• Title/Summary/Keyword: 분산분해

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Dyeing on PLA with Disperse Dyes (1) - Effect of Ultrasound (PLA섬유의 분산염료에 의한 염색 (1) - 초음파의 영향)

  • Jeong, Dong-Seok;Cheon, Tae-Il;Lee, Mun-Cheul
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.53-53
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    • 2011
  • Poly(lactic acid)(이하 PLA라 칭함)는 1970-80년대의 초기 연구에서는 높은 제조비용과 희귀성에 의해 봉합사와 약물전달시스템으로 용도가 제한적이었으나 1980년대를 거쳐 1990년 이후 농업의 혁신적인 변화를 거쳐 옥수수의 다양한 측면의 이용의 하나로서 6-7년 전부터 양산화에 성공하여, 의류, 필름 및 플라스틱의 여러 가지 분야에서 적용가능성을 모색하고 있다. PLA의 장점은 석유가 아닌 천연 원료에서 얻을 수 있으며, 기존의 합성섬유와는 달리 일정한 조건하에서 미생물 등에 의해 물과 이산화탄소로 90% 이상 분해되는 친환경적인 소재이다. 합성섬유에서 의류용으로 대부분 사용되는 폴리에스테르(이하 PET라 칭함)와 유사한 물성을 가지고 있는 PLA섬유는 PET섬유와 유사한 분산염료로 염색할 수 있다. 따라서 PLA섬유는 분산염료에 의한 염색법을 중심으로 연구되어지고 있으나, PET 섬유의 융점이 $254^{\circ}C$부근인 반면, PLA섬유는 $160-170^{\circ}C$부근이다. 이로 인해 PLA를 섬유로 용도전개에 있어서 약점으로 작용하고 있다. 그러나 PLA섬유는 특유의 경량감과 새로운 촉감 등의 많은 장점을 지니고 있어 여러 가지 용도전개가 되어지고 있다. 초음파는 사람이 들을 수 없는, 사람마다 한계값은 다르지만, 주파수 약 25kHz이상의 음파를 말하며, 주파수가 높고 파장이 짧기 때문에 강한 진동을 수반한다. 초음파의 이용 원리는 Cavitation이라는 현상으로 생성된 기포가 터지면서 강력한 에너지를 방출한다. 이것은 강력하여 사방으로 퍼져 물질표면이나 내부에 영향을 미친다. 섬유에서는 표면에 뭍은 불순물을 제거하는 세정 등에 응용되고 있으며, 염색분야에서도 다양하게 연구되어지고 있다. 본 연구에서는 초음파에 의한 PLA섬유의 염색성을 조사하였다. PLA섬유를 정련하여 초음파작용의 유무에 따라 염색하여 그 결과를 고찰하였다. 초음파 작용에 따른 분산염료의 표면 색변화는 없었으며, 섬유 표면 색 농도의 차이는 초음파 작용에 의하여 저온에서는 차이가 나타나지만, 고온인 $80^{\circ}C$에서는 오히려 낮아졌다.

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A Study on Construction of an Optimal Fossil Fuel Mix: A Portfolio-Based Approach (평균-분산 모형을 이용한 화석에너지원 소비조합 구성에 관한 연구)

  • Cha, Kyungsoo
    • Environmental and Resource Economics Review
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    • v.20 no.2
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    • pp.335-356
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    • 2011
  • In this paper, we attempted to suggest a way to evaluate appropriateness and efficiency for the energy consumption structure. For this, based on Markowitz (1952)' mean-variance portfolio model, we constructed an optimal fossil fuel mix. In constructing the optimal mix, we first defined returns on fossil fuels (oil, coal and natural gas) as TOE (Ton of Oil Equivalent) per $1. Then, by using the dynamic latent common factor model, we decomposed the growth rates of the returns on each fossil fuel into two parts : the common part and the idiosyncratic part. Finally, based on the results from the dynamic latent common factor model, we constructed the optimal fossil fuel mix implied by the mean-variance portfolio model. Our results indicate that for the fossil fuel mix to be on the efficient frontier, it is crucial to reduce oil consumption as low as possible. Moreover, our results imply that it is more efficient to increase natural gas consumption rather than coal consumption in reducing oil consumption. These results are in line with the strategies for the future energy consumption structure pursued by Korea and indicate that reduction in oil use can improve overall efficiency in energy consumption.

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Ground-Roll Suppression of the Land Seismic Data using the Singular Value Decomposition (SVD) (특이값 분해를 이용한 육상 탄성파자료의 그라운드롤 제거)

  • Sa, Jin-Hyeon;Kim, Sung-Soo;Kim, Ji-Soo
    • The Journal of Engineering Geology
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    • v.28 no.3
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    • pp.465-473
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    • 2018
  • The application of singular value decomposition (SVD) filtering is examined for attenuation of the ground-roll in land seismic data. Prior to the SVD computation to seek singular values containing the highly correlatable reflection energy, processing steps such as automatic gain control, elevation and refraction statics, NMO correction, and residual statics are performed to enhance the horizontal correlationships and continuities of reflections. Optimal parameters of SVD filtering are effectively chosen with diagnostic display of inverse NMO (INMO) corrected CSP (common shot point) gather. On the field data with dispersion of ground-roll overwhelmed, continuities of reflection events are much improved by SVD filtering than f-k filtering by eliminating the ground-roll with preserving the low-frequency reflections. This is well explained in the average amplitude spectra of the f-k and SVD filtered data. The reflectors including horizontal layer of the reservoir are much clearer on the stack section, with laminated events by SVD filtering and subsequent processing steps of spiking deconvolution and time-variant spectral whitening.

ACE Inhibitory and Antioxidative Activities of Silkworm Larvae (Bombyx mori) Hydrolysate (번데기 가수분해물의 ACE 저해활성과 항산화활성)

  • Yu, Jung-Sik;Woo, Koan-Sik;Hwang, In-Guk;Lee, Youn-Ri;Kang, Tae-Su;Jeong, Heon-Sang
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.2
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    • pp.136-140
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    • 2008
  • In order to utilize the silkworm larvae (Bombyx mori) protein, defatted silkworm protein was hydrolysed by four enzymes (pepsin, trypsin, neutrase and alcalase) at various hydrolysis times (6, 12, 18, 24 and 30 hr) and suspension concentrations (2, 5, 10, 15 and 20%). Protein solubility index, ACE (angiotensin converting enzyme) inhibitory activity and antioxidative activity of silkworm protein hydrolysates were investigated. The optimum condition of hydrolysis was 10% suspension concentration and 18 hr. Protein solubility index of trypsin treatment was higher than other enzyme treatments. ACE inhibitory activity and $IC_{50}$ value of antioxidative activity of neutrase treatment were 86.16% at $100\;{\mu}g/mL$ and $352.75\;{\mu}g/mL$, respectively; also, these values were higher than other enzyme treatments.

Evaporation Characteristics of Oil and Abundance Ratio of Hydrocarbon Compounds at Different Temperatures (온도 변수에 대한 유류의 휘발특성 및 탄화수소 화합물의 존재비에 관한 연구)

  • Choi, Jung-Sik
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.7
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    • pp.1116-1123
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    • 2021
  • Oil spilled in seawater undergoes physical and chemical changes as well as biological degradation through various weathering processes, such as evaporation, diffusion, dispersion, emulsification, dissolution, oxidation, and sedimentation. Evaporation is one of the most immediate and prompt weathering processes, and it has the greatest influence on majority of pollutants. In this study, the evaporation characteristics of different oil samples were studied; the volatilization characteristics of gasoline, kerosene, and diesel were compared at average seawater (25 ℃) and near-equator (35 ℃) temperatures. The oil samples were pre-treated and then collected at regular intervals. Gas chromatography-mass spectrometry analysis was performed, and the changes in the amount of the hydrocarbons were calculated.

Effects of Thermal Dispersion Damage on the Pyrolysis and Reactor Relarionship Using Comutational Fluids Dynamics (전산유체역학을 활용한 폐플라스틱열분해 반응기의 기체분산판에 대한 유동해석)

  • Jongil, Han;SungSoo, Park;InJea, Kim;Kwangho, Na
    • New & Renewable Energy
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    • v.19 no.4
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    • pp.53-60
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    • 2023
  • The Computational Fluid Dynamics (CFD) model is a method of studying the flow phenomenon of fluid using a computer and finding partial differential equations that dominate processes such as heat dispersion through numerical analysis. Through CFD, a lot of information about flow disorders such as speed, pressure, density, and concentration can be obtained, and it is used in various fields from energy and aircraft design to weather prediction and environmental modeling. The simulation used for fluid analysis in this study utilized Gexcon's (FLACS) CODE, such as Norway, through overseas journals, for the accuracy of the analysis results through many experiments. It was analyzed that a technology for treating two or more catalysts with physical properties under low-temperature atmospheric pressure conditions could not be found in the prior art. Therefore, it would be desirable to establish a continuous plan by reinforcing data that can prove the effectiveness of producing efficient synthetic oil (renewable oil) through the application that pyrolysis under low-temperature and atmospheric pressure conditions.

A Case Study of Monitored Natural Attenuation at the Petroleum Hydrocarbon Contaminated Site : II. Evaluation of Natural Attenuation by Groundwater Monitoring (유류오염부지에서 자연저감기법 적용 사례연구 II. 지하수모니터링에 의한 자연저감 평가)

  • Yun Jeong Ki;Lee Min Hyo;Lee Suk Young;Noh Hoe Jung;Kim Moon Soo;Lee Kang Kun;Yang Chang Sool
    • Journal of Soil and Groundwater Environment
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    • v.9 no.3
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    • pp.38-48
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    • 2004
  • Natural attenuation of petroleum hydrocarbon was investigated at an industrial complex about 45 Km away from Seoul. The three-years monitoring results indicated that the concentrations of DO, nitrate, and sulfate in the contaminated area were significantly lower than the background monitoring groundwater under the non-contaminated area. The results also showed a higher ferrous iron concentration, a lower redox potential, and a higher (neutral) pH in the contaminated groundwater, suggesting that biodegradation of TEX(Toluene, Ethylbenzene, Xylene) is the major on-going process in the contaminated area. Groundwater in the contaminated area is anaerobic, and sulfate reduction is the dominant terminal electron accepting process in the area. The total attenuation rate was about 0.0017∼0.0224day$^{-1}$ and the estimated first-order degradation rate constant(λ) was 0.0008∼0.0106day$^{-1}$ . However, the reduction of TEX concentration in the groundwater was resulted from not only biodegradation but also dilution and reaeration through recharge of uncotaminated surface and groundwater. The natural attenuation was, therefore, found to be an effective, on-going remedial process at the site.

UV Light-assisted Photocatalytic Degradation of Simluated Methylene blue Dye by Multilayered ZnO Films (다층 ZnO 막에 의한 모의 메틸렌블루 염료의 자외선 광촉매분해)

  • Khan, Shenawar Ali;Zafar, Muhammad;Kim, Woo Young
    • Journal of the Korean Applied Science and Technology
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    • v.39 no.1
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    • pp.34-41
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    • 2022
  • As the use of chemical products increases in daily life, the removal of dye waste has also emerged as an important environmental issue. This dye waste can be decomposed using a photocatalyst, and the photocatalyst can be synthesized very cost-effectively by using the sol-gel technology. The sol-gel technology is not only very useful for nanoscale film formation, but also can simply form multilayer structures. Using a multiple spin coating method, in this study, a ZnO film with a multilayered structure (3 layers, 5 layers) was formed by using zinc oxide (ZnO), which is effective in decomposing various dyes. For performance comparison, a ZnO film having a single layer structure by a single spin coating method was prepared as a control. Structural and elemental analysis of ZnO film was performed using an X-ray diffraction analyzer and an energy dispersive X-ray spectrometer. A nanowire-like surface morphology could be observed through a scanning electron microscope. Additionally, UV-Vis spectrophotometer was used to measure the absorbance of UV light. The ZnO film with a five-layer structure degraded the simulated methylene blue by 49% more than the ZnO film with a single-layer structure. In conclusion, it was found that ZnO having a multilayered structure is useful as a photocatalyst that decomposes methylene blue dye more effectively.

Biodegradation of Bunker-C Oil by the Mixed Enrichment Culture of Marine Bacteria (혼합배양 해양세균에 의한 Bunker-C유의 생물분해)

  • PARK In-Sick;PARK Jung-Youn;SUH Kuen-Hack;HONG Yong-Ki
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.20 no.2
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    • pp.152-156
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    • 1987
  • A mixed population of marine bacteria was obtained to catalize the biodegradation of bunker-C fuel oil by means of the enrichment culture technique. Samples used for the enrichment culture were collected from sea water and sediments in the vicinity of Pusan, Chungmu, and Ulsan in Korea. As the biodegradation of bunker-C oil proceeded, the number of bacteria increased from $1.1\times10^6\;to\;8.7\times10^8$ cells per ml when pH was bufferized by 0.1 M Tris-HCl buffer to 7.6, then oil dispersion increased to $OD^{540}$ 2.2 and approximately $48\%$ of the oil was biodegradated in 10 days. Oil dispersion was absolutely dependent on the addition of nitrogen and phosphate sources in sea water. High and low sulfur-containing bunker-C and crude oil could be dispersed similarly. Bunker-C oil was dispersed rapidly at the pH ranging from 7.0 to 8.0 and dispersed to the amount of 7.5 g per liter of sea water medium.

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A study on the multifrontal method in interior point method (내부점 선형계획법에서의 멀티프런탈방법에 관한 연구)

  • 김병규;박순달
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 1995.09a
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    • pp.370-380
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    • 1995
  • 선형계획법의 해법으로 최근에는 내부점기법(Interior Point Method)가 관심 을 끌고 있다. 이 내부점 기법은 계산복잡도 뿐만 아니라 수행속도면에서도 우수한 결과를 보이고 있다. 이 방법은 매 회 대칭양정치(Symmetric Positive Definite)인 선형시스템을 풀어야 하는데 이 과정이 전체 내부점 수 행시간의 80-90%를 차지한다. 따라서 내부점 기법의 수행속도는 대칭양정치 인 선형시스템을 효율적으로 푸는 방법에 달려 있다. 대칭양정치인 선형시스 템을 풀기 위해서는 상하분해를 이용하게 되는 데 가우스소거를 이용해서 상하 분해를 하는 경우 매 단계에서 행렬의 모든 요소를 가지고 있을 필요 가 없다. 행렬의 모든 요소에 대한 정보를 동시에 필요로 하지 않는다. 즉, 현 단계에서 가우스소거와 관련된 열들에 대한 정보만 있으면 상하 분해가 가능하고 이러한 개념을 이용한 방법이 프런탈방법이다. 프런탈 방법은 대형 선형계획 문제를 풀기에 유리하다는 장점이 있다. 이러한 프런탈 방법을 확 장해서 동시에 여러 개의 프런탈을 계산하는 방법이 멀티프런탈방법이다. 이 방법은 알고리듬 자체가 병렬처리에 적합하기 때문에 병렬처리와 관련해서 도 많은 연구가 수행되고 있다. 본 연구에서는 삭제나무(Elimination Tree)를 이용한 프런탈 방법과 프런탈방법에 슈퍼노드의 개념을 도입한 슈퍼노들 프 런탈방법등에 대해서 이제까지의 연구 현황을 알아보고 프런탈방법에 적합 하고 효율적인 자료 구조와 멀티프런탈 방법에 적용 가능한 병렬알고리듬에 대하여 연구하고자 한다. 본 연구결과 기대효과로는 프런탈 방법에 적합하고 효율적인 자료 구조와 멀티프런탈 방법에 적용 가능한 병렬알고리듬을 개발 함으로써 내부점 선형계획법의 수행속도의 개선에 도움이 될 것이다.성요소들을 제시하였다.용자 만족도가 보다 높은 것으 로 나타났다. 할 수 있는 효율적인 distributed system를 개발하는 것을 제시하였다. 본 논문은 데이타베이스론의 입장에서 아직 정립되어 있지 않은 분산 환경하에서의 관계형 데이타베이스의 데이타관리의 분류체계를 나름대로 정립하였다는데 그 의의가 있다. 또한 이것의 응용은 현재 분산데이타베이스 구축에 있어 나타나는 기술적인 문제점들을 어느정도 보완할 수 있다는 점에서 그 중요성이 있다.ence of a small(IxEpc),hot(Tex> SOK) core which contains two tempegatlue peaks at -15" east and north of MDS. The column density of HCaN is (1-3):n1014cm-2. Column density at distant position from MD5 is larger than that in the (:entral region. We have deduced that this hot-core has a mass of 10sR1 which i:s about an order of magnitude larger those obtained by previous studies.previous studies.업순서들의 상관관계를 고려하여 보다 개선된 해를 구하기 위한 연구가 요구된다. 또한, 준비작업비용을 발생시키는 작업장의 작업순서결정에 대해서도 연구를 행하여, 보완작업비용과 준비비용을 고려한 GMMAL 작업순서문제를 해결하기 위한 연구가 수행되어야 할 것이다.로 이루어 져야 할 것이다.태를 보다 효율적으로 증진시킬 수 있는 대안이 마련되어져야 한다고 사료된다.$\ulcorner$순응$\lrcorner$<

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