• Title/Summary/Keyword: 산화마그네슘(MgO)

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Effect of $TiO_2$ Addition on the Secondary Electron Emission and Discharge Properties of MgO Protective Layer (산화마그네슘 보호막의 이차전자방출과 방전특성에 미치는 산화티타늄첨가의 효과)

  • Kim, Young-Hyun;Kim, Rak-Hwan;Kim, Hee-Jae;Park, Jong-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04a
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    • pp.148-151
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    • 2000
  • $Mg_{2-2x}Ti_xO_2$ films were prepared by e-beam evaporation method to be used as possible substitutes for the conventional MgO protective layer. The oxygen content in the films and in turn, the ratio of metal to oxygen gradually increased with increasing the $TiO_2$ content in the starting materials. The pure MgO films exhibited the crystallinity with strong (111) orientation. The $Mg_{2-2x}Ti_xO_2$ films, however, had the crystallinity with (311) preferred orientation. When the $[TiO_2/(MgO+TiO_2)]$ ratios of 0.1 and 0.15 were used, the deposited films exhibited the secondary electron emission yields improved by 50% compared to that of the conventional MgO protective layer, which resulted in reduction in discharge voltage by 12%.

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Haze Characteristics of Mica Coated with Magnesium Oxide (산화마그네슘을 코팅한 마이카의 헤이즈 특성)

  • Kang, Kuk-Hyoun;Hyun, Mi-Ho;Lee, Dong-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.1
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    • pp.888-894
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    • 2015
  • Inorganic composite particles have excellent physical and chemical characteristics and have been applied in various industries. Recently, many studies have examined the optical properties, such as light scattering, refraction, transmission characteristics, by coating organic-inorganic materials on a substrate, such as mica. Mica is widely applied as a pigment, plastics, painted products, and ceramics because of its high chemical stability, durability and non-toxicity. Magnesium oxide has a range of properties, such as high light transmittance, corrosion resistance and non-toxicity, and it is used as an optical material and polymer additives. To use the optical properties of mica and magnesium oxide, mica was coated with magnesium hydroxide by a dissolution and recrystallization process. In this study, the optimal conditions for the haze value of the particles were found by adjusting the amount of precursors and pH. Magnesium hydroxide layers were formed on the surfaces of mica and converted to MgO after calcination at $400^{\circ}C$ for 4 h. The results showed that the value of MgO-coated mica haze can be controlled easily by the amount of the magnesium hydroxide and pH. The optical properties of the inorganic composite powder were analyzed using a hazemeter and the highest haze value was 85.92 % at pH 9. The physicochemical properties of the synthesized composite was analyzed by SEM, XRD, EDS, and PSA.

Effect of Magnesium Oxide on Physical and Chemical Properties of FKM Elastomer (FKM Elastomer의 물리적 및 화학적 성질에 미치는 산화마그네슘의 영향)

  • Lee, Chang-Seop;Choi, Gi-Tae;Choi, Han-Hwal
    • Elastomers and Composites
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    • v.38 no.1
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    • pp.57-64
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    • 2003
  • Metal oxide(MgO) was added to FKM rubber in order to develop automotive fuel hose which ran show elastic characteristics under extreme condition. Cure characteristics, physical properties, thermal resistance and fuel resistance of FKM compounded rubber with MgO were investigated. MgO was mixed to FKM rubber materials within the range of $0{\sim}20phr$. From the test results of rheological properties and Mooney viscosity, the $t_{s2}$, $T_{c90}$ values increased as the MgO contents increased in FKM rubber compounding. Hardness and 100% modulus of FKM compounded rubber slightly increased, but tensile strength and elongations at break slightly decreased. From the test results of thermal resistance of rubber specimens at 130, 150, and $170^{\circ}C$ for 70 hrs, the changing rate of physical properties was found to be relatively small. Fuel resistance tests were carried out for fuel A, B, C and D at $40^{\circ}C$ for 70hrs, and the results showed that the changing rate in physical properties was found to increase from Fuel A to D, Furthermore thermal properties of FKM compounded rubber containing MgO were also investigated by using TGA/DSC. The optimum mixing ratio of additive to FKM rubber to get the maximum effect on thermal resistance and fuel resistance, within the range of desirable specification for rubber material, was determined to be 6 phr for MgO.

Discharge Properties of $Al_2O_3$/MgO as a Dielectric Protection Layer ($Al_2O_3$/MgO 유전체 보호막의 방전특성)

  • Jeoung, Jin-Man;Shin, Kyung;Lee, Young-Jong;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.307-310
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    • 1998
  • In this paper, $Al_2$O$_3$/MgO belayer was prepared with Electron-beam evaporation and the properties of the film was investigated in order to improve the property of MgO film, which is used for the protection layer in PDP(Plasma Display Panel). $Al_2$O$_3$/MgO belayer were improved of roughness and it were condensed by annealing, and the result of XPS analysis for $Al_2$O$_3$/MgO belayer unchanged binding energy. To investigate electric characteristics, discharge properties of $Al_2$O$_3$/MgO belayer were compared with discharge minimum voltage for MgO monolayer through Ar discharge experiments.

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A Study on the Mirror-like machining of MgO Single Crystal with Optimum In-process Electrolytic Dressing System (최적 전해드레싱을 적용한 단결정 산화마그네슘(MgO)의 경면가공에 관한 연구)

  • 김정두
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1995.10a
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    • pp.76-81
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    • 1995
  • MgO single crystal is widely used as a the material of high temperature resistance, but is difficult to grind because of brittleness and crack generation. Therefore, superabrasive diamond wheel is required for mirror like grinding of this material. This study describes a newly proposed optimum in-process electrolytic dressing system for carrying out effective dressing of superbrasive diamond wheel. Using this system the grinding surface of MgO single crystal was improved, the grinding force was very l9ow and crack was removed. In conclusion, this system is good to obtain the efficient grinding and mirror-like grinding without crack of MgO single crystal.

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Acidic Properties of Mg-Al Mixed Oxides in the Dehydration of iso-Propanol (이소프로판올의 탈수반응에 있어서 Mg-Al 혼합 산화물의 산점 특성)

  • Youn, Hyunki;Ahn, Ji-Hye;Park, Jung-Hyun;Shin, Chae-Ho
    • Clean Technology
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    • v.20 no.3
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    • pp.330-336
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    • 2014
  • Mg-Al mixed oxides with molar ratio of Mg/Al = 1-3 were prepared by co-precipitation and characterized by using X-ray diffraction, scanning electron microscopy, BET surface area and pore volume measured by $N_2$ sorption analysis, and temperature programmed desorption of iso-propanol. As Al content in Mg-Al mixed oxide increased, the acidity and BET surface area proportionally increased. This increase of acidity directly influenced the catalytic activity of iso-propanol conversion and selectivity to propylene.

Effect of Na2SiO3 concentration on the formation of plasma electrolytic oxidation films on AZ31 Mg alloy in CO32- containing aqueous solution. (탄산 이온이 포함된 수용액에서 AZ31 마그네슘 합금의 플라즈마전해산화 피막 형성에 미치는 규산나트륨 농도의 영향)

  • Kim, Ye-Jin;Mun, Seong-Mo;Sin, Heon-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.193.2-193.2
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    • 2016
  • 본 연구에서는 탄산이온이 포함된 수용액에서 규산나트륨의 농도가 AZ31 마그네슘 합금의 플라즈마전해산화 피막형성에 미치는 영향에 대해 알아보았다. 다양한 농도의 규산나트륨 용액에서 DC와 펄스전류를 인가하여 플라즈마전해산화피막을 형성하였으며, 형성된 피막의 surface roughness와 thickness를 분석하였다. 탄산 이온이 포함된 수용액에서 플라즈마전해산화 피막의 형성전압은 규산나트륨의 농도가 높아질수록 높아지는 것으로 나타났다. 하지만 탄산이온이 존재하지 않은 규산나트륨 용액에서의 플라즈마전해산화 피막 형성전압보다 더 낮은 값을 나타내었다. 탄산 이온이 포함된 수용액에서 규산나트륨의 농도가 높아질수록 플라즈마전해산화 피막의 surface roughness와 thickness는 증가하였으며, DC와 펄스전류 모두에서 더 밝은 색상의 균일한 산화피막을 형성할 수 있었다.

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Physical and Mechanical Properties of Magnesium Oxide Matrix depending on Addition Ratio of Magnesium Chloride (염화마그네슘 첨가율에 따른 산화마그네슘 경화체의 물리 및 역학적 특성)

  • Kim, Heon-Tae;Jung, Byeong-Yeol;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.4
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    • pp.308-313
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    • 2014
  • Recently, for longevity of resident building, the main trend is that the change of the inside space organization of resident building from wall construction to rhamen construction, which resulted in increase in use of lightweight composite panel. Thus, in this study, authors analyzed the engineering property of oxide of magnesium depending on the magnesium chloride addition ratio. The results of this research is expected to contribute on providing a fundamental material for the surface materials of lightweight composite panel. As the result of the experiment, as fluidity increased, air content decreased and initial set and final set as the magnesium chloride addition ratio increase. In the aspect of flexural strength and compressive strength, the test specimen showed the highest strength at 40% of the magnesium chloride addition ratio. At 20% of the magnesium chloride addition ratio, the test specimen showed the lowest water absorption rate. As the magnesium chloride addition ratio increases, the expansibility tends to increase as well in the aspect of shrinkage strain. After observing microstructure, we can see hydration products in the form of needle. It appeared high flexural strength because the hydration products have mineral fibrous tissue shape, which also contribute to the cause of the expansibility.

A Study on the Thermal Characteristics of a $MgO/H_2O$ Chemical Heat Pump ($MgO/H_2O$ 계 화학식 열펌프의 열적 특성에 관한 연구)

  • ;;;;Yukitaka Kato
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.1
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    • pp.34-41
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    • 2004
  • The chemical heat pump based on the Dehydration/Hydration process with a MgO/$H_2O$ system has been researched. The reactor bed could be expected to store the heat around 200∼37$0^{\circ}C$ by the dehydration reaction and to release the heat around 100∼16$0^{\circ}C$ by the hydration reaction under the heat amplification mode operation. The heat output rate of the heat pump system was evaluated using the experimentally determined parameters. The results show that 6∼50 W/kg of heat output and 0.5∼0.8 of heat recovery ratio are attainable. The heat pump will be applicable for a load leveling in a co-generation system by chemical storage of surplus heat at low heat demand and by supplying heat in the peak load period.

Deposition of MgO Thin Films by Electrostatic Spray Pyrolysis(ESP) method and Application to AC-PDP (정전기 분무 열분해법에 의한 MgO 박막 증착과 AC-PDP로의 용용에 대한 연구)

  • Kim, Soo-Gil;Eun, Jae-Hwan;Kim, Hyeong-Joon;Kim, Young-Kee;Park, Chung-Hoo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04a
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    • pp.133-138
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    • 2000
  • MgO thin films were deposited using $Mg(tmhd)_2$ as a precursor dissolved in a solvent by electrostatic spray pyrolysis. When a pure tetra hydro furan was used as a solvent, a large number of particles appeared on the MgO thin film surface due to homogeneous nucleation. However, by adding 1-butyl alcohol or 1-octyl alcohol to THF, homogeneous nucleation was restricted and the number density of the large particles was also drastically reduced. X-ray diffraction analysis showed that the MgO films had a (100) preferred orientation regardless of the type of solvents used. Characterization using Fourier Transformed-Infrared and spectroscopic photometer revealed that the crystallized MgO thin films on the glass substrate had a high optical transmittance (> 85 %) in the visible range. Discharge characteristics of MgO thin films deposited by ESP method on an alternating-current plasma display panel were compared with a MgO thin film prepared by reactive radio-frequency planar magnetron sputtering.

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