• Title/Summary/Keyword: 사슬 길이

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A New Additi$on_{}$traction Chain Algorithm for East Computation over Elliptic Curve Cryptosystem (타원곡선 암호시스템에서의 빠른 연산을 위한 새로운 덧셈/뺄셈 사슬 알고리즘)

  • 홍성민;오상엽;윤현수
    • Proceedings of the Korea Institutes of Information Security and Cryptology Conference
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    • 1995.11a
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    • pp.151-162
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    • 1995
  • 보다 짧은 길이의 덧셈/뺄셈 사슬($addition_{traction-chain}$)을 찾는 문제는 정수론을 기반으로 하는 많은 암호시스템들에 있어서 중요한 문제이다. 특히, RSA에서의 모듈라멱승(modular exponentiation)이나 타원 곡선(elliptic curve)에서의 곱셈 연산시간은 덧셈사슬(addition-chain) 또는 덧셈/뺄셈 사슬의 길이와 정비례한다 본 논문에서는 덧셈/뻘셈 사슬을 구하는 새로운 알고리즘을 제안하고, 그 성능을 분석하여 기존의 방법들과 비교한다. 본 논문에서 제안하는 알고리즘은 작은윈도우(small-window) 기법을 기반으로 하고, 뺄셈을사용해서 윈도우의 개수를 최적화함으로써 덧셈/뺄셈 사슬의 길이를 짧게 한다. 본 논문에서 제안하는 알고리즘은 512비트의 정수에 대해 평균길이 595.6의 덧셈/뺄셈 사슬을 찾는다.

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Reactivity of Phospholipase D toward Phosphatidylcholines with Different Length of Acyl Chains (길이가 틀린 아실사슬을 갖는 콜린 인지질에 대한 포스포리파제 D의 반응성)

  • Koh, Eun-Hie;Park, Insook
    • Journal of the Korean Chemical Society
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    • v.40 no.9
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    • pp.630-634
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    • 1996
  • In order to explore a substrate specificity for cabbage phospholipase D, we examined the PLD reactivity toward the phosphatidylcholines with different chain length of acyl groups. The selected acyl chains were the saturated fatty acid of $C_8:0,\;C_{12}:0,\;C_{16}:0,\;C_{20}:0$. The reactivity of these phospholipids were dependent largely on the ratio of PC : SDS. The PC : SDS ratio showing the optimal PLD activity were found to be 1:1.4, 1:2.2, 1:2.5, and 1:3.6 respectively as the increase of the acyl chain length. Likewise the optimum temperature for the maximal PLD activity were altered markedly to 25$^{\circ}C$, 30$^{\circ}C$, 35$^{\circ}C$, 45$^{\circ}C$ when the length of acyl chains increased. On the contrary the pH and concentration of $Ca^{2+}$ necessary for the optimum PLD activity were not altered significantly. The kinetic parameter $V_{max}$ for short acyl chain substrate was greater than the values for the longer acyl chain, which indicates the fastest rate of hydrolysis. By the same token, the reactivity of longer chain substrate became slower for the hydrolysis activity.

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Optimum Chain Extension and Change of the Average Particle Size of Aqueous Polyurethane Dispersion (수분산 폴리우레탄 제조시 최적 사슬연장 조건과 입도 변화에 관한 연구)

  • Kong, H.C.;Jhon, Y.K.;Cheong, I.W.;Kim, J.H.
    • Journal of Adhesion and Interface
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    • v.3 no.2
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    • pp.9-16
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    • 2002
  • In the synthesis of water-based polyurethane using self-emulsification process, after being neutralized, polyurethane pre-polymers containing ionic pendant groups are dispersed by simple convective mixing. Preparation of dispersion is followed by chain extension reaction, which is considered as important step for growth of the molecular weight of polyurethane. In this work, pH variations in the aqueous phase were monitored during the chain extension process in the presence of water-soluble diamines. The optimum degree of chain extension and the average particle size in the polyurethane dispersions were examined with varying ionic pendent group contents, type of chain extenders, and feed rate of chain extenders, The initial pH value in the aqueous phase linearly increased and the optimum chain extension point could be obtained from the intersection of two linear lines having different slopes, All average particle sizes before chain extension reaction were almost same, however, the final average particle size increased as feed rates of chain extenders increased, In addition, as the ionic pendant group contents increased, the particle size decreased since the hydrophilicity and hydrodynamic volume increased. As carbon numbers of the chain extenders increased, the final particle size increased significantly. From the results, it was concluded that the chain extension reaction took place among the particles not only in a particle.

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Effects of Benzyltrialkylammonium Type Cationic Surfactants on the Preparation and Properties of Liposome (벤질트리알킬암모늄계 양이온성 계면활성제가 리포좀 제조와 특성에 미치는 영향)

  • Jung, Yeonseok;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.428-434
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    • 2016
  • In this study, benzyltrialkylammonium chlorides with different alkyl chain length were synthesized and applied to liposome. Prepared cationic surfactant embedded liposomes were measured particle size, zetapotential, release property and antibacterial activity. The average particle size of liposomes was 120~140 nm. As alkyl chain length was increased, the liposome size was increased. Zetapotential for the solution of liposomes added cationic surfactants were in the range of +80~90 mV. In release test, collagen release rate could be controlled by alkyl chain length. liposome embedded long alkyl chain surfactant had enhanced sustained release property. Entrapment efficiency of hydrophilic collagen were 25.9~27.5%.

Chemo-mechanical Analsis of Bifunctional Linear DGEBA/Linear Amine Resin Casting Systems (DGEBA/선형 아민경화제의 주쇄에 포함된 질소 및 탄소원자 개수에 따른 물성 변화 연구)

  • 명인호;정인재;이재락
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.201-210
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    • 2000
  • To determine the effect of chain length of linear amine curing agents on the thermal and mechanical properties, standard epoxy resin, diglycidyl ether of bisphenol A (DGEBA) was cured with diethylenetriamine (DETA), triethylenetetraamine (TETA) and tetraethylenepentaamine (TEPA) in a stoichiometrically equivalent ratio. From this work, the effect of linear amine curing agents on the thermal and mechanical properties was significantly influenced by chain length of curing agents. In contrast, the results showed that the DGEBA/DETA system had higher values than the DGEBA/TETA and DGEBA/TEPA system in the density, shrinkage (%), thermal expansion coefficient, tensile modulus, and flexural strength. Whereas the DGEBA/DETA cure system had lower values than the DGEBA/TETA and DGEBA/TEPA cure system in the maximum exothermic temperature, conversion (%), and T$_{g}$. These findings imply that the differences in the maximum conversion about the chain length of curing agents affect the thermal and mechanical properties.s.

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고무소재의 열응력

  • Gang, Sin-Yeong;Hong, Chang-Guk
    • Rubber Technology
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    • v.11 no.1
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    • pp.12-26
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    • 2010
  • 각종 산업제품의 주요 부품으로 사용되고 있는 고무재료는 사용 중 온도변화에 의해 체적 또는 길이 변화를 수반할 수 있어 결과적으로 고무제품의 성능이나 효율이 영향을 받게 된다. 특히 고온에서 고무제품의 치수변화를 제한하거나 일정치수를 강제할 경우 열수축이나 열팽창에 의해 응력이 발생하게 된다. 따라서 온도 변화에 따른 열응력의 측정은 고무제품의 정밀성과 성능을 평가하는 중요한 수단을 제공한다. 본 연구에서는 고무소재의 열응력 측정을 위한 새로운 측정방법을 개발하였고 이와 관련 새로운 시험장치를 설계, 제작하였다. 고무시편에 일정 변형의 인장을 준 상태에서 가열하면 열응력이 발생한다. 이 때의 열응력은 고무분자 사슬들의 운동성에 기인하며 배향된 고무분자 사슬들이 열역학적으로 랜덤 사슬형태로 돌아가려는 엔트로피적 힘이다. 따라서 온도가 높을수록 그 수축력은 증가하게 된다. 또한 고무분자 사슬의 사전 변형이 증가하면 그 열응력은 증가한다. 이때 열응력은 측정시간이 지남에 따라 최대치에 도달한 후 완화되며 그 완화속도는 설정온도에 의해 영향을 받는다. 여기서는 온도변화에 따른 고무시편의 열응력 측정결과를 소개하고, 고무분자 사슬의 엔트로피 변화와 점탄성적 흐름, 그리고 가열에 따른 고무 시편의 팽창 또는 수축이 열응력에 미치는 영향 등을 논의하였다. 특히 천연고무와 SBR 고무시편의 열응력 차이를 분자사슬의 운동과 연관하여 검토하였고, 가교밀도와 가교시스템이 각각 다른 고무시편에 대해 열응력 발생과에 따른 상관관계를 고찰하였다. 또한 시편의 형태와 두께가 열응력 발생에 미치는 영향도 검토하였다. 충전 배합고무의 경우 열응력에 영향을 미치는 인자로 고무분자 사슬의 운동성과 가교밀도 외에 고무재료와 충전제 사이의 물리 화학적 상호작용도 매우 중요한 요소가 된다. 배합고무에서 충전제의 영향을 검토하기 위해 실리카와 카본블랙을 선택하였고 배합고무의 열응력을 각각 측정하여 이들의 보강효과가 열응력에 미치는 영향에 대해 논하였다.

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Vibrational Spectroscopic Studies of Crystallization in Mixed n-Paraffins (진동분광실험을 이용한 n-Paraffin혼합물의 결정화에 관한 연구)

  • 김도균;임현주;최선남;김성수;송기국
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.752-758
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    • 2002
  • FTIR, FT-Raman, and X-ray diffraction techniques were used to determine chain segregations and lamellar structures of the mixed binary n-paraffins with different chain lengths. The results of three different techniques, infrared spectroscopic studies of crystal field splitting, the Raman longitudinal acoustic mode, and the SAXS long period measurements were compared one another to understand the crystallization mechanism of separated or mixed n- paraffin lamellae.

Identifying Variable-Length Palindromic Pairs in DNA Sequences (DNA사슬 내에서 다양한 길이의 팰린드롬쌍 검색 연구)

  • Kim, Hyoung-Rae;Jeong, Kyoung-Hee;Jeon, Do-Hong
    • The KIPS Transactions:PartB
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    • v.14B no.6
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    • pp.461-472
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    • 2007
  • The emphasis in genome projects has Been moving towards the sequence analysis in order to extract biological "meaning"(e.g., evolutionary history of particular molecules or their functions) from the sequence. Especially. palindromic or direct repeats that appear in a sequence have a biophysical meaning and the problem is to recognize interesting patterns and configurations of words(strings of characters) over complementary alphabets. In this paper, we propose an algorithm to identify variable length palindromic pairs(longer than a threshold), where we can allow gaps(distance between words). The algorithm is called palindrome algorithm(PA) and has O(N) time complexity. A palindromic pair consists of a hairpin structure. By composing collected palindromic pairs we build n-pair palindromic patterns. In addition, we dot some of the longest pairs in a circle to represent the structure of a DNA sequence. We run the algorithm over several selected genomes and the results of E.coli K12 are presented. There existed very long palindromic pair patterns in the genomes, which hardly occur in a random sequence.

Effects of the Chain Length of High α-olefins on the Terpolymerization (High α-olefin의 사슬길이가 삼원공중합에 미치는 영향)

  • Kim, Tae-Wan;Lee, Jun Chul;Park, No-Hyung;Kim, Hyun Ki;Cho, Ur-Ryong;Kim, Dong Hyun
    • Elastomers and Composites
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    • v.47 no.4
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    • pp.329-335
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    • 2012
  • In this study, we synthesized poly(ethylene-ter-high ${\alpha}$-olefin-ter-p-methylstyrene) using Zr metallocene catalyst/borate type cocatalyst system. Various effects of the high ${\alpha}$-olefin (1-hexene, 1-octene, 1-decene, and 1-dodecene) were observed. The structure and composition of the terpolymers were characterized using $^{13}C$ NMR and $^1H$ NMR. Catalytic activity, polymer yield, molecular weight and molecular weight distribution were analyzed according to the chain length of high ${\alpha}$-olefin. We determined morphology, crystallinity and thermal properties of the terpolymers.

A Theory for the Helix/Coil Transition of Oligopeptide Chain Dimer (올리고펩티드 사슬이합체의 헬릭스-코일 전이 이론)

  • Kim, Younggu;Pak, Hyungsuk
    • Journal of the Korean Chemical Society
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    • v.39 no.10
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    • pp.776-782
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    • 1995
  • A theory of the helix/coil transition for $\alpha$ helical dimer such as $\alpha$ tropomycin and paramycin is developed. The treatment differs from those formulated previously for oligopeptide dimer which is explained by the matrix method using Zimm-Bragg parameter: In the present treatement, it is explained by the zipper model which can account for the dangling H-bond. We calculate the fractional helicity in $\alpha$ helical dimer as a function of helix initiation $constant(\sigma)$, helix stability constant(${\xi}$) and hydrophobic interaction parameter(w). For $\alpha$ tropomycin, the helix stability profile is also calculated. The transitions of this oligomer due to the change of temperature and the concentration of oligopeptide involve simultaneous dissociation of the dimer. The transitions of dimers which have cross-linked S-S bonds or have long chains don't occur, because they keep always helical structures. The transitons due to the concentration of the oligopeptides are steeper than those due to the chain length or temperature.

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