• Composites Research
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• v.30 no.3
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• pp.223-228
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• 2017

The article explains about development of flame retardant self-reinforced composites (FR-SRC) through compression molding technique by utilizing Polypropylene (PP), Ammonium polyphosphate (APP) and chitosan. The effect of APP and chitosan on mechanical, thermal and flame retardant properties in FR-SRC were studied. The mechanical strength of FR-SRC is enhanced than Pure SRC. However, the strength is decreased significantly with increasing the concentration of both flame retardant fillers. But comparison, chitosan filled FR-SRC is stronger than APP filled FR-SRC. In case of flame retardancy, APP is more effective than chitosan. These results can be applicable to provide light weight and recyclable flame retardant self-reinforced composites for automobile and packaging industries, etc.

• Applied Chemistry for Engineering
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• v.24 no.5
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• pp.476-482
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• 2013

In this work, the effects of electrochemical oxidation of carbon fiber surfaces on mechanical interfacial properties of carbon fibers-reinforced polarized-polypropylene matrix composites were studied with various current densities during the treatments. Surface properties of the fibers before and after treatments were observed by SEM, AFM, XPS, and contact angle measurements. Mechanical interfacial properties of the composites were measured in terms of critical stress intensity factor ($K_{IC}$). From the results it was found that $O_{1s}$ peaks of the fiber surfaces were strengthened after electrochemical oxidation which led to the enhancement of surface free energy of the fiber, resulting in good mechanical performance of the composites. It can be concluded that electrochemical oxidation of the carbon fiber surfaces can control the interfacial adhesion between the carbon fibers and polarized-polypropylene in this composites system.

• Polymer(Korea)
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• v.37 no.5
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• pp.613-617
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• 2013

The effects of nano size kenaf cellulose fiber on mechanical property of polypropylene (PP) composite were investigated. The addition of nano-kenaf in place of natural kenaf showed higher tensile strength, flexural strength, impact strength, and heat deflection temperature compared to the natural kenaf filled PP composite, while it shows lower melt flow index, elongation%, and flexural modulus. These seemed to be due to the increased surface area of nano-kenaf fiber contacting PP matrix and reduced impurities such as volatile extractives on the fiber surface.

• Journal of Adhesion and Interface
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• v.8 no.3
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• pp.9-15
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• 2007

The interfacial evaluation of surface modified Jute fiber/polypropylene (PP) composites before and after hydration was investigated using micromechanical test and dynamic contact angle measurement. The IFSS of alkaline and silane-treated Jute fiber/PP composites increased, whereas after hydration, the IFSS of the untreated, alkaline- and silane-treated Jute fibers/PP composites decreased due to swelled fibrils by water infiltration. The interfacial adhesion of silane treated fiber/PP composites was higher than alkaline-treated or the untreated cases. The surface energies of Jute fiber treated under various conditions were obtained using dynamic contact angle measurement. Especially after hydration, the thermodynamic work of adhesion was calculated by considering water interlayer, which indicated the stability of IFSS between silane treated Jute fiber and PP matrix showing better than others.

• Polymer(Korea)
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• v.27 no.4
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• pp.299-306
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• 2003

It is well known that the interaction and adhesion between the glass fiber (GF) and polymer matrix has a significant effect in determining the properties of fiber-reinforced materials. Therefore, it is one of important considerations to modify the surface of glass fiber with an appropriate sizing. We investigated the treatment method of glass fiber with coupling agent to improve the interaction of the interfacial region. The correlation between interfacial property and interphase microstructure was also examined in an attempt to realize a proper morphology at the glass fiber surfaces.

• Composites Research
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• v.26 no.4
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• pp.245-253
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• 2013

In this paper, we developed a theoretical model which is able to predict the tensile strength and elastic modulus of hybrid composites reinforced by two types of randomly distributed discontinuous reinforcements. For this, we considered two known models; One is a prediction model based on the assumption that the composite is reinforced by two types of well aligned continuous reinforcements. The other is a statistical model for the composite which is reinforced by only one type of randomly distributed discontinuous reinforcements. In order to evaluate the validity of accuracy of our prediction model, we measured the strength and elastic modulus of polypropylene hybrid composite reinforced by talc and short glass fiber. We found that the present model drastically enhances the accuracy of strength prediction compared to an existing model, and predicts the elastic modulus within the same order with experimentally measured values.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.04a
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• pp.5.2-8
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• 1999

• Polymer(Korea)
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• v.38 no.3
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• pp.327-332
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• 2014

Polymer/wood flour composites are recently attracting a lot of interest because they are economic and ecofriendly. In this study, the effects of wood flour size on the thermal and mechanical properties of a polypropylene/wood flour composite were investigated. Mechanical properties of the composite samples prepared by melt-mixing and compression molding were tested by UTM and an izod impact tester, and thermal properties of them were measured by TGA, DMA, DSC and TMA. The best coupling agent was selected by testing three kinds of maleic anhydride modified polypropylene coupling agents, and under the same condition, the effects of wood flour size on the physical properties of the composite were investigated. According to the test results for four different wood flour sizes of 600, 250, 180 and $150{\mu}m$, flexural strength, flexural modulus, crystallinity and water-resistivity of the composite increased with decreasing wood flour size.

• Composites Research
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• v.27 no.4
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• pp.135-140
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• 2014

A constitutive equation, which was suggested for describing the compressive deformation behaviour of the expanded polyurethane, was applied to the expanded polypropylene under dynamic loading. This equation consists of seven parameters, five of which are obtained by fitting the stress strain curve obtained from the quasi-static compression test at the lowest base strain rate. The remaining two parameters are able to be determined by fitting the curve from the compression test at different two stage strain rates. In order to check the eligibility of the equation at high strain rate, the impact test was performed and the results were compared to the analytical constitutive equation results for the expanded polypropylene with expansion ratios of 30 and 40 times, respectively.

• Composites Research
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• v.20 no.3
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• pp.55-62
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• 2007

Interfacial evaluation and durability of Jute and Hemp fibers/polypropylene (PP) composites were investigated. Moisture content of various treated conditions were measured by thermogravimetic analyzer (TGA). After boiling water test, mechanical properties and IFSS between Jute, Hemp fibers and PP matrix decreased. On the other hand, work of adhesion increased due to swelled fibril by water. Surface energies of Jute and Hemp fibers before and after boiling water test were obtained using dynamic contact angle measurement. IFSS was not always consistent with thermodynamic work of adhesion. In boiling water case, since Jute and Hemp fibers could be swelled by water, surface area and moisture infiltration space increased. Environmental effect on microfailure modes of Jute or Hemp fibers and Jute or Hemp fibers/PP composites were obtained by observing via optical microscope and by monitoring acoustic emission (AE) events and their AE parameters. After boiling water test, unlike Hemp fiber, microfailure process of Jute fiber could occur due to low tensile strength by swelled fibril. In addition, AE events occurred more and AE amplitude and energy became lower than those of before boiling water test.