• Title/Summary/Keyword: 불안정 현상

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Effects of the Thickness and the Morphology of a ZnO Buffer Layer in Inverted Organic Solar Cells

  • Lee, Hyeon-U;O, Jin-Yeong;Baek, Hong-Gu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.151-151
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    • 2013
  • 무기물 기반, Si-based 태양전지에 비해 가볍고 저렴하다는 관점에서 유기태양전지에 대한 연구가 진행되고 있다. 유기태양전지는 Si-based 태양전지에 비해 그 효율이 낮다는 점이 문제로 제기되어 왔지만, 억셉터와 도너의 nanocomposite 구조인 bulk-heterojunction (BHJ) 구조가 개발이 되면서 유기물의 짧은 엑시톤(exciton) 거리를 극복할 수 있게 되어 그 효율이 비약적으로 증가되는 결과를 낳았다. 또한 넓은 범위의 파장을 흡수 할 수 있는 작은 band-gap을 갖는 물질이 개발됨으로써 유기 태양전지의 효율은 점차 증가하고 있다. 최근에는 독일 회사인 Heliatek에서 12%가 넘는 유기태양전지를 발표함으로써 유기태양전지가 Si-based 태양전지를 대체할 수 있는 차세대 에너지 공급원으로의 가능성을 충분히 보였다. 이런 유기 태양전지는 하부 투명전극인 인듐주석산화물(ITO)/정공이동층(PEDOT:PSS)/광흡수층/전자이동층(LiF)/낮은 일함수를 갖는 상부전극인 Al 구조의 일반적인 구조; ITO/전자이동층/광흡수층/정공이동층/높은 일함수를 갖는 상부전극(Ag), 전하의 이동방향이 반대인 역구조 태양전지, 두 가지로 분류할 수 있다. 하지만 소자 안정성의 관점에서 일반적인 구조의 태양전지는 ITO/PEDOT:PSS 계면에서의 화학적 불안정성과, 낮을 일함수를 갖는 상부전극이 쉽게 산화되는 등의 문제가 있어 상부전극으로 높은 일함수를 갖는 전극을 사용하는 역구조 태양전지가 더 유리하다. 이러한 역구조 태양전지에서 효율을 높일 수 있는 요인 중 하나는 전자이동층에 있다. 광흡수층에서 형성되어 분리된 전자가 전극으로 이동하기위해서는 전자이동층을 거쳐야 한다. 하지만 이 전자이동층 내에서의 전자 이동속도가 느리다면, 즉 저항이 크다면 광흡수증과의 계면에서 Back electron trasnfer현상으로 재결합이 일어나게 되어 전극으로 도달하는 전자의 양이 줄어들게 되고, 이는 유기태양전지 효율을 낮추는 요인이 된다. 전자이동층 자체의 저항뿐만 아니라, 전자이동층의 표면 거칠기(morphology) 또한 유기 태양전지의 효율을 좌우하는 요인 중 하나이다. 광흡수층과 전자이동층의 계면에서 전자의 이동이 일어나는데, 전자이동층의 표면 거칠기가 크게되면 그 위에 박막으로 형성되는 광흡수층과의 계면저항이 증가하게 되고, 이는 광흡수층에서 전자이동층으로의 원활한 전자이동을 저해함으로써 소자 효율의 감소를 일으키게 된다. 따라서 우리는 전자이동층인 ZnO 박막의 스퍼터링 조건을 변화시킴으로써 ZnO 층의 두께에 따른 광투과도, 전기전도성 변화 및 유기태양전지의 효율변화와, 표면 거칠기에 따른 광변환 효율 변화를 관찰하고자 한다.

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Stabilizing Properties of SiOF Film with Low Dielectric Constant by $N_2O$ Plasma Annealing ($N_2O$ 플라즈마 열처리에 의한 저유전율 SiOF 박막의 물성 안정화)

  • Kim, Yoon-Hae;Lee, Seok-Kiu;Kim, Sun-Oo;Kim, Hyeong-Joon
    • Korean Journal of Materials Research
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    • v.8 no.4
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    • pp.317-322
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    • 1998
  • The stabilization of low dielectric constant SiOF films prepared by conventional PECVD using TEOS and $C_2F_6$ was evaluated by the $N_2O$-plasma post-deposition annealing. Properties of SiOF film became unstable when it was air-exposed or heat-treated. Water absorption of SiOF films was increased as F content was increased due to the for¬mation of F -Si- F bonds. Also F content of SiOF films decreased after heat treatment. $N_2O$-plasma post-deposition annealing was proved to be effective on stabilizing SiOF films. which was mainly due to the formation of thin SiON layer near the top surface of films. However. the value of dielectric constant was greatly increased again when $N_2O$-plasma post-deposition annealing was done for a long time. To stabilize the SiOF films without an increase of dielec¬tric constant by $N_2O$- plasma post-deposition annealing. the annealing time should be kept the minimum value. to which stabilizing effects against air environment and heat treatment were preserved.

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Youth Poverty and Employment (청년 빈곤 및 고용실태 분석)

  • Kim, Anna;Hong, Hyunwoo
    • Korean Journal of Social Welfare Studies
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    • v.49 no.2
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    • pp.93-124
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    • 2018
  • Using the Korean Survey of Household Finances and Living Conditions panel data from 2012~2016, this study analyzed youth (19~34 years) poverty and employment and examined the factors that affect employment status. The analysis revealed an increase in the proportion of young people who are students or jobless; the economic conditions of the young people varied by factors such as marital status, education, job status, and loans; and the government public transfer policy had little impact on reducing the relative poverty rate of the youth. We also examined the factors affecting the youth's employment status and the risk of being employed in low-paid jobs, using multi-logit and logit regression model respectively. Considering employment status, the older and more educated the youth were, the less frequently they were employed in temporary or daily jobs instead of regular ones, but there was no difference between genders in terms of having temporary or daily jobs. A logit analysis on the determinants of low-paid jobs demonstrated that women, the less educated, spouses or children of the household, and temporary or daily workers have a greater probability of working at low-paid jobs. As women became older, their risk of having low-paid jobs increased, which demonstrated the phenomenon of "lock-in" at low-paid jobs. Temporary or daily workers of all age groups faced a higher risk of lowpaid employment, which stood out for the youth. Based on these results, we suggest that government employment and welfare policies should consider individual characteristics of the youth and their life cycle, along with efforts to supply decent jobs, continuously and stably.

A multiphase flow modeling of gravity currents in a rectangular channel (사각형 수로에서 중력류의 다상흐름 수치모의)

  • Kim, Byungjoo;Paik, Joongcheol
    • Journal of Korea Water Resources Association
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    • v.52 no.10
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    • pp.697-706
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    • 2019
  • A multiphase flow modeling approach equipped with a hybrid turbulence modeling method is applied to compute the gravity currents in a rectangular channel. The present multiphase solver considers the dense fluid, the less-dense ambient fluid and the air above free surface as three phases with separate flow equations for each phase. The turbulent effect is simulated by the IDDES (improved delayed detach eddy simulation), a hybrid RANS/LES, approach which resolves the turbulent flow away from the wall in the LES mode and models the near wall flow in RANS mode on moderately fine computational meshes. The numerical results show that the present model can successfully reproduce the gravity currents in terms of the propagation speed of the current heads and the emergence of large-scale Kelvin-Helmholtz type interfacial billows and their three dimensional break down into smaller turbulent structures, even on the relatively coarse mesh for wall-modeled RANS computation with low-Reynolds number turbulence model. The present solutions reveal that the modeling approach can capture the large-scale three dimensional behaviors of gravity current head accompanied by the lobe-and-cleft instability at affordable computational resources, which is comparable to the LES results obtained on much fine meshes. It demonstrates that the multiphase modeling method using the hybrid turbulence model can be a promising engineering solver for predicting the physical behaviors of gravity currents in natural environmental configurations.

Analysis Model for Design Based on Stiffness Requirement of Direct Drive Electromechanical Actuator (직구동 전기기계식 구동기의 강성요구규격에 기반한 설계용 해석모델)

  • Oh, Sang Gwan;Lee, Hee Joong;Park, Hyun Jong;Oh, Dongho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.47 no.10
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    • pp.738-746
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    • 2019
  • Instead of hydraulic actuation systems, an electromechanical actuation system is more efficient in terms of weight, cost, and test evaluation in the thrust vector control of the 7-ton gimbal engine used in the Korea Space Launch Vehicle-II(KSLV-II) $3^{rd}$ stage. The electromechanical actuator is a kind of servo actuator with position feedback and uses a BLDC motor that can operate at high vacuum. In the case of the gimballed rocket engine, a synthetic resonance phenomenon may occur due to a combination of a vibration mode of the actuator itself, a bending mode of the launcher structure, and an inertial load of the gimbals engine. When the synthetic resonance occurs, the control of the rocket attitude becomes unstable. Therefore, the requirements for the stiffness have been applied in consideration of the gimbal engine characteristics, the support structure, and the actuating system. For the 7-ton gimbal engine of the KSLV-II $3^{rd}$ stage, the stiffness requirement of the actuation system is $3.94{\times}10^7N/m$, and the direct drive type electromechanical actuator is designed to satisfy this requirement. In this paper, an equivalent stiffness analysis model of a direct drive electromechanical actuator designed based on the stiffness requirements is proposed and verified by experimental results.

High-power Yb Fiber Laser with 3.0-kW Output (3.0 kW 고출력 발진 단일 모드 Yb 광섬유 레이저)

  • Park, Jong Seon;Park, Eun Ji;Oh, Ye Jin;Jeong, Hoon;Kim, Ji Won;Jung, Yeji;Lee, Kangin;Lee, Yongsoo;Cho, Joonyong
    • Korean Journal of Optics and Photonics
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    • v.32 no.4
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    • pp.147-152
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    • 2021
  • We report high-power continuous-wave operation of a Yb-doped fiber laser at 1070 nm, pumped by high-power laser diodes at 976 nm. Based on theoretical calculation of the stimulated Raman scattering and temperature distribution in the fiber, we construct a bidirectionally pumped Yb-fiberlaser system incorporating a pair of fiber Bragg gratings and a cladding light stripper. The fiber laser yields 3.0 kW of continuous-wave output at 1070 nm in a diffraction-limited beam with M2 ≈ 1.26 for 4.1 kW of incident pump power, corresponding to a slope efficiency of 81.5%. The prospects for further power scaling are discussed.

Increased Youth Single-person Households and Solitary Deaths realized by College Students (대학생이 인식한 청년 1인 가구 및 청년 고독사 증가 현상)

  • Park, Su-Sun
    • Journal of Digital Convergence
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    • v.16 no.12
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    • pp.635-640
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    • 2018
  • The study conducted a Focus Group Interview (FGI) on college students to identify single-person households and Solitary Deaths of single-person households recognized by college students. This can be provided as basic data to address problems in single-person households and social problems such as future youth solitary death and will contribute to building a social safety net. This study conducted FGI to analyze data for five fourth graders majoring in social welfare. In the case of involuntary independent living, the high poverty and unemployment rate of single-person households was cited as the cause of economic instability, housing problems and emotional relationship formation. He said that he thinks about young loneliness because he has vague fears about what happens in the media and what can happen to them. As the number of young single-person households will inevitably increase in the coming months and economic difficulties are the biggest problem and the biggest cause of young solitude, institutional support is needed first, especially for housing costs.

A Study of the Employment Condition and Labour Experience of Elementary After-School Care Teachers: A Case of Gwangju Metropolitan City (초등돌봄교사의 고용형태와 노동경험에 관한 연구: 광주광역시 사례를 중심으로)

  • Kim, Hyun Mi;Shin, Julia Jiwon
    • 한국사회정책
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    • v.23 no.2
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    • pp.141-172
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    • 2016
  • This study examines the employment conditions and labour experience of elementary after-school care teachers in South Korea. Based on the empirical data collected through in-depth interviews with after-school care teachers in Gwangju Metropolitan City, the study considers multifaceted problems faced by after-school care teachers in their workplace. The after-school care class is part of educational policies initiated and rapidly expanded by the Ministry of Education, resulting in the substantial increase of non-regular school workers. The irregularization of after-school care teachers illustrates that the common problems faced by female non-regular workers, such as social discrimination, exclusion and inequality, are also transplanted into the typical public sector. In the case of Gwangju Metropolitan City, during the past two years there have been evident increases both in under 15-hour short time contract care teachers and outsourcing of care classes. Temporary part-time contract care teachers suffer relentless job insecurity and experience poor working conditions, exclusion and discrimination within the workplace and labour alienation. In order to minimize the organized resistance of care teachers, school authorities implicitly individualize and isolate care teachers through hierarchization, the division of labour and the spatial division of classes between indefinite and temporary contract teachers.

Linearly Polarized 1-kW 20/400-㎛ Yb-doped Fiber Laser with 10-GHz Linewidth (선편광된 10 GHz 선폭의 1 kW급 20/400-㎛ 이터븀 첨가 광섬유 레이저)

  • Jung, Yeji;Jung, Minwan;Lee, Kangin;Kim, Taewoo;Kim, Jae-Ihn;Lee, Yongsoo;Cho, Joonyong
    • Korean Journal of Optics and Photonics
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    • v.32 no.3
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    • pp.120-125
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    • 2021
  • We have developed a linearly polarized high-power Yb-doped fiber laser in the master oscillator power amplifier (MOPA) scheme for efficient spectral beam combining. We modulated the phase of the seed laser by pseudo-random binary sequence (PRBS), with the bit length optimized to suppress stimulated Brillouin scattering (SBS), and subsequently amplified seed power in a 3-stage amplifier system. We have constructed by coiling the polarization-maintaining (PM) Yb-doped fiber, with core and cladding diameters of 20 ㎛ and 400 ㎛ respectively, to a diameter of 9-12 cm for suppression of the mode instability (MI). Finally, we obtained an output power of 1.004 kW with a slope efficiency of 83.7% in the main amplification stage. The beam quality factor M2 and the polarization extinction ratio (PER) were measured to be 1.12 and 21.5 dB respectively. Furthermore, the peak-intensity difference between the Rayleigh signal and SBS signal was observed to be 2.36 dB in the backward spectra, indicating that SBS is successfully suppressed. In addition, it can be expected that the MI does not occur because not only there is no decrease in slope efficiency, but also the beam quality for each amplified output is maintained.

A Basic Study on Welfare of Retired Clergy in Daesoon Jinrihoe (성직자 노후복지 조성을 위한 기초연구 - 대순진리회를 중심으로 -)

  • Kim, Jin-young;Lee, Young-jun
    • Journal of the Daesoon Academy of Sciences
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    • v.40
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    • pp.115-153
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    • 2022
  • Korea has rapidly become an aging society, and this phenomenon is found not only in common population but also in many religious circles. In this context, interest in the welfare of retired clergy members is increasing, and some religious organizations are trying to devise and perform rules and/or policies that ensure a secure post-retirement life for their clergy. However, the welfare benefits differ from one religion to another according to the characteristics of the given religion's organizational structure. For instance, denominations with a centralized hierarchy such as Catholicism or Won Buddhism implement a relatively stable welfare system for their elderly clergy members whereas autonomous denominations like many Buddhist or Christian orders are often found to have somewhat insecure welfare systems. Clergy welfare in Daesoon Jinrihoe, one of the representative new religions in Korea, is emerging as an important issue as Daesoon Jinrihoe is also affected by the problems of Korea's aging society. However, since the order has a mixed system of a centralized hierarchy and autonomous local branches, the welfare for their elderly clergy lacks clear lines of accountability. Consequently, there have been talks to devise a proper welfare system; however, these talks have come to a standstill. In this regard, this study aims to look into and analyze how various structures and welfare systems within Korean religious organizations impact elderly clergy. Lastly, this research will provide suggestions on practical alternatives for Daesoon Jinrihoe which could resolve the problems within their welfare system that negatively impact elderly clergy members at present.