• Title/Summary/Keyword: 복합 사이클

Search Result 200, Processing Time 0.037 seconds

Electrochemical Properties of Poly(Styrenesulfonate)-Carbon Composite Anode for Organic Rechargeable Battery (유기이차전지를 위한 Poly(Styrenesulfonate)-Carbon 복합 음극의 전기화학적 특성)

  • Lim, Ji-Eun;Kang, Dong-Won;Kim, Jae-Kwang
    • Journal of the Korean Electrochemical Society
    • /
    • v.19 no.4
    • /
    • pp.129-133
    • /
    • 2016
  • In this study, a polymer-carbon composite material is prepared for environmental-friendly organic anode. On poly(styrenesulfonate)(PSS)-carbon composite anode, the carbon is coated by PSS as a core-shell structure and the PSS-carbon composite anode has $524mAh\;g^{-1}$ theoretical capacity with <0.6V voltage. Moreover, the PSS-carbon composite anode shows $519.6mAh\;g^{-1}$, $461.2mAh\;g^{-1}$, $411.8mAh\;g^{-1}$ and $315.9mAh\;g^{-1}$ discharge capacities at 0.1, 0.5, 1 and 10 C, respectively, and stable cycle performance up to 30 cycles. The PSS-carbon composite anode, containing polystyrene and sulfonate functional groups, is suitable for high electrochemical properties organic rechargeable battery.

Electrochemical Properties of SiOx Anode for Lithium-Ion Batteries According to Particle Size and Carbon Coating (입자 크기 및 탄소 코팅에 따른 리튬이온배터리용 SiOx 음극활물질의 전기화학적 특성)

  • Anna Park;Byung-Ki Na
    • Korean Chemical Engineering Research
    • /
    • v.62 no.1
    • /
    • pp.19-26
    • /
    • 2024
  • In this study, the electrochemical properties of SiOx@C composite materials were prepared to alleviate volume expansion and cycle stability of silicon and to increase the capacity of anode material for LIBs. SiO2 particles of 100, 200, and 500 nm were synthesized by the Stӧber method, and reduced to SiOx (0≤x≤2) through the magnesiothermic reduction method. Then, SiOx@C anode materials were synthesized by carbonization of PVC on SiOx. The physical properties of prepared SiOx and SiOx@C anode materials were analyzed by XRD, SEM, TGA, Raman spectroscopy, XPS and BET. The electrochemical properties were investigated by cycling performance, rate performance, CV and EIS test. As a result, the SiOx@C-7030 manufactured by coating carbon at SiOx : C = 70 : 30 on a 100 nm SiOx with the smallest particle size showed the best electrochemical properties with a discharge capacity of 1055 mAh/g and a capacity retention rate of 81.9% at 100 cycles. It was confirmed that cycle stability was impoved by reducing particle size and carbon coating.

Effect of Fiber Orientation and Fiber Contents on the Tensile Strength in Fiber-reinforced Thermoplastic Composites (섬유배향과 섬유함유량이 섬유강화 열가소성수지 복합재료의 인장강도에 미치는 영향)

  • Kim, Jin-Woo;Lee, Dong-Gi
    • Composites Research
    • /
    • v.20 no.5
    • /
    • pp.13-19
    • /
    • 2007
  • Fiber-reinforced thermoplastic composites not only approach almost near to the strength of thermosetting composite but also has excellent productivity, recycling property, and impact resistance, which are pointed as weaknesses of thermosetting composites. The study for strength calculation of one direction fiber-reinforced thermoplastic composites and the study measuring precisely fiber orientation distribution were presented. Need the systematic study for the data base that can predict mechanical properties of composite material and fiber orientation distribution by the fiber content ratio was not constructed. Therefore, this study was investigated what affect the fiber content ratio and fiber orientation distribution have on the strength of composites. Fiber-reinforced thermoplastic composites by changing fiber orientation distribution and the fiber content ratio were made. Tensile strength ratio of $0^{\circ}$ direction of fiber-reinforced composites increased being proportional the fiber content and fiber orientation function as change from isotropy(J=0) to anisotropy(J=1). But, tensile strength ratio of $90^{\circ}$ direction by separation of fiber filament decreased when tensile load is imposed fur width direction of reinforcement fiber length direction.

Modeling of the gasifier section for IGCC plant (IGCC 플랜트에 적용할 가스화기부의 모델링)

  • Park, Jin-Hoo;Kim, Tae-Hyun;Go, Young-Gun;Choi, Sang-Min
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2007.11a
    • /
    • pp.445-448
    • /
    • 2007
  • 석탄가스화 복합발전(IGCC)에서 석탄 가스화 기술이 전 공정의 성능에 큰 영향을 미치는 중요한 요소이다. 연료 및 산화제의 공급방식, 가스화기의 기본 구조, 벽면의 구성 방식, 용융 슬랙 및 생산되는 합성가스 배출 방식 등에 따라 가스화의 성능이 영향을 받는다. IGCC plant의 정확한 성능 해석을 위해서는 석탄가스화기 공정 모델의 정밀도를 높일 필요성이 있다. 기존의 열병합 발전 사이클 해석에서 적용되었던 열 및 물질정산과 평형계산 방식을 통하여 석탄가스화기 공정을 해석하는 방법을 확인, 정리하고 이를 개선하기 위한 절차 및 방안을 제시하고자 한다. 가스화기 내부 공정을 크게 탈휘발과 가스화의 단계로 구분하여 가스화기 출구조건을 예측하였으며, ASPEN PLUS를 이용한 공정해석을 실시하였다. 가스화기 출구에서의 합성가스는 주생성가스인 CO, $H_2$를 위주로 하여 조성을 얻을 수 있고, 그 결과들을 선행연구들과의 비교를 통하여 가스화기 모델의 분석을 실시한다. 그리고 가스화기 해석의 정밀도를 높이기 위한 향후 고려될 가스화기 모델에 관하여 논의한다.

  • PDF

Effect of Carbon Capture Using Pre-combustion Technology on the Performance of Gas Turbine Combined Cycle (연소전 처리를 이용한 탄소포집이 가스터빈 복합화력 플랜트의 성능에 미치는 영향)

  • YOON, SUKYOUNG;AHN, JIHO;CHOI, BYEONGSEON;KIM, TONGSEOP
    • Journal of Hydrogen and New Energy
    • /
    • v.27 no.5
    • /
    • pp.571-580
    • /
    • 2016
  • In this paper, performance of the gas turbine combined cycle(GTCC) using pre-combustion carbon capture technology was comparatively analysed. Steam reforming and autothermal reforming were used. In the latter, two different methods were adopted to supply oxygen for the reforming process. One is to extract air form gas turbine compressor (air blowing) and the other is to supply oxygen directly from air separation unit ($O_2$ blowing). To separate $CO_2$ from the reformed gas, the chemical absorption system using MEA solution was used. The net cycle efficiency of the system adopting $O_2$ blown autothermal reforming was higher than the other two systems. The system using air blown autothermal reforming exhibited the largest net cycle power output. In addition to the performance analysis, the influence of fuel reforming and carbon capture on the operating condition of the gas turbine and the necessity of turbine re-design were investigated.

Analysis of combined cycle for desalination process and $CO_2$ refrigeration system (담수화 공정과 이산화탄소 냉동 시스템의 복합사이클 해석)

  • 신지영
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.24 no.1
    • /
    • pp.41-48
    • /
    • 2000
  • The characteristics of a combined cycle for the production of fresh water and air-conditioning was analyzed. The combined cycle consisted of an open water cycle and a $CO_2$ refrigeration cycle interlinked in the pre-heater of the water cycle, which is the condenser of the refrigeration cycle. The oprating conditions and criteria for the fresh water production and air-conditioning was described and their effects on the total system were evaluated. The results indicated an increase of desalinated water with the increase of hot water temperature, which resulted in the decrease of cooling capacity of the refrigeration system in this study. However, the energy saving correspond to the pre-heating of the water cycle by the condensing of the refrigeration system shows the avilable advantage of the proposed cycle as compared to other single purpose plants for desalination.

  • PDF

Multi-Ejector Design for High Altitude Simulation (고고도 환경 모사를 위한 멀티 이젝터 설계)

  • NamKoung, Hyuck-Joon;Shim, Chang-Yol;Lee, Jae-Ho;Park, Sun-Sang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2011.11a
    • /
    • pp.705-708
    • /
    • 2011
  • Ejector system can induce the secondary flow or affect the secondary chamber pressure by both shear stress and pressure drop which are generated in the primary jet boundary. Ejectors are widely used in a range of applications such as a turbine-based combined-cycle propulsion system and a high altitude test facility for rocket engine, pressure recovery system, desalination plant and ejector ramjet etc. The primary interest of this study is to set up an design procedure on the configuration and operating condition of multi-ejector for the various high altitude simulation.

  • PDF

자동차를 둘러싼 정보통신기술의 동향

  • 대한전기협회
    • JOURNAL OF ELECTRICAL WORLD
    • /
    • s.290
    • /
    • pp.85-89
    • /
    • 2001
  • 새로운 세기를 맞이하면서 이제 새삼 IT(Information Technology: 정보기술)가 주목을 받고 있다. 급속한 기세로 세계에 퍼진 인터넷이 정보의 흐름과 ''물건''의 움직임을 크게 바꾸려 하고 있기 때문이다. 외출지나 자동차 등의 이동환경에서도 휴대전화를 통하여 언제든지, 어디서나, 간단하게 인터넷 접속이 가능하게 되어 바야흐로 시간과 공간을 초월한 본격적인 네트워크사회를 맞이하려 하고 있다. 모바일 단말과 정보통신인프라의 발전은 네트워크에 의한 정보취득이나 전자상거래 등의 새로운 정보서비스를 창출하여 라이프사이클의 변화도 일으키고 있다. 한편 자동차를 둘러싼 정보통신환경은 카 내비게이션 등의 차재 정보단말과 함께 발전해가고 있다. FM다중, 광비컨, 전파비컨을 통한 VICS(Cehicle Information and Communication Systems: 도로교통정보통신 시스템)와 휴대전화를 통한 인터넷 접속, 자동차를 위한 정보제공서비스는 이미 실용화되고, 특히 노차간 통신전용 DSRC(Dedicated Short Range Communication: 협성통신)를 통해 유료도로에서 요금을 자동으로 징수하는 ETC(Electronic Toll Collection: 자동요금 징수시스템)의 실용화가 임박하고 있다. 앞으로는 IMT-2000(International Mobile Telecommunications-2000) 차세대휴대전화와 디지털방송서비스 등 보다 더 새로워진 정보통신 고속화$\cdot$고품질화가 기대되고 있으며, 이것들을 조합한 복합미디어에 의해 가까운 장래에는 차내에서도 다양한 정보제공서비스를 받아서 누릴 수 있을 것으로 생각된다.

  • PDF

A study for a Performance analysis of Hybrid heat pump Air conditioning system (복합열원형 히트펌프 냉난방 시스템의 성능분석에 관한 연구)

  • Lim, Hyun-Mook;Park, Hee-Moon;Cho, Soo;Sung, Uk-Joo;Park, Jin-Hoon;Park, Tae-Jin
    • Proceedings of the SAREK Conference
    • /
    • 2009.06a
    • /
    • pp.1373-1378
    • /
    • 2009
  • This study is aiming comparison and analization between efficiency of hybride air conditioning system which uses low temperature water under dam and air and EHP(Electric Heat Pump). The experimental was carried out with air cooling tests for EHP system having 80HP and composition heat pump system. P-i diagram of both systems and COP was used to derive schemetic and calcuations. As results of the tests, hybride system has 1.4 time higher efficiency coefficient.

  • PDF

The Effect of Cyclic Loading History on the Creep of $SiC_f/Si_3N_4$ Fiber-reinforced Composite (사이클 하중이력이 $SiC_f/Si_3N_4섬유강화 복합재료의 크리프에 미치는 영향)

  • 박용환
    • Journal of the Korean Society of Safety
    • /
    • v.15 no.4
    • /
    • pp.35-40
    • /
    • 2000
  • The influence of cyclic loading history on the creep behavior of the 30 vol% hot-pressed $SiC_f/Si_3N_4copmposite was experimentally investigated at $1200^{\circ}C$. The duration of loading/unloading had great effects on the creep behaviors. The short term duration cyclic loading history test results showed significant reduction in the primary and steady-state creep rates. For example, 300sec loading/300sec unloading history resulted in 70% lower steady-state creep rate than that of the continuous loading. However the long term duration cyclic loading history test results showed little change in creep rates compared to those of the continuous one. The reason for the significant change in the short term duration cycles was estimated due to the change in the stress redistribution between the fiber and matrix during the creep recovery in the primary stage.

  • PDF