• Title/Summary/Keyword: 삼계면

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An Interface Reactions between Sintered Mn-Zn Ferrite and $SiO_2$-PbO-ZnO Bonding Glass (Mn-Zn 페라이트 소결체와 $SiO_2$-PbO-ZnO 삼성분계 봉착유리와의 계면반응)

  • 이대희;박명식;김정주;이병교;조상희
    • Journal of the Korean Ceramic Society
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    • v.37 no.12
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    • pp.1204-1211
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    • 2000
  • Mn-Zn 페라이트 소결체와 SiO$_2$-PbO-ZnO 삼성분계 유리와의 계면반응에서 페라이트와 유리에 각각 첨가된 ZnO가 계면반응에 미치는 영향을 조사하였다. SiO$_2$-PbO-ZnO 삼성분계 유리에 첨가된 ZnO 함량이 낮은 경우 페라이트와의 접합계면에서 생성되는 중간상은 Pb$_2$(Mn,Fe)$_2$Si$_2$O$_{9}$와 Pb$_{8}$(Mn,Fe)Si$_{6}$O$_{21}$의 고용체였으며, ZnO 농도가 증가함에 따라 중간상은 사라졌다. 유리속의 ZnO 성분이 증가함에 따라 페라이트 소결체 쪽의 계면부근에 Zn의 농도가 증가하는 특이한 분포가 나타났다. 이는 유리 속에 첨가된 Zn 이온의 높은 활동도로 인해 페라이트에 포함된 Zn 이온의 용해반응이 선택적으로 억제되어 나타난 것으로 생각된다. 페라이트에 첨가된 ZnO 함량이 낮은 경우 SiO$_2$-PbO 이성분계 유리와의 접합계면에서 페라이트의 용해에 따른 침식과 입계를 통한 유리의 침투가 심하게 일어났으며, ZnO 함량이 증가함에 따라 계면을 통한 상호확산과 반응이 억제되었다.

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Evolution of Phase Morphology During Compounding of Ternary Blends in a Twin Screw Extruder (이축 압출기를 이용한 혼련에서 삼성분계 블렌드의 상구조 형성과정)

  • Kim, Hyungsu;Lee, Shi-Choon;D .Y. Yu;C. G. Gogos
    • The Korean Journal of Rheology
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    • v.10 no.4
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    • pp.247-255
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    • 1998
  • The morphological changes during melt compounding of ternary blends containing various combinations of acrylonitrile-butadiene-styrene(ABS), methyl methacrylate-butadiene-ethyl acrylate(MBE), styrene-acrylonitrile(SAM) copolymers, and poly(methyl methacrylate)(PMMA) as dispersed components in a fixed matrix of polycarbonate(PC) have been investigated. Depending on the composition of the blend, MBE particles and PMMA phase appear to locate at the PC-SAN interface under the influence of interfacial tensions and motion induced coalescence. The interfacial viscosity is found to be a critical factor that affects the amount of coalescence.

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Phase Behavior of Sorbitan Monopalmitate Surfactant in Supercritical Carbon Dioxide (초임계 이산화탄소에서 소르비탄 모노팔미테이트 계면활성제의 상거동에 관한 연구)

  • Oh, Kyung Hwan;Kim, Eun Jin;Shin, Hun Yong
    • Clean Technology
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    • v.19 no.1
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    • pp.8-12
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    • 2013
  • Phase behavior of carbon dioxide + surfactant binary system and carbon dioxide + surfactant + water ternary system was investigated at the temperatures from 318 K to 348 K by using high pressure vapor liquid equilibrium apparatus containing variable-volume view cell. Sorbitan monopalmitate was used as the surfactant. The cloud point pressures for the binary mixture of carbon dioxide + sorbitan monopalmitate increased with an increasing of system temperatures and the maximum cloud point pressure was observed at the composition of 0.226 wt% of sorbitan monopalmitate. On the other hand, as the temperatures and compositions of water increased, the cloud point pressures for ternary system containing 0.1 wt% of sorbitan monopalmitate increased significantly. For the ternary system of constant 0.2 wt% of water, the cloud point pressure curves show relatively flat according to the change of compositions of surfactant. The cloud point pressures increased when the temperatures and compositions of water increased.

A Study on the Architectural and Spatial Characteristics of the Eoeun Village Samgye-myeon Imsil-gun, Jeonbuk (전북 임실군 삼계면 어은마을의 건축-공간적 특성 고찰)

  • Heo, Jeong-Joo;Oh, Su-Min
    • Journal of the Korean Institute of Rural Architecture
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    • v.25 no.2
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    • pp.35-42
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    • 2023
  • This study investigated and analyzed the village space and architectural characteristics of Eoeun Village, Samgye-myeon, Imsil-gun, Jeonbuk. The space of the village was formed based on the idea of feng shui, and the Confucian hierarchical idea determined the location, size, and structure of the building. Recently, clan villages in rural areas have been dismantled and damaged due to population outflow and urbanization. In this situation, Eoeun Village, which preserves the traditional space and residential form at the time of the village's creation, is considered to be worth preserving and studying.

Effect of Surfactant Concentration and pH on Surfactant-Enhanced Remediation in lowa Soil Contaminated by TCB (삼염화벤젠으로 오염된 아이오와토양의 복원시 계면활성제의 농도와 pH의 영향)

  • Dal-Heui Lee;Robert D. Cody
    • Economic and Environmental Geology
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    • v.35 no.2
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    • pp.149-154
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    • 2002
  • Column tests were carried out to examine the effect of surfactant solution conditions on surfactant-enhanced remediation of contaminated soil. The selected conditions of the surfactant solution were concentration and pH. 1,2,4-trichlo-robenzene (TCB) was chosen as the model hydrophobic organic substances. Sodium diphenyl oxide disulfonate (DOSL) and octylphenoxypoly ethoxyethanol (OPEE) surfactants were selected for this study. Two Iowa soils, Fruitfield sand and Webster clay loam, were leached with surfactant solution. The test results revealed that an optimum condition was achieved for 4 %(v/v) of concentration and 10 of pH, respectively. The maximum recoveries of added TCB (93-98%) were obtained when optimal conditions of each surfactant solution parameter were simultaneously met. The optimum conditions of these parameters may be useful for surfactant-assisted remediation in soil contaminated by TCB.

The Roles of Ingredients in Fade Resistance of Brake Friction Materials (자동차용 마찰재 원료가 열화 저항성에 미치는 영향)

  • Jang, Ho;Cho, Keun-Hyung;Han, Jae-Min;Park, Sung-Bin;Shin, Min-Wook
    • Tribology and Lubricants
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    • v.25 no.1
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    • pp.31-37
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    • 2009
  • 상용화 마찰재를 사용하여 고온 열화에 대한 원료들의 영향을 연구하였다. 제한된 영역에서의 실험계획법에 의해 25개의 마찰재가 제작되었으며, 축소 마찰 시험기로 마찰, 마모특성을 조사하였다. 아라미드 섬유, 흑연, 구리섬유는 열화에 대한 저항성을 향상시켰으며, 반면 삼황화 안티몬, 지르콘은 열화현상을 가속시키는 것으로 나타났다. 이러한 결과는 각 원료들이 계면에 미치는 영향이 각기 다르기 때문으로 사료된다. 아라미드 섬유, 흑연, 구리섬유등은 계면을 안정화 시켰으며, 삼황화 안티몬, 지르콘등은 고온에서 불안정한 계면을 형성시키는 것으로 나타났다.

Effects of Tri-functional Monomers on the Properties of UV-curable Pressure Sensitive Adhesives (PSAs) (삼관능 모노머의 종류 및 함량에 따른 자외선 경화형 감압 점착 필름의 특성)

  • Won, Jong-Woo;Kim, Ju-Yeol;Jang, Ki-Deog;Park, Myung-Chul;Chun, Jae Hwan;Kwon, Oh Hyeong;Hwang, Jin-Sang
    • Journal of Adhesion and Interface
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    • v.20 no.1
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    • pp.15-22
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    • 2019
  • In this study, polybutadiene based di-functional urethane acrylate oligomer (PB-UAO) were synthesized from polybutadiene diol and isophorone diisocyanate. And then, pressure sensitive adhesive films were prepared by mixing with synthesized oligomer, tri-functional acrylate monomer (Tris(2-acryloyloxyethyl) isocyanurate (TAOEIC) or Trimethylolpropane triacrylate (TMPTA) or Pentaerythritol triacrylate (PETA)), mono-functional acrylate monomer (Stearyl acrylate) and UV initiators. Effects of types and contents of trifunctional acrylate monomers on peel strength, tensile strength, elongation, thermal stability and water absorption property were studied. As the contents of tri-functional acrylate monomer increased, and as the molecular weight of tri-functional acrylate monomer decreased, peel strength, elongation and water absorption showed a tendency to decrease whereas tensile strength and thermal stability showed a tendency to increase.

Spectrophotometric Determination of Rare Earths by Ternary Complex Formation with MTB and Surfactant (글로방전 발광분광법에 의한 란탄족 원소의 정밀 분석. MTB와 계면활성제의 삼성분 착물 형성에 의한 희토류 원소의 분광광도법 정량에 관한 연구)

  • Cha Ki-Won;Yun Jeong-Sook;Kim Kyung-Hwan;Ha Young-Gu;Kim Ha-Suek
    • Journal of the Korean Chemical Society
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    • v.37 no.5
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    • pp.496-502
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    • 1993
  • Spectrophotometric determination of rare earth elements with MTB and the composition ratio were investigated in the presence of surfactants of cetylpyridinium chloride (CPC), Triton X-100, dodecyltrimethylammonium bromide (DTMAB) and cetyltrimethylammonium bromide (CTMAB) at pH 6.5. The colour development between MTB and rare earths in the presence of cationic surfactants was very stable and more sensitive than that in the absence of surfactants. The largest absorbance increase was provided by CPC, which was therefore chosen for determination of rare earth elements. REE-MTB-CPC complex has absorption maxima at 650 nm and obeys the Beer's law in the range of 0∼100 ng/ml. Molar absorptivity is $6.6{\sim}9.4{\times}10^4\;mol^{-1}l\;cm^{-1}$.

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Study on the Spectrophotometric Determination of Rare Earth by Ternary Complex Using Xylenol Orange and Surfactant (Xylenol Orange와 계면활성제의 삼성분 착물에 의한 희토류원소의 분광광도법 정량에 관한 연구)

  • Cha, Ki-Won;Park, Chan-Il;Kang, Sun-Hee;Chang, Byung-Du
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.277-284
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    • 1994
  • The spectrophotometric determination of rare earth elements with XO was investigated in the presence of cetylpyridium chloride(CPC), dodecyltrimethylammonium bromide(DTMAB), cetyltrimetylammonium bromide (CTMAB), Triton X-100 at pH 6.2. The complex between XO and rare earth elements in the presence of cationic surfactants was very stable and more sensitive than in the absence of surfactants. The largest absorbance increase was provided by CTMAB, which was therefore chosen for determination of rare earth elements. REE-XO-CTMAB complex has absorption maxima at 618nm and obeys the Beer's law in the range of 0~0.5 ppm. Molar absorptivity was $1.5{\times}10^5mol^{-1}cm^{-1}l$.

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