• Title/Summary/Keyword: 비선형 공정 특성

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Effect of Polymerization Condition on Atom Transfer Radical Copolymerization Behaviors of Styrene with Methyl Acrylate (스티렌과 메틸아크릴레이트의 원자 이동 라디칼 공중합에서 중합조건에 따른 중합 특성 연구)

  • Song, Seon-Ja;Ko, Young Soo
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.676-680
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    • 2011
  • Investigated was the effect of the crucial polymerization conditions such as methyl acrylate(MA) mole fraction in feed, polymerization temperature and time on Atom Radical Transfer Polymerization(ATRP) behavior of styrene and methyl acrylate(MA). As MA mole fraction in feed increased, molecular weight(MW) of the resulting copolymer increased. At polymerization time of 3 hrs the composition of MA in the resulting copolymer was shown to have a linear relationship with the mole fraction of MA in feed. MW was increased and the composition of MA in copolymer was decreased as the polymerization time increased, showing the characteristics of ATRP. MW was also increased as polymerization temperature increased, and the composition of MA in copolymer was shown to be increased drastically at polymerization temperature of $110^{\circ}C$.

Modeling of Foam Separator for Sea Water Treatment (해수 포말분리공정의 해석 및 모델)

  • HUR Hyun-Chul;SEO Jae-Koan;PARK Eun-ju;KIM Sung-Koo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.2
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    • pp.165-169
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    • 1999
  • Experiments were conducted to evaluate a experimental model developed for the protein removal by foam separation. The foam separator was operated in well-mixed tank which would be considered as a completely mixed condition. The feasibility of foam separation to remove protein from sea water was investigated. Protein removal characteristics of the foam separator were obtained by batch experiments. To find the effect of the operating parameter to protein removal rate, the foam separation was carried with variation of initial protein concentration and superficial air velocity. The result indicated that the protein removal efficiency was increased with increasing protein concentration and superficial air velocity. The relationship between operation parameters and protein removal rate were evaluated by non-linear regression as the form of exponential function, Using both relationships, the simplified model was determined. The simplified foam separator operation model was verified by the batch operation. The simulation results showed a good relationship with the experimental data.

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The Design of Continuous-Time MOSFET-C Filter (연속시간의 MOSFET-C 필터 설계)

  • 최석우;윤창훈;조성익;조해풍;이종인;김동용
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.18 no.2
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    • pp.184-191
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    • 1993
  • Continuous-time integrated filters, implemented in MOS VLSI technology, have been receiving considerable attention. In this paper, a continuous-time fifth order elliptic low-pass MOSFET-C filter has been designed with a cutoff frequency 3,400Hz. First an active RC filter is designed using cascade method which each block can be tunable. And then the resistors of an active RC network are replaced by a linear resistor using NMOS depletion transistors operated in the triode region. This continuous-time MOSFET filter have simpler structure than switched-capacitor filter, so reduce the chip area. The designed MOSFET-C filter characteristics are simulated by PSPICE program.

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Material Properties of Polymer-Impregnated Concrete and Nonlinear Fracture Analysis of Flexural Members (폴리머 침투콘크리트의 재료특성과 휨부재의 비선형 파괴해석)

  • 변근주;이상민;최홍식;노병철
    • Magazine of the Korea Concrete Institute
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    • v.6 no.2
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    • pp.97-107
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    • 1994
  • The objective of this study is to develop polymer-impregnated concrete(PIC), which is a newly developed composite material made by impregnating polymer impregnanls into hardened normal concrete, and to develop analytical techniques for its proper applications. Crystalline methyl methacrylate(MMA) is chosen as a monomer of polymer impregnants. The corrlpositions of polymer impregnants and producing processes are developed by analyzing the effects of penetration, polymerization, thermal safety, and strengthening characteristics. On t he basis of experimental results of this study, various strength characteristics and stress strain constitutive relations are formulated in terms of the compressive strength of normal concrete and the polymer loadings, which can be applied for analysis and design of PIC members. In order to provide a model for fracture analysis of flexural members, fracture toughness, fracture energy, critical crack width, and tension softening relations near crack tip are also formulated in terms of member depth, initial notch depth, and the flexural strength of normal concrete. The structural analysis procedure and the finite element computer program developed in the study are applicable to evaluate elastic behavior, ultimate strength, and tension softening behavior of MMA type PIC structural members subject to various loading conditions. The accuracy and effectiveness of the developed computer program is examined by comparing the anal ytical results with the experimental results. Therefore, it is concluded that the developed structural analysis procedure and the finite element computer program are applicable to analysis and design of in-situ and precast PIC structural members.

A CMOS Switched-Capacitor Interface Circuit for MEMS Capacitive Sensors (MEMS 용량형 센서를 위한 CMOS 스위치드-커패시터 인터페이스 회로)

  • Ju, Min-sik;Jeong, Baek-ryong;Choi, Se-young;Yang, Min-Jae;Yoon, Eun-jung;Yu, Chong-gun
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2014.10a
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    • pp.569-572
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    • 2014
  • This paper presents a CMOS switched-capacitor interface circuit for MEMS capacitive sensors. It consist of a capacitance to voltage converter(CVC), a second-order ${\Sigma}{\Delta}$ modulator, and a comparator. A bias circuit is also designed to supply constant bias voltages and currents. This circuit employes the correlated-double-sampling(CDS) and chopper-stabilization(CHS) techniques to reduce low-frequency noise and offset. The designed CVC has a sensitivity of 20.53mV/fF and linearity errors less than 0.036%. The duty cycle of the designed ${\Sigma}{\Delta}$ modulator output increases about 5% as the input voltage amplitude increases by 100mV. The designed interface circuit shows linearity errors less than 0.13%, and the current consumption is 0.73mA. The proposed circuit is designed in a 0.35um CMOS process with a supply voltage of 3.3V. The size of the designed chip including PADs is $1117um{\times}983um$.

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Characteristics of Gas Furnace Process by Means of Partition of Input Spaces in Trapezoid-type Function (사다리꼴형 함수의 입력 공간분할에 의한 가스로공정의 특성분석)

  • Lee, Dong-Yoon
    • Journal of Digital Convergence
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    • v.12 no.4
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    • pp.277-283
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    • 2014
  • Fuzzy modeling is generally using the given data and the fuzzy rules are established by the input variables and the space division by selecting the input variable and dividing the input space for each input variables. The premise part of the fuzzy rule is presented by selection of the input variables, the number of space division and membership functions and in this paper the consequent part of the fuzzy rule is identified by polynomial functions in the form of linear inference and modified quadratic. Parameter identification in the premise part devides input space Min-Max method using the minimum and maximum values of input data set and C-Means clustering algorithm forming input data into the hard clusters. The identification of the consequence parameters, namely polynomial coefficients, of each rule are carried out by the standard least square method. In this paper, membership function of the premise part is dividing input space by using trapezoid-type membership function and by using gas furnace process which is widely used in nonlinear process we evaluate the performance.

The Assessing Comparative Study for Statistical Process Control of Software Reliability Model Based on polynomial hazard function (다항 위험함수에 근거한 NHPP 소프트웨어 신뢰모형에 관한 통계적 공정관리 접근방법 비교연구)

  • Kim, Hee-Cheul;Shin, Hyun-Cheul
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.8 no.5
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    • pp.345-353
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    • 2015
  • There are many software reliability models that are based on the times of occurrences of errors in the debugging of software. It is shown that it is possible to do parameter inference for software reliability models based on finite failure model and non-homogeneous Poisson Processes (NHPP). For someone making a decision to market software, the conditional failure rate is an important variables. In this case, finite failure model are used in a wide variety of practical situations. Their use in characterization problems, detection of outlier, linear estimation, study of system reliability, life-testing, survival analysis, data compression and many other fields can be seen from the many study. Statistical process control (SPC) can monitor the forecasting of software failure and thereby contribute significantly to the improvement of software reliability. Control charts are widely used for software process control in the software industry. In this paper, proposed a control mechanism based on NHPP using mean value function of polynomial hazard function.

Pulse DC $O_2$ 플라즈마를 이용한 PMMA와 폴리카보네이트 기판의 건식 식각

  • Park, Ju-Hong;No, Gang-Hyeon;Lee, Seong-Hyeon;Choe, Gyeong-Hun;Jo, Gwan-Sik;Lee, Je-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.105-105
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    • 2010
  • 펄스 DC $O_2$플라즈마를 이용하여 PMMA와 폴리카보네이트 기판을 건식 식각 한 후 그 결과에 대하여 분석하였다. 식각 공정 변수는 펄스 파워 (300~500 V), 펄스 시간 ($0.5{\sim}2.0\;{\mu}s$), 펄스 주파수 (100~250 kHz)의 변화이었다. 특성 분석은 PMMA와 폴리카보네이트의 식각률, 두재료의 포토레지스트에 대한 식각 선택도, 식각 후 표면 거칠기 변화에 대해 실시하였다. 또한 주사 전자 현미경을 이용하여 식각 후 패턴의 표면 형상을 관찰하였다. 실험 결과, PMMA의 식각률이 폴리카보네이트보다 높음을 알 수 있었다. 펄스 파워를 300 V 에서 500 V로 증가함에 따라 PMMA의 식각률은 $0.17\;{\mu}m/min$ 에서 $0.53\;{\mu}m/min$ 로 증가하였다. 폴리카보네이트는 같은 식각 조건에서 $0.09\;{\mu}m/min$ 에서 $0.22\;{\mu}m/min$ 로 증가하였다. 그 이유는 폴리카보네이트의 경우, 결합력이 큰 벤젠 분자 구조를 포함하고 있기 때문에 PMMA보다 식각률이 더 낮다고 추측한다. 또한 PMMA 와 폴리카보네이트의 포토레지스트에 대한 식각 선택비는 펄스 파워가 증가함에 따라 같이 증가하는 것을 알 수 있었다. 5 sccm O2, 55 mTorr 공정 압력, 400 V 펄스 파워, 200 kHz 펄스 주파수의 조건에서 펄스 시간이 $0.5\;{\mu}s$ 에서 $1.0\;{\mu}s$ 로 증가할 때 PMMA와 폴리카보네이트의 식각률은 거의 변화가 없었다. 그러나 같은 조건에서 펄스 시간이 $1.0\;{\mu}s$ 에서 $2.0\;{\mu}s$ 로 증가한 경우에는 PMMA와 폴리카보네이트의 식각률은 선형적으로 증가하였다. 펄스 시간이 고분자 소재의 건식 식각에 영향을 줄 수 있다는 사실을 알 수 있었다. 주사현미경을 이용하여 식각된 표면 형상을 분석한 결과, 폴리카보네이트가 PMMA보다 표면이 매끈하게 관찰되었다. 요약하면, 펄스 DC $O_2$플라즈마는 PMMA와 폴리카보네이트 등의 고분자 소재의 건식 식각에 중요하게 활용될 수 있다는 사실을 본 연구를 통해 이해할 수 있다.

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An Implementation of Temperature Independent Bias Scheme in Voltage Detector (온도에 무관한 전압검출기의 바이어스 구현)

  • Moon, Jong-Kyu;Kim, Duk-Gyoo
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.39 no.6
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    • pp.34-42
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    • 2002
  • In this paper, we propose a temperature independent the detective voltage source in voltage detector. The value of a detective voltage source is designed to become m times of silicon bandgap voltage at zero absolute temperature. By properly choosing the temperature coefficient of diode, the temperature coefficient of a concave voltage nonlinearities generated by the ${\Delta}V_{BE}$ section of diode between base and emitter of transistors with a different area can be summed with convex nonlinearities the $V_{BE}$ voltage to achieve the near zero temperature coefficient of the detective voltage source. We designed that the value of a detective voltage can be varied by ${\Delta}V_{BE}$, the $V_{BE}$multiplier circuit and resistor. In order to verify the performance of a proposed detective voltage source, we manufactured the voltage detector IC for 1.9V which is fabricated in $6{\mu}m$ Bipolar technology and measured the operating characteristics, the temperature coefficient of a detective voltage. To reduce the deviation of a detective voltage in the IC process step, we introduced a trimming technology, ion implantation and an isotropic etching. In manufactured IC, the detective voltage source could achieve the stable temperature coefficient of 29ppm/$^{\circ}C$ over the temperature range of -30$^{\circ}C$ to 70$^{\circ}C$. The current consumption of a voltage detector constituted by the proposed detective voltage source is $10{\mu}A$ from 1.9V-supply voltage at room temperature.

광대역 및 전방향 높은 투과도를 갖는 사파이어 나노구조 제작 및 광학적 특성연구

  • Kim, Myeong-Seop;Im, Jeong-U;Go, Yeong-Hwan;Jeong, Gwan-Su;Yu, Jae-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.338-338
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    • 2012
  • 사파이어 ($Al_2O_3$)는 높은 밴드갭 에너지 (~19.5 eV)를 가진 물질로서 우수한 내마모성, 강도, 전기 절연성 및 안정한 화학적 특성을 갖고 발광다이오드 기판, 보석재료 등 각종 산업 및 기술적 분야에서 널리 사용되고 있다. 특히, 플립칩 발광다이오드 구조의 경우 광추출효율을 향상시키기 위해 높은 투과도를 갖는 사파이어 기판이 요구되어 왔으며, 지금까지 건식/습식식각방법을 이용한 사파이어 표면에 마이크로 크기의 심한 거칠기 또는 요철이 형성된 나노크기의 격자구조를 형성시키는 연구가 진행되어 오고 있다. 그 중, 나노 크기의 격자구조는 공기에서 반도체 기판까지 선형적인 유효굴절률 분포를 갖기 때문에 표면에서 생기는 Fresnel 반사 손실을 줄일 수 있다. 이러한 구조를 형성하기 위해서는 식각 마스크가 필요한데, 형성 방법으로 레이저 간섭 리소그래피, 전자빔 리소그래피, 나노임프린트 리소그래피 등이 있으나, 비싼 가격과 복잡한 공정 절차 등의 단점을 지니고 있다. 따라서 본 연구에서는 식각 마스크 패턴을 위해, 보다 저렴하고 간단한 실리카 나노구 및 열적응집 금 나노 입자를 이용하였다. 양면 폴리싱 c-plane 사파이어 기판을 사용하였고, 단일 층의 주기적인 실리카 나노구를 기판 표면에 스핀코팅에 의해 도포한 후 유도결합플라즈마 식각 장비를 이용하여 식각하여 주기적인 패턴을 갖는 렌즈모양의 격자구조를 형성하였다. 그리고 주기적으로 형성된 격자 위에 열 증착기를 이용하여 금 박막을 증착한 후 급속열적어닐닝(rapid thermal annealing)을 이용하여 열처리함으로써 비주기적인 금 나노입자를 형성시켰다. 형성된 금 나노패턴을 이용하여 동일한 조건으로 식각함으로써 광대역 및 전방향성 높은 투과도를 갖는 원뿔 모양의 사파이어 나노구조를 제작하였다. 제작된 샘플의 패턴 및 식각 형상은 전자현미경을 사용하여 관찰하였으며, UV-vis-NIR 분광광도계 (spectrophotometer)를 사용하여 투과율을 측정하였다. 렌즈 모양 표면 위에 원뿔모양의 나노구조를 갖는 사파이어 기판은 일반적인 사파이어 기판보다 향상된 투과율 특성을 보였다.

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