• Title/Summary/Keyword: 붕산

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Effects of Operating Variables on the Conversion of Meta Boric Acid Formation in a Bubble Column Reactor (기포탑 반응기에서 조작변수가 meta 붕산 생성반응 전환율에 미치는 영향)

  • Cho, Soo-Haeng;Do, Jae-Bum;Kang, Y.
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.573-579
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    • 1996
  • Effects of operating variables on the conversion of the formation reaction of meta boric acid from ortho boric acid in a laboratory-scale bubble column reactor were investigated to obtain the basic data which are indispensable for the design, scale-up, control, development and operation of industrial bubble column reactors. Reaction time and pressure, particle size of reactant and gas flow rate were chosen as experimental variables. Effects of the experimental variables on the gas holdup in the bubble column reactor were also discussed in relation to the conversion of reaction. From the results of this study, the optimum conditions were drawn as follows : Reaction time ; 35~40(min), reaction pressure ; 92~95(kPa), particle size ; under $0.6{\times}10^{-3}(m)$, gas flow rate ; 0.07~0.08(m/s).

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Feasibility Study on the Vitrification of Concentrated Boric Acid Waste (붕산농축폐액 유리화 타당성 연구)

  • Cho, Hyun-Je;Kim, Deuk-Man;Park, Jong-Kil
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.2
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    • pp.143-150
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    • 2010
  • Vitrification technology has been gradually recognized as one of effective solidification methods for concentrated boric acid wastes generated in PWR. Vitrification for low- and intermediate-level radioactive wastes has a large volume reduction and good durability for the final products. A feasibility study for the vitrification of concentrated boric acid wastes has been performed with developing the pre-treatment methods of powdered wastes, glass compositions using glass formulation and demonstration test. The pre-treatment method is pelletizing the powder type for stable feeding within cold crucible melter. The glass compositions should be developed considering molten glass are related with wastes reduction. High contents of sodium and boron within borate wastes give influence to waste loading. A variety of factors obtained from the demonstration test are reviewed, which is wastes feeding rate, off-gas characteristics on stack and glass characteristics of final products such as durability for implementing the wastes disposal requirement. The aim of this paper is to present the feasibility of vitrification and review the solidification method for concentrated boric acid wastes and obtain the physicochemical characteristics of solidified glass.

Determination of Trace Silicon in Uranium Dioxide by UV-VIS Spectrophometry (UV-VIS 분광광도법을 이용한 이산화우라늄 중 미량 규소 분석)

  • Choi, Kwang-Soon;Joe, Kihsoo;Han, Sun-Ho;Song, Kyuseok
    • Analytical Science and Technology
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    • v.21 no.5
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    • pp.397-402
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    • 2008
  • Uranium dioxide was dissolved with nitric acid and a trace amount of HF. The analytical conditions of a spectrophotometer were investigated to determine a trace amount of silicon in the uranium matrices without a separation process. The effects of a trace amount of HF on the determination of silicon were examined. Boric acid was used to eliminate HF the interference in the colorimetric process. The recovery of silicon in the presence of a trace amount of HF in uranium solutions with or without saturated boric acid was $103.3{\pm}0.8$ and $76.6{\pm}6.8%$, respectively. The amount of saturated boric acid did not affect the recovery of the silicon. Therefore it was possible for this procedure to measure a trace amount of silicon in a uranium matrix without a separation by a UV-VIS spectrophotometry.