• Title/Summary/Keyword: 분배 특성

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Photolysis of the insecticide imidacloprid in water and water-paddy soil systems (살충제 imidacloprid의 물 및 물-토양계 중 광분해)

  • Ihm, Yang-Bin;Kyung, Kee-Sung;Kim, Chan-Sub;Choi, Byeong-Ryeol;Hong, Soo-Myung;Lee, Jae-Koo
    • The Korean Journal of Pesticide Science
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    • v.8 no.1
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    • pp.38-45
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    • 2004
  • To elucidate the photolysis characteristics of the insecticide imidacloprid in the environment, $[^{14}C]$imidacloprid was treated into water and paddy soil-water system. In water system, the amount of $^{14}C$-radioactivity distributed in aqueous phase was rapidly increased up to 80% of total $^{14}C$ in water during 7 days of exposure to sunlight. Also, the amounts of imidacloprid in water at day 0 and 3 days after treatment were 1.2461 and 0.8594 mg/kg, respectively, not being detected 7 days after treatment, indicating rapid degradation of imidacloprid in water by sunlight. One photodegradation product, imidacloprid urea, in which the $N-NO_2$ moiety of imidacloprid was replaced by oxygen, was detected from water in water and water-paddy systems. The amount of the metabolite detected from water in water system was 0.0112 mg/kg 1 day after treatment and reached the top concentration of 0.0391 mg/kg 7 days after treatment. In case of water-paddy system, its amount was 0.0117 mg/kg 1 day after treatment and reached the highest concentration of 0.0259 mg/kg 3 days after treatment. Rapid transformation of imidacloprid into polar compounds continued until 7 days after treatment, considering that 80% of $^{14}C$ in water distributed in aqueous phase 7 days after treatment, amount of imidacloprid was 1.6538 mg/kg at day 0 and 0.8785 mg/kg 1 day after treatment, not being detected after 15 days, indicating rapid degradation of imidacloprid in water-paddy soil system by sunlight. The direct degradation of imidacloprid to imidacloprid urea would be a major photodegradation pathway in water and water-paddy soil systems.

크리프와 건조수축을 고려한 철근콘크리트 기둥과 동바리의 축력 재분배 해석법

  • 김선영;이태규;김진근;이수곤
    • Journal of the Korea Concrete Institute
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    • v.13 no.6
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    • pp.629-636
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    • 2001
  • To apply the research results to the design and the construction of the high rise buildings, long-term behavior of reinforced concrete structure have been widely studied. However, shoring and reshoring at early ages have not been considered in the most of studies. The removal of forms and shores has been dealt with one construction sequence. i.e. the deformation occurred at the early age before the removal of shore has been neglected. In this paper, two-dimensional frame analysis program for long-term behavior of reinforced concrete was developed. In the developed program, construction sequence including the settlement and the removal of shores is considered to predict axial force variation due to forms ,shores, and time-dependent concrete stiffness. Analysis results show that the time-dependent axial force of shores is reduced, and the redistributed axial force of the interior column is greater than the value by elastic analysis and that of the exterior column is smaller. In order to demonstrate the validity of this program, the test frame was constructed in sequence of the placement of concrete, form removal, reshoring, shore removal, and the application of additional load. The proposed program predicts experimental results well.

Current States of the Global Water Market and Considerations for the Groundwater Industry in South Korea (물 시장의 현주소와 지하수 산업에 대한 고찰)

  • Kim, Byung-Woo;Koh, Yong-Kwon;Choi, Doo-Houng;Kim, Deog-Geun;Kim, Gyoo-Bum
    • The Journal of Engineering Geology
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    • v.24 no.3
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    • pp.431-440
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    • 2014
  • Since the establishment of the Groundwater Act in Korea in 1993, the national policy on groundwater has focused on the preservation and management of groundwater, which should be used only as a subsidiary water resource. However, population growth, increased water demand, climate change, and the need for uniform water distribution have brought changes to groundwater policy, and have led to the prioritization of development projects such as groundwater dams and river bank filtration. Population growth, changes to the water environment, and increased water risks have all played a role in triggering rapid growth within the water industry; the size of the investment in water resources will also continue to increase worldwide. Until now, private wells and bottled mineral water have led the groundwater industry in South Korea. However, a new area of the groundwater industry, which includes the health and medical sciences, employs groundwater properties derived from regional geology, and is growing. This requires the advancement of groundwater research and technical development connected with ICT (Information and Communication Technology) and medical science, and that the public development of groundwater and its various applications is expanded through locating groundwater in the core of the water industry cluster.

A study on teaching the system of numbers considering mathematical connections (수학적 연결성을 고려한 수 체계의 지도에 관한 연구)

  • Chung, Young-Woo;Kim, Boo-Yoon;Pyo, Sung-Soo
    • Communications of Mathematical Education
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    • v.25 no.2
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    • pp.473-495
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    • 2011
  • Across the secondary school, students deal with the algebraic conditions like as identity, inverse, commutative law, associative law and distributive law. The algebraic structures, group, ring and field, are determined by these algebraic conditions. But the conditioning of these algebraic structures are not mentioned at all, as well as the meaning of the algebraic structures. Thus, students is likely to be considered the algebraic conditions as productions from the number sets. In this study, we systematize didactically the meanings of algebraic conditions and algebraic structures, considering connections between the number systems and the solutions of the equation. Didactically systematizing is to construct the model for student's natural mental activity, that is, to construct the stream of experience through which students are considered mathematical concepts as productions from necessities and high probability. For this purpose, we develop the program for the gifted, which its objective is to teach the meanings of the number system and to grasp the algebraic structure conceptually that is guaranteed to solve equations. And we verify the effectiveness of this developed program using didactical experiment. Moreover, the program can be used in ordinary students by replacement the term 'algebraic structure' with the term such as identity, inverse, commutative law, associative law and distributive law, to teach their meaning.

Solubility Change of Gasoline Components Under Evaporation (휘발에 의한 가솔린 성분의 조성 및 용해도 변화특성)

  • 염익태;이상현;염혜정;안규홍
    • Journal of the Korean Society of Groundwater Environment
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    • v.5 no.1
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    • pp.37-43
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    • 1998
  • Batch experiments were conducted to study the dissolution behavior of gasoline components. First, the dissolution kinetics of gasoline components and the applicability of Raoult's law in predicting their solubilities were investigated. In addition, the effects of compositional change of gasoline due to evaporization on the solubilities of individual components and TPH were determined. The kinetics of gasoline-water man transfer was found to be very similar for most components except for MTBE, which is a major additive for commercial gasoline. At equilibrium, the gasoline-water partitioning coefficients of individual components showed a log-linear relationship with their pure solubilities, though the slope was a little less than that predicted by Raoult's law. The concentrations of the individual components in the gasolines concentrated by volatilization could be characterized by the initial increase followed by substantial decrease. Almost the same behavior was observed for their solubilities. The total solubility (TPH) of gasoline decreased rapidly with the initial volume reduction and gradually decreased afterwards. The solubilities of BTEX, the major regulatory compounds, decreased even faster than the TPH solubilities. It was concluded that the compositional change of gasoline by volatilization may greatly affect their leaching potential and the toxicity of the contacting groundwater. The toxicity reduction efficiency by evaporating gasoline could be much more than the mass removal efficiency.

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Study of Composite Adsorbent Synthesis and Characterization for the Removal of Cs in the High-salt and High-radioactive Wastewater (고염/고방사성 폐액 내 Cs 제거를 위한 복합 흡착제 합성 및 특성 연구)

  • Kim, Jimin;Lee, Keun-Young;Kim, Kwang-Wook;Lee, Eil-Hee;Chung, Dong-Yong;Moon, Jei-Kwon;Hyun, Jae-Hyuk
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.15 no.1
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    • pp.1-14
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    • 2017
  • For the removal of cesium (Cs) from high radioactive/high salt-laden liquid waste, this study synthesized a highly efficient composite adsorbent (potassium cobalt ferrocyanide (PCFC)-loaded chabazite (CHA)) and evaluated its applicability. The composite adsorbent used CHA, which could accommodate Cs as well as other molecules, as a supporting material and was synthesized by immobilizing the PCFC in the pores of CHA through stepwise impregnation/precipitation with $CoCl_2$ and $K_4Fe(CN)_6$ solutions. When CHA, with average particle size of more than $10{\mu}m$, is used in synthesizing the composite adsorbent, the PCFC particles were immobilized in a stable form. Also, the physical stability of the composite adsorbent was improved by optimizing the washing methodology to increase the purity of the composite adsorbent during the synthesis. The composite adsorbent obtained from the optimal synthesis showed a high adsorption rate of Cs in both fresh water (salt-free condition) and seawater (high-salt condition), and had a relatively high value of distribution coefficient (larger than $10^4mL{\cdot}g^{-1}$) regardless of the salt concentration. Therefore, the composite adsorbent synthesized in this study is an optimized material considering both the high selectivity of PCFC on Cs and the physical stability of CHA. It is proved that this composite adsorbent can remove rapidly Cs contained in high radioactive/high salt-laden liquid waste with high efficiency.

Game Based Cooperative Negotiation among Cloud Providers in a Dynamic Collaborative Cloud Services Platform (게임 이론 기반 동적 협력 클라우드 서비스 플랫폼에서의 클라우드 공급자간 협상 기법)

  • Hassan, Mohammad Mehedi;Huh, Eui-Nam
    • Journal of Internet Computing and Services
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    • v.11 no.5
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    • pp.105-117
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    • 2010
  • In recent years, dynamic collaboration (DC) among cloud providers (CPs) is becoming an inevitable approach for the widely use of cloud computing and to realize the greatest value of it. In our previous paper, we proposed a combinatorial auction (CA) based cloud market model called CACM that enables a DC platform among different CPs. The CACM model allows any CP to dynamically collaborate with suitable partner CPs to form a group before joining an auction and thus addresses the issue of conflicts minimization that may occur when negotiating among providers. But how to determine optimal group bidding prices, how to obtain the stability condition of the group and how to distribute the winning prices/profits among the group members in the CACM model have not been studied thoroughly. In this paper, we propose to formulate the above problems of cooperative negotiation in the CACM model as a bankruptcy game which is a special type of N-person cooperative game. The stability of the group is analyzed by using the concept of the core and the amount of allocationsto each member of the group is obtained by using Shapley value. Numerical results are presented to demonstrate the behaviors of the proposed approaches.

Evaluation of A Removal Process for the Residual Uranium from the Simulated Radwaste Solution by Solvent Extraction with TBP (TBP 용매추출에 의한 잔존 우라늄 제거공정 평가)

  • Lee, Eil-Hee;Kim, Kwang-Wook;Lim, Jae-Gwan;Kwon, Seon-Gil;Yoo, Jae-Hyung
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.232-237
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    • 1998
  • This study was carried out to find the optimal operating conditions for separation of residual uranium from the simulated radwaste solution containing 19 elements, and to evaluate the validity of the process. The selected process was based on the solvent extraction with TBP(tributyl phosphate). As an extractor, two miniature mixer-settlers with a total of 18 stages were used. Extraction yield of U, Np and Tc was about 99.2%. 32.1%, and 99.9%, respectively. The other elements were coextracted in the range of 1~4%. Extraction yield of U exceeded those of the previous work performed with batch system, which resulted in the low extractability of U (about 80%) according to the coexisting element such as Nd and Fe. It was due to the characteristics of multi-stage extractor. On the other hand, low extractability of Np was caused by various oxidation states in the nitric acid medium. In the case of Tc, its high extractability may be attributed to the complex formation with Zr and U, which is not well proved yet. All elements extracted with TBP were stripped into aqueous phase more than 99% by 0.01M $HNO_3$. From the results, this process has no problem with respect to in the same step was required, because Np was distributed in the raffinate and U product, respectively.

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Enhanced Removal of Benzene-NAPL in Soil using Concurrent Injection of Cosolvent and Air (Cosolvent와 공기 동시 주입 공정에 의한 토양 내 벤젠-NAPL 세정 증대 연구)

  • Song, Chung-Hyun;Jeong, Seung-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.11
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    • pp.1095-1101
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    • 2008
  • Nonaqueous phase liquids (NAPL) are the continuous source for soil and groundwater contamination. The first objective of the study was to verify the effect of co-injection of cosolvent and air on NAPL removal from soil-column system. The second objective of the study was to investigate the effect of alcohol-partitioning property on the NAPL removal by the co-injection process of cosolvent and air. Enhanced removal of benzene-NAPL by the co-injection process of ethanol and air was also verified within the soilcolumn system. However, the co-injection process of Tert-butanol (TBA) and air showed no enhancement of benzene-NAPL removal. This study found that the viscous pressure of TBA was so higher than the capillary pressure and TBA easily displaced the benzene-NAPL and air present in soil pores. Air of the coinjection process did not work for NAPL removal but hindered NAPL mobilization. NAPL partitioning property and viscous pressure of cosovlent should be considered for application of the co-injection process of cosolvent and air.

A Case Study on the Spatial Configuration and Allocation of Catering Facilities of Newly-Built Elementary Schools in Sejong City (세종시 신설초등학교의 조리장 공간구성과 면적에 관한 사례 연구)

  • Song, Byung-Ha
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.2
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    • pp.433-442
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    • 2017
  • This study consists of five case studies of the catering facilities of newly-built elementary schools' in Sejong City, regarding the spatial configuration and allocation. The analysis indicated that the space allocated in the cooking area in the five schools compared to the standard was as follows: School A; 99.2%, B; 91.1%, C; 81.4%, D; 110.8%, E; 88.1%. Accordingly, the cooking area was close to, or slightly above the standard; nevertheless, other areas in the facilities were not allocated sufficient space and were not appropriately planned. Among the other findings, the receiving areas of three schools were not even planned, and the receiving works were carried out in the pre-preparation area. Considering the flow of the dish-washing process, the width of the room should be at least 3.6 meters with a passage width of 1.6 meters, and easy access to the cooking and dining areas must be equipped. An interview with all five supervisors showed that most complaints focused on the cooking and dishwashing areas, whereas there were none in the storage and workers' area. The result highlights the importance of the cooking and dishwashing areas as the main functions in catering facilities, and future planning strategies should consider this aspect.