• Korean Journal of Soil Science and Fertilizer
• /
• v.45 no.2
• /
• pp.287-292
• /
• 2012

This study was to build the database by collecting the results of legal leak test and self-test conducted by the owners of soil contamination facilities at soil-related specialized agency to grip objective status on soil contamination facilities and evaluate classification results. The results of the study showed that the unsuitable rate of business unit is 53.6%, the business with leak that could cause actual pollution is 25.7%, the unsuitable rate of the voluntary self-test is 57.3%, that of the compulsory inspection is 17.2% depending on the test motivation, that of the direct-test is 58.9%, and that of the indirect-test is 22.5% depending on the test methods. There was a significant difference between the test motivation conducted and the test methods applied. From the results of the unsuitable reasons obtained we could assume that about 20% of the whole target tanks became potential sources with natural defects occurred when such tanks were made, and 2.2% of the whole tankers examined that persisting period was caused by progressing corrosion below the minimum thickness.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.23 no.7
• /
• pp.113-119
• /
• 2019

Concrete structures built on reclaimed land are combined with chemical erosion such as chlorine and sulfate ions from seawater. Chloride attack deteriorates the performance of the structure by corroding reinforcing bars. In addition, the waste water treatment structure has a problem that the concrete is deteriorated by the sulfate generated inside. Therefore, in this study, the characteristics and chemical resistance of low heat cement concrete used in wastewater treatment structures constructed on reclaimed land were evaluated. As a result of the experiment, the target slump and air content were satisfied under all the mixing conditions. The slump of low heat cement (LHC) concrete was higher than that of ordinary portland cement (OPC) concrete, while the air content of LHC concrete was smaller than that of OPC concrete with the same mix proportion. As a result of compressive strength test, OPC concrete showed higher strength at younger age compared to 28 days. In contrast, LHC concrete exhibited higher strength than OPC concrete at the age of 56 days. As a result of chlorine ion penetration tests, LHC-B concrete showed chlorine ion penetration resistance performance of the "very low" level at the age of 56 days. As a result of chemical resistance evaluation, when the LHC concrete is applied without epoxy treatment, chemical resistance is improved by about 18% compared to OPC concrete. In testing chemical resistance, the epoxy coated concrete exhibited less than 5% strength reduction when compared to sound concrete.

• Journal of the Korean Applied Science and Technology
• /
• v.34 no.2
• /
• pp.327-337
• /
• 2017

A continuous low temperature ($510^{\circ}C{\sim}530^{\circ}C$) pyrolysis experiment in a pilot-scale of 85.3 kg/hr was carried out by the mixed feedstock of half dried digested sewage sludge and waste plastics. As a result, the amount of pyrolysis gas generated was maximum 68.3% of input dry mass and scored $40.9MJ/Nm^3$ of lower heating value (LHV), and the percentage of air inflow caused by continuous pyrolysis was 19.6%. The oil was produced 4.2% of the input dry mass, and the LHV was 32.5 MJ/kg. The sulfur and chlorine contents, which could cause corrosion of the facility, were found to be 0.2% or more respectively. The carbide generated was 27.5% of the input dry mass which shows LHV of 10.2 MJ/kg, and did not fall under designated waste from the elution test. The concentration of carbon monoxide, sulfur oxides and hydrogen cyanide of emitted flu gas from pyrolysis gas combustion was especially high, and dioxin (PCDDs/DFs) was within the legal standards as $0.034ng-TEQ/Sm^3$. Among the 47 water pollutant contents of waste water generated from dry flue gas condensation, several contents such as total nitrogen, n-H extract and cyanide showed high concentration. Therefore, the merge treatment in the sewage treatment plants after pre-treatment could be considered.

• Korean Chemical Engineering Research
• /
• v.49 no.5
• /
• pp.530-534
• /
• 2011

The synthesis of dimethyl carbonate by liquid phase oxidative carbonylation of methanol was studied under batch reaction system. Reaction factors such as effect on various metals, anion containing in copper catalyst, temperature, carbon monoxide and oxygen molar ratio and copper content were investigated. In particular $CuCl_2{\cdot}2H_2O$ showed the excellent of the methanol conversion 65.2%, DMC selectivity 96.6% reaction condition under 1.0 g, $150^{\circ}C$, MeOH/CO/$O_2$=0.2/0.215/0.05 (molar ratio). $CuCl_2$ led to corrosion of the reactor. Thus, a new catalyst system using supports was investigated to resolve these corrosion problem. Influence on various supports were examined and copper catalyst supported on zeolite Y showed the most excellent activity on the formation of dimethyl carbonate. The amount of Fe dissolved during the reaction using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometer) was compared with catalysts, calcined Cu/zeolite Y showed the lower value below 5% than $CuCl_2-2H_2O$.

• Journal of the Korea Concrete Institute
• /
• v.22 no.3
• /
• pp.335-343
• /
• 2010

Steel corrosion in reinforced concrete (RC) structures is a critical problem to structural safety and many researches are being actively conducted on developing methods to maintain the required performance of the RC structures during their intended service lives. In this study, concrete mixture proportioning technique through genetic algorithm (GA) for RC structures under carbonation, which is considered to be serious in underground site and big cities, is investigated. For this, mixture proportions and diffusion coefficients of $CO_2$ from the previous researches were analyzed and fitness function for $CO_2$ diffusion coefficient was derived through regression analysis. This function based on the 12 experimental results consisted of 5 variables including water-cement ratio (W/C), cement content, sand percentage, coarse aggregate content per unit volume of concrete in unit, and relative humidity. Through genetic algorithm (GA) technique, simulated mixture proportions were proposed for 3 cases of verification and they showed reasonable results with less than relative error of 10%. Finally, assuming intended service life, different exposure conditions, design parameters, intended $CO_2$ diffusion coefficients, and cement contents were determined and related mixture proportions were simulated. This proposed technique is capable of suggesting reasonable mix proportions and can be modified based on experimental data which consider various mixing components like mineral admixtures.

• The Korean Journal of Soil Zoology
• /
• v.5 no.2
• /
• pp.47-62
• /
• 2000

This study investigated the effect of soil animals at forest fire area, and it carried out the mountain located at Jundae Ri, Houeng-chen Myen, Ha-dong Gun, Kyoung-Nam Province, southern part of Korea, where burned out about 50 hectars on April 11, 1997. Vegetation of the examined area absolutely dominated with the pines of 7-14 cm in diameter and 20 to 30 years old and the rest were covered with mixed forest with a shrub such as the oak (Quereus mongolia Fisch, Quereus variabilis BI, Quereus dentana Thunb), snowbell(Styrax japonica, S, et, z), lacquer tree (Rhus trichocarpa Mig), azalea (Rhododendron mucronulatum Turcz), etc. And there were simple area organized as a herbaceous plant, and the burnt area was poor experimental sites, where litter layer and herbaceous plant disappeard due to fire, and the unburnt area was rich in surface plant, dead leaves, twigs, etc. But the ground cover vegetations were poor in the unburnt area. The distribution of each animal groups, the seasonal fluctuation in population density, the biomass of meso$.$macroarthropods and the relationship between soil animal and some environmental factors were investigated and analyzed at each experimental area. The result are summarized as follow: 1. Identificated 257,087 individuals of soil microarthropods were classified into 7 classes and 24 orders of Arachinida, Insecta, Chilopoda, Symphyla, Diplopoda, Isopoda and Oligochaeta., and identified 8,006 individuals of the total meso$.$macroarthropods were classified into 7 classes and 20 orders of Arachinida, Insecta, Chilopoda, Symphyla, Diplopoda, Isopoda and Oligochaeta. 2. Among the total soil microarthropods, Arachinida formed 70.9%, followed by Insecta for 28.4% and among the total meso$.$macroarthropod , Insecta formed 57.6%, followed by Chilopoda for 23.8%.

• Resources Recycling
• /
• v.19 no.5
• /
• pp.31-43
• /
• 2010

To fabricate porous SiC candle filter for filtration facility of the IGCC system, the candle type filter preforms were fabricated by ramming and vacuum extrusion process. A commercially available ${\alpha}$-SiC powders with various particle size were used as starting raw materials, and $44\;{\mu}m$ mullite, $CaCO_3$ powder were used as non-clay based inorganic sintering additive. The candle typed preforms by ramming process and vacuum extrusion were sintered at $1400^{\circ}C$ for 2h in air atmosphere. The effect of forming method and particle size of filter matrix on porosity, density, strength (flexural and compressive strength) and microstructure of the sintered porous SiC candle tilters were investigated. The sintered porous SiC filters which were fabricated by ramming process have more higher density and strength than extruded filter in same particle size of the matrix, and its maximum density and 3-point bending strength were $2.00\;g/cm^3$ and 45 MPa, respectively. Also, corrosion test of the sintered candle filter specimens by different forming method was performed at $600^{\circ}C$ for 2400h using IGCC syngas atmosphere for estimation of long-term reliability of the candle filter matrix.

• Korean Journal of Soil Science and Fertilizer
• /
• v.29 no.3
• /
• pp.303-311
• /
• 1996

The microflora changes of 10 water-controled treatments combined with livestock manures(pig, chicken) and bulking agents(sawdust, paper sludge) were investigated. The B/F values of the P-1 and C-1(65%, $H_2O$) treatments were 3571 and 5400 respectively, but those of the P-4 and C-4(50%, $H_2O$) treatments showed very low values, 667 and 334, respectively. The B/F values tended to increase with higher water content of the treatments. In the composting processes, the successions of microflora, adapting the compost environments, took place via fluctuating temperature. In the high temperature period, the numbers of mesophilic bacteria and fungi decreased, but that of the spore forming bacteria increased. However, the number of mesophilic bacteria inereased during the cold period. The B/F values of compost ranged 25-300, which indicates a decrease in the quantity of bacteria. The time required for the temperature of compost to reach $60^{\circ}C$ showed different patterns. There was no pathogenic microorganism in the treatments which reached a high temperature in a short period of time, but, in the treatments which reached a high temperature over a Long period of time, the pathgenic microorganism was not still alive.

• Journal of the Mineralogical Society of Korea
• /
• v.27 no.4
• /
• pp.183-195
• /
• 2014

In order to study the mineralogical characteristics of a cathodic deposition-metallic powder, electrowinning experiments were carrier out on different electrolytic solutions at varying electric distances and electric currents. Under the same experimental conditions, Cu recovery was obtained much more effectively using a sodium chloride electrolyte than with a sulfuric acid electrolyte. In XRD analysis, copper ($Cu^0$), chalcanthite and cuprite were identified in the sulfuric acid electrolyte, while copper, nantokite and chalcanthite were observed in the sodium chloride electrolyte. In the sodium chloride electrolyte solution, increasing the electric distance and the electric current increased the Cu recovery rate, anode weight and anodic corrosion. The results of XRD analysis with non-pulverized cathodic deposition-metallic powder showed the average copper crystallite size was increased by increasing the electric current and decreasing the electric distance. It is suggested that the mass transfer was controlled with diffusion on the boundary between the electrode and the electrolytic solution due to the formation of dendrite copper.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.33 no.6
• /
• pp.520-523
• /
• 2000

Anti-ulcer effects of depolymerized alginate (HAG-10, average molecular weight 10,000; HAG-50, average molecular weight 50,000; HAG-100, average molecular weight 100,000) obtained by hydrolysis of alginate by heating at $121^{\circ}C$, against $HCl{\cdot}ethanol$ and water-immersion stress in rats were investigated. The acute gastritis, induced by $HCl{\cdot}ethanol$, and the gastric ulcer, induced by water-immersion stress, were inhibited dose-dependently by administration of HAG-50, HAG-100 and alginate. Histopathological lesions of the gastritis and gastric ulcer in rats treated with HAG-50, HAG-100 and alginate were significantly lower than those in rats fed with HAG-10. The inhibition rates (${\%}$) on acute gastritis induced by $HCl{\cdot}ethanol$ and gastritis ulcer induced by water-immersion stress in rats, were $13.00{\%}\;and\;15.74{\%}$of HAG-10, $41.15{\%}\;and\;35.72{\%}$ of HAG-50, $41.58{\%}\;and\;35.37{\%}$ of HAG-100, and $45.17{\%}\;and\;41.11{\%}$ of alginate, respectively. These results suggested that HAG-50, HAG-100 and slginate had a protective effect against the gastritis and gastric ulcer. The effect was not as visible when using HAG-10 in rats. From the present results, it was suggested that HAG-50 was an effective anti-ulcer agent against $HCl{\cdot}ethanol$and water-immersion stress in rats.