• Title/Summary/Keyword: 비열

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The Characteristics of Isothermal Conduction Calorimetry and Specific Heat in Coal Gasification Slag (석탄 가스화 용융 슬래그의 비열 및 미소수화열 특성)

  • Han, Jun-Hui;Hu, Yun-Yao;Lim, Gun-Su;Kim, Su-Hoo;Kim, Jong;Han, Min-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.182-183
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    • 2021
  • In this study, This is the result of thermal characteristics analysis to suggest an efficient method of using coal gasification slag(CGS) of byproduct from integrated gasification combined cycle(IGCC). In Specific Heat characteristics, CGS and CS showed similar values. Isothermal Conduction Calorimetry showed that the hydration reaction of cement was retarded when CGS was used. Therefore, it is expected that CGS will be used as an efficient alternative to reducing the hydration heat of mass concrete as a functional aggregate combination.

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Study on the Thermal Storage Characteristics of Phase Change Materials for Greenhouse Heating (온실보온(溫室保溫)을 위한 상변화(相變化) 물질(物質)의 축열특성연구(蓄熱特性硏究))

  • Song, Hyun-Kap;Ryou, Young-Sun;Kim, Young-Bok
    • Solar Energy
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    • v.13 no.2_3
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    • pp.65-78
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    • 1993
  • An overdose of fossil fuel for greenhouse heating causes not only the high cost and low quality of agricultural products, but also the environmental pollution of farm village. To solve these problems it is desirable to maximize the solar energy utilization for the heating of greenhouse in winter season. In this study phase change materials were selected to store solar energy concentratively for heating the greenhouse and their characteristics of thermal energy storage were analyzed. The results were summarized as follows. The organic $C_{28}H_{58}$, and the inorganic $CH_3COONa{\cdot}3H_2O\;and\;Na_2SO_4{\cdot}10H_2O$ were selected as low temperature latent heat storage materials. The equation of critical radius was derived to define the generating mechanism of the maximum latent heat of phase change materials. The melting point of $C_{28}H_{58}$ was $62^{\circ}C$, and the latent heat was $50.0{\sim}52.0kcal/kg$. The specific heat of liquid and solid phase was $0.54{\sim}0.69kcal/kg^{\circ}C$ and $0.57{\sim}0.75kcal/kg^{\circ}C$ respectively. The melting point of $CH_3COONa{\cdot}3H_2O$ was $61{\sim}62^{\circ}C$, the latent heat was $64.9{\sim}65.8$ kcal/kg and the specific heat of liquid and solid phase was respectively $0.83kcal/kg^{\circ}C$ and $0.51{\sim}0.52kcal/kg^{\circ}C$. The melting point of $Na_2SO_4{\cdot}10H_2O$ was $30{\sim}30.9^{\circ}C$, the latent heat was 53.0 kcal/kg and the specific heat of liquid and solid phase was respectively $0.78{\sim}0.89kcal/kg^{\circ}C$ and $0.50{\sim}0.7kcal/kg^{\circ}C$ When the urea of 21.85% was added to control the melting point of $Na_2SO_4{\cdot}10H_2O$ and the phase change cycles were repeated from 0 to 600, the melting point was $16.7{\sim}16.0^{\circ}C$ and the latent heat was $36.0{\sim}28.0kcal/kg^{\circ}C$.

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A Study on Thermal Properties of Rocks from Gyeonggi-do Gangwon-do, Chungchung-do, Korea (경기도, 강원도, 충청도 일대의 암석 열물성 특성 연구)

  • Park, Jeong-Min;Kim, Hyoung-Chan;Lee, Young-Min;Song, Moo-Young
    • Economic and Environmental Geology
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    • v.40 no.6
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    • pp.761-769
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    • 2007
  • We made 712 thermal property measurements on igneous, metamorphic and sedimentary rock samples from Gyeonggi-do, Gangwon-do and Chungchung-do, Korea. The average thermal conductivities of igneous, metamorphic and sedimentary rocks are 3.58W/m-K, 4.16W/m-K and 4.53W/m-K, respectively. Thermal conductivity of granite and gneiss are 2.13-5.87W/m-K and 2.26-6.67W/m-K, with average values of 3.57W/m-K and 3.945W/m-K, respectively. The average of thermal diffusivities are $1.43mm^2/sec\;and\;1.55mm^2/sec$, respectively; the average of specific heat values are 0.914J/gK, 0.912J/gK for granite and gneiss samples, respectively. The thermal conductivity of a rock type generally have a wide range because it depends on various factors such as dominant mineral phase, micro-structure, anisotropy, and so on.

Thermophysical Properties of $UO_2$ Fuel Materials

  • Lee, Hung-Joo;Kim, Chul-Whan
    • Nuclear Engineering and Technology
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    • v.8 no.2
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    • pp.81-88
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    • 1976
  • A flash method for measuring the unknown thermal property (the density, specific heat, or thermal diffusivity could be chosen as unknown) is described. The thermal diffusivity of UO$_2$ fuel samples is obtained from room temperature (300 K) to high temperature (1400 K). The specific heat is measured using a commercially available differential scanning calorimeter from room temperature to 500 K. The thermal conductivity of UO$_2$ fuel samples is calculated from the density, thermal diffusivity, and specific heat at constant pressure. The present results are in complete agreement with the usual trends for the thermal conductivity of dielectric materials, in which impurity levels are very important at low temperatures but become relatively unimportant at high temperatures. In addition, the thermal diffusivity values at room temperature are reexamined by measuring the thermal diffusivity of several UO$_2$ fuel samples with same level of doped Gd$_2$O$_3$.

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Microbial Decontamination of Vegetables and Spices Using Cold Plasma Treatments (비열 플라즈마 처리를 이용한 채소와 향신료의 미생물 저감화)

  • Kim, Jung Eun;Kim, In-Hah;Min, Sea C.
    • Korean Journal of Food Science and Technology
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    • v.45 no.6
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    • pp.735-741
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    • 2013
  • Effects of cold plasma treatment (CPT) against Salmonella Typhimurium inoculated on cabbage and lettuce, naturally occurring bacteria in black pepper powder and red pepper powder, and Bacillus cereus inoculated onto red pepper powder were investigated. The numbers of S. Typhimurium on cabbage and lettuce were reduced by $1.5{\pm}0.2CFU/cm^2$ (900W, 5 min) and $1.1{\pm}0.1$ log $CFU/cm^2$ (900W, 10 min), respectively. The numbers of naturally occurring aerobic bacteria in both black pepper powder and red pepper powder were reduced by $2.3{\pm}0.3$ and $0.6{\pm}0.2$ log CFU/g, respectively. The numbers of B. cereus vegetative cells on red pepper powder were reduced by $1.5{\pm}0.1$ log CFU/g, but the numbers of spores remained unchanged. The inhibition of S. Typhimurium on cabbage was adequately described by Fermi's model and the Weibull model. The predicted optimum treatment power and time for S. Typhimurium inoculated onto cabbage were 746 W and 6.8 min, respectively. Our results indicate that CPT represents a useful method for microbial decontamination of vegetables and spices.

A Study on Cooling Characteristics of Clathrate Compound with Concentration of TMA (TMA 농도에 따른 포접화합물의 냉각특성에 대한 연구)

  • Kim Jin-Heung;Chung Nak-Kyu;Kim Chang-Oh
    • Journal of Energy Engineering
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    • v.14 no.1
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    • pp.18-23
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    • 2005
  • This study is investigated the cooling characteristics of the TMA clathrate compound including TMA (Tri-methyl-amine, (CH₃)₃N) of 20~25 wt% as a low temperature storage material at -5℃ heat source. The results showed that as the concentration of TMA is increased, phase change temperature and specific heat are increased, but the supercooling and retention time of liquid phase are decreased. Especially, low temperature storage material containing TMA 25 wt% has the average of phase change temperature of 5.8℃, supercooling of 8.0℃, retention time of liquid phase for 10 minutes and specific heat of 4.099 kJ/kg℃ in the cooling process. From the results of this study, TMA clathrate compound showed higher phase change temperature than water md supercooling repression effect.

A Study on Physicochemical Characteristics of Hydrogen Gas Explosion (수소가스 폭발의 물리화학적 특성 연구)

  • Jo, Young-Do
    • Journal of the Korean Institute of Gas
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    • v.16 no.1
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    • pp.8-14
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    • 2012
  • Hydrogen is considered to be the most important future energy carrier in many applications reducing significantly greenhouse gas emissions, but the explosion safety issues associated with hydrogen applications need to be investigated and fully understood to be applicable as the carrier. The risk associated with a explosion depends on an understanding of the impacts of the explosion, particularly the pressure-time history during the explosion. This work provides the effects of explosion parameters, such as specific heat ratio of burned and unburned gas, equilibrium maximum explosion pressure, and burning velocity, on the pressure-time history with flame growth model. The pressure-time history is dominantly depending on the burning velocity and equilibrium maximum explosion pressure of hydrogen-air mixture. The pressure rise rate increase with the burning velocity and equilibrium maximum explosion pressure. The specific heat ratio of unburned gas has more effect on the final explosion pressure increase rate than initial explosion pressure increase rate. However, the specific heat ratio of burned gas has more influence on initial explosion pressure increase rate. The flame speeds are obtained by fitting the experimental data sets. The flame speeds for hydrogen in air based on our experimental data is very low, making a transition from deflagration to detonation in a confined space unlikely under these conditions.

Mechanical and Thermal Characteristics of Cement-Based Composite for Solar Thermal Energy Storage System (태양열 에너지 저장시스템 적용을 위한 시멘트 기반 복합재료의 역학 및 열적 특성)

  • Yang, In-Hwan;Kim, Kyoung-Chul
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.4
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    • pp.9-18
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    • 2016
  • The thermal and mechanical properties of fiber-reinforced cement-based composite for solar thermal energy storage were investigated in this paper. The effect of the addition of different cement-based materials to Ordinary Portland cement on the thermal and mechanical characteristics of fiber-reinforced composite was investigated. Experiments were performed to measure mechanical properties including compressive strength before and after thermal cycling and split tensile strength, and to measure thermal properties including thermal conductivity and specific heat. Test results showed that the residual compressive strength of mixtures with OPC and slag was greatest among cement-based composite. Thermal conductivity of mixtures including graphite was greater than that of any other mixtures, indicating favor of graphite for improving thermal transfer in terms of charging and discharging in thermal energy storage system. The addition of CSA or zirconium increased specific heat of fiber-reinforced cement-based composite. Test results of this study could be actually used for the design of thermal energy storage system in concentrating solar power plants.