• Title/Summary/Keyword: 불포화 폴리에스테르 수지

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Experimental Investigation of the Effect of Manufacturing and Working Conditions on the Deformation of Laminated Composite Structures (적층복합재료구조물의 변형에 미치는 제작조건과 작동조건의 영향에 대한 실험적 고찰)

  • Nhut, Pham Thanh;Yum, Young-Jin
    • Composites Research
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    • v.26 no.4
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    • pp.265-272
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    • 2013
  • Fiber-reinforced plastic (FRP) is applied to fabricate the main structures of composite boats. Most of them are made from molds. These products deform after releasing from the mold and they also deform in high temperature environment. Therefore, experimental investigation and evaluation of deformation of laminated composite structures under various manufacturing and working conditions are necessary. The specimens of L-shape and curveshape were made from unsaturated polyester resin and fiberglass material. Input factors (independent variables) are percentage of hardener and manufacturing temperature and four levels of working temperature and output factor is the deformation which is measured on these specimens. From the results, it was observed that the higher the hardener rate and temperature, the lower the deformation. When the working temperature increased, the specimens showed great variations for the initial deformation values. Besides, the values of deformation or input factors could be predicted by regression equations.

A study on the Spectra reinforcement composite of its ballistic performance (방탄용 Spectra 섬유 강화 복합재료에 관한 연구)

  • 강은영;윤영기;윤희석
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.83-86
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    • 2001
  • This paper presents an investigation of the contribution of fibers in energy absorption during impact and the effect of resin types on properties of the high strength polyethylene (Spectra-900 PE) composite. In high strength polyethylene fiber, main impact energy absorbing mechanism was tensile breakage and deformation of fiber. Two types of resin were examined : Unsaturated polyester (UP) and Epoxy. Tensile and 3-point bending test have been performed to investigate the changes of mechanical properties. In tensile and flexural testes, the Spectra Composite prepregged with UP showed higher properties than Spectra Composite prepregged with epoxy.

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Effect of Unsaturated Polyester Resin Content on Properties of PMMA Mortars (PMMA 모르타르의 성질에 미치는 불포화 폴리에스테르 수지 첨가율의 영향)

  • Choi Nak Woon;Lee Chol Woong;Kim Wan Young;So Yang Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.332-335
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    • 2004
  • Polymethyl Methacrylate(PMMA) mortars using EPS solution-based binders are prepared with various unsaturated polyester resin(UP) contents of binder, and tested for working life. heat exothorm temperature, length change. compressive strength and temperature dependence of compressive strength. As a result, the working life of PMMA mortar is lengthened with raising UP content of binder. Length change of the mortar was condensed from expansion to shrinkage with increasing UP content, and non shrinkage of the mortar is obtained at about UP content of $2.5\%$. The compressive strength of the mortar is increased with an increase in the UP content and reach maximum at UP content of $5\%$. However thermal resistance improvement of the mortar by increasing UP content was not recognized. UP resin was recommended as an effective agent for shrinkage control and strength development of PMMA mortar.

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Dielectric Properties of Unsaturated Polyester Resin for Electric Safety (전기 안전에 관한 불포화폴리에스테르 수지의 유전특성)

  • 이성일;권호영
    • Journal of the Korean Society of Safety
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    • v.6 no.3
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    • pp.12-20
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    • 1991
  • The dielectric properties that effect to electric safety for unsaturated Pelvester resin were studied over the temperature range of 30-40[$^{\circ}C$] and the frequency range of 110~3$\times$10$^{6}$ [Hz]. According to the results of the study, it has been observed that two kinds of dielectric losses in electric safety were existed by the molecular movement of C-H and OH group. When the ,adio of hardener was 1.5[%], the characteristics of specimens were excellent in view of the electrical materical. In the range of measuring frequency the dielectric constants and the dielectric losses were 3.5~5.5 and 10$^2$~10$^3$ respectly. The activation energy of loss spectrum in aspect of electric safety and the entropy appeared at the 30[$^{\circ}C$] were 33.4[Kacl/mole] and 54.9[cal/mole.deg] respectly.

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Recycling of Separate Glass Fiber from Waste Printed Circuit Boards Using Attrition Mill and DMF (어트리션 밀과 DMF 용매를 이용한 폐 인쇄회로기판에서 분리된 재생 유리섬유의 재활용)

  • Kim, Jong-Seok;Lee, Jae-Cheon;Jeong, Jin-Ki
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.894-899
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    • 2012
  • In recent years, recycling process has come to be necessary for separating metals, glass fibers and polymer from WPCBs (waste printed circuit boards) due to an increasing amount of electronic device waste. In this study, dimethylformamide (DMF) and attrition mill reactor were used to separate the component such as metals, glass fiber and epoxy resin from WPCBs. Separation of glass fiber from WPCBs was carried out under stirring rates 300~600 revolution per minute (rpm) for 1~2 h as the various agitator. The recycled glass fibers (RGF) were analyzed by thermogravimetric analyzer (TGA) for degree of separation of epoxy resin in the WPCBs. The degree of separation of epoxy resin of WPCBs increased in attrition mill agitator as a mechanochemical process for recycling WPCBs. The RGF separated in the WPCBs was applied as a reinforcement in the RGF/unsaturated polyester composites to reuse as a reinforcement.

An Experimental Study on the fluidity properties of Polymer Concrete According to Replacement Ratio of Rapidly-Chilled Steel Slag and polymer resin (급냉 제강 슬래그 대체율과 폴리머 수지에 따른 폴리머 콘크리트의 유동특성에 관한 실험적 연구)

  • Choi, Duck-Jin;Kim, Jae-Won;Sun, Joung-Soo;Kim, Ha-Suk;Hwang, Eui-Hwan;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.75-78
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    • 2007
  • The steel slag, a by-product which is produced by refining pig iron during the manufacture of steel, is mainly used as road materials after aging. It is necessary to age steel slag for long time in air because the reaction with water and free-CaO in steel slag could make the expansion of volume. This problem prevents steel slag from being used as aggregate for concrete. However, steel slag used in this study was controled by a air-jet method which rapidly cools substance melted at a high temperature. The rapidly-chilled method would prevent from generation of free-CaO in steel slag. Also, Molten steel slag rapidly-chilled by air in high speed becomes a fine aggregate of nearly spherical shape. This study dealt with the influence of the using rate of rapidly-chilled steel slag and polymer resin on fluidity of polymer concrete, as a results Since RCSS has spherical shape and high density, up to replacement ratio of 100%, increases concrete fluidity under same polymer content and decrease polymer content in order to secure the same fluidity

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Preparations and Interfacial Phenomena of Hybrid Composites (Hycom) Containing Wasted Stone Powders and Tire Chips (폐석분과 폐타이어 칩을 충진제로 한 혼성복합재(Hycom)의 제조 및 계면현상 연구)

  • Hwang, Teak-Sung;Cha, Ki-Sik
    • Journal of Adhesion and Interface
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    • v.2 no.1
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    • pp.1-8
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    • 2001
  • In this study, wasted stone powders (WSP) obtained from sludge and Wasted Tire Chips (WTC) as fillers have been used to formulate polymer hybrid composites based on Unsaturated Polyester (UPE) resin. To further enhance not only the interfacial bond between the inorganic filler and the polymer matrix, but also the filler dispersion by wetting the particulate surfaces to uniformly spread the resin during the mixing, silane coupling agent[${\gamma}$-methacryloxy propyl trimethoxy silane (${\gamma}$-MPS)] was used. The influences of organic recycled fillers contents and the concentrations of coupling agent in polymer hybrid composite formulations have been investigated from a mechanical and microstructural point o view through Mercury Porosimeter and SEM.

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Properties of Strength and Stress-Strain of Recycled-Plastic Polymer Concrete (폐플라스틱 재활용 폴리머콘크리트의 강도와 응력-변형률 특성)

  • Jo Byung-Wan;Koo Jakap;Park Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.329-334
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    • 2005
  • The use of Polymer Concrete (PC) is growing very rapidly in many structural and construction applications such as box culverts, hazardous waste containers, trench lines, floor drains and the repair and overlay of damaged cement concrete surfaces in pavements, bridges, etc. However, PC has a defect economically because resin which be used for binder is expensive. Therefore the latest research is being progressed to replace existing resin with new resin which can reduce the high cost. Here, Polymer concrete using the recycled PET(polyethylene terephthalate) has some merits such as decrease of environmental destruction, decrease of environmental pollution and development of new construction materials. The variables of this study are amount of resin, curing condition and maximum size of coarse aggregate to find out mechanic properties of this. Stress-strain curve was obtained using MTS equipment by strain control. The results indicated that modulus of elasticity was increased gradually in an ascending branch of curve, as an increase of resin content. Compressive strength was the highest for resin content of $13\%$. And Compressive strength was increased as maximum size of coarse aggregate increases. The strain at maximum stress increases with an increase of resin content and size of coarse aggregate. For the descending branch of stress-strain curve the brittle fracture was decreased when it was cured at the room temperature compared to high temperature.

A Study on the Preparation and Mechanical Properties of Hybrid Composites Reinforced Waste FRP and Urethane Foam (폐 FRP/Urethane Foam 충진 혼성복합재의 제조 및 기계적 물성에 관한 연구)

  • 황택성;신경섭;박진원
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.564-570
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    • 2000
  • The waste FRP occured in the fabrication of SMC (sheet molding compound) bathtubs and the waste polyurethane foam occured in electronic manufacture and waste insulator were applied as a soundproof and light weight pannel in the waste FRP unsaturated polyester matrix resin composites to recycle. The effect of filler contents on the mechanical properties and interfacial phenomena of the filler and matrix on the composites was evaluated. The tensile strength of composites reached its maximum value of 82.34 MPa when the filler content was 70 wt%, and the more content of reinforcement is increased, the more tensile modulus was decreased. The flexural strength and modulus of composites, reinforced 70 wt% with filler content, were dominant compared to the other samples to 72.5 MPa, 958.4 MPa respectively. When composite of reinforced 70 wt% with filler content, it was confirmed that pull out phenomena and cracks did not occur in the interface of reinforcement and matrix resin through the SEM observation. Also, waste FRP and urethane foam were dispersed well into matrix resin as filler.

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Development of Surface Improvement Technique of Japanese Larch Flooring Board(II) (낙엽송 마루판재의 표면강화 처리기술 개발(II))

  • Park, Sang-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.1
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    • pp.28-35
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    • 2000
  • This paper deals with a coating technique for hardening surface layer of softwood(Larix leptolepis) flooring board to improve its surface properties such as hardness and abrasion resistance, Two coating methods were applied for surface hardening of the wood in this study. First, several functional monomers were added in UV-curing epoxy acrylate varnish. Secondly, unsaturated polyester varnish was used as under coat and acryl varnish including anti-abrasive agent was used as top coat. The hardness of the treated wood was similar to that of high density hardwood such as keruing by the first coating method. The abrasion resistance of the coated wood was greatly improved by the second method. Adhesion properties and impact resistance of the coated wood surface were also good. It was suggested that the well-coated softwood could be used as interior flooring board for heavy walking as substitute for hardwood.

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