• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2003.09a
• /
• pp.346-349
• /
• 2003

광산 및 폐광산으로부터의 오염 및 유해영향에 대한 보고와 관심이 대두되면서 휴ㆍ폐광산에 대한 연구가 활발히 진행되고 있다. 본 연구는 경북 군위군의 고로 폐광산 주변 중 광미 및 광폐석으로 오염된 것으로 생각되어지는 하천 및 농경지에 대한 오염 정도와 분포를 규명하기 위하여 토양정밀조사를 실시하였다. 토양 오염 정밀조사 지침에 따라 총 741개의 토양 시료 분석 결과 Cu, Cd, Pb은 토양오염 우려 기준에 훨씬 미치지 못하였지만 As는 표토 및 심토 구간(0-30cm)에서 토양 오염 우려 기준 농도를 상당 수 초과하여 하천 및 농경지의 복원이 필수적임을 알 수 있었다. 합리적인 복원물량을 산출하기 위하여 배경치 농도(1.23mg/kg), 토양오염우려기준 40%농도(2.4mg/kg), 토양오염우려기준농도(6mg/kg), 토양오염대책기준농도(15mg/kg)별로 오염 등급을 나누어 오염 지도를 작성하고 각 등급별 복원목표에 따라 복원이 필요한 면적과 복원대상물량을 산출하였다. 본 연구는 오염토양의 복원을 목적으로 국내에서 최초로 실시된 대규모의 토양정밀조사라는 점에서 의미가 있으며, 이 결과는 실제 고로 폐광산지역의 복원 사업설계에 중요한 자료로 사용될 수 있다.

• Proceedings of the KSEEG Conference
• /
• 2003.04a
• /
• pp.69-71
• /
• 2003

토양 및 수질 유기물질과 금속 산화물사이의 상호 반응관계는 환경지구화학적으로 중요하게 다루어진다 (Sposito, 1984). 토양내 광물들의 표면은 토양 유기물질의 주요한 부분을 차지하는 휴믹물질, 즉 휴믹산과 펄빅산에 의해서 이온강도와 산도에 따라 피복하는 현상을 일으킨다. 특히, 휴믹산과 펄빅산은 토양 및 수질내 주요한 구성 유기물로 존재하며 다양한 유기화합물과 분자량을 갖으며, 중금속들의 유출에 의한 오염 환경에서 그 화학종과 이동도에 영향을 주게된다 (Thurman, 1985). (중략)

• Journal of Korea Soil Environment Society
• /
• v.3 no.3
• /
• pp.3-10
• /
• 1998

Acid/Base buffer capacity of soil is very important in prediction of contaminant transport for its direct impact on pH change of the system composed of soil-contaminant-water, In this research, diffuse double layer theory as well as two layer electrostatic adsorption model are applied to develop a theoretical model of buffer capacity of soil. Model application procedures are presented as well. Buffer capacity of Georgia kaolinite and Milwhite kaolinite was measured by acid-base titration. Model prediction and experimental results are compared.

• Economic and Environmental Geology
• /
• v.55 no.5
• /
• pp.439-445
• /
• 2022

Organic pollutants that contained in stream sediments have origins of mountain soil in natural and cattle manure in human activity. Nitrogen and carbon isotope analysis for mountain soil, cattle manure and stream sediment were performed for contribution evaluation of organic pollutants in Toil stream of Yeongju dam basin. Average carbon isotope ratio(δ¹³C) is -25.17‰, -22.34‰, and -26.39‰ for river sediments, cattle manure and mountain soil, respectively. Result of carbon isotope analysis suggests that river sediments are more affected by acid soils. Average value of the nitrogen isotope ratio (δ¹⁵N) is 9.46% for river sediment, 1.99% for mountain soil, and 19.53% for cattle manure. Result of nitrogen isotopic analysis show that contribution of cattle mature is slightly higher than that of mountain soil in Toil stream sediments.

• The Korean Journal of Ecology
• /
• v.22 no.1
• /
• pp.7-11
• /
• 1999

The measurement of pH in the rhizosphere soil was conducted to clarify whether the growth of pokeberry plants affect the acidity of rhizosphere soil in two environmentally contrasting area Ulsan and Chongju city. The rhizosphere pH between 5.25 and 5.33 was shown in the pokeberry stand at Mt. Boomo located at Chongju. The rhizosphere pH of pokeberry stands at Mt. Bongdae, Mt. Sinsun and Mt. Totchil was below 5.0, and did not differ with depth and distance from the main axis of root. At Mt. Bongdae, however, the pH in the rhizosphere soil was significantly changed with soil depths though that was not changed horizontally. The rhizosphere pH at top soil was lower than that at subsoil, which indicates the fact that soil acidification at Mt. Bongdae was not caused by pokeberry plants. Furthermore, the rhizosphere pH did not change with the growth of pokeberry plants. These results indicate that the hypothesis that pokeberry plants acidify local soil environment should be reconsidered.

• Proceedings of the Turfgrass Society of Korea Conference
• /
• 2004.01a
• /
• pp.24-31
• /
• 2004

This experiment was carried out to study an effect of liquid fertilizer contained amino acids(LFcAA) on the growth of Bentgrass(Agrostis palustris Huds. penncross) and the change of soil chemicals characteristics. In tested soil, the utilization rate of nitrogen in treatment was more than control. Fresh weight, dry weight and concentration of T-N, Mg and chlorophyll were increased in grass treated LFcAA. These results suggested that treatment of LFcAA was promoted utilization of nitrogen in soil and growth of bentgrass.

• Analytical Science and Technology
• /
• v.15 no.4
• /
• pp.373-380
• /
• 2002

Humic and fulvic acids present in soil of different depth were extracted and their characteristics were analyzed as a basic study to evaluate the effect of humic substances on the behaviour of radioactive elements deposited on soil. Molecular size distribution of the humic and fulvic acids was measured by stirred cell ultrafiltration technique and the structural informations were obtained from their UV-Vis., IR and synchronous fluorescence (SyF) spectral analysis. Main molecular size ranges of the soil 1) humic and fulvic acids were 30~100 kDa (46~56%) and 10~30 kDa (33~43%) respectively, and their overall molecular sizes were found to became smaller with increasing the soil depth. Absorptivities measured at 280 nm in the UV-Visible spectra of humic acids were 1.4~1.5 times higher than those of fulvic acids, and increased with increasing the soil depth. SyF spectral data showed two distinct peak components having maximum peak positions of 428 nm (type I) and 498 nm (type II) for the soil humic and fulvic acids. From the analysis of the peak components, it was found that humic molecules are mainly made up of aromatic compounds corresponding to longer wavelength (type II), and the molecular components increased with increasing the soil depth. Analysis of IR spectral data indicated that the humic molecules contain a higher relative concentration of carboxylic groups than those of fulvic molecules, and the carboxylic group contents are seen to increase as the soil depth increase.

• Economic and Environmental Geology
• /
• v.48 no.3
• /
• pp.213-219
• /
• 2015

Samples from soils and crops were collected and analyzed in order to investigate the interactions of selenium among rocks, soils, and crops by hydrothermal alteration near epithermal mines in the region of Mio-san, Haenam. Soil samples included 6 samples each from mountain and farm area and compositional minerals and their contents were analyzed by water content, pH, ICP, XRD, XRF. Crop samples from onion and scallion were analyzed for chemical composition to elucidate the relationship with soils. Results from XRD analysis for soil samples showed that major compositional minerals are qualtz and feldspar, and illite, chlorite, hematite formed by hydrothermal alteration were included on a small scale. The pH ranges of soil samples from mountain and farm were measured at 4.6~4.9 and 5.2~6.7, respectively. The higher pH in farm soils may result from fertilization during agricultural activities. Results from ICP analysis showed that, compared to soil samples from mountain area with no potassium and calcium, significant amount of K and Ca were detected in soil samples from farms which is affected by fertilization. In a similar manner, potassium and calcium were absorbed and detected in crop samples at relatively high concentrations (116.89~169.79 ppm for K and 20.18~32.29 ppm for Ca). While the selenium contents in soil samples ranged from 18.35 ppb to 70.31 ppb which showed no significant difference, high concentrations of selenium were detected in onion (119.48~179.50 ppb) and scallion (146.65 ppb). These difference in enrichment for each element may result from the distinctive adsorption characteristics depending on crops.

• Proceedings of the Korea Water Resources Association Conference
• /
• 1991.07a
• /
• pp.102-113
• /
• 1991

한정된 수자원을 관리하기 위한 물관리시스템을 구축운영하는데 수문학적 물손실의 관점에서 증발산은 매우 중요한 요소이다. 본 연구에서는 이러한 증발산이 실제 유역에서 변화하는 것을 일별로 추정하기 위해서 유역일증발산 모형을 개발하여 실제증발산을 추정하였다. 실제증발산은 잠재증발산을 먼저 산정하고 이를 이용하여 강우차단에 의한 증발, 토양증발, 지표하 증산으로 나누어 추정하였다. 잠재증발산 추정방법은 토양-식생-대기의 관계를 정교히 모식할 수 있는 Penman-Monteith 방법을 채택하였고, 강우차단에 의한 증발은 Bultot와 Dupriez가 제안한 모형을, 토양증발은 Ritchie가 제시한 모형을 채택하였다. 증산은 토양층을 상부·하부층으로 나누어 상부층증산과 하부층 증산으로 분리 추정하였으며, 증발산과 토양수분의 관계는 Thornthwait-Mather의 관계를 이용하여 추정하였다. 이 모형의 타당성을 임업연구원에서 운영하고 있는 2개의 시험유역을 대상으로 검토하였다. 그결과 실제일증발산을 년단위로 계산한 실제증발산값은 물수지 개념에 의한 실제증발산결과와 비교할 때 약 8~30% 오차를 수반하고 있었다. 이러한 결과는 모형의 실제유역의 적용에 있어서 입력되는 여러 매개변수가 가정에 의해 결정된 것이기 때문일 것이라고 판단된다.

• Applied Biological Chemistry
• /
• v.12
• /
• pp.115-118
• /
• 1969

In a series of studies on the formation processes and chemical properties of humic substances from paddy soils the photoabsorption spectra of hymatomelanic and humic acids were recorded in the visible, ultraviolet and infrared regions. The spectra patterns of both fractions in the visible range were indicative of the decrease in optical density with the rise of wavelength and the UV-spectra showed the maximum peak at $235\;m{\mu}$, the minimum at $395\;m{\mu}$. The IR-spectra indicate a typical pattern showing a few sharp peaks in both fractions. The spectra of both fractions were compared and discussed.