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T$a_2O_5$Dielectric Thin Films by Thermal Oxidation and PECVD (열산화법 및 PECVD 법에 의한 T$a_2O_5$ 유전 박막)

  • Mun, Hwan-Seong;Lee, Jae-Seok;Lee, Jae-Seok;Lee, Jae-Seok;Yang, Seung-Gi;Lee, Jae-hak;Park, Hyung-ho;Park, Jong-wan
    • Korean Journal of Materials Research
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    • v.2 no.5
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    • pp.353-359
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    • 1992
  • Thermal oxidation and plasma enhanced chemical vapor deposition of tantalum oxide thin films on p-type (100) Si substrates were studied to examine the dielectric nature of T$a_2O_5$ as a Al/T$a_2O_5$/p-Si capacitor. Microstructure and dielectric properties of the capacitors were investigated by XRD, AES, high frequency C-V analyzer, I-V meter and TEM. XRD analysis showed that the structure of T$a_2O_5$ films were amorphous, but the films were crystallized to hexagonal $\delta$-T$a_2O_5$ by 65$0^{\circ}C$ thermal oxidation treatment. It was found that the stoichiometry of the films was more or less close to 2 : 5. Leakage current density and relative dielectric constant of thermal oxidation T$a_2O_5$ film at 60$0^{\circ}C$ was 5.0${ imes}10^{-6}$/A/c$m^2 and 31.5, respectively. In the case of PECVD T$a_2O_5$film deposited at 0.47W/c$m^2 they were 2.5${ imes}10^{-5}$/A/$ extrm{cm}^2$ and 24.0, respectively. The morphology of the films and interfaces were investigated by TEM.

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Confucius's Theory of Poetics in Analects (공자의 『시경』 재구성과 시론(詩論) - 『논어』를 중심으로)

  • Lim, Heon-gyu
    • Journal of Korean Philosophical Society
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    • v.137
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    • pp.439-462
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    • 2016
  • This Article's aim is to articulate Confucius's theory of poetics in analects. Confucius tried to establish Humanism and educate the idea of 'learning to become a sage' based upon six classics. He empathized with the education of The Book of Poetry. Sze-ma Tseen said that the old poems amounted to more than 3,000. Confucius removed those which were only repetitions of others and sang to them with his lute, bringing them into accordance with the appropriate musical style. This is the first notice which we have of any compilation of the ancient poems by Confucius. Confucius said, "If you do not learn the Odes, you are not fit to converse with. The Odes 1) serve to stimulate the mind, 2) may be used for purposes of self-contemplation, 3) teach the art of sociability, 4) show how to regulate feelings of resentment, 5-6.) 'From them you learn the more immediate duty of serving one's father, and the remoter one of serving one's prince. and from them we become largely acquainted with the names of birds, beasts, and plants.' Confucius' said, 'In the Book of Poetry are three hundred pieces, but the design of them all may be embraced in one sentence-- "Having no depraved thoughts."' This sentence is the final definition of Poetics.

Variation of Water Content and Thermal Behavior of Talc Upon Grinding: Effect of Repeated Slip on Fault Weakening (활석 분쇄에 따른 함수율 및 열적거동 변화: 단층의 반복되는 미끌림이 단층 약화에 미치는 영향)

  • Kim, Min Sik;Kim, Jin Woo;Kang, Chang Du;So, Byung Dal;Kim, Hyun Na
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.3
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    • pp.201-211
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    • 2019
  • The particle size and crystallinity of fault gouge generally decreases with slip. Phyllosilicates including talc are known to be present in fault gouge and play an important role in fault weakening. In particular, the coefficient of friction varies depending on the presence of a water molecule on the surface of mineral. The purpose of this study is to investigate the effect of talc on fault weakening by changing the water content and dehydration behavior of talc before and after grinding, which systematically varied particle size and crystallinity using high energy ball mill. Infrared spectroscopy and thermal analysis show that the as-received talc is hydrophobic before grinding and the water molecule is rarely present. After grinding up to 720 minutes, the particle size decreased to around 100 ~300 nm, and in talc, where amorphization proceeded, the water content increased by about 8 wt.% and water molecule would be attached on the surface of talc. As a result, the amount of vaporized water by heating increased after grinding. The dihydroxylation temperature also decreased by ${\sim}750^{\circ}C$ after 720 minutes of grinding at ${\sim}950^{\circ}C$ before grinding due to the decrease of particle size and crystallinity. These results indicate that the hydrophobicity of talc is changed to hydrophilic by grinding, and water molecules attached on the surface, which is thought to lower the coefficient of friction of phyllosilicates. The repeated slip throughout the seismic cycle would consistently lower the coefficient of friction of talc present in fault gouge, which could provide the clue to the weakening of matured fault.

A Hydration Reaction and Strength Development Properties of Cement Using Pond Ash in Coal Fired Power Plant (화력 발전소 매립회를 치환한 시멘트의 수화반응 및 강도발현 특성)

  • Lee, Jae-Seung;Noh, Sang-Kyun;Shin, Hong-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.578-584
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    • 2021
  • This study comparatively analyzed the properties of hydration reaction and strength development of four types of pond ash(PA) and fly ash(FA), aiming for the effective use of PA. The PA whose chlorine content was highest due to the seawater movement method had a faster setting time, higher cumulative heat, and greater initial strength development than those of FA due to the acceleration of the cement hydration reaction. However, the activity factor increase rate decreased after seven days of curing due to the rapid generation of early hydrates. The PA that contained impurities, such as a large amount of unburned carbon, had a delayed setting time due to the lower hydration reaction. Moreover, the strength was degraded in all curing ages. The PA whose chlorine content was lower due to the freshwater movement method and the amorphous content exhibited similar hydration reactivity and strength development characteristics compared to that of FA. The thermogravimetric analysis results verified that it had a similar level of Ca(OH)2 consumption and pozzolanic reactivity with that of FA. Conclusively, it is necessary to expand the application of the freshwater movement method and manage the ignition loss to raise PA's usability.

Analysis of Radiation Dose Enhancement for Spread Out Bragg-peak of Proton (확산된 피크의 양성자에서 선량 증강 현상에 대한 분석)

  • Hwang, Chulhwan;Kim, JungHoon
    • Journal of the Korean Society of Radiology
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    • v.13 no.2
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    • pp.253-260
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    • 2019
  • Radiation dose enhancement is a method of increasing the cross section of interaction, thus increasing the deposited dose. This can contribute to linear energy transfer, LET and relative biological effectiveness, RBE. Previous studies on dose enhancement have been mainly focused on X, ${\gamma}-rays$, but in this study, the dose enhancement was analyzed for proton using Monte Carlo simulation using MCNP6. Based on the mathematical modeling method, energy spectrum and relative intensity of spread out Bragg-peak were calculated, and evaluated dose enhancement factor and dose distribution of dose enhancement material, such as aurum and gadolinium. Dose enhancement factor of 1.085-1.120 folds in aurum, 1.047-1.091 folds in gadolinium was shown. In addition, it showed a decrease of 95% modulation range and practical range. This may lead to an uncertain dose in the tumor tissue as well as dose enhancement. Therefore, it is necessary to make appropriate corrections for spread out Bragg-peak and practical range from mass stopping power. It is expected that Monte Carlo simulation for dose enhancement will be used as basic data for in-vivo and in-vitro experiments.

MgO doping and annealing effect on high temperature electrical resistivity of AlN-Y2O3 ceramics (MgO doping 및 annealing이 AlN-Y2O3 세라믹스의 고온전기저항에 미치는 영향)

  • Yu, Dongsu;Lee, Sung-Min;Hwang, Kwang-Taek;Kim, Jong-Young;Shim, Wooyoung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.6
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    • pp.235-242
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    • 2018
  • High temperature electrical conductivity of Aluminum Nitride (AlN) ceramics sintered with $Y_2O_3$ as a sintering aid has been investigated with respect to various sintering conditions and MgO-dopant. When magnesium oxide is added as a dopant, liquid glass-film and crystalline phases such as spinel, perovskite are formed as second phases, which affects their electrical properties. According to high temperature impedance analysis, MgO doping leads to reduction of activation energy and electrical resistivity due to AlN grains. On the other hand, the activation energy and electrical resistivity due to grain boundary were increased by MgO doping. This is a result of the formation of liquid glass film in the grain boundary, which contains Mg ions, or the elevation of schottky barrier due to the precipitation of Mg in the grain boundary. For the annealed sample of MgO doped AlN, the electrical resistivity and activation energy were increased further compared to MgO doped AlN, which results from diffusion of Mg in the grains from grain boundary as shown in the microstructure.

Fundamental Research on Reactivity of Silica Source in the Rapidly Cured Inorganic Micro-Defect-Free(MiDF) Concrete (촉진 양생한 무기계 MiDF 콘크리트에서 실리카질 원료의 반응성에 관한 기초 연구)

  • Choi, Hong-Beom;Kim, Jin-Man
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.166-173
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    • 2019
  • In this paper, the reaction properties of silica source in the accelerated curing conditions using autoclave and the fundamental properties of inorganic Micro Defect Free(MiDF) concrete using silica source are studied. Studies show that Si ions elution rate from silica source in autoclave curing is higher in amorphous source. In tap water conditions, solids which is source after autoclaved curing show a higher mass reduction in amorphous materials, which is attributed to the higher elution rate of ion. In $Ca(OH)_2$ solution conditions, amorphous materials show higher mass increase, due to increase in C-S-H minerals. From experiment for influence on the properties of MiDF concrete by using nano silica materials, the specimen with silica fume shows an increase in compressive strength and a decrease in absorption depending on replacement rate up to 5.5%, while nano silica with amorphous phase and high-fineness shows a decrease in compressive strength and decrease in the water absorption. The specimen with nano silica increases the pore below 10,000nm, but reduces pore between 10,000 and 100,000nm. The above results show that the porosity and absorption rate of MiDF concrete can be reduced by using amorphous nano-size silica. However, to reduce the pore of 50 to 10,000nm, better dispersion of nano material in the cement matrix will be necessary. We will focus on the this item in the next research.

The Study on the Change of Construction of Namwoneupseong Fortress in the Joseon Dynasty (조선시대 남원읍성(南原邑城)의 축성변천(築城變遷)에 관한 연구)

  • Oh, Jun-young;Kim, Young-mo
    • Korean Journal of Heritage: History & Science
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    • v.46 no.4
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    • pp.144-159
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    • 2013
  • This study covers Namwoneupseong Fortress(南原邑城), Historic Site No. 298, which played a pivotal role in the urban development and military defense history of Namwon during the Joseon Dynasty. From the related historical records, Namwoneupseong Fortress was first constructed during the reign of King Seongjong. Discussion on the extension of Namwoneupseong Fortress, afterwards, was mainly guided by he traces of Yuingweseong Fortress(劉仁軌城). In other words, the original construction of the Fortress was in the original shape of the current Namwoneupseong Fortress, and Yuingweseong Fortress heavily impacted the extension works of Namwoneupseong Fortress. Although some studies covered Namwoneupseong Fortress and its overall construction process, no in-depth study exists on the original Namwoneupseong Fortress and Yuingweseong Fortress. This study covers the overall construction process of Namwoneupseong Fortress. At the same time, we tried to confirm inclusively and objectively the facts related to the relationship between Yuingweseong Fortress and Namwoneupseong Fortress, process and range of the expansion of Namwoneupseong Fortress among others through the location search of the originally built Namwoneupseong Fortress and Yuingweseong Fortress. The study discovered that Yuingweseong Fortress was built in A.D. 660~665 and that Namwoneupseong Fortress, which was built in the early stage of King Seongjong's reign, was extended along the traces of Yuingweseong Fortress towards the southeast. Furthermore, the study confirmed that Namwoneupseong Fortress is consisted of three sections - the section with Namwoneupseong Fortress's original walls preserved, newly constructed section, and the section following Yuingweseong Fortress's traces.

A Study on the Original Position of Wibongmun and Joyangru and Signboard Handwriting in the Chuncheon (춘천 위봉문(威鳳門)·조양루(朝陽樓)의 원위치 비정과 현판 글씨 고찰)

  • Lee, Sang-kyun
    • Korean Journal of Heritage: History & Science
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    • v.46 no.2
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    • pp.150-165
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    • 2013
  • This study aims to investigate the original position, the writer of signboard handwriting and the period of Wibongmun and Joyangru in order to restore Wibongmun and Joyangru which have been designated as tangible cultural properties (有形文化財). They also have to be moved in the Gangwon Provincial Office. Wibongmun and Joyangru were established as government offices in chuncheon(春川官衙) and they were used as attached buildings in Chunceon (春川離宮) in 1890. Wibongmun was moved to Gangwon Provincial Office 5 times and Joyangru was moved twice. In order to move them back to the original place, by using the topographic map made by the Japanese Government-General in Korea, we find out Joyangru was located in the exit of Gangwon Provincial Office and greenhouse and we also figure out Wibongmun was located in the garden. While we study historical evidence on handwriting, we also find out the handwriting of Joyangmun was written by Songhaong (松下翁) Jo, Yun-Hyeong (曺允亨). Especially, Joyangru had played a role as a government office and it may be called 'Joyangru' after reconstructing 'Joyangmun' when attached buildings were established. Through this study, we found that the first period and reason of establishing Wibongmun and Joyangru was at least before 1788. Through this study, we can find the period of both and its historic meaning more clearly.

Freeze-Thaw Resistance of Alkali Activated Ternary Blended Cement Incorporated with Ferronickel Slag (알칼리 활성화제를 첨가한 페로니켈슬래그 혼입 삼성분계 콘크리트의 동결융해 저항성)

  • Cho, Won-Jung;Park, Kwang-Pil;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.2
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    • pp.159-167
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    • 2022
  • The present study assessed the micro structure and durability characteristics of ternary blended cement with different types of alkali activators. Ground granulated blast furnace slag(GGBS) and ferronickel slag(FNS) was replaced until 50 % of the weight of cement. In addition, potassuim hydroxide and sodium hydroxide were used for comparing the properties of different type of alkali activator. Ternary blended cement with alkali activators showed higher peak portlandite peak than that of OPC(Ordinary Portlande Cement) and non activated ternary blended cement. Also, there was no new hydration products in ternary blended cement or/and alkali activators. Based on the mercury intrustion porosimetry(MIP) test result, ternary blended cement increased macro pore while alkali activated ternary blended cement modified pore structure and increased microp pore as compared to OPC as control. Combination with alkali activators is desirable to enhance the compressive strength and freeze thaw resistance.