• Title/Summary/Keyword: 부식율

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Ni-Cr-Fe-합금에서 Cr 함량 변화의 영향

  • 장진성;김우곤;정만교;한창희;국일현
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.151-157
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    • 1996
  • Cr 함량이 alloy 600과 alloy 690의 Cr함량 사이에 위치하는 Ni-Cr-Fe 합금을 진공유도 용해법을 이용하여 제조하였다. 합금 인고트에 대하여 열간 가공성 시험을 수행하여 열간 압연 조건을 구하였다. 열간 및 냉간 압연을 거친 시편을 900~120$0^{\circ}C$ 사이의 여러 온도에서 소둔 열처리하였고, 열처리한 시편에 대하여 기계적 특성과 부식특성을 측정, 분석하였다. Cr 함량은 기계적 강도에는 다소 영향을 미치는 것이 발견되었으나 연신율에는 거의 영향을 미치지 않는 것으로 나타났다. 부식속도는 Cr 함량 변화보다 소둔 열처리 온도에 따라 증가하였으며, 110$0^{\circ}C$ 에서 열처리한 경우에는 부식속도가 얼마간 감소하는 것으로 나타났다.

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The Study on Anticorrosive Effect of Paint Finish for the Maritime Aircraft (해상운용 항공기의 도장에 따른 방식효과에 관한 연구)

  • Kim, Chan-Su;Lee, Sang-Yul
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.142-142
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    • 2015
  • 해상에서 운용하는 항공기는 염분이 포함된 대기로 인하여 부식이 발생하기 쉬우므로 항공기 기체에 영향을 주는 부식인자를 가장 효과적으로 차단할 수 있는 도장 방안에 대한 연구가 필요하다. 따라서 본 연구에서는 이러한 해상운용 항공기의 부식방지를 위해서 염수분무실험과 밀착력실험을 통해 효과적인 도장적용 방법과 도료의 내식성을 확인하였다.

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The Study on the Wear Corrosion Behavior of Induction Hardening High Strength Cast Iron in the pH Environments (고주파 열처리한 강인주철재의 마멸부식거동에 관한 연구)

  • Park, Yun-Sik;Lim, Uh-Joh;Park, Dong-Gi
    • Journal of the Korean Institute of Gas
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    • v.12 no.4
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    • pp.52-57
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    • 2008
  • This paper studies on the wear corrosion behavior of induction hardening high strength cast iron in the acidic environments. In a variety of pH solutions, wear corrosion behavior of GC 300 with a variety of contact pressures was investigated, and corrosion wear behavior after immersion test was considered. Also, electrochemical polarization test for GC 300 was carried out in various pH solutions. The main results are as following: In the strong acidic environment, wear corrosion rate of GC 300 appears highly and in the neutral environment is stable. Also, graphitic corrosion in the strong acidic environment occurs. The corrosion current density of GC 300 becomes high in a order of pH 1 > pH 2 > pH 4 > pH 6.5.

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Evaluation of Corrosion Fatigue Crack Propagation Characteristics at Equivalent Potential of Zinc Sacrificial Anode (아연(Zn)희생양극 등가전위에서 부식피로균열 진전특성에 관한 연구)

  • Won Beom Kim
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.1
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    • pp.363-368
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    • 2024
  • Steel structures used in marine environments, such as ships, offshore structures or sub-structures in wind power generation facilities are prone to corrosion. In this study, the corrosion fatigue crack propagation characteristics due to the environmental load are examined by experiment at -1050 mV vs. SCE, which is equivalent to the anti-corrosion potential of zinc anodes that are widely used as sacrificial anodes. In this study, for this purpose, an experimental study is conducted on the effect of cathodic protection on the propagation of fatigue cracks in the seawater environment under the condition of -1050 mV vs. SCE, considering the wave period in synthetic seawater. Cathodic protection prevents corrosion; however, excessive protection generates hydrogen through chemical reactions as well as calcareous deposits. The fatigue crack propagation rate appeared to be faster than the rate in a seawater corrosion environment at the early stages of the experiment. As the crack length and stress intensity factor K increased, the crack propagation rate became slower than the fatigue crack propagation rate in seawater. However, the crack growth rate was faster than that in the atmosphere.

Evaluation of Maturity Index for Garbage Composting Using the Sawdust as Bulking Agent (톱밥을 공극개량제로 사용한 음식쓰레기 퇴비화시 숙성도 지표의 적합성 평가)

  • Namkoong, Wan;Park, Sang-Hoo;In, Byung-Hoon;Park, Joon-Seok;Lee, Noh-Sup
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.3
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    • pp.73-80
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    • 2000
  • The objective of study was to evaluate the apropriate maturity indices for garbage composting using sawdust as bulking agent. Materials used in this study were the average composition garbage(G20) and garbage conditioned by sawdust(GS30, GS50) and cereals(GSC30). Indices for evaluating maturity were VS, water soluble TOC, polysaccharide, Humification Index(HI), and E4/E6. Experiment results showed that VS reduction was the most desirable index for evaluating compost maturity except for the GS50 which were conditioned with high sawdust Water soluble TOC decreased rapidly during the composting of first one month and then little changed. Therefore, water soluble TOC was recommended as maturity index. Polysaccharide was considered as a maturity index in case of garbage conditioned with sawdust and high cereals. Humification Index(HI) and E4/E6 were available as maturity indices in case of only some garbage composting so additional study was needed to confirm them as maturity indices for all garbage composting. Correlation analysis indicated that indices for evaluating maturity of garbage(about 30 C/N ratio) adding sawdust as bulking agent and high cereals, were VS reduction, water soluble TOC, polysaccharide, and E4/E6.

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Formation of Hydrogen Peroxide by the Ozonation of Aqueous Humic Acid (수중 부식산의 오존처리시 생성되는 과산화수소의 농도 변화에 대한 연구)

  • Kim, Kei Woul;Rhee, Dong Seok
    • Analytical Science and Technology
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    • v.13 no.5
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    • pp.659-665
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    • 2000
  • The changes in $UV_{254}$ and concentrations of $H_2O_2$ formed by ozonation of aqueous humic acid in ozone/high pH, peroxone process and in the presence of radical scavenger, $HCO_3{^-}$ were investigated. This study confirmed that the formation of $H_2O_2$ by ozonation may undergo different reaction pathways compared to those of $UV_{254}$ reduction in the degradation of the humic acid. The concentration of $H_2O_2$ produced by ozonation was found to be increased with decreasing pH of the sample solution due to the higher stability of ozone molecules at acidic conditions. On the while, $UV_{254}$ reduction was found to be higher at alkaline conditions or larger amount of $H_2O_2$ additions as a radical promoter in which the producing of ${\cdot}OH$, ${\cdot}HO_2$ radicals can be more favorable. From the results, it has been suggested that the formation of $H_2O_2$ by ozonation depends mainly on the direct reactions of ozone with humic acid molecules, while $UV_{254}$ reduction is affected by both the indirect reactions of the radicals and direct reactions of ozone with humic acid.

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Economic Analysis of Reinforced Concrete Bridges Considering Performance Evalution (성능평가를 고려한 철근콘크리트교의 경제성 분석)

  • 손용우;정영채;김종길
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.17 no.2
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    • pp.141-150
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    • 2004
  • Recently, it is really concerned about corrosion and aging of reinforced concrete bridges. Corrosional steel reinforcing in concrete affects not only safety of bridges structure but also bending strength of reinforced concrete's member. Rate of corrosion, characteristic of bending strength, and economical evaluation aren't clear in reinforced concrete, considering performance evaluation. The purpose of study is as follows. It studies about ability of resistance's strength and cost of life cycle according to reduction of steel reinforcing's corrosion. Moreover, it shows calculating formula of bending strength with corrosion of current rate and exactly evaluates about the rest life at corrosional reinforced concrete bridges.

Analysis of Structural Safety for Rebar Exposure and Corrosion in PSC I-Girder Bridge Slab (PSC I형 교량 바닥판의 철근노출 및 부식에 대한 구조적 안전성 분석)

  • Han, Manseok;Park, Ju-Hyun;Lee, Jong-Han;Min, Jiyoung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.1
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    • pp.67-74
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    • 2021
  • This paper evaluated the structural safety of an aging PSC I-girder bridge with rebar corrosion in the deck. The geometry and rebar of the bridge were designed based on an actual PSC I-girder bridge, and the numerical analysis was performed considering the crack of concrete and yielding of steel rebar. According to the evaluation criteria of Korea Infrastructure Safety and Technology Corporation, this study defined two criteria of rebar exposure and corrosion rates to construct a total of 32 corrosion scenarios. Rebar exposure was defined as the exposure of tensile rebars in the bridge deck due to the removal of cover concrete. The results of the analysis showed that the safety and rating factors of the bridge decreased with increasing rebar exposure and corrosion rates. For the rebar corrosion rate more than 50%, the safety grade of the bridge should be carefully evaluated for all the rebar exposure rate. When the rebar corrosion rate exceeds 57%, the bridge was evaluated as E grade regardless of rebar exposure rate. A correlation analysis for a 2% of rebar exposure rate found that the bridge was evaluated as A grade up to 55.8% corrosion rate, C grade up to 56.9%, D grade up to 58.5%, and E grade for corrosion rate greater than 58.5%. This study indicates the necessity of a quantitative evaluation of rebar corrosion for evaluating the structural safety of aging bridges.

Mechanical Deterioration of Overhead Transmission Lines by Forest Fires (산불에 의한 가공 송전선로의 기계적 열화 특성)

  • 김영달;김성덕;심재명;정동화;강지원
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.14 no.6
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    • pp.26-34
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    • 2000
  • The considerations for remaining life of ACSR (Aluminum Stranded Conductors Steel Reinforced) in transmission lines have become gradually important to hold reliability and stability of power supply. The remaining life of ACSR exposed to the atmosphere for a long period may rely on deterioration caused by environmental indices such as atmospheric corrosion, galvanic corrosion, crevice corrosion and fatigue corrosion. One of reduction of useful life in overhead transmission lines built on the ridge of mountain is often caused by forest fires.This paper deals with investigation of strength deterioration performance of ASCR due to fires through several testing and analyzing data for tension load and extension of blazed ACSR. Test samples are ACSR 480[$\textrm{mm}^2$] conductors, which are artificially fired to regular durations. Mechanical properties such as tension load and extension for fired ACSR conductors are tested and estimation functions for mechanical performances corresponding to fire duration are determined. As a result, it can be verified that both tension load and extension of ACSR are reduced by increasing fire duration. Hence, it is obvious that ACSR due to forest fires may lead to mechanical deterioration.

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Improvement on the Corrosion Resistance and Stress Corrosion Cracking of Ultra-high Strenght AISI 4340 Steel (초강인 AISI 4340 강의 부식 저항성 향상 및 응력부식균열)

  • Hong, Won-Sik;Park, Gyeong-Sun;Lee, Sang-Yul;Kim, Gwang-Bae
    • Korean Journal of Materials Research
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    • v.6 no.9
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    • pp.885-899
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    • 1996
  • 초강인 AISI 4340강을 85$0^{\circ}C$에서 2시간 동안 오스테나이징 처리 후 수냉하고, 250, 400, $600^{\circ}C$에서 각각 2시간 동안 템퍼링 처리를 하였다. AISI 4340강의 인장 특성은 상온에서 측정되었다. AISI 4340강 위에 니켈 전해도금된 것과 도금되지 않은 시편의 분극 특성이 3.5wt%NaCI 수용액과 인공해수에서 측정되었다. AISI 4340강위에 니켈 전해도금된 시편은 500mV(vs. Ag/AgCI)이하의 전위에서 부식 저항이 크게 향상되었다. 그러나 1A/$\textrm{cm}^2$의 전류밀도에서 30분 이상 니켈 전해도금된 시편은 도금층에 불순물과 기공이 형성되었기 때문에 AISI 4340강의 부식 저항은 감소되었다. AISI 4340강의 수소취화형 응력부식균열을 여러 작용 응력과 음극인가전력에서 U-bend 시편을 이용하여 IN 3.5 wt% NaCI 수용액에서 조사되었고, 수소취화형 응력부식균열 거동은 주사전자현미경으로 조사되었다.

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