• 제목/요약/키워드: 비정질 용사

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비정질 기지 복합재 코팅층의 미세조직 분석 및 기계적 거동 (Analysis and Mechanical Behavior of Coating Layer in Metallic Glass Matrix Composite)

  • 장범택;이승훈
    • 대한기계학회논문집A
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    • 제38권6호
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    • pp.629-636
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    • 2014
  • 비정질합금이 가지고 있는 우수한 기계적 성질과 화학적 특성을 부품소재에 표면개질을 목적으로 고속화염 용사법으로 대면적 코팅층을 형성하였고 내열성이 높은 자융성합금과 초경합금 성분들을 적절히 혼합하여 비정질기지 복합재료를 제조하여 코팅들의 미세조직 관찰과 나노인덴테이션을 이용한 미세표면의 기계적 거동을 분석하였다. 각 코팅층의 미세조직을 관찰한 결과, 단일상 비정질 코팅에는 미용융 입자와 lamellae 영역이 존재하고 자융성합금이 고용된 복합재에는 in-situ $Cr_2Ni_3$ 석출물, 자융성합금과 초경합금성분이 함께 혼합된 코팅층은 석출물과 ex-situ WC 강화입자가 공존하였다. 이들 미세표면의 기계적 거동은 제 2 상이 고용된 비정질 기지 복합재의 코팅층의 기계적 특성이 전체적으로 향상되었다.

나노구조 용사코팅층의 형성에 관한 기초적 연구 (Fundamental Study on the Formation of Nanostructured Coating Layer)

  • 김영식
    • 동력기계공학회지
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    • 제9권4호
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    • pp.90-95
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    • 2005
  • The wire-arc process is a low-cost thermal spray method simply utilizes electrical energy to melt the feedstock wire. It is more userful for field applications, especially to coat large surface area. In this paper, a special Fe-based alloy coatings by using the wire-arc process were developed. Nanoscale composite coatings were achieved either during spraying or through a post heat treatment. As-sprayed Fe-based alloy coatings had been an amorphous matrix structure, after heating to $700^{\circ}C$ for 10 minutes a solid state transformation occurred in the some fraction of amorphous matrix which resulted in the formation of nanostructured recrystallized phase. Scanning electron microscopy (SEM) and field emotional scanning electron microscope(FE-SEM) were applied to analyze the microstructure of the coatings. Additionally hardness and bend resistance of the Fe-based alloy coatings were examined, and these results were compared with those of partially stabilized zirconia(PSZ) coatings by using the plasma spray process.

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벌크 비정질 용사코팅과 비정질 기지 복합재료의 건조 마찰특성 (Dry Friction Characteristics of Bulk Amorphous Thermal Spray Coating and Amorphous Metallic Matrix Composites)

  • 장범택;이승훈
    • Tribology and Lubricants
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    • 제30권2호
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    • pp.108-115
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    • 2014
  • The friction behaviors of bulk amorphous thermal spray coating (BAC) and second phase-reinforced composite coatings using a high velocity oxy-fuel spraying process were investigated using a ball-on-disk test rig that slides against a ceramic ball in an atmospheric environment. The surface temperatures were measured using an infrared thermometer installed 50 mm from the contact surface. The crystallinities of the coating layers were determined using X-ray diffraction. The morphologies of the coating layers and worn surfaces were observed using a scanning electron microscope and energy-dispersive spectroscopy. The results show that the friction behavior of the monolithic amorphous coating was sensitive to the testing conditions. Under lower than normal loads, a low and stable friction coefficient of about 0.1 was observed, whereas under a higher relative load, a high and unstable friction coefficient of greater than 0.3 was obtained with an instant temperature increase. For the composite coatings, a sudden increase in friction coefficient did not occur, i.e., the transition region did not exist and during the friction test, a gradual increase occurred only after a significant delay. The BAC morphology observations indicate that viscous plastic flow was generated with low loads, but severe surface damage (i.e., tearing) occurred at high loads. For composite coatings, a relatively smooth surface was observed on the worn surface for all applied loads.

Ni-Cr-B-Si계 비정질 용사피막의 제조 및 특성 (Fabrication and Characteristics of Thermal Sprayed Ni-Cr-B-Si System Amorphous Coatings)

  • 정하윤;김태형;박경채
    • Journal of Welding and Joining
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    • 제17권4호
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    • pp.53-59
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    • 1999
  • Amorphous alloys have also been called glassy alloys or non-crystalline alloys. They are made by the rapid solidification. The solidification occurs so rapid that the atoms are frozen in their liquid configuration. There are unique magnetic, mechanical, electrical and corrosive behaviors which result form their amorphous structure. In the study. amorphous coatings were manufactured with Ni-Cr-B-Si powders by flame spray. Measurement of hardness, were resistance, corrosion resistance and observation of microstructures and XRD, DSC were performed to investigate characteristics of amorphous coatings. The experimental results obtained as follow: 1) Amorphous powders could not be manufactured with the spraying in the spraying in the liquid nitrogen. But, amorphous coatings could be manufactured with the rotation cooling method by liquid nitrogen. In the fabrication of amorphous coatings, major factor was the rapid cooling by rotation of the substrate. 2) Hardness of coatings was obtained Hv 960 by formation of amorphous phase. But, wear resistance decreased. That was due to porosity in the coatings by the rapid cooling. 3) In the case of corrosion resistance, amorphous coatings were superior to air-cooled coatings. That was due to formation of amorphous phase. 4) After amorphous coatings were heat-treated at 520℃ for 1hr. hardness increased 80% and wear resistance increased 30% comparing with air cooled coatings. These were due to crystallization of amorphous phase and decrease of porosity by heat-treatment.

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실험계획법을 이용한 ALBC3에 대한 고속화염용사의 최적 공정 설계 (A Process Optimization of HVOF on ALBC3 by Experiments Design)

  • 김영문;임병철;김민태;박상흡
    • 한국산학기술학회논문지
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    • 제17권4호
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    • pp.448-453
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    • 2016
  • 선박의 프로펠러나 임펠러와 같은 유체기기에서는 캐비테이션 현상으로 인해 마모와 침식이 발생한다. 이와 같은 기기손상은 소음과 진동을 발생시켜 기기수명을 단축시키는 문제점을 가지고 있다. 본 연구에서는 캐비테이션 현상에 대한 저항성을 높이기 위해 산업 현장에서 많이 사용되고 있는 고속화염용사코팅의 공정 최적화에 따른 각 요소별 중요도를 분석하였다. 다구찌 실험계획법을 적용하여 ALBC3 모재 표면에 비정질 분말을 코팅하였고 기공도 실험을 통해 각 요소별 특성을 분석하였다. 다구찌 실험계획법에 의해 고속 화염용사(HVOF) 코팅의 최적 공정을 찾아낸 결과 연소압이 80 psi, 코팅거리가 270 mm, 이송속도가 200 mm/s, 분말속도는 25 g/min으로 확인되었고, 그 결과, 연소압, 코팅거리 및 분말속도는 25% 이상으로 비슷한 기여도를 나타냈고 이송속도는 19%로 다소 떨어지는 수준을 나타내었다. 공정에 대한 각 인자별 기여도는 약간의 차이는 있지만 그 차이가 크지 않으므로 네 개의 인자 모두 고속 화염용사(HVOF) 코팅 공정에서 중요한 기여를 하였다.

대기 플라즈마 용사공정을 이용한 Fe계 벌크 비정질 금속 코팅의 초기 분말의 화학조성과 크기에 대한 미세 조직 및 마모 특성 (Microstructure and Tribological Properties along with Chemical Composition and Size of Initial Powder in Fe-based BMG Coating through APS)

  • 김정환;윤상훈;나현택;이창희
    • 한국표면공학회지
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    • 제41권5호
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    • pp.220-225
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    • 2008
  • In this study, two kinds of Fe-based bulk metallic glasses (BMG) powder were built-up through atmospheric plasma spray (APS) technique. The microstructure of two coatings was analyzed through X-ray diffraction, scanning electron microscopy and transmission electron microscopy. Crystallization and oxidation in coatings were affected by chemical composition and initial powder size. Then, both of them influenced the tribological property.