• Title/Summary/Keyword: 비결정성

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A Novel Runner Design for Flow Balance of Cavities in Multi-Cavity Injection Molding (다수 빼기 사출성형에서 캐비티간 충전균형을 위한 새로운 런너의 설계)

  • Park, Seo-Ri;Kim, Ji-Hyun;Lyu, Min-Young
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.561-568
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    • 2009
  • Small injection molded articles are generally molded by multi-cavity injection molding. The most important thing in multi-cavity molding is flow imbalance among the cavities because it affects the physical property and the quality of products. The cavity filling balance can be achieved by flow balance in the runner through the thermal balance. In this study, novel screw type runner or helical type runner has been developed for the flow balance in the runner and performed experiment and computer simulation. Flow balance has been observed using various screw type runners for several resins such as amorphous and crystalline polymers including low and high viscosities grades. Flow balance experiments have been performed for various injection speeds since the flow balance can be affected by injection speed among the injection conditions. Experimental results have been compared with computational results and they showed good agreement. The cavity filling balance can be achieved by the screw runner where the temperature distribution is uniform through the circulation flow along the screw channel in the screw runner. It has been verified that the novel screw runner is very effective device in flow balance in the multi-cavity injection molding. cavity filling imbalance, multi-cavity injection molding, runner design, screw runner, thermal balance.

Synthesis of Silicon-Carbon by Polymer Coating and Electrochemical Properties of Si-C|Li Cell (고분자 도포를 이용한 실리콘-탄소의 합성 및 Si-C|Li Cell의 전기화학적 특성)

  • Doh, Chil-Hoon;Jeong, Ki-Young;Jin, Bong-Soo;An, Kay-Hyeok;Min, Byung-Chul;Choi, Im-Goo;Park, Chul-Wan;Lee, Kyeong-Jik;Moon, Seong-In;Yun, Mun-Soo
    • Journal of the Korean Electrochemical Society
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    • v.9 no.3
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    • pp.107-112
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    • 2006
  • Si-C composites were prepared by the carbonization of silicon powder covered by polyaniline(PAn). Physical and electrochemical properties of the Si-C composites were characterized by the particle size analysis, X-ray diffraction technique, scanning electron microscope, and electrochemical test of battery. The average particle size of the Si was increased by the coating of PAn and somewhat reduced by the carbonization to give silicone-carbon composites. XRD analysis' results were confirmed co-existence of crystalline silicon and amorphous-like carbon. SEM photos showed that the silicon particle were well covered with carbonacious materials depend on the PAn content. Si-C|Li cells were fabricated using the Si-C composites and were tested using the galvanostatic charge-discharge test. Si-C|Li cells gave better electrochemical properties than that of Si|Li cell. Si-C|Li cell using the Si-C from HCl undoped PAn Precursor showed better electrochemical properties than that from HCl doped PAn Precursor. Using the electrolyte containing FEC as an additive, the initial discharge capacity was increased. After that the galvanostatic charge-discharge test with the GISOC(gradual increasing of the state of charge) condition was carried out. Si-C(Si:PAn:50:50 wt. ratio)|Li cell showed 414 mAh/g of the reversible specific capacity, 75.7% of IIE(initial intercalation efficiency), 35.4 mAh/g of IICs(surface irreversible specific capacity).

Low Velocity Impact Property of CF/Epoxy Laminate according to Interleaved Structure of Amorphous Halloysite Nanotubes (비정질 할로이사이트 나노입자의 교차적층 구조에 따른 탄소섬유/에폭시 라미네이트의 저속 충격 특성)

  • Ye-Rim Park;Sanjay Kumar;Yun-Hae Kim
    • Composites Research
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    • v.36 no.4
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    • pp.270-274
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    • 2023
  • The stacking configuration of fiber-reinforced polymer (FRP) composites, achieved via the filament winding process, exhibits distinct variations compared to conventional FRP composite stacking arrangements. Consequently, it becomes challenging to ascertain the influence of mechanical properties based on the typical stacking structures. Thus, it becomes imperative to enhance the mechanical behavior and optimize the interleaved structures to improve overall performance. Therefore, this study aims to investigate the impact of incorporating amorphous halloysite nanotubes (A-HNTs) within different layers of five unique layer arrangements on the low-velocity impact properties of interleaved carbon fiber-reinforced polymer (CFRP) structures. The low-velocity impact characteristics of the laminate were validated using a drop weight impact test, wherein the resulting impact damage modes and extent of damage were compared and evaluated under microscopic analysis. Each interleaved structure laminate according to whether nanoparticles are added was compared at impact energies of 10 J and 15 J. In the case of 10 J, the absorption energy showed a similar tendency in each structure. However, at 15 J, the absorption energy varies from structure to structure. Among them, a structure in which nanoparticles are not added exhibits the highest absorption energy. Additionally, various impact fracture modes were observed in each structure through optical microscopy.

A Case Report on Managing the Side Effects of Anti-tuberculosis Drugs for Nontuberculous Mucobacteriosis (NTM) by Concurrently using Traditional Korean Medicine and Antibiotics (한방치료를 병행하여 항결핵제의 부작용을 관리한 비결핵 항산균증 환자 1례)

  • Lee, Ji-yoon;Jang, Kwon-jun;Yang, Jung-min;Moon, Hyang-ran;Ko, Eun-bi;Yoon, Min-ji;Jo, On-yu;Jeong, Seong-heon;Shin, Kwang-soon;Shin, Dong-guk;Hwang, Woo-seok
    • The Journal of Internal Korean Medicine
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    • v.42 no.5
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    • pp.1148-1159
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    • 2021
  • Objectives: This study investigated the effect of combined Korean medical treatment and antibiotics on a patient diagnosed with nontuberculous mycobacterial lung disease. Methods: The patient had been treated with antibiotics since July 2020 concurrently with Maekmoondong-tang, Banhasasim-tang, Gwakhyangjunggi-san and Bojungikgi-tang. The improvement of symptoms was evaluated using scores for the numerical rating scale (NRS), the Medical Research Council (MRC) dyspnea scale, C-reactive protein (CRP) levels, and computed tomography (CT). Results: Following treatment, the NRS, MRC dyspnea scale and CT images significantly improved. Also, CRP levels remained in the normal range during treatment. Conclusions: Traditional Korean medical treatment combined with antibiotics could be effective for treating patients with nontuberculous mycobacterial lung disease.

Evaluation of 1,1,2-trichloroethylene Removal Efficiency Using Composites of Nano-ZnO Photocatalyst and Various Organic Supports (다양한 유기계 지지체와 광촉매 Nano-ZnO 복합체를 활용한 1,1,2-trichloroethylene 제거 효율 평가)

  • Jang, Dae Gyu;Ahn, Hosang;Kim, Jeong Yeon;Ahn, Chang Hyuk;Lee, Saeromi;Kim, Jong Kyu;Joo, Jin Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.11
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    • pp.771-780
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    • 2014
  • In this study, the various organic supports (i.e., silicone, acrylonitrile-butadiene-styrene, epoxy, and, butadiene rubber) with great sorption capacity of organic contaminants were chosen to develop nano-ZnO/organic composites (NZOCs) and to prevent the detachment of nano-ZnO particles. The water resistance of the developed NZOCs were evaluated, and the feasibility of the developed NZOCs were investigated by evaluating the removal efficiency of 1,1,2-trichloroethylene (TCE) in the aqueous phase. Based on the results from water-resistance experiments, long-term water treatment usage of all NZOCs was found to be feasible. According to the FE-SEM, EDX, and imaging analysis, nano-ZnO/butadiene rubber composite (NZBC) with various sizes and types of porosity and crack was measured to be coated with relatively homogeneously-distributed nano-ZnO particles whereas nano-ZnO/silicone composite (NZSC), nano-ZnO/ABS composite (NZAC), and nano-ZnO/epoxy composite (NZEC) with poorly-developed porosity and crack were measured to be coated with relatively heterogeneously-distributed nano-ZnO particles. The sorption capacity of NZBC was close to 60% relative to the initial concentration, and this result was mainly attributed to the amorphous structure of NZBC, hence the hydrophobic partitioning of TCE to the amorphous structure of NZBC intensively occurred. The removal efficiency of TCE in aqueous phase using NZBC was close to 99% relative to the initial concentration, and the removal efficiency of TCE was improved as the amount of NZBC increased. These results stemmed from the synergistic mechanisms with great sorption capability of butadiene rubber and superior photocatalytic activities of nano-ZnO. Finally, the removal efficiency of TCE in aqueous phase using NZBC was well represented by linear model ($R^2{\geq}0.936$), and the $K_{app}$ values of NZBC were from 2.64 to 3.85 times greater than those of $K_{photolysis}$, indicating that butadiene rubber was found to be the suitable organic supporting materials with enhanced sorption capacity and without inhibition of photocatalytic activities of nano-ZnO.

Study on the Species Distributions of Dissolved U(VI) and Adsorbed U(VI) on Silica Surface (용존 6가 우라늄 및 실리카 표면 흡착 6가 우라늄 화학종 분포 연구)

  • Jung, Euo Chang;Kim, Tae-Hyeong;Jo, Yongheum;Kim, Hee-Kyung;Cho, Hye-Ryun;Cha, Wansik;Baik, Min Hoon;Yun, Jong-Il
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.1
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    • pp.63-72
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    • 2020
  • Dissolved hexavalent uranium can exist in the form of several different chemical species. Furthermore, species distributions depend on the pH value of the aqueous solution. Representatively, UO22+, UO2OH+, (UO2)2(OH)22+, and (UO2)3(OH)5+ species coexist in solutions at acidic and circumneutral pH values. When amorphous silica particles are suspended in an aqueous solution, the dissolved chemical species are easily adsorbed onto silica surfaces. In this study, it was examined whether the species distribution of the adsorbed U(VI) on a silica surface followed that of the dissolved U(VI) in an aqueous solution. Time-resolved luminescence spectra of three different dissolved species (UO22+, UO2OH+, and (UO2)3(OH)5+) and two different adsorbed species (≡SiO2UO2, ≡SiO2(UO2)OH-, or ≡SiO2(UO2)3(OH)5-) were measured in the pH range 3.5-7.5. The spectral shapes of these chemical species were compared by changing the pH value; consequently, it was confirmed that the species distribution of the adsorbed U(VI) species was different from that of the dissolved U(VI) species.

Study on Affecting Variables Appearing through Chemical Pretreatments of Poplar Wood (Populus euramericana) to Enzymatic Hydrolysis (이태리 포플러의 화학적 전처리 공정을 통한 효소가수분해 영향 인자 분석)

  • Koo, Bon-Wook;Park, Nahyun;Yeo, Hwanmyeong;Kim, Hoon;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.3
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    • pp.255-264
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    • 2009
  • To evaluate the effects of chemical pretreatments of lignocellulosic biomass on enzymatic hydrolysis process, Populus euramericana was pretreated for 1 hr with 1% sulfuric acid ($H_2SO_4$) at $150^{\circ}C$ and 1% sodium hydroxide (NaOH) at $160^{\circ}C$, respectively. Before the enzymatic hydrolysis, each pretreated sample was subjected to drying process and thus finally divided into four subgroups; dried or non-dried acid pretreated samples and dried or non-dried alkali pretreated samples and chemical and physical properties of them were analyzed. Biomass degradation by acid pretreatment was determined to 6% higher compared to alkali pretreatment. By the action of acid ca. 24.5% of biomass was dissolved into solution, while alkali degraded ca. 18.6% of biomass. However, reverse results were observed in delignification rates, in which alkali pretreatment released 2% more lignin fragment from biomass to the solution than acid pretreatment. Unexpectedly, samples after both pretreatments were determined to somewhat higher crystallinity than untreated samples. This result may be explained by selective disrupture of amorphous region in cellulose during pretreatments, thus the cellulose crystallinity seems to be accumulated in the pretreated samples. SEM images revealed that pretreated samples showed relative rough and partly cracked surfaces due to the decomposition of components, but the image of acid pretreated samples which were dried was similar to that of the control. In pore size distribution, dried acid pretreated samples were similar to the control, while that in alkali pretreated samples was gradually increased as pore diameter increased. The pore volume which increased by acid pretreatment rapidly decreased by drying process. Alkali pretreatment was much more effective on enzymatic digestibility than acid pretreatment. The sample after alkali pretreatment was enzymatically hydrolyzed up to 45.8%, while only 26.9% of acid pretreated sample was digested at the same condition. The high digestibility of the sample was also influenced to the yields of monomeric sugars during enzymatic hydrolysis. In addition, drying process of pretreated samples affected detrimentally not only to digestibility but also to the yields of monomeric sugars.

A Relief Method to Obtain the Solution of Optimal Problems (최적화문제를 해결하기 위한 완화(Relief)법)

  • Song, Jeong-Young;Lee, Kyu-Beom;Jang, Jigeul
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.20 no.1
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    • pp.155-161
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    • 2020
  • In general, optimization problems are difficult to solve simply. The reason is that the given problem is solved as soon as it is simple, but the more complex it is, the very large number of cases. This study is about the optimization of AI neural network. What we are dealing with here is the relief method for constructing AI network. The main topics deal with non-deterministic issues such as the stability and unstability of the overall network state, cost down and energy down. For this one, we discuss associative memory models, that is, a method in which local minimum memory information does not select fake information. The simulated annealing, this is a method of estimating the direction with the lowest possible value and combining it with the previous one to modify it to a lower value. And nonlinear planning problems, it is a method of checking and correcting the input / output by applying the appropriate gradient descent method to minimize the very large number of objective functions. This research suggests a useful approach to relief method as a theoretical approach to solving optimization problems. Therefore, this research will be a good proposal to apply efficiently when constructing a new AI neural network.

Effect of Hydrothermal and Enzymatic Treatments on the Physicochemical Properties of Waxy Maize Flour (열수 및 효소 처리에 의한 찰옥수수가루의 물리화학적 특성)

  • Lee, Dong-Jin;Choi, So-Mang;Lim, Seung-Taik
    • Korean Journal of Food Science and Technology
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    • v.48 no.2
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    • pp.165-171
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    • 2016
  • Physicochemical properties of waxy maize flours prepared by hydrothermal and enzymatic treatments were evaluated. Waxy maize flours were hydrothermally treated using heat-moisture treatment (HMT) and annealing (ANN) and enzymatically treated using commercial enzymes (cellulase, proteinase, and pectinase). The HMT-modified waxy maize flours had low water absorption index (WAI), melting enthalpy, viscosity, and crystallinity. However, ANN-modified and enzymatically modified waxy maize flours had high WAI, melting enthalpy, and viscosity. X-ray diffraction analysis of ANN-modified and enzymatically modified waxy maize flours revealed a typical A-type pattern and displayed sharper crystalline peaks than those observed for the control groups (native waxy maize flours). In contrast, the crystallinity of HMT-modified waxy maize flours were decreased by hydrothermal treatment.

Analysis on optical pulse propagation in atomic medium for amplification without inversion (밀도 반전 없는 증폭 매질에서 광펄스 군속도의 제어 과정 분석)

  • Kim, Haeng-Hwa;Kim, Kyung-Dae;Lee, Rim;An, Moon-Hee;Kim, Joong-Bok
    • Korean Journal of Optics and Photonics
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    • v.14 no.5
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    • pp.483-490
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    • 2003
  • We have analyzed theoretically optical pulse propagation in a coherent atomic medium for amplification without inversion (AWI), which is achieved by adding incoherent optical pumping to a typical EIT system. In order to explain experimental results [Kim et al., J. Phys. B, 36, 2671(2003)] to control the group velocity of the optical pulse by changing pumping power, we established a 5-level atomic system and applied density matrix equations. This AWI model system is different from previous AWI systems from the viewpoint of using two levels for incoherent optical pumping isolated optically from the EIT (electromagentically induced transparency) system so that more atoms can participate in pulse speed control. We have found that population transfer by collisions between ground states plays a decisive role for efficient AWI, and more atoms are effective for slowing the pulse. Our numerical results are in good agreement qualitatively with experimental results.