• Title/Summary/Keyword: 분말 야금

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Friction Welding of Ni-Base ODS Alloy Prepared by Mechanical Alloying (기계적 합금법으로 제조된 Ni기 산화물 분산강화 합금의 마찰압접에 관한 연구)

  • 강지훈;박성계;김지순;권영순
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 1994.10b
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    • pp.15-15
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    • 1994
  • M MA ODS 합금의 보다 폭넓용 실용확훌 위해 크게 요구되고 있는 적정 접합기술 개발의 한 방안£로, 마찰압접(Friction Welding) 방법의 가능성옳 조사하기 위하여 마찰압력과 시간, 마 찰 후 접촉압력(Upset Pressure) 풍을 다양하게 변화시켜 접합체톨 제조한 후, 접합체 강도에 대한 인장시험과 접합계연의 결합 및 미세구조에 대한 현미경 관찰, EDS에 의한 원소분석, 접 합이옴부의 경도분포와 파단면 분석 풍율 행하였다. 실험에 사용된 모재는 기계적 합금법으로 제조된 Inca사의 Ni기 MA 754 합금이었으며, 직경 l 10 mm, 길이 50 mm로 가공한 후, 아세통£로 초음파 세척하여 접합에 사용하였다. 접합온 브 레이크식 마찰압접기틀 사용하여 행하였으며, 회전시험편의 회전수는 2400 rpm이었A며, 다른 한쪽의 고정시험편과의 마찰압력 및 마찰시간온 각각 50 - 500 MPa과 1-5초로, 또한 업셋압 력도 50 - 600 MPa로 변화시켰다. 이때 업셋압력은 모든 시편에 대해 일정하게 6초동안 가하 였다. 얻어진 접합체는 각 압접조건 당 2개 이상의 접합시험편에 대해 상온 인장강도톨 측정하 였으며, 파단이 일어난 위치를 확인한 후 파면에 대한 분석율 주사전자현미경(SEM)과 에너지 분산형 분광분석기mDS)릎 사용하여 행하였다. 컵합이옴부의 첩합성올 확인하기 위하여, 접합 체를 접합변에 수직으로 절단, 연마한 후 광학현미경과 SEM, EDS 퉁으로 관찰, 분석하여 접 합부의 형상과 결합형성 여부, 접합계면의 미세조직 퉁옳 조사하였다. 또한 마찰압접에 따론 모재와 접합계연부의 경도분포훌 접합이옴부로부터 모재쪽으로 일정 간격율 두어 마이크로 비 커스 경도기로 측정, 조사하였다. 이상의 설험 결과, 다옴과 같온 결론옳 얻었다. ( (1) 접합체 강도가 모채 강도의 95% 이상이 되는 양호한 렵합체흩 얻기 위한 마찰압력 조건 온, 2400 rpm의 회전속도와 6초의 업셋압력 유지시간에서 마찰압력과 업셋압력, 그리고 마찰시 간이 각각 400 MPa 이상과 500 MPa 이상,2초입율 확인하였다. ( (2) 컵합이옴부의 관찰 결과, 모든 마찰압접 조건에서 컵합이옴부는, 기폰 모재의 texture 조직 을 유지하고 있는 모재부 영역(영역 ill)과 첩합계면부에 인접하여 업셋압력이 주어질 때 단조 효과에 의해 계연 외부로 metal flow가 일어나면서 형성된 영역 II, 매우 미세한 결정립으로 구성된 중앙부의 영역 1 로 이투어져 있옴융 확인하였다. ( (3) 최적접합조건이 충족되지 않온 경우, 접합부의 영역 I 에서 관찰된 void와 균열, 불균일한 접합계면 통의 접합결함에 Al과 Y. Ti 퉁£로 구성된 산화물률이 용집되어 있옴을 확인하였 다-( (4) 접합체의 파단 양상온 크게 접합부 파단과 모재부 파단, 이률의 혼합형 파단i로 나눌수 있었다. 모재부 파단의 경우, 파단면이 매끄럽고 파변상의 결정립도 매우 미세하였으며, 산확물 의 용집도 찾아보기 어려웠 나, 접합부 파단의 경우에는 파변의 굴곡이 비교척 심하고 연성 입계파괴의 형태를 보였£며, 결정립도 모채부 파단의 경우에 비해 조대하였다. 조대하였다.

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Additive Manufacturing Optimization of Directed Energy Deposition-Processed Ti-6Al-4V Alloy using Energy Density and Powder Deposition Density (에너지 밀도 및 분말 증착 밀도를 고려한 직접 에너지 증착법 기반 Ti-6Al-4V 합금의 적층공정 최적화)

  • Lee, Yukyeong;Kim, Eun Sung;Chun, Se-Ho;Seol, Jae Bok;Sung, Hyokyung;Oh, Jung Seok;Kim, Hyoung Seop;Lee, Taekyung;Nam, Tae-Hyun;Kim, Jung Gi
    • Journal of Powder Materials
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    • v.28 no.6
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    • pp.491-496
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    • 2021
  • The process optimization of directed energy deposition (DED) has become imperative in the manufacture of reliable products. However, an energy-density-based approach without a sufficient powder feed rate hinders the attainment of an appropriate processing window for DED-processed materials. Optimizing the processing of DED-processed Ti-6Al- 4V alloys using energy per unit area (Eeff) and powder deposition density (PDDeff) as parameters helps overcome this problem in the present work. The experimental results show a lack of fusion, complete melting, and overmelting regions, which can be differentiated using energy per unit mass as a measure. Moreover, the optimized processing window (Eeff = 44~47 J/mm2 and PDDeff = 0.002~0.0025 g/mm2) is located within the complete melting region. This result shows that the Eeff and PDDeff-based processing optimization methodology is effective for estimating the properties of DED-processed materials.

자기펄스압축성형법 및 방전 플라즈마 소결법의 연속공정을 이용한 $95%Bi_2Te_3-5%Bi_2Se_3$ 소결체제조 및 열전특성평가

  • Lee, Cheol-Hui;Kim, Hyo-Seop;Kim, Taek-Su;Gu, Ja-Myeong;Hong, Sun-Jik
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.48.2-48.2
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    • 2011
  • 열전재료는 열과 전기에너지의 상호 변환이 가능한 재료로 이를 이용한 응용제품의 개발이 크게 주목을 받고 있으며, 특히 $Bi_2Te_3$계 합금의 경우 상온에서 가장 우수한 성능지수를 가지는 재료로 많은 연구가 진행되고 있다. 그러나 기존의 $Bi_2Te_3$계 합금은 일방향응고법으로 제조되어 많은 시간과 비용을 필요로 하고, 특히 C축의 Van der Waals 결합으로 인해 기계적 강도가 약하다는 단점이 있었다. 최근 분말야금법을 이용하여 기계적강도를 높이고, 격자산란에 의한 열전도도의 감소로 성능지수를 높일수 있는 방법들이 제시되고 있다. 본 연구에서는 급속응고공정인 가스분무법을 이용하여 n-type의 $95%Bi_2Te_3-5%Bi_2Se_3$분말을 제조하였고, 이 재료의 경우 성형조건에 따라 조직이 쉽게 변하기 때문에 이를 제어하기 위해 단시간동안 고압으로 성형가능한 자기펄스압축성형법(Magnetic Pulsed Compaction)을 이용하여 성형체를 제조하였다. 제조된 성형체는 밀도를 증가시키고 결정립성장을 억제시킬수 있는 방전플라즈마소결법(Spark Plasma Sintering)을 이용하여 소결체로 제조되었으며, 각각의 공정이 열전성능에 미치는 영향을 고찰하였다. OM (Optical Microscope) 및 SEM (Scaning Electric Microscope)을 이용하여 미세구조를 관찰하였고 XRD (X-Ray Diffraction)를 이용하여 상의 변화를 분석하였으며, 상온에서 경도를 측정함으로서 공정조건에 따른 기계적강도를 비교하였다. Seebeck계수는 시편의 양단에 온도차를 주어 발생하는 기전압을 측정하여 계산하였고, 전기비저항은 4point probe방법으로 측정하였다. 전하이동도 및 전하농도는 Hall측정으로부터 구하였고 열전도도를 측정하여 종합적인 열전성능을 평가하였다.

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Experimental Analysis for Core Losses Prediction in Electric Machines by Using Soft Magnetic Composite (복합 연자성 소재의 전동기 코어손실 예측을 위한 실험적 분석)

  • Park, Eui-Jong;Kim, Yong-Jae
    • The Journal of the Korea institute of electronic communication sciences
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    • v.16 no.3
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    • pp.471-476
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    • 2021
  • Soft magnetic composite (SMC) materials based on powder metallurgy have a number of advantages over the conventional electrical steel sheets commonly used in electric machines. Thus, technologies related to these materials have shown significant improvement in recent years. In general, SMCs are magnetically isotropic owing to the shape of the powder, which makes them suitable for the construction of electric machines with three-dimensional flux and complex structures. However, the materials with isotropic magnetic properties (such as SMCs) have complex vector hysteresis; thus, it is very difficult to predict accurate loss properties. Therefore, we manufactured ring-type specimens of electrical steel sheets and SMC, which analyzed their magnetic properties according to the specimen size, and performed the electromagnetic field analysis of a high-speed permanent magnet (PM) motor driven at 800 Hz or higher using the measured magnetic information to compare the core loss of the motor. The reliability of this paper has been verified by measuring the efficiency after manufacturing the motor.

Volumetric Thermal Analysis of Hydrogen Desorption from Mg-13.5wt%Ni Hydride (Mg-13.5wt%Ni 합금 수소화합물의 수소방출에 대한 부피법에 의한 열분석)

  • HAN, JEONG SEB;PARK, KYUNG DUCK
    • Journal of Hydrogen and New Energy
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    • v.26 no.4
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    • pp.308-317
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    • 2015
  • To investigate the effect of microstructure on the formation of the desorption peak, the volumetric thermal analysis technique (VTA) was applied to the Mg-13.5 wt% Ni hydride system. The sample made by the HCS (hydriding combustion synthesis) process had two kinds of Mg microstructures. Linear heating was started with various constant heating rates. Only one peak was appeared in the case of the small initial hydrogen wt% (0.83 wt%). Yet, two peaks were appeared with increasing initial hydrogen wt% (1.85 and 3.73 wt%) when only Mg was hydrogenated. The first peak was formed through the evolution of hydrogen from $MgH_2$, made by eutectic Mg. The second peak was formed through the evolution of hydrogen from $MgH_2$, made by primary Mg. Therefore, this result shows that the microstructure also has a considerable effect on forming the desorption peak. We have also derived the hydrogen desorption equations by VTA to get apparent activation energy when the rate-controlling step for the desorption of the hydrided system is the diffusion of hydrogen through the ${\alpha}$ phase and the chemical reaction ${\beta}{\rightarrow}{\alpha}$.

Analysis and Design of Powder Metallurgy Process using Finite Element Method (유한요소법을 이용한 분말야금 공정 해석 및 설계)

  • Kwon Y. S.;Lee M. C.;Chung S. T.;Chung S. H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.241-244
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    • 2005
  • Though the history of finite element analysis in field of powder metallurgy is not short, industrial engineer is still being dependent on the trial and error approach based on engineer's experience in selecting process conditions. This problem is mainly due to the difficulty in establishing models for the behavior of a powder compact during compaction and sintering as well as finding material parameters for the models and the absence of CAE software with which industrial engineer can easily investigate the effect of process conditions on the quality of product. Therefore, we established very simple and cheap procedure to find material parameters for powder compaction behavior and implemented it in self-developed commercial CAE software for powder metallurgy, PMsolver. Basically, the development strategy of PMsolver lies on simplification and convenience so as for industrial engineers to use it with least training. Using PMsolver, optimal process conditions were found for some geometry and powders. Prior to process condition design, the accuracy of finite element analysis was verified.

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Studies on Density Measurement of Green Fe/Ni P/M Sheet Using ${\gamma}-ray$ (감마선을 이용한 소결 전 Fe/Ni 분말야금 판재의 밀도측정에 관한 연구)

  • Cho, K.S.;Lee, J.O.;Lee, S.Y.;Lee, J.S.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.12 no.3
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    • pp.7-11
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    • 1992
  • Accurate measurement of green density of compacted part in the powder metallurgy industry is rather fundamental but extremely important process that decide the quality of the sintered part. In case of green sheet P/M product, the green density as well as the distribution of the density must be examined for the same reasons. Currently in most cases, density measuring process is being performed applying conventional Archimedes principles. However this method is not only time-consuming but also often inaccurate because of the inherent nature of the process, such as part sectioning, closing of surface porosity with wax and weighing in air and in water. Therefore, it is necessary to develop a faster and more accurate method to measure the density of green sheet P/M product. In this work, a nondestructive density measurement device using gamma-ray absorption principles was constructed and the optimum condition for measuring green density of P/M sheet and its distribution was sought. The results showed that this method was very effective in terms of measuring time and accuracy.

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Analysis of Microstructure Evolution using Different Powder Metallurgy Process in Ti-X Alloy System (Ti-X계 합금의 분말야금 공정 차이에 따른 미세조직변화 분석)

  • Kwon, Hyeok-Gon;Kim, Doo-Hyeon;Gang, Min;Park, Ji-Hwan;Oh, Myung-Hoon
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.1
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    • pp.17-24
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    • 2021
  • In this study, Ti-X (X=Mn, Fe, Mo) powder alloys were designed and manufactured by both powder metallurgy (PM) and metal powder injection molding (MIM) process to improve strength and formability compared to CP-Ti powder materials. It was found that the lamellar microstructure consisted of α and β phases was formed in PM-processed alloys. However, MIM-processed alloys showed not the lamellar microstucture but the equiaxed α + β microstructure. It was also revealed that the contents of X component and feedstock were not affected to microstructure evolution. The reason why different microstructure was appeared between PM-processed and MIM-processed alloys is not clear yet, but supposed to be the effect of intersticial elements such as C, H and N derived from feedstock during debinding process of MIM.

Synthesis and Optical Property of (GaN)1-x(ZnO)x Nanoparticles Using an Ultrasonic Spray Pyrolysis Process and Subsequent Chemical Transformation (초음파 분무 열분해와 화학적 변환 공정을 이용한 (GaN)1-x(ZnO)x 나노입자의 합성과 광학적 성질)

  • Kim, Jeong Hyun;Ryu, Cheol-Hui;Ji, Myungjun;Choi, Yomin;Lee, Young-In
    • Journal of Powder Materials
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    • v.28 no.2
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    • pp.143-149
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    • 2021
  • In this study, (GaN)1-x(ZnO)x solid solution nanoparticles with a high zinc content are prepared by ultrasonic spray pyrolysis and subsequent nitridation. The structure and morphology of the samples are investigated by X-ray diffraction (XRD), field-emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The characterization results show a phase transition from the Zn and Ga-based oxides (ZnO or ZnGa2O4) to a (GaN)1-x(ZnO)x solid solution under an NH3 atmosphere. The effect of the precursor solution concentration and nitridation temperature on the final products are systematically investigated to obtain (GaN)1-x(ZnO)x nanoparticles with a high Zn concentration. It is confirmed that the powder synthesized from the solution in which the ratio of Zn and Ga was set to 0.8:0.2, as the initial precursor composition was composed of about 0.8-mole fraction of Zn, similar to the initially set one, through nitriding treatment at 700℃. Besides, the synthesized nanoparticles exhibited the typical XRD pattern of (GaN)1-x(ZnO)x, and a strong absorption of visible light with a bandgap energy of approximately 2.78 eV, confirming their potential use as a hydrogen production photocatalyst.

Recycling of Hardmetal Tool through Alkali Leaching Process and Fabrication Process of Nano-sized Tungsten Carbide Powder using Self-propagation High-temperature Synthesis (알칼리 침출법을 통한 초경 공구의 재활용 및 자전연소합성법을 통해 제조된 나노급 탄화텅스텐 제조공정 연구)

  • Kang, Hee-Nam;Jeong, Dong Il;Kim, Young Il;Kim, In Yeong;Park, Sang Cheol;Nam, Cheol Woo;Seo, Seok-Jun;Lee, Jin Yeong;Lee, Bin
    • Journal of Powder Materials
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    • v.29 no.1
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    • pp.47-55
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    • 2022
  • Tungsten carbide is widely used in carbide tools. However, its production process generates a significant number of end-of-life products and by-products. Therefore, it is necessary to develop efficient recycling methods and investigate the remanufacturing of tungsten carbide using recycled materials. Herein, we have recovered 99.9% of the tungsten in cemented carbide hard scrap as tungsten oxide via an alkali leaching process. Subsequently, using the recovered tungsten oxide as a starting material, tungsten carbide has been produced by employing a self-propagating high-temperature synthesis (SHS) method. SHS is advantageous as it reduces the reaction time and is energy-efficient. Tungsten carbide with a carbon content of 6.18 wt % and a particle size of 116 nm has been successfully synthesized by optimizing the SHS process parameters, pulverization, and mixing. In this study, a series of processes for the high-efficiency recycling and quality improvement of tungsten-based materials have been developed.