• Title/Summary/Keyword: 비결정질

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Absorption Characteristics of Amorphous Metal during Processing with Nd:YAG laser (Nd:YAG 레이저를 이용한 비결정질 재료의 용접 시 레이저의 흡수 거동)

  • 이건상
    • Laser Solutions
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    • v.2 no.1
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    • pp.43-50
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    • 1999
  • For the conventional welding method. the high heat transfer makes the crystallized zone of the work material unavoidable. Whereas the laser is able to weld the amorphous metal without a crystallized zone, because heat transfer is limited within a very small restricted volume. In this paper, the possibilities and the limits of the laser welding were studied to utilize the advantageous properties of amorphous metal foils.

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Investigation of the Properties of Laser-Welded Amorphous Metal in a Deep Frozen Environment (극저온 환경하에서 레이저 용접된 비결정질 재료의 특성에 관한 연구)

  • 이건상
    • Journal of Welding and Joining
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    • v.15 no.3
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    • pp.99-108
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    • 1997
  • For the conventional welding method, the high heat transfer makes the crystallization of the work material unavoidable. Whereas the laser is able to weld the amorphous metal without a crystallized zone, because heat transfer is limited withn a very small restricted volume. In this paper, the possibilities and the limits of the laser welding in a deep frozen environment by liquid nitrogen were studied to utilize the advantageous properties of amorphous metal foils. The author investigated, after laser welding in a deep frozen environment with a solid state laser (Nd:YAG-laser), the achievable strengths and the influences of the laser beam parameters on the strengths.

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Electric characteristics of poly-Si TFT using High-k Gate-dielectric and excimer laser annealing (Excimer laser annealing에 의한 결정화 및 High-k Gate-dielectric을 사용한 poly-Si TFT의 특성)

  • Lee, Woo-Hyun;Koo, Hyun-Mo;Oh, Soon-Young;Ahn, Chang-Geun;Jung, Jong-Wan;Cho, Won-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.19-19
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    • 2007
  • Excimer laser annealing (ELA) 방법을 이용하여 결정화하고 게이트 절연체로써 high-k 물질을 가지는 다결정 실리콘박막 트랜지스터의 전기적 특성을 평가하였다. 다결정 실리콘 박막 트랜지스터는 비결정질 실리콘 박막 트랜지스터 보다 높은 전계 효과 이동도와 운전 용이한 장점을 가진다. 기존의 결정화 방법으로는 다결정 실리콘 박막 트랜지스터의 높은 열 공급을 피할 수 없기 때문에, 매몰 산화막 위의 비결정질 박막은 저온에서 다결정 실리콘 결정화를 위해 KrF excimer laser (248nm)를 이용하여 가열 냉각 공정을 했다. 게다가 케이트 절연체로써 atomic layer deposition (ALD) 방법에 의해 저온에서 20 nm의 고 유전율을 가지는 $HfO_2$ 박막을 증착하였다. 알루미늄은 n-MOS 박막 트랜지스터의 게이트 전극으로 사용되었다. 금속 케이트 전극을 사용하여 게이트 공핍 효과와 관계되는 케이트 절연막 두께의 증가를 예방할 수 있고, 게이트 저항의 감소에 의해 소자 속도를 증가 시킬 수 있다. 추가적으로, 비결정질 실리콘 박막의 결정화 기술로써 사용된 ELA 방법은 SPC (solid phase crystallization) 방법과 SLS (sequential lateral solidification) 방법에 의해 비교되었다. 결과적으로, ELA 방법에 의해 결정화된 다결정 실리콘 박막의 결정도와 표면 거칠기는 SPC와 SLS 방법에 비해 개선되었다. 또한, 우리는 ELA 결정화 방법에 의한 다결정 실리콘 박막 트랜지스터로부터 우수한 소자 특성을 얻었다.

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Origin of New Broad Raman D and G Peaks in Graphene Annealed under Oxygen-Free Atmosphere

  • Hong, Jin-Pyo;Park, Min-Gyu;Lee, Eun-Jeong;Hwang, Dong-Seok;Ryu, Sun-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.610-610
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    • 2013
  • 그래핀을 구성하는 탄소 원자는 모두 표면에 존재하기 때문에, 맞닿아 있는 물질에 따라 그래핀의 물리적 특성에 민감한 영향을 미치기도 한다. 본 연구에서는 라만분광법과 원자 힘 현미경(atomic force microscopy, AFM)을 이용하여 통상적인 열처리 조건에서 그래핀에 탄화수소가 흡착될 수 있는 가능성을 탐구하였다. 산소가 없는 조건에서 열처리된 그래핀으로부터 D, G, 2D 봉우리와 겹쳐지는 폭이 넓은 새로운 라만 봉우리들이 관찰되었다. 열처리 시간, 온도 및 진공도에 따른 라만 스펙트럼의 변화와AFM에 의해 확인된 표면의 구조 변화로부터 새로이 관찰된 라만 봉우리는 탄화수소의 탄화에 의해 그래핀의 표면에 형성된 비결정성 탄소물질(amorphous carbon)임을 확인하였다. 기계적 박리법과 화학기상증착법으로 시료를 준비할 때 사용된 폴리머 잔유물이 열처리 과정에서 탄화수소를 배출하는 것으로 판단된다. 이 연구는 그래핀 소자의 작동에 있어서 환경적인 효과를 이해하고 탄화에 의해 그래핀 표면에 만들어진 비결정질 탄소를 정량화하는데 도움을 줄 것이다.

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Fundamental Research on Reactivity of Silica Source in the Rapidly Cured Inorganic Micro-Defect-Free(MiDF) Concrete (촉진 양생한 무기계 MiDF 콘크리트에서 실리카질 원료의 반응성에 관한 기초 연구)

  • Choi, Hong-Beom;Kim, Jin-Man
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.166-173
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    • 2019
  • In this paper, the reaction properties of silica source in the accelerated curing conditions using autoclave and the fundamental properties of inorganic Micro Defect Free(MiDF) concrete using silica source are studied. Studies show that Si ions elution rate from silica source in autoclave curing is higher in amorphous source. In tap water conditions, solids which is source after autoclaved curing show a higher mass reduction in amorphous materials, which is attributed to the higher elution rate of ion. In $Ca(OH)_2$ solution conditions, amorphous materials show higher mass increase, due to increase in C-S-H minerals. From experiment for influence on the properties of MiDF concrete by using nano silica materials, the specimen with silica fume shows an increase in compressive strength and a decrease in absorption depending on replacement rate up to 5.5%, while nano silica with amorphous phase and high-fineness shows a decrease in compressive strength and decrease in the water absorption. The specimen with nano silica increases the pore below 10,000nm, but reduces pore between 10,000 and 100,000nm. The above results show that the porosity and absorption rate of MiDF concrete can be reduced by using amorphous nano-size silica. However, to reduce the pore of 50 to 10,000nm, better dispersion of nano material in the cement matrix will be necessary. We will focus on the this item in the next research.

Synthesis of Cobalt Phosphates and their Catalytic Properties of the Hydrogen Generation from the Hydrolysis of NaBH4 (비결정질 코발트 인산염 합성 및 NaBH4 가수분해를 통한 수소발생 촉매 활성 연구)

  • Kim, Youngyong;Park, Joon Bum;Kwon, Ki-Young
    • Applied Chemistry for Engineering
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    • v.26 no.6
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    • pp.743-745
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    • 2015
  • Amorphous cobalt phosphates were synthesized with their distinct morphology by controlling the amount of base in the synthetic condition. The crystallinity and morphology of cobalt phosphates were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The prepared cobalt phosphates were applied as a heterogeneous catalyst for generating hydrogen gas from the hydrolysis reaction of sodium borohydride. We found that the catalyst prepared using the least amount of base condition at room temperature showed a plate shape with less than 10 nm thickness, which resulted in the best catalytic activity among all catalysts due to the large surface area.

A Droplet-Manipulation Method using Opto-thermal Flows on Amorphous Silicon Thin Film (비결정질 실리콘 박막 상에서의 광열 유동을 이용한 액적 조작)

  • Lee, Horim;Yoon, Jin Sung;Kim, Dong Sung;Lim, Geunbae
    • Journal of the Korean Society for Precision Engineering
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    • v.31 no.1
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    • pp.91-96
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    • 2014
  • We present a droplet-manipulation method using opto-thermal flows in oils. The flows are originated from Marangoni and buoyancy effects due to temperature gradient, generated by the adsorption of light on an amorphous silicon thin film. Using this method, we can transport, merge and mix droplets in an extremely simple system. Since the temperature rise during the operation is small, this method can be used for biological applications without the damage on cell viability.

High Temperature Deformation Behavior of Fe-base High Strength Alloys (고강도 Fe계 합금의 고온 변형 특성)

  • Kwon, Woon-Hyun;Choi, Il-Dong
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.6
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    • pp.938-946
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    • 2008
  • Fe-base amorphous alloy and two crystalline phases composite were fabricated. The effect of temperature and strain rate on mechanical properties was evaluated utilizing compression test. Mixture of non-crystalline and crystalline phases were found using X-ray diffraction (XRD) and differential thermal analysis (DTA) tests. Based on glass transition temperature and crystallization temperature. compression tests were performed in the temperature ranging from $560^{\circ}C$ to $700^{\circ}C$ with $20^{\circ}C$ interval. Relationship between microstructure, including fracture surface morphology, and mechanical behavior was studied. The peak stress of Fe-base amorphous alloy was over 2GPa and expected to have a good wear resistance, but it is expected hard to deform because of low ductility. The peak stress and elongation of two crystalline phases composite was over 1GPa and about 20%, therefore it is possible to deform high strength wear resistant materials such as engine valve.