• Title/Summary/Keyword: 부식율

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Recovery of Copper from Waste Water by $H_2$Reduction (동폐수용액으로부터 수소환원법에 의한 동의 회수)

  • 서영식;이종현;원창완
    • Resources Recycling
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    • v.3 no.3
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    • pp.7-11
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    • 1994
  • The recovery of copper from $\alpha$-Etchent waste and pure copper solution was studied by the $H_2$reduction process. The results of test were as following: 1) The recovery of copper was increased with increasing hydrogen pressure and stirring speed up to 300 psi and 500 rpm, respectively, and was decreased in the higher values. But the recovery of copper from the fresh copper solution and $\alpha$-Etchent solution reached 90% and 60%, respectively. And in all tests the copper recovery from pure copper solution is higher by 30~40% than that from $\alpha$Etchent solution. 2) The recovery of copper was increased up to 30 minute of reaction time, and after then it became constant. The copper particles prepared in the initial 30 min have the needle-like shapes and in the longer reaction time than 30 min the shape was changed into noudle-like form. The average particle size was about $2~3\mu\textrm{m}$.

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Comparison of Biomarkers of Haliotis discus hannai and Hybrid Abalone (H. madaka♀*H. discus discus♂) in Marine Net Cage (해상가두리에서 북방전복 Haliotis discus hannai와 둥근전복속 교잡종(왕전복 H. madaka♀*둥근전복 H. discus discus♂)의 생물지표 비교)

  • Hyeon Jin, Kim;So Ryung, Shin;Seong Jin, Kim;Jung Jun, Park;Jung Sick, Lee
    • Journal of Marine Life Science
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    • v.7 no.2
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    • pp.163-170
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    • 2022
  • In this study, the results of hybridization were evaluated by analyzing the biomarkers of Haliotis discus hannai and hybrid abalone (H. madaka♀*H. discus discus♂) in marine net cage. The survival rate was similar both experimental groups, but the growth (shell length) was about 10% faster in hybrid abalone. The deformity of respiratory pore in the hybrid abalone was about 6% lower than H. discus hannai, and the shell depression was about 15% lower in the hybrid abalone. In the biochemical composition, crude protein was about 3.1% higher in hybrid abalone, and showed similar values except for the crude protein. In the histological structure of the hepatopancreas, which performs the functions of digestion, absorption and detoxification of abalone, good results were obtained in the hybrid abalone. On these results, it is judged that the hybrid abalone will have high aquaculture productivity in the aquaculture environment.

Degradation of Humic Acid Using N-Doped TiO2 (질소를 도핑한 TiO2를 이용한 부식산 분해)

  • So, Ji-Yang;Rhee, Dong-Seock
    • Journal of Industrial Technology
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    • v.31 no.B
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    • pp.119-125
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    • 2011
  • N-doped Titanium oxides were prepared by using urea as a source of nitrogen. The photoactivities of the doped $TiO_2$ were evaluated on the basis of degradation of humic acid in aqueous solutions with different light sources, ultraviolet lamp, fluorescent lamp and solar light. XRD analysis was conducted to identify the crystal structure of the synthesized photocatalysts. N-doped $TiO_2$ and $pure-TiO_2$ was anatase type. SEM results showed that spherical particles were formed, which are the characteristics of the anatase form. N doped $TiO_2$ showed higher $UV_{254}$ decrease ratio and DOC removal ratio compared to $pure-TiO_2$. The humic acid degradation reaction using the UV-A lamp and UV-C lamp was assigned to pseudo-first order reaction. For solar light, only $pure-TiO_2$ and $N-TiO_2$ exhibited the pseudo-first order reaction.

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Fundamental Study on Cathodic Protection and Material Development as Erosion-Control Methods of Oceanic Centrifugal Pump(2) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구(2))

  • Lee, Jin Yeol;Im, U Jo;O, In Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.92-92
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    • 1996
  • Recently, with the rapid development in the oceanic systems such as the oceanic structures and vessel, there occurs much interest in the impingement erosion-corrosion. In this paper, Cu-metal was tested by using of erosion apparatus with water-jet type and was investigated under the behaviour of impingement erosion-corrosion according to various environmental conditions, and the properties of Cu-metal were evaluated through the measurement by weight loss, weight loss rate, protective efficiency. The results were compared with those obtained using Cu-metal applied to cathodic protection and Cu-alloys added to Zn or Al-metal. As a basis of those results, the best protective efficiencies could be taken as using cathodic protection method and Cu-alloy with Al & Zn material addings, and will be suggested as the fundamental data of the anti-impingement erosion-corrosion on Cu-metal of impeller material for oceanic centrifugal pump.

Fundamental Study on Cathodic Protection and Material Development as Erosion - Control Methods of Oceanic Centrifugal Pump(2) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구 (2))

  • 이진열;임우조;오인호
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.24-31
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    • 1996
  • Recently, with the rapid development in the oceanic systems such as the oceanic structures and vessel, there occurs much interest in the impingement erosion-corrosion. In this paper, Cu-metal was tested by using of erosion apparatus with water-jet type and was investigated under the behaviour of impingement erosion-corrosion according to various environmental conditions, and the properties of Cu-metal were evaluated through the measurement by weight loss, weight loss rate, protective efficiency. The results were compared with those obtained using Cu-metal applied to cathodic protection and Cu-alloys added to Zn or Al-metal. As a basis of those results, the best protective efficiencies could be taken as using cathodic protection method and Cu-alloy with Al & Zn material addings, and will be suggested as the fundamental data of the anti-impingement erosion-corrosion on Cu-metal of impeller material for oceanic centrifugal pump.

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Affinity of Diazinon and Humic Substances as a Substrate of Microorganisms in Paddy Soil (논토양미생물의 Diazinon과 부식물질에 대한 기질 친화성)

  • Song, Jae-Young;Lee, Kyu-Seung
    • Korean Journal of Environmental Agriculture
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    • v.11 no.2
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    • pp.109-115
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    • 1992
  • In order to investigate waether soil microorganism prefer diazinon to humic substances as their substate, the growth of soil bacteria and the activities of monooxygenase and ${\alpha}-,{\beta}-esterase$ were measured after treatment of diazinon and humic substances in defined medium at $30{\pm}1^{\circ}C$. Also, the degradation rate of diazinon was determined by addition of humic substances to the medium. The number of soil bacteria was increased from 1 day and 3 days after the treatment with humic substances and diazinon, respectively. And it showed about 1.5 times more with humic substances than diazinon at 10 days. Monooxygenase(MO) activity with the treatment of humic substances was higher than diazinon until 3 days after treatment in the order of HA > FA > humin. Esterase(ES) activity with the treament of humin and HA was higher than dizainon from 5 dyas, but FA was much similar to diazinon. The degradation rate of diazinon showed more persistancy by addition of humic substances ; 51.4% with humin treatment, 58.9% with HA, 62.4% with FA and 71.9% in control at 10 days after treatment. Therefore, as soil microorganisms perfer humic substances to diazinon, the degreadation rate of diazinon might be delayed by addition of humic stbstances in submerged soil.

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Evaluation of Core Residence Time of Fuel Cruds from Hanul Unit 1 Cycle 17 (한울1호기 17주기 연료 크러드의 노내 체류시간 평가)

  • Lee, Doo Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.3
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    • pp.211-216
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    • 2014
  • Corrosion products are released to the primary coolant in the corrosion process of structural materials. They are deposited on fuel surfaces and activated on exposure to a neutron flux with formation of radionuclides that can become incorporated into out-of-core surface films. To get a clear understanding of activated crud formation process, the specific activity and core residence time of fuel cruds was calculated as a function of exposure time to the core neutron flux on the assumption that parent nuclide is being deposited continuously. Fuel cruds were sampled in the fuel scraping campaign from Hanul Unit 1 Cycle 17 and analyzed for elemental concentration and radioisotope activity.

Effect of Corrosion Inhibitor for Reinforcing Steel in Concrete Containing Chlorides (염화물을 함유한 콘크리트 중의 철근방식을 위한 방청제의 효과)

  • 문한영;김성수
    • Magazine of the Korea Concrete Institute
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    • v.10 no.6
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    • pp.325-333
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    • 1998
  • Under the seawater environment, the reinforced concrete structure is deteriorated due to physical and chemical attacks. The main deterioration mechanism is the chloride corrosion of reinforcing steel. The corrosion inhibitors have been used to protect the rebars from corrosion which are susceptible to chlorides in concrete. However, there is not clear conclusion about corrosion inhibitors yet. In this study, it is made the accelerated experiment with 3 kinds of corrosion inhibitors for various chloride ingresses. It is estimated corrosion inhibitors that inhibitors by Half-Cell Potential, corrosion area ratio and weight loss ratio. It is concluded that inhibitors are not effective to corrosion inhibition for excessive chloride ingress. However, the effect of inhibition is directly proportional ot contents of corrosion inhibitors in some chloride ingress.

An Experimental Study on the Corrosion Characteristics of Reinforcement Concrete According to Types of Surface Covering Material (표면피복재 종류에 따른 철근콘크리트의 철근 부식특성에 관한 실험적 연구)

  • 김갑수;장종호;김재환;김용로;오시덕;김무한
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.39-43
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    • 2003
  • Chloride ions are considered to be the major cause of steel corrosion in concrete structures exposed to seashore environments and also permeation of chloride is controlled by chloride diffusion. Therefore, the study on chloride diffusion of concrete have been done so far by many researchers. It is reported that coating material as surface covering material is effect about deterioration of salt damage and carbonation, therefore these materials are important in durability of concrete structure. In this study, corrosion characteristics of reinforcement concrete according to types of surface covering material were evaluated by water-cement ratio, chloride penetration by age on the corrosion area rate and mass decrement of reinforcement. And it is considered that the result of this study on application of the corrosion characteristics of reinforcements under salt damage environmental will be suggested as fundamental data of control performance of salt damage. It is performed that comparison and examination of control performance of salt damage by the corrosion characteristics under salt damage environmental.

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Comparison of Phylogenetic Characteristics of Bacterial Populations in a Quercus and Pine Humus Forest Soil (활엽수림과 침엽수림 부식토 내 세균군집의 계통학적 특성 비교)

  • Han, Song-Ih;Cho, Min-Hye;Whang, Kyung-Sook
    • Korean Journal of Microbiology
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    • v.44 no.3
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    • pp.237-243
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    • 2008
  • Chemical and microbial characteristics of bacterial populations were investigated in a quercus and pine humus forest soil. Soil pH was $5.3\pm0.4$ and $4.1\pm0.9$ from each sample of a quercus and pine humus forest soil; C/N ratio of humus forest soil was $17.84\pm4.6%$ and $21.76\pm8%$, respectively. Total organic acid was investigated as 69.57 mM/g dry soil and 53.72 mM/g dry soil in each humus forest soil. Glutamine, pyruvate, succinate, lactic acid and acetic acid of pine humus forest soil were $1.5\sim4.5$ times higher than those of quercus humus forest soil. As we evaluated phylogenetic characteristics of bacterial populations by 16S rRNA-ARDRA analysis with DNA extracted from each humus forest soil. Based on the 16S rRNA sequences, 44 clone from ARDRA groups of quercus humus forest soil were classified into 7 phyla: ${\alpha},{\beta},{\gamma},{\delta}$-Proteobacteria, Acidobacteria, Actinobacteria, and Firmicutes. Thirty-two clone from ARDRA groups of pine humus forest soil were classified into 8 phyla: ${\alpha},{\beta},{\gamma}$-Proteobacteria, Acidobacteria, Bacteroides, Verrucomicrobia, Planctomycetes, and Gemmatomonadetes. According to PCA (Principal Component Analysis) based on 16S rRNA base sequence, there were three main groups of bacteria. All clone of Cluster I were originated from quercus humus forest soil, while 67% clone of Cluster II and 63% clone of Clusters III were separated from pine humus forest soil.