• Title/Summary/Keyword: 비등 곡선

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The Generation of Vacuum Scale Using the Vapour Pressure of Water (물의 증기압을 이용한 진공도눈금의 생성)

  • Seong D. J.;Shin Y. H.;Chung K. H.
    • Journal of the Korean Vacuum Society
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    • v.14 no.4
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    • pp.180-185
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    • 2005
  • The possibility of generation of the vacuum scale using the vapour pressure of water was evaluated. The range of vacuum from 3.3 kPa to 101.3 kPa was corresponds the vapour pressure of water in the temperature range from $25^{\circ}C$ to $100^{\circ}C$ The measured values of the vapour pressure of water were agreed within the deviation of $5\%$ comparing to reference value. This result shows the vapour pressure of water can be used as an secondary reference of the vacuum scale. Moreover it shows the thermo-dynamical properties such as, triple point, temperature-pressure curve of a material have a applicability in the vacuum scale as a reference in corresponding range of vacuum.

Development of an anisotropic spatial interpolation method for velocity in meandering river channel (비등방성을 고려한 사행하천의 유속 공간보간기법 개발)

  • You, Hojun;Kim, Dongsu
    • Journal of Korea Water Resources Association
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    • v.50 no.7
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    • pp.455-465
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    • 2017
  • Understanding of the two-dimensional velocity field is crucial in terms of analyzing various hydrodynamic and fluvial processes in the riverine environments. Until recently, many numerical models have played major roles of providing such velocity field instead of in-situ flow measurements, because there were limitations in instruments and methodologies suitable for efficiently measuring in the broad range of river reaches. In the last decades, however, the advent of modernized instrumentations started to revolutionize the flow measurements. Among others, acoustic Doppler current profilers (ADCPs) became very promising especially for accurately assessing streamflow discharge, and they are also able to provide the detailed velocity field very efficiently. Thus it became possible to capture the velocity field only with field observations. Since most of ADCPs measurements have been mostly conducted in the cross-sectional lines despite their capabilities, it is still required to apply appropriate interpolation methods to obtain dense velocity field as likely as results from numerical simulations. However, anisotropic nature of the meandering river channel could have brought in the difficulties for applying simple spatial interpolation methods for handling dynamic flow velocity vector, since the flow direction continuously changes over the curvature of the channel shape. Without considering anisotropic characteristics in terms of the meandering, therefore, conventional interpolation methods such as IDW and Kriging possibly lead to erroneous results, when they dealt with velocity vectors in the meandering channel. Based on the consecutive ADCP cross-sectional measurements in the meandering river channel. For this purpose, the geographic coordinate with the measured ADCP velocity was converted from the conventional Cartesian coordinate (x, y) to a curvilinear coordinate (s, n). The results from application of A-VIM showed significant improvement in accuracy as much as 41.5% in RMSE.

The Behavior of Overall Strain Range in Undrained Triaxial Compression Tests for a Weathered Soil (풍화토의 비배수 삼축압축시험시 전체 변형률 영역의 거동에 관한 연구)

  • 안영대;오세붕;고동희;김동수
    • Journal of the Korean Geotechnical Society
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    • v.18 no.1
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    • pp.29-39
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    • 2002
  • In order to evaluate the behavior of overall range from small strain to failure, the triaxial compression tests with LVDTs were performed for local displacement measurements. According to the result it was possible to evaluate the total range behavior from 0.001% to 10% and both secant moduli of undisturbed and disturbed weathered soils had a similar result in the small slain level. The normalized shear moduli$(G/G_{max})$ in the undrained triaxial compression tests were similar to those of resonant column tests but the maximum shear moduli$(G/G_{max})$ were strongly affected by the ratio of saturation. As a result of parametric study a constitutive model with anisotropic hardening could predict the behavior of total strain range.

Optimum Reaction Kinetics Model of Heat-resistant and Flame-Retardant Polymethyl Methacrylate (내열 및 난연성 Polymethyl Methacrylate의 최적 반응속도 모델에 관한 연구)

  • Kim, Dong-Keun;Seul, Soo-Duk;Sohn, Jin-Eon
    • Elastomers and Composites
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    • v.22 no.4
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    • pp.324-332
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    • 1987
  • The thermal degradation of the homopolymer poly(methyl methacrylate) (PMMA) and flame-retardant tetrabrormobisphenol-A(TBBA) as well as of their blends were carried out using the thermogravimetric method in the stream of nitrogen gas with 60ml/min at various heating rate from 1 to $20^{\circ}C/min$. Friedman and Ozawa mathematical methods were used to obtain the value of activation energy.

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Numerical Analysis of the Effects of Stress Anisotropy and Tunnel Excavation Shape on Initial Elastic-wall Displacement (지반응력의 비등방성에 따른 터널측벽의 초기탄성변위 특성에 대한 수치해석적 연구)

  • 김상환;정혁일
    • Journal of the Korean Geotechnical Society
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    • v.18 no.6
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    • pp.33-42
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    • 2002
  • Ground reaction curve is a very important information for evaluating the side wall displacements and installation time of the tunnle support. The ground reaction curve can be estimated by analytical closed form solutions derived on the supposition of circular section and isotropic stress condition. The conditions of stress field and tunnel configurations, however, are quite different in practice. Therefore, it is necessary to investigate the effects of stress anisotropy and tunnel configurations in order to use simply in practical design. This paper describes a study of influence factors in the ground reaction curve. In order to evaluate the applicability of analytical closed form solution in practical design, two sets of parametric studies were carried out by numerical analysis in elastic tunnel behaviour: one set of studies investigated the influence of the K and the other set investigated the influence of the tunnel configurations such as circular and horse-shoe shape. In the studies, K value varies between 0.5 and 3.0, initial ground vertical stress varies between 5~30MPa far each K values. The results indicated that the self-supportability of ground is larger in the ground having lower K value. However, it is suggested that the applicability of closed form solution may not be adequate to determine directly the installation time of the support and self-supportability of ground. It is necessary to consider stress anisotropy and tunnel configurations.

Analysis of Magnetic Isotropy Property using Magnetoresistance Curve of CoFe/Cu/CoFe/PtMn Multilayer Film (CoFe/Cu/CoFe/PtMn 다층박막의 자기저항 곡선을 이용한 자기 등방성 특성 분석)

  • Choi, Jong-Gu;Kim, Su-Hee;Choi, Sang-Heon;Lee, Sang-Suk;Rhee, Jang-Roh
    • Journal of the Korean Magnetics Society
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    • v.27 no.4
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    • pp.123-128
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    • 2017
  • The magnetic isotropy property from the magnetoresistance (MR) curve and magnetization (MH) loop for the PtMn based spin valve (SV) multilayer films fabricated with different the bottom structure after post-annealing treatment was investigated. The exchange biased coupling field ($H_{ex}$), coercivity ($H_c$), and MR ratio of Glass/Ta(10 nm)/CoFe(6 nm)/Cu(2.5 nm)/CoFe(3 nm)/Ta(4 nm) SV multilayer film without antiferromagnetic PtMn layer are 0 Oe, 25 Oe, and 3.3 %, respectively. MR curve for the Glass/Ta(10 nm)/CoFe(6 nm)/Cu(2.5 nm)/CoFe(3 nm)/PtMn(6 nm)/Ta(4 nm) SV multilayer film showed $H_{ex}=2Oe$, $H_c=316Oe$, and MR (%) = 4.4 % with one butterfly MR curve having by the effect of antiferromagnetic PtMn layer. MR curve for the dualtype Glass/Ta(10 nm)/CoFe(6 nm)/Cu(2.5 nm)/CoFe(3 nm)/PtMn(6 nm)/CoFe(3 nm)/Cu(2.5 nm)/CoFe(6 nm)/Ta(4 nm) SV multilayer film showed $H_c=37.5Oe$ and 386 Oe, MR = 3.5 % and 6.5 % with two butterfly MR curves and square-like hysteresis MH loops. The anisotropy property in CoFe spin valve-PtMn multilayer is neglected by the effects of a very small value of $H_{ex}$ and a very slightly shape magnetic anisotropy. This result is possible to explain the effect of magnetization configuration spin array of the bottom SV film and the top SV film of PtMn layer.

Geochemistry of Cu-Pb-Zn-Ag Deposits from the Euiseong Mineralized Area (의성 광화대 동-연-아연-은 광상의 지화학적 연구)

  • Chi, Se-Jung;Doh, Seong-Jae;Choi, Seon-Gyu;Lee, Jae-Ho
    • Economic and Environmental Geology
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    • v.22 no.3
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    • pp.253-266
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    • 1989
  • The Cu-Pb-Zn-Ag hydrothermal vein type deposits which comprise the Dongil and Dong-cheogogsan mines occur within the Cretaceous sedimentary rocks in the Euiseong Basin of the southern Korean peninsula. The ore mineralization is contained within three stage(I,II and III) quartz and calcite veins. Ore minerals occur as dominant chalcopyrite, galena, sphalerite, tetrahedrite and Pb, Ag, Sb and Bi-bearing sulfosalts. Stage I ore minerals were deposited between $400^{\circ}C$ and $200^{\circ}C$ from the fluid with moderate salinities(7.0 to 4.5 eq. wt. % NaCl). Evidence of boiling suggests pressure of less than 150 bars during stage I mineralization. This pressure corresponds to maximum depths of 650 m and 1700 m, respectively, assuming lithostatic and hydrostatic loads. The data on mineralogy, temperature and salinity, together with information on the solubility of Cu complex, suggest that Cu deposition is a result of boiling coupled with declining temperature from $350^{\circ}$ to $250^{\circ}C$ or declining log $a_{o_2}$(from -29.8 to -35.9 atm.)and increasing in pH. Pb, Ag, Sb and Bi-bearing sulfosalts were deposited by cooling and dilution at temperature of less than $250^{\circ}C$ from the ore fluid with less than -35.9 atm. of log $a_{o_2}$.

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Numerical Simulations of Cellular Secondary Currents in Open-Channel Flows using Non-linear k-ε Model (비선형 k-ε 모형을 이용한 개수로 흐름에서의 격자형 이차흐름 구조 수치모의)

  • Kang, Hyeongsik;Choi, Sung-Uk;Park, Moonhyeong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.6B
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    • pp.643-651
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    • 2008
  • In the present paper, turbulent open-channel flows over longitudinal bedforms are numerically simulated. The Reynolds- averaged Navier-Stokes equations in curvilinear coordinates are solved with the non-linear $k-{\varepsilon}$ model by Speziale( 1987). First, the developed model is applied to rectangular open channel flows for purposes of model validation and parameter sensitivity studies. It is found that the parameters $C_D$ and $C_E$ are important to the intensity of secondary currents and the level of turbulent anisotropy, respectively. It is found that the non-linear $k-{\varepsilon}$ model can hardly reproduce the turbulence anisotropy near the free surface. However, the overall pattern of the secondary currents by the present model is seen to coincide with measured data. Then, numerical simulations of turbulent flows over longitudinal bedforms are performed, and the simulated results are compared with the experimental data in the literature. The simulated secondary currents clearly show upflows and downflows over the ridges and troughs, respectively. The numerical results of secondary currents, streamwise mean velocity, and turbulence structures compare favorably with the measured data. However, it is observed that the secondary currents towards the troughs were significantly weak compared with the measured data.

Thermal Characterization for HTPE IM Propellants (HTPE 둔감 추진제의 열특성)

  • Yoo, Ji-Chang;Kim, Jun-Hyung;Kim, Chang-Kee;Seo, Tae-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.177-180
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    • 2009
  • This study was investigated to know the thermal decomposition for the propellant ingredients and 2 kinds of HTPE propellants. The thermal analysis of the propellant ingredients used in this study showed that the thermal stability of these materials decreases in the following order : AP > HTPE > AN > BuNENA. In addition, propellant HTPE 002 containing AN showed that an endothermic process at around $125^{\circ}C$ corresponding to the solid-solid phase change($II{\rightarrow}I$) of AN was followed by the exothermic process due to decomposition of BuNENA/AN until $200^{\circ}C$. The critical temperature, $T_c$, of thermal explosion for the propellants HTPE 001 and HTPE 002, were obtained from the non-isothermal curves at various heating rates, by using Semenov's thermal explosion theory. Kissinger's method was employed to obtain the activation energy of the thermal decomposition, and it was used to calculate the $T_c$.

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A Study on the Kinetics of Thermal Degradation of Polyethylene (폴리에틸렌 열분해의 속도론적 연구)

  • Kim, Myung Soo;Oh, Sea Cheon;Lee, Hae Pyeong;Kim, Hee Taik;Yoo, Kyong Ok
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.548-556
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    • 1999
  • The thermal degradation of polyethylene has been studied using a nonisothermal thermogravimetric technique under a nitrogen atmosphere condition at several heating rates from 10 to $50^{\circ}C/min$. To obtain information on the kinetic parameters, the dynamic thermogravimetric analysis curve and its derivative have been analyzed by a variety of analytical methods such as Kissinger, Freeman-Carroll, Flynn-Wall, Coats-Redfern, Chatterjee-Conrad, Friedman, Horowitz-Metzger, Ozawa and Denq methods. The comparative works for the kinetic results obtained from various methods should be performed to determine the kinetic parameters, because three are tremendous differences in the calculated kinetic parameters depending upon the mathematical method taken in the analysis. From this work, it was found that the apparent activation energy of HDPE was larger than those of LDPE and LLDPE.

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