• Title/Summary/Keyword: 불활성

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Oxyfluorination of Pitch-based Activated Carbon Fibers for High Power Electric Double Layer Capacitor (고출력 전기이중층 캐패시터를 위한 핏치계 활성탄소섬유의 함산소불소화 처리)

  • Jung, Min-Jung;Ko, Yoonyoung;Kim, Kyung Hoon;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.638-644
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    • 2017
  • Pitch based activated carbon fibers for electric double layer capacitor (EDLC) electrodes were treated by oxyfluorination via varying the ratio of fluorine and oxygen gases to improve high power property. As the partial pressure of fluorine increased, the oxyfluorinated activated carbon fibers showed an increase of linear fluorine functional groups. While the oxygen functional groups increased, no changes was observed with respect to the partial gas pressure. The specific surface area and pore volume decreased due to the etching reaction on the activated carbon fiber surface through oxyfluorination, but the mesopore volume increased about 4.5 times. In the case of activated carbon fibers treated with 50% of the fluorine gas partial pressure, the specific capacitance increased to about 29% and 61% at scan rates of 5 and 50 mV/s, respectively. The improvement of the specific capacitance was believed to be due to the introduction of oxygen and fluorine functional groups on the activated carbon fiber surface and the increase of mesopores through oxyfluorination.

마찰계수에 관하여

  • 신효철
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1986.11a
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    • pp.29-41
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    • 1986
  • 마찰계수는 서로 접촉하여 운동하는 두 물체간의 특성으로 간주되며 일반적으로 상대속도나 작용하중에 별로 영향을 받지 않는 것으로 알려져 있다. 화학적으로나 물리적으로 오염되지 않은 깨끗한 금속간의 마찰실험의 경우, 이 실험이 불활성 가스나 진공내에서 행해질 경우 상당히 큰 마찰저항을 경험하게 되나, 공기중에서의 실험에서는 작은 마찰저항이 기록되어 산화막이나 다른 오염물에 의해 형성된 막이 마찰저항을 감소시킨다고 보고 있다.

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Thermodynamic Empirical Equations for Physical Properties of Inert Gas Mixtures (불활성 기체 혼합물의 물성에 관한 열역학적 실험식)

  • 김재덕;여미순;이윤우;노경호
    • Fire Science and Engineering
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    • v.17 no.2
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    • pp.43-49
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    • 2003
  • For the inert gases of Ar, $N_2$and $CO_2$, the empirical equations of the gas mixture were correlated in terms of saturated pressure, density and viscosity. They were obtained by regression analysis based on the mixing rule. The empirical equation of saturated pressure was assumed as the first order function of temperature. The empirical form of density was expressed as compressibility factor and saturated pressure while the empirical equation of viscosity was formulated as a power function of temperature. This empirical equations of the physical properties were obtained in the composition of Ar, $N_2$and $CO_2$, 40/50/10(mol. %).

Anoxia Techniques to Eradicate Insects for Conservation of Cultural Properties in Museums (박물관에서의 저산소 농도를 이용한 살충 기술)

  • Oh, Joon-Suk
    • Journal of Conservation Science
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    • v.27 no.2
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    • pp.231-241
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    • 2011
  • Anoxia Treatment using inert gas like nitrogen and argon has been used to eradicate insects successfully in museums as alternative of methyl bromide and toxic insecticide. Killing efficacy of insect for anoxia treatment is depend on species of insects, oxygen concentration, temperature, relative humidity and gas. It is possible to kill museum insects which are most tolerant in anoxia environment, within 1 month below 0.03% of oxygen concentration in temperature $15{\sim}25^{\circ}C$ and relative humidity 40~60% of museum environment. And various systems like bag, tent, bubble and chamber depending on size and quantity of objects, are used.

Study of the characteristics of Secondary Electron Emission from MgO Layer for Low-Energy Noble Ions (저에너지 불활성 기체이온에 의한 AC 플라즈마 디스플레이 패널용 MgO막의 이차전자 방출특성에 관한 연구)

  • 이상국;김재홍;이지화;황기웅
    • Journal of the Korean Vacuum Society
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    • v.11 no.2
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    • pp.108-112
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    • 2002
  • We investigated the secondary electron emission characteristics of MgO layer used as the protecting material in a.c. plasma display panel(a.c.-PDPs) using a pulsed ion beam technique, where the surface charging can be effectively suppressed during the measurement. The measurement of the secondary electron emission coefficients ($\gamma$) on the surface of $SiO_2$ was carried out and then, it was found that the yields were dependent on incident ion energies. In addition, it was clearly demonstrated that the sputtering on MgO surface leads to lower yields, which suggests that the surface plays a key role on the operating conditions, such as life time, fast response, and etc.