• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.512-518
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• 2019

To develop a membrane electrode assembly (MEA) with lower Pt loading and higher performance in proton exchange membrane fuel cells (PEMFCs), it is an important research issue to understand interfacial structure of Pt/C catalyst and ionomer and design the catalyst layer structure. In this study, we prepared short-side-chain Nafion-based ionomer dispersion using propylene glycol (PG) as a solvent instead of water which is commonly used as a solvent for commercially available ionomers. Cathode catalyst layers with different ionomer content from 20 to 35 wt% were prepared using the ionomer dispersion for the fabrication of four different MEAs, and their fuel cell performance was evaluated. As the ionomer content increased to 35 wt%, the performance of the prepared MEAs increased proportionally, unlike the commercially available water-based ionomer, which exhibited an optimum at about 25 wt%. Small size micelles and slow evaporation of PG in the ionomer dispersion were effective in proton transfer by inducing the formation of a uniformly structured catalyst layer, but the low oxygen permeability problem of the PG-based ionomer film should be resolved to improve the MEA performance.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.4 no.1
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• pp.40-49
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• 1999

A laboratory flume experiment, using turbulence-generating acryl tank and natural sediments, was conducted to investigate the effects of salinity, concentration of suspended sediment, turbulence and clay minerals on the flocculation and settling of fine-grained suspended sediments. While experiments were run, a sequence of water samples were taken near the bottom of the tank to analyze the variations of size distribution and relative contents of clay minerals. The results of the salinity experiment indicate that median settling velocity ($W_{50}$) increases linearly with salinity. Different settling processes of suspended sediments under variable concentrations appear to be predictable, depending upon the range of the suspension concentration. At concentrations less than 200 mg/l, $W_{50}$ is rarely varied with concentration probably because of the individual--grain settling mode. In the range of 200 to 13,000 mg/l show $W_{50}$ and concentration a good relationship following an empirical formula: $W_{50}=0.45C^{0.44}$. This relationship, however, no longer holds in concentrations exceeding 13,000 mg/l; instead, a more or less reverse one is shown. This result suggests an effect of hindered settling. The turbulence effect is somewhat different from that of concentration. Turbulence accelerates the flocculation and settling susepended sediments at low concentration (200 mg/l), whereas at high concentration turbulence breaks floes down and impedes the settling. Size distribution of suspended sediments sampled near the bottom of the tank tend to be more negatively skewed and leptokurtic in turbulent conditions compared to those in static conditions. The clay mineral analysis from the sequential water samples shows that over time the content of smectite decreases most rapidly with illite remaining concentrated in suspension. This means that smectite, among other clay minerals, plays the most effective role in the flocculation of fine-grained sediment in saline water.

• The Journal of Engineering Geology
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• v.15 no.4 s.42
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• pp.447-462
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• 2005

The purposes of this study are to evaluate and discuss the importance of geochemical properties of soil materials that play an important role in the occurrence of the landslide, using analyses of microtexture, particle size distribution, XRC, and FE-SEM equipped with energy dispersive spectrum on soils collected from landslide slopes of gneiss, granite and sedimentary rock areas. Soils from gneiss and granite areas where landslides took place have much clay content relative to those from non landslide areas, particularly pronounced in the granite area. Therefore the clay content is considered a sensitive factor on landslide. Clay minerals contained in soils are illite, chlorite, kaolinite and montmorillonite. Especially the content of clay minerals in soils from the Tertiary sedimentary rocks is highest, with abundant montmorillonite as expandable species. It is believed that this area was much vulnerable to landslide comparable to other areas because of its high content of monoorillonite, even though there might be weak precipitation. Since no conspicuous differentiation in mineralogy between the landslide area and non landslide area can be made, the occurrence of landslide may be influenced not by mineralogy, but by local geography and mechanical properties of soils. Geochemical information on weathering properties, mineralogy, and microtexture of soils is helpful to better understand the causes and patterns of landslide, together with engineering geological analyses.

• Food Engineering Progress
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• v.14 no.2
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• pp.85-91
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• 2010

In the food process, twist screen is widely used to divide particles on the basis of size. As screen equipped in the twist screen perfoms an important part in the particle size distribution mechanism, the contact area of screen and particles, retention time of particles on the screen, mesh and string thickness of screen and the flow pattern of particles on the screen are major points of the separation efficiency. To improve the separation efficiency, increase the retention time and control the flow pattern of particles, screen frame dam and spiral blockage are installed on the sieve of twist screen ${\emptyset}$ 1200 and ${\emptyset}$ 1500. Twist screen ${\emptyset}$ 1500 with frame dam treated similar separation capacity, 37% higher separation ratio and less non-separated particles of product output 1 than general twist screen. Twist screens with frame dam and spiral blockage showed less treatment capacity, three times higher division ratio and entire separation than general twist screen.

• Journal of the Korean Society of Marine Environment & Safety
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• v.19 no.2
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• pp.101-110
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• 2013

In order to classify the trophic state and environmental quality of marine coastal system, an approach using the characteristics and biochemical composition in the sediments can be available. This research, including 25 coastal bay, belong to 131 stations, was carried out along the south coasts of Korea in February 2007. Type of sediment, total ogranic carbon, total nitrogen, phytopigments and biochemical composition(proteins, lipids, carbohydrates) were analyzed. Result from Multi-dimensional Scaling(MDS) ordination indicates that four group can be identified. The result of ANOVA with tukey test shows that the concentrations of proteins, carbohydrates and biopolymeric carbon were significantly different to four groups. We propose the trophic state classification for these groups using the biochemical composition of sediment organic matter. I group(Masan, Jinhae, Haengam) has been defined as hypertrophic state, II group(Tongyeong, Goseong；Jaran, Geoje et al.), as eutrophic; III group(Gamak, Deungnyang, Yeoja et al.), as mesotrophic and IV group(Sinan, Jindo, Muan), as oligotrophic. On the basis of results reported in this study, the biochemical composition of sediment organic matter could be considered an useful and sensitive tool for the classification of the trophic state of marine coastal systems.

• Journal of the Korean Chemical Society
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• v.47 no.5
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• pp.479-486
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• 2003

In this study, poly(DL-lactide-co-glycolide) nanoparticles loaded with water-insoluble vitamins such as vitamin A (Retinol) and vitamin E acetate were prepared by the emulsification diffusion method. Polymer solution was prepared by the two water-miscible organic solvent, such as ethanol and acetone. Because of its biocompatible property, polyethyleneglycol-polypropyleneglycol diblock copolymer was used as surfactant and stabilizer. The influence of some preparative variables on the nanoparticle formation and on the loading efficiency of active agents, such as the type and concentration of stabilizing agent, the stirring methods, the water/oil phase ratio and the polymer concentration were investigated in order to control and optimize the process. After preparation of nanoparticles loaded with active agent, particle size and distribution were evaluated by the light scattering particle analyzer. The loading efficiency of active agents was evaluated by the UV-visible spectroscopy. As the results, particle size were 50-200 nm and dispersibility was monodisperse. The optimum loading efficiency of active agents was observed 50-60%. It was found that the appropriate of selections of binary solvent mixtures and polymeric concentrations in both organic and aqueous phases could provide good yield and favorable physical properties of PLGA nanoparticles.

• Journal of the Korean earth science society
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• v.23 no.7
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• pp.565-574
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• 2002

Based on previous investigations of aerial photographs and topographical surveys, this study focuses on the sedimentologic features of the Daebudo area including sedimentation processes, sedimentary facies and hydrologic conditions of the erosional coast. A total of 137 surface sediments and one core (by hand auger) sediment were obtained to interpret the depositional environment of the erosional coast in the macro-tidal coast. Surface sediments are distributed from sandy gravel (sG) to silt (Z). Textural parameters are characterized not only by coarse, poorly sorted, positive skewed and multi-modal distribution in the supra-tidal flat, but also finer, relatively well-sorted, symmetric distribution in the intertidal flat. According to the C/M diagram, sediment transport modes of study area are characterized by the mixed mode of suspension and bedload in the upper-, middle-tidal flat and by uniform suspension in the lower-tidal flat due to tidal effect. Vertical sediment distribution of the core, collected near shoreline, shows coarsening-upward, poorly sorted pattern by the input of detritus resulting from coastal erosion. Considering the sedimentological features of the study area, it appears to be composed of a coastal zone changed by not only artificial reclamation, but also by natural processes such as strong wave action due to typhoons and storms during high water level and long/short-term sea level rising. As a result, tide-dominated erosional coasts show that the shore is affected by local, temporal and hydrological conditions near high tide level and that the intertidal flat is represented by a general tide-dominated sedimentary environment.

• Economic and Environmental Geology
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• v.37 no.1
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• pp.143-151
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• 2004

This study focused on examining the possibility of recycling mine solid waste as environmental materials, especially for porous media. Basic properties including mineralogical compositions, chemical compositions, and particle size distribution of the tailings from the Sangdong W mine were checked. The mineralogical and chemical compositions of the tailings samples were not much different in depth. According to Korean Standard Leaching Test for Wastes(KSLT), concentrations of heavy metals leached from the tailings were below the standard values. As a result of particle size analysis, the median diameter (d$_{50}$) of the tailings was in the range of 10 to 30 ${\mu}{\textrm}{m}$. The stable tailings slurry made up of 3 ${\mu}{\textrm}{m}$ in d$_{50}$ was prepared using Attrition Mill. The milling condition was 40 vol% in slurry concentration, 700 rpm in stirring speed, and 1 hour in milling time. PEI was added as dispersing agent. Concentrated slurry was extended to 3 times by foaming method. In the case of 3 times foamed slurry, the total and open porosity of ceramic supports sintered at 1,075$^{\circ}C$ for 90 minutes was about 80% and 72%, respectively. Pore size was in the range of 30∼350${\mu}{\textrm}{m}$. Therefore, the tailings could be recycled starting material for environmental materials such as macroporous ceramic support.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.39 no.3
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• pp.230-238
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• 2003

An effect on the enhancing production of hollow 'jumbo' structures and the condition of artificial reefs (dice and hollow jumbo structure) by side scan sonar were described. The experiment of the capture of fish in the jumbo structures and control site (non-artificial site) by trammel net and traps was done twice every year from 1998 to 2000. The relative catches by trammel net between in the jumbo structure and in the control site was significantly different in number and in weight at 5% level and also that by traps significantly different in weight. The t-test of the catch of finespotted flounder showed that the hollow jumbo structure was regarded as a breeding field because the average size of the flounder in the jumbo site was smaller than that in the control site. The search on the condition of the artificial reefs (dice and hollow jumbo structure) was performed by side scanning sonar which showed various phase of it such as accumulated, dispersed, scouring and partly buried. The result implied that in the area of sand bottom with strong tide like the western sea of Korea, the current criterion for constructing artificial reef should be modified because of the sand moving on the bottom.

• Polymer(Korea)
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• v.29 no.4
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• pp.350-356
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• 2005

Poly(methyl methauylate)/montmorillonite nanocomposites were incorporated into acrylic bone cement in order to improve the mechanical properties and reduce the exotherm of acrylic bone cement. The nanocomposites were prepared using a suspension polymerization and characterized by scanning electron microscopy, X-ray diffraction, trans-mission electron microscopy, gel permeation chromatography, particle size analyzer and electron dispersive spectroscopy. The acrylic bone cements with poly (methyl methacrylate)/nanocomposite s were prepared and their thermal and mechanical properties were characterized. The prepared polymeric beads were composed of polymer-intercalated nanocomposites with partially exfoliated MMT layers, and the mean diameter of them was $50\~60$ fm with the spherical shape. The maximum setting temperature of the acrylic bone cements decreased from 98 to $81\~87^{circ}C$. The mechanical strengths and moduli of the acrylic bone cement with 0.1 $wt\%$ MMT were increased. compared to that without MMT. However, the mechanical properties were generally decreased with increasing incorporated MMT amounts. It is presumably due to the bubbles in nanocomposite beads generated during polymerization.