• Title/Summary/Keyword: 분산 방법

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EFFECT OF SURFACE TREATMENTS ON THE REPAIR BOND STRENGTH OF COMPOSITES (복합레진의 수리 시 표면처리가 결합강도에 미치는 영향)

  • Choi, Jung-In;Kim, Young-Jae;Kim, Jung-Wook;Lee, Sang-Hoon;Kim, Chong-Chul;Hahn, Se-Hyun;Jang, Ki-Taek
    • Journal of the korean academy of Pediatric Dentistry
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    • v.35 no.4
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    • pp.692-699
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    • 2008
  • The purpose of this study was to evaluate the effect of surface treatment on the shear bond strength between new and old composite resin. The prepared resin specimens were separated 6 groups, and each group then received a different surface treatment. Then the repair material was added. Shear bond strengths for repair were measured after 7 days and the results were analyzed by using one way ANOVA. The results were as follows; 1. Group 3, 4(air abrasion) showed significantly higher shear bond strength than Group 1(phosphoric acid)(p<0.05). Group 5, 6(diamond bur) showed higher bond strength than Group 1(phosphoric acid) but not significantly different( p>0.05). 2. Group 2(self-etching adhesive) showed lower shear bond strength than Group 1(phosphoric acid) but not significantly different(p>0.05). 3. There was no statistically significant difference between Group 3(air abrasion) and Group 4(air abrasion+etching). 4. There was no statistically significant difference between Group 5(diamond bur) and Group 6(diamond bur+etching). In conclusion, the surface treatment with air abrasion resulted in higher repair bond strength than other methods. Repair bond strength was not significantly affected by acid etching.

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Decision of Optimized Mix Design for Lightweight Foamed Concrete Using Bottom Ash by Statistical Procedure (통계적 방법에 의한 바텀애쉬를 사용한 경량기포 콘크리트의 최적배합 결정)

  • Kim, Jin-Man;Kwak, Eun-Gu;Cho, Sung-Hyun;Kang, Cheol
    • Journal of the Korea Concrete Institute
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    • v.21 no.1
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    • pp.3-11
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    • 2009
  • The increased demand and consumption of coal has intensified problems associated with disposal of solid waste generated in utilization of coal. Major utilization of coal by-products has been in construction-related applications. Since fly ash accounts for the part of the production of utility waste, the majority of scientific investigations have focused on its utilization in a multitude of use, while little attention has been directed to the use of bottom ash. As a consequence of this neglect, a large amount of bottom ash has been stockpiled. However, the need to obtain safe and economical solution for its proper utilization has been more urgent. The study presented herein is designed to ascertain the performance characteristics of bottom ash, as autoclaved lightweight foamed concrete product. The laboratory test results indicated that tobermorite was generated when bottom ash was used as materials for hydro-thermal reaction. According to the analysis of variance, at the fresh state, water ratio affects on flow and slurry density of autoclaved lightweight foamed concrete, but foam ratio influences on slurry density, while, at the hardened state, foam ratio affects on the density of dry and the compressive strength but doesn't affect on flexural and tensile strength. In the results of response surface analysis, to obtain target performance, the most suitable mix condition for lightweight foamed concrete using bottom ash was water ratio of 70$\sim$80% and foaming ratio of 90$\sim$100%.

Characteristics of Al2O3/ZrO2 Ceramics by the Dispersion Process of ZrO2 Particles (ZrO2 입자의 분산방법에 따른 Al2O3/ZrO2 요업체의 특성)

  • Youn, Sang-Hum;Kim, Jae-Jun;Hwang, Kyu-Hong;Lee, Jong-Kook;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.42 no.8 s.279
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    • pp.561-566
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    • 2005
  • For the homogeneous dispersion of $ZrO_2$ particles in $Al_2O_3/ZrO_2$ceramics, Zr-precusors were mixed with oxide $Al_2O_3$powders by chemical routes such as partial precipitation or partial polymerization of Zr-nitrate solutions. In case of the mechanical mixing of ultrafine $Al_2O_3$ and $ZrO_2$ oxide powders, relatively homogeneous dispersion was difficult to achieve so that the particle size and distributions of $ZrO_2$ were relatively inhomogeneous after sintering at high temperature. But when the Zr-Y-hydroxide were co-precipitated to ultrafine $Al_2O_3$ oxide powders followed by calcinations, homogeneous dispersion of nano-sized $ZrO_2$ particles in $Al_2O_3/ZrO_2$ composite ceramics were obtained. But because of the coalescence of dispersed $ZrO_2$ particles, dispersed $ZrO_2$ was grown up to more than 0.2${mu}m$ (200 nm) when sintered at the temperature of higher than $1500^{\circ}C$ But when the sintering temperature was kept to lower than $1400^{\circ}C$ by using nano-sized $\alpha-alumina$, the particle size of dispersed $ZrO_2$ could be sustained below 0.1 ${\mu}m$. But the coalescence of dispersed $ZrO_2$ between $Al_2O_3$ particles could not be avoided so that the mechanical properties were not enhanced contrary to the expectations. So Zr-polyester precursors were precipitated and coated to the surface of ultrafine $\alpha-alumina$ powders by the polymerization of Ethylene Glycol with Citric Acid and Zirconium Nitrate. By this dispersion much more uniform dispersion of $ZrO_2$ was achieved at $1450\~1600^{\circ}C$ of sintering temperature ranges. And due to especially discrete dispersion of $ZrO_2$ between $Al_2O_3$ particles, their mechanical strength was more enhanced than mechanical mixing or hydroxide precipitation methods.

Performance Estimation of Hexagonal Rockfall Protection Net by Numerical Analysis (수치해석을 이용한 육각 낙석방지망의 성능 평가)

  • Oh, Sewook;Park, Soobeom;Kwon, Youngcheul
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.11
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    • pp.53-59
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    • 2014
  • It has been generally recognized that the conventional rockfall protection nets have several problems to actual field application in the aspect of shock absorption, lack of pullout bearing capacities, and net damages. Because of the recognition, authors have tried to develop a new rockfall protection system consisted of shock absorption parts and hexagonal net configuration. In the previous research by the authors, the performance of the newly developed rockfall protection system has been investigated through the laboratory tests and the full-scale testing. In this study, subsequently, numerical analysis program is organized to make a confirmation of the structural stability and performance. For the correct design procedure of the hexagonal net system, it is essential to understand the various mechanical behavior of the entire system. It is also important to be reproduced the systematic characteristics of the system acquired by laboratory and full-scale testing by numerical analysis in order to carry out the numerical experiment to understand various mechanical behavior of the system. As a conclusion, the hexagonal net has better performance in mechanical and physical behavior compared with that of the rectangular net. Furthermore, due to the hexagonal net shows a good performance in aspect of the load distribution, it gives a good alternative in long-term management of the rockfall protection net.

A Study on Characteristic Analysis of Major Issues in Negotiating Concession Agreement for BTO Projects Using AHP (계층화분석법에 의한 BTO 민간투자사업 협상의 주요쟁점 특성분석에 관한 고찰)

  • Roh, Tae-Ho;Kim, Jong-Won;Lim, Chang-Sik;Lee, Jong-Chool
    • Korean Journal of Construction Engineering and Management
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    • v.9 no.6
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    • pp.137-146
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    • 2008
  • Both competent authorities and private entrepreneurs face plenty of risks when negotiating BTO(Build Transfer Operation) methods of PPI(Private Participations in Infrastructures) projects. Also, success and failure of projects largely depend on the concession agreement contract. In this study, for more efficient negotiation, major issues are examined, and quantitatively analyzed to find out not only the relationship but also the characteristics of which these issues share. Questionnaire research was conducted through both research and by experts who were divided into an ordering agency, design company and constructor. Characteristics of major issues were quantitatively analyzed using the Likert index method, ANOVA(ANalysis of VAriance) and AHP(Analytic Hierarchy Process) analysis. Case studies were examined in order to estimate construction cost, rates of return, government finance support, level of operation-revenues guarantees, estimating operational costs and usage fees. With these 6 items, relative priority, relative impression which is sensible to risk and extent of difficulty in presenting data which is objective were quantitatively analyzed by the ordering agency, design company and constructor groups. From the analysis, there were some similarities between the design company and constructor groups while there was less of similarities between the ordering agency and design company or constructor. The government is diversifying the methods of project promotion, and PPI project from infrastructure-centered to public culture facilities are being expand. The current study will provide not only supporting efficient negotiation but also revitalizing PPI projects.

Synthesis of pH-Sensitive Hydrogel Nanoparticles in Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 pH 감응성 하이드로젤 입자의 합성)

  • Yang, Juseung;Ryu, Won;Lee, Sangmin;Kim, Kyusik;Choi, Moonjae;Lee, Youngmoo;Kim, Bumsang
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.453-458
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    • 2009
  • Recently, new methods to synthesize and process polymers without toxic organic solvents are needed in order to solve environmental problems. The use of supercritical carbon dioxide as a solvent for the polymer synthesis is attractive since it is non-toxic, non-flammable, naturally abundant, and the product may be easily separated from the solvent. In this study, we developed the method using super critical $CO_2$ to prepare P(MAA-co-EGMA) hydrogel nanoparticles as an intelligent drug delivery carrier. The effects of concentrations of PtBuMA-PEO as a dispersion stabilizer and AIBN as an initiator on the particle synthesis were investigated. When PtBuMA-PEO concentration increased, the particle size decreased. However, there was no significant difference in the particle size according to the AIBN concentration. There was a drastic change of the equilibrium weight swelling ratio of P(MAA-co-EGMA) hydrogel nanoparticles at a pH of around 5, which is the $pK_a$ of PMAA. At a pH below 5, the hydrogels were in a relatively collapsed state but at a pH higher than 5, the hydrogels swelled to a high degree. In release experiments using Rh-B as a model solute, the P(MAA-co-EGMA) hydrogel nanoparticles showed a pH-sensitive release behavior. At low pH(pH 4.0) a small amount of Rh-B was released while at high pH(pH 6.0) a relatively large amount of Rh-B was released from the hydrogels.

High-Yield Gas-Phase Laser Photolysis Synthesis of Germanium Nanocrystals for High-Performance Lithium Ion Batteries (고성능 리튬이온 전지를 위한 저마늄 나노입자의 가스상 레이저 광분해 대량 합성법 개발)

  • Kim, Cang-Hyun;Im, Hyung-Soon;Cho, Yong-Jae;Chung, Chan-Su;Jang, Dong-Myung;Myung, Yoon;Kim, Han-Sung;Back, Seung-Hyuk;Im, Young-Rok;Park, Jeung-Hee;Song, Min-Seob;Cho, Won-Il;Cha, Eun-Hee
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.181-189
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    • 2012
  • We developed a new high-yield synthesis method of free-standing germanium nanocrystals (Ge NCs) by means of the gas-phase photolysis of tetramethyl germanium in a closed reactor using an Nd-YAG pulsed laser. Size control (5-100 nm) can be simply achieved using a quenching gas. The $Ge_{1-x}Si_x$ NCs were synthesized by the photolysis of a tetramethyl silicon gas mixture and their composition was controlled by the partial pressure of precursors. The as-grown NCs are sheathed with thin (1-2 nm) carbon layers, and well dispersed to form a stable colloidal solution. Both Ge NC and Ge-RGO hybrids exhibit excellent cycling performance and high capacity of the lithium ion battery (800 and 1100 mAh/g after 50 cycles, respectively) as promising anode materials for the development of high-performance lithium batteries. This novel synthesis method of Ge NCs is expected to contribute to expand their applications in high-performance energy conversion systems.

Cluster-Based Routing Mechanism for Efficient Data Delivery to Group Mobile Users in Wireless Ad-Hoc Networks (그룹 이동성을 가지는 모바일 사용자들 간의 효율적인 데이터 공유를 위한 클러스터 기반 그룹 라우팅 기법 메커니즘)

  • Yoo, Jinhee;Han, Kyeongah;Jeong, Dahee;Lee, HyungJune
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.38C no.11
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    • pp.1060-1073
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    • 2013
  • In this paper, we present a cluster-based routing scheme for efficiently delivering data to group mobile users by extracting and clustering mobile user group simply from beacon message information in wireless ad-hoc networks. First, we propose an online-clustering mechanism that uses a local neighbor table on each node by recursively transmitting to neighbor nodes, and forms a group table where a set of listed nodes are classified as group members, without incurring much overhead. A node that appears the most frequently from neighbor tables throughout the network is selected as the cluster-head node, serving as a data gateway for the intra-cluster. Second, we design an inter-cluster routing that delivers data from stationary data sources to the selected cluster-head node, and a intra-cluster routing to deliver from the cluster-head node to users. Simulation results based on ns-2 in the ad-hoc networks consisting of 518 stationary nodes and 20 mobile nodes show that our proposed clustering mechanism achieves high clustering accuracy of 96 % on average. Regarding routing performance, our cluster-based routing scheme outperforms a naive one-to-one routing scheme without any clustering by reducing routing cost up to 1/20. Also, our intra-cluster routing utilizing a selected cluster-head node reduces routing cost in half as opposed to a counterpart of the intra-cluster routing through a randomly-selected internal group member.

Traffic Lights Detection Based on Visual Attention and Spot-Lights Regions Detection (시각적 주의 및 Spot-Lights 영역 검출 기반의 교통신호등 검출 방안)

  • Kim, JongBae
    • Journal of the Institute of Electronics and Information Engineers
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    • v.51 no.6
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    • pp.132-142
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    • 2014
  • In this paper, we propose a traffic lights detection method using visual attention and spot-lights detection. To detect traffic lights in city streets at day and night time, the proposed method is used the structural form of a traffic lights such as colors, intensity, shape, textures. In general, traffic lights are installed at a position to increase the visibility of the drivers. The proposed method detects the candidate traffic lights regions using the top-down visual saliency model and spot-lights detect models. The visual saliency and spot-lights regions are positions of its difference from the neighboring locations in multiple features and multiple scales. For detecting traffic lights, by not using a color thresholding method, the proposed method can be applied to urban environments of variety changes in illumination and night times.

Pyroelectric Properties of the $\beta$-PVDF (Poly(vilnylidene fluoride)) Thin Film Prepared by Vacuum Deposition with Applying Electric Field (전계인가 진공 증착법으로 제작된$\beta$ -PVDF (Poly(vinylidene fluoride)) 박막의 초전 특성)

  • Chang, Dong-Hoon;Kang, Seong-Jun;Yoon, Yung-Sup
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.39 no.5
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    • pp.23-30
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    • 2002
  • The PVDF (Polyvinylidene Fluoride) thin film having P phase is prepared by the vacuum deposition with applying the electric field and its pyroelectric properties are studied by using a dynamic method to examine the possibility of the application to the pyroelectric IR sensor. The pyroelectric responses of the PVDF thin film are characterized as the frequency dispersion in both low and high modulation frequency regions, and their frequency dependences are observed. In the low frequency region (2~10Hzz), the polarization can easily rotate with the increase of modulation frequency and show the maximum since the reorientation rate of domains is higher than the modulation frequency. On the other hand, in the high frequency region (100~1000Hz), the pyroelectric response decreases as the frequency increases, because the reorienatation rate of domains is suppressed and thus, the change of polarization decreases. Pyroelectric coefficient, figure of merits for noise equivalent power and detectivity of the PVDF thin film are measured as 3.2$\times$10$^{-10}$ C/$\textrm{cm}^2$.K, 2.34$\times$10$^{-10}$ C.cm/J and 1.32$\times$10$^{-9}$ C.cm/J, respectively. Also, the noise equivalent and the detectivity are 1.66$\times$10$^{-7}$ W/H $z^{$\sfrac{1}{2}$}$, 6.03$\times$10$^{5}$ cm.H $z^{$\sfrac{1}{2}$}$W, respectively.