• Proceedings of the Materials Research Society of Korea Conference
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• 2009.05a
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• pp.51.2-51.2
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• 2009

본 실험에서는 레이저 간섭 리소그래피를 이용한 2차원 나노 패턴을 형성하였고, 수열합성법을 이용하여 90 도에서 ZnO 나노 기둥을 ZnO/Si 기판 상에 제작 하였다. ZnO 버퍼층은 스퍼터를 이용하여 200도, Ar 분위기에서 증착 하였으며, 레이저 간섭 리소그래피를 이용하여 두 번의 노광을 통해 2차원 나노 패턴을 형성하였다. 먼저, 최적화된 포토레지스트를 ZnO/Si 기판 위에 도포하고, 2500rpm에서 30초간 스핀코팅 한 후, 첫번째 노광을 실시 하였고, ZnO/Si 기판을 회전시켜 첫번째 노광과 교차 시킨 다음 두 번째 노광을 통해 교차하는 부분만 현상되도록 하였다. 기판의 회전 및 기판과 입사 레이저 사이의 각도를 조절하여 제작된 나노 패턴의 종류는 square lattice, centered rectangular lattice, oblique lattice, hexagonal lattice, rectangular lattice, 5가지로, 2차원의 모든 격자를 제작 하였다. 저온 수열합성법에서는 Na citrate를 형상제어제 (surfactant ions)로 사용하여 ZnO 나노 기둥을 형성하였다. $NH_4OH$를 이용하여 용액의 pH를 조절하였고, Zn nitrate hexahydrate를 Zn의 원료 물질로 사용하였다. 2차원 나노 패턴의 3차원 형태는 Atomic force microscopy (AFM, Veeco instruments, USA)를 이용하여 접촉 모드에서 관찰하였고, ZnO 나노 구조는 주사 전자 현미경 (FE-SEM, Model: JSM-6701F, Tokyo, Japan) 를 통하여 분석 하였다. 나노 패턴의 AFM 분석 결과 ZnO/Si 기판상에 포토레지스트가 주기적인 배열을 가지는 것을 확인하였고, ZnO/Si 기판상에 포토레지스트가 완전히 현상된 부분이 일정한 배열을 가지는 것을 확인하였다. 포토레지스트가 현상되어 기판의 표면이 드러난 부분의 크기는 약 250nm로 측정되었다. ZnO 나노 구조의 FE-SEM 분석 결과, 각각의 나노 구조가 나노패턴 중 완전히 현상된 부분만을 통하여 성장되었다는 것을 확인하였고, 형상 제어제로 사용된 Na citrate의 첨가 여부에 따라 나노 구조의 모양이 변화되었다는 것을 알 수 있었다. Na citrate 가 첨가된 나노 기둥의 경우 약 500nm의 길이를 가지는 하나의 기둥 형태로 성장하였다는 것을 확인하였다.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.2
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• pp.324-330
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• 1990

In this study, in order to perform dynamic design of machine tools reasonably and effectively, a method was formulated to be applicable to the damped structures connected by joints having elasticity and damping by using substructure synthesis method. And a nonlinear solution method was proposed and it formulates the nonlinear parts by describing functions and uses the reducing transformation matrix by the substructure synthesis method. The results of frequency response analysis of a machine tool, where an NC lathe was partitioned by three parts of spindle, housing and bed-base part and the nonlinearity of bearing parts between spindle and housing was modelled, showed force dependency of the response.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.16 no.7 s.112
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• pp.712-719
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• 2006

This paper is concerned with the comparison of substructure synthesis methods based on global and local coordinates. The substructure synthesis methods based on the global coordinates were first proposed for the dynamic analysis of complex structure and the substructure synthesis method based on the local coordinates was proposed to solve the dynamic problem of tree-like structure. However, the conceptual difference between two methods in solving the dynamic problem has never been explained. In this paper, a structure consisting of two beams is considered to show the conceptual difference of two methods. The dynamic formulation shows the characteristics and differences of two methods explicitly. The procedure for choosing proper substructure modes in each method is also explained in detail. In addition, the advantage of the substructure synthesis method based on the local coordinate system is discussed based on the numerical example. Numerical examples show how two methods are applied to the addressed problem.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1994.10a
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• pp.225-230
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• 1994

본 연구에서는 진동특성을 개선하기 위한 방법으로서 구조물이 가지는 공간적인 좌표를 설계변수로 하여 감도를 구하고, 이를 이용하여 구조물의 길이와 높이에 대한 형상을 변경하는 최적구조변경법에 대해 예시하고자 한다. 먼저 모우드합성법을 이용하여 임의 치수의 L형 구조물의 진동특성을 해석하고, 진동 특성을 변경하기 위해 감도해석법으로 변경할 부분의 감도를 구하여 변경할 부분의 변경량을 계산한다. 그리고 변경한 후 재해석을 통해 결과를 비교함으로써 제시한 방법의 타당성을 고찰하고자 한다.

• Journal of Advanced Marine Engineering and Technology
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• v.24 no.1
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• pp.82-87
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• 2000

The component mode synthesis method(CMS) used for vibration analysis has demerit that error becomes larger, as degree of natural frequency grows higher. The reason of error occurrence is that Guyan's static reduction is used and the number of modes taken in each component is deficient. This paper proposes the substructure synthesis method using dynamic reduction to solve the problem from the component mode synthesis method. Computer simulation for the proposed method. FEM and the component mode synthesis method(CMS) on a rectrangular plate has been carried out to prove the avilability of the proposed method.

• Journal of KSNVE
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• v.7 no.5
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• pp.737-746
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• 1997

The substructure synthesis method is used for making it easy to analyze vibration systems generally in vibration field. In the past, this method has been to be used mainly because of shortage of computer memory and CPU time. But recently this method is used for analyzing complex structure or identifying the characteristics of systems precisely. The purpose of this study is to develop acoustic substructure synthesis method that can be applied to acoustic modal analysis of complex acoustic systems. Acoustic modal analysis method to be introduced here is a method that analyze acoustic natural mode shape of the complex acoustic system by the principle of CMS(component mode synthesis method). This paper describes the acoustic modal analysis of the acoustic finite element model of simple expansion pipe by acoustic substructure synthesis method. The resutls of acoustic modal analysis analyzed by Acoustic substructure synthesis method and the results by FEM(finite element method) shows good agreement.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.20 no.5
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• pp.593-604
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• 2007

Although composite construction has more mechanical advantages compared to noncomposite construction, the design of noncomposite construction for skew bridges with large skew angels has been often checked because composite construction may cause large stresses in the bridge deck. In this study, the analytical model considered dynamic behaviors for noncomposite skew bridges was proposed. Using the proposed analytical model, the validity of the application of noncomposite construction to skew bridges was checked. Also, the effects of interactions between the concrete deck and steel girders such as composite construction, partial composite construction, and noncomposite construction on the dynamic characteristics and dynamic behaviors of simply supported skew bridges were investigated. A series of parametric studies for the total 27 skew bridges was conducted with respect to parameters such as girder spacing, skew angle, and deck aspect ratio. Although the slip at the interfaces between the concrete deck and steel girders results in the reduction of seismic total base shear in the transverse direction due to period elongation, it causes an undesirable behavior of skew bridges by the modification in mode shapes and distributions of stiffness. Shear connectors placed by minimum requirements for partial composite action have an effect on reducing the girder stresses and deck stresses; except case of some skew bridges, the magnitude of the girder stresses and deck stresses obtained from partial composite skew bridges is similar to or slightly more than those acquired from composite skew bridges.

• Proceedings of the Korean Society of Applied Pharmacology
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• 1994.04a
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• pp.223-223
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• 1994

FDA가 공인한 항 HIV제로서 사용중인 AZT나 DDI와 같은 화합물은 장기 투여로 심각한 부작용들이 나타나고 있다. 그래서 기존의 activity를 가진 nucleoside류의 sugar 부분에 새로운 base 즉, 5-ethoxymethyl uracil을 축합, 3'-azido-2',3'-dideoxy-5-ethoxy-methyl uridine, 2',3'-aideoxy-3'-fluoro-5-ethoxymethyl uridine과 2',3'-dideoxy-5-ethoxymethyl uridine들을 합성, 구조활성 상관관계를 검토하였다. 이들의 합성은 먼저 적절한 group으로 sugar의 -OH group을 보호한후 uracil류와 반응, uridine 유도체를 먼저 합성하였다. 각각의 uridine 유도체들의 5-위치에 ethoxymethyl group을 도입하기 위해 formalin과 반응시킨후 5-hydroxy-methyl group을 도입하고 산촉매 하에 ethanol과 반응, ethyl ether류를 합성하였다.

• Journal of the Korean Wood Science and Technology
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• v.23 no.4
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• pp.98-107
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• 1995

천연물 중 casbene-type diterpenoid의 하나인 crotonitenone의 합성이 시도되었다. 합성 방법으로는 crotonitenone의 각 부분을 먼저 합성하여 이들을 합하는 방법(convergent method)을 적용하였으며, 각 부분이 최종물질에 적합한 sterochemistry를 갖게 하기 위하여 시작물질로는 chiron으로 S-(-)-citronellol과 IS-chrysanthemic acid를 사용하였다. 환구조를 형성하는데 중요한 역할을 할 TBDMS protecting group이 붙은 phosphonium salt(synthon A) 가 고압반응으로부터 고수율 (70%)로 생성되었다. 또한, 중요한 반응으로서 synthon A와 hydroxy lactone(synthon B)과의 Witting reaction이 성공적으로 이루어졌다. 그러나, TBDMS protecting group의 존재하에 이중 치환된 이중결합(disubstituted double bond)과 삼중치환된 것과의 선택적인 환원의 어려움으로 인하여 최종 물질의 합성방법이 재고되었으며 이에 대해 간단히 논하였다.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.6
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• pp.666-673
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• 2014

Finite Element Method(FEM) is the essential tools for analyzing structural and vibration problem. But common commercial program is high-priced and the usage is not easy. Hereby the authors developed FEM program by using Matlab, whose usage is very simple and whose performance is very high. For the convenience of use and calculating efficiency Component Mode Synthesis Method is adopted, which divides a structure by some sub-structures for easy handling, analyzes them by parts and analyzes the structure with encompassing Degrees of Freedom(DOF). And encompassed DOF could be restored to full DOF. To confirm the accuracy the program was applied to a flat plate, and the results were compared to experiment, and good agreements were achieved. The developed program is going to be opened to public.