aggregates was approximately three times larger than the Stokes' diameter of them.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.5 no.1
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• pp.52-59
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• 2012

The bone material is a composite material consisted of collagen and mineral crystals. Also it shows transversely isotropic symmetry. So far none has shown that the components of the elasticity tensor satisfy the Voigt and Reuss bounds. To determine the effective elastic constant of bone material, the Voigt and Reuss bounds are employed and we show that the components of the elasticity tensor satisfy the Voigt and Reuss bounds. Mathematically this bounds are satisfied on two conditions only out of four conditions.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1997.11a
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• pp.5-5
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• 1997

고체추진제에 대한 비선형 점탄성 구성모델이 제시되었다 추진제 손상의 원인으로서 바인더와 AP 충전제사이의 접착분리를 고려하였으며, 점탄성 드웨팅판별식이 개발되었다. 손상에 의한 추진제의 연화는 모듈러스 저하로서 취급되었으며, 모듈러스저하 계산시에 드웨팅에 의하여 야기된 미소진공구의 모듈러스는 유한 상수로서 간주되었다. 바인더와 AP 충전제사이의 접착에너지는 180$^{\circ}$ 접착박리시험으로 측정하였다. 반복하중시의 비선형성은 전단변형률 불변량의 함수로서 고려되었다. 이 구성모델은 여러 하중조건에 대한 시편실험과 비교되어 잘 일치하였으며, 복잡한 미시구조학적 역학기구 없이 간단하게 고체 추진제의 거동을 예측할 수 있게 한다.