• 제목/요약/키워드: 복합화약

Search Result 48, Processing Time 0.019 seconds

A Case Study on Explosives Demolition of the Dongdaemoon Complex Stadium(Baseball field) in Republic of Korea (동대문 운동장(야구장) 발파해체 시험시공 사례)

  • Min, Hyung-Dong;Park, Jong-Ho;Song, Young-Suk;Seo, Young-Su;Kim, Rea-Hoe;Jung, Byeong-Ho
    • Explosives and Blasting
    • /
    • v.26 no.1
    • /
    • pp.23-37
    • /
    • 2008
  • The Dongdaemoon complex stadium is scheduled to remodelled into an international park, which will be named Design Plaza. The Dongdaemoon baseball field was constructed with Rahmen Structure which comprised beams, slabs and columns. In order to assure for viewing, the stadium was composed unusual structure that the height of the front column and the back column was designed differently. The bleachers was an upper arch form for viewing. The slab was not flat unliked the general infrastructure and tilted in stairway type for viewing. If we had applied the mechanical demolition method, we could have predicted several problems. Firstly, the stand could be unstable when the heavy equipment was to crush the reinforced concrete on the slab. Because the slab was not flat. Secondly, the construction expense and construction duration could be increase when the large equipment was to crush the reinforced concrete on the ground. Because the height of the stand was too high to crush on the ground so it needed to build a filling. Thus, we applied both the mechanical demolition method and explosives demolition method at the design stage. The result of explosives demolition was of complete success in terms of structural movement and controlled blasting noise and vibration. This case study provided a good example for a successful application of explosives demolition in urban areas.

Study on the Long-term Thermal Stability by DSC & ARC and its ISCO behaviors with different AP Quality (DSC, ARC, ISCO를 활용한 다양한 순도를 가진 AP의 장기 열적안정성 연구)

  • Kim, Seunghee;Kwon, Kuktae;Lee, So Jung
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.22 no.2
    • /
    • pp.59-65
    • /
    • 2018
  • We conducted an isothermal slow cook-off(ISCO) test for an aluminized explosive containing AP. The sample bulged before the run-away reaction, and therefore we were unable to obtain the ISCO data. However, these phenomena did not occur for a certain AP grade, which means that the quality of the AP exerted a significant effect on the thermal stability of the explosive formulation. In this study, we investigated the thermal stability difference between a good and bad AP grade. First, we characterized the thermal properties of all APs by Differential Scanning Calorimeter(DSC) and correlated them to the ISCO phenomena. In addition to the DSC study and ISCO test, we also investigated and calculated the SADT and self-heating rate by the ARC of the different AP qualities to interpret the thermal stability of the explosive formulation. Moreover, we investigated the impurity of the AP and a preparation method to remove the included impurity and crystallization. Finally, we implemented qualification methods to identify the quality of AP by DSC using a high-pressure crucible.

Establishment of Hygrothermal Aging Mechanism via Thermal Analysis and Extraction of Reaction Kinetics of Ti Metal-based Pyrotechnic Materials (티타늄 금속 기반의 파이로테크닉 물질에 대한 열분석 및 반응특성 추출을 통한 열·수분 노화 메커니즘 구축)

  • Oh, Juyoung;Yoh, Jai-ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.49 no.9
    • /
    • pp.759-769
    • /
    • 2021
  • For aerospace propulsion systems, Titanium Hydride Potassium Perchlorate (THPP) is a material commonly used as a pyrotechnic initiator that generates gas when energy is supplied or as a supplement charge for NASA standard initiator (NSI). However, when the energetic materials are stored for a long time, it faces the problem of 'aging'. In this study, changes in thermodynamic properties of THPP aged under various humidity environments were identified through thermal analysis and surface analysis. First, a considerable amount of cracks on the surface of the oxidant was found in the aged THPPs. Particularly, when the humidity level increased, the number and length of the cracks rapidly increased. Also, the deterioration of Viton was found only in the thermally aged sample whereas the oxidation of the fuel was more pronounced in the hygrothermally aged samples. The extracted kinetic parameters of THPP on the reaction progress vary greatly by the humidity level, indicating that moisture significantly changes the performance and combustion reaction of THPP, which may eventually result in a reduced lifespan.

Evaluation of Beam Behavior with External Bonded L-type GFRP Plate through bending Test (L형 GFRP 외부부착 보강된 보의 휨 실험을 통한 보강 거동분석)

  • Jeong, Yeong-Seok;Kwon, Min-Ho;Kim, Jin-Sup;Nam, Gwang-sik
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.21 no.11
    • /
    • pp.86-93
    • /
    • 2020
  • The demand for maintenance in Korea infrastructure facilities constructed since the 1970s has increased significantly compared to the demand for new construction. Moreover, after the Gyeongju and Pohang earthquakes, seismic performance evaluation, repair, and retrofitting projects have been carried out. Therefore, in this study, a specimen was designed following the L-type GFRP Plate Externally Bonded Retrofit method, one among other retrofit methods. The L-type GFRP Plate was bonded to the specimen by epoxy and a washered steel nail. A four-point bending test was performed to confirm the strengthening effect of the Externally Bonded Retrofit method using an L-type GFRP Plate. The strengthening effect of the L-type GFRP plate was proven experimentally, and the behavior of the beam designed following the L-type GFRP Plate Externally Bonded Retrofit method was evaluated according to Korea's "Design Manual & Specification for Strengthening of RC Structures by Advanced Composites System". Furthermore, the effectiveness of the bonding method, a combination of epoxy and washered steel nail, was also checked. The results showed that the design, according to the guidelines mentioned above, predicted the strength of the member well, but the failure mode did not satisfy the design assumption because of unexpected damage to the GFRP plate due to the fixing method, washered steel nail.

A Study on the Removal of TNT(2,4,6-trinitrotoluene) using Marsh and Pond Type Microcosm Wetland Systems (Marsh와 Pond 형태의 Microcosm 습지 시스템을 이용한 TNT(2,4,6-trinitrotoluene)의 분해 연구)

  • Choi, Jong-Kyu;Kim, Se-Kyung;Kang, Ho-Jeong;Zoh, Kyung-Duk
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.27 no.2
    • /
    • pp.198-205
    • /
    • 2005
  • This study was carried out to investigate the removal of TNT (2,4,6-trinitrotoluene) in the batch and continuous type microcosm systems consisting of marsh and pond. First, the batch reactor study showed that TNT (10 mg/L) was completely removed in the marsh and pond system within 20 days. The major reductive metabolites of TNT include 4-amino-2,6-dinitrotoluene (4-ADNT), 2-amino-4,6-dinitrotoluene (2-ADNT), 2,4-diamino-6-nitrotoluene (2,4-DANT), and 2,6-diamino-4-nitrotoluene (2,6-DANT). These metabolites concentration also decreased during further treatment. The continuous reactor systems combining marsh and pond indicated the similar pattern of TNT degadation and the metabolites production. Among the continuous reactor combinations, marsh-pond system showed more stable TNT removal and metabolites production. The toxicity of the effluent from the continuous system was examined by Microtox Assay using Vibrio fischeri. The result showed that the effluent toxicity was reduced below toxicity endpoint ($EC_{50}$) after continuous marsh pond system, indicating that metabolites of TNT are less toxic than TNT itself. Based on the results, TNT contaminated wastewater can be efficiently treated using marsh and pond wetland systems.

A Study on martial arts when Equipped with Weapons, Clothes and Other Accessories (복식과 무기의 갖춤 상황에서의 무예연구)

  • Hwang, Ho-Young;Choi, Jea-Geun
    • Journal of Digital Convergence
    • /
    • v.11 no.1
    • /
    • pp.413-421
    • /
    • 2013
  • We, currently settled on the peninsula, have a long history and our ancestors lived over the vast land further to the central Asia and northern China. Normally, our ancestors traded with many countries, but they fought battles when they were on bad terms and many countries emerged and disappeared. In this history, a variety of cultures have been established and the traditional martial arts is a part of those cultures. Our martial arts has been almost severed because of the development of fire weapons in the late Chosun Dynasty, Japan's colonial rule, and 1950-53 Korean War. Fortunately, we can study the traditional martial arts from history books, the records on the martial art books and relics. Muyeadobotongji, the martial art book published in the late Chosun Dynasty, regrets the negligence of martial arts Giyae(arts) after Japanese Invasion of Korea in 1592 and the Manchu war of 1636 and accommodated the martial art skills from Chosun, China and Japan. It is useful for studying martial arts, because it contains detailed description and drawings, clothes and accessories, and the specification of the weapons. However, the problem is the level of Giyae of the martial arts organization and individuals based on Muyeadobotongji vary and some organizations are arguing about the numbers.

A study on the effect of blasting vibration and the optimal blasting offset according to the depth of tunnel (터널 심도에 따른 발파 진동 영향 및 최적 발파 이격거리 연구)

  • Kong, Suk-Min;Choi, Sang-Il;Kim, Yeong-Bae;Noh, Won-Seok;Kim, Chang-Yong;Lee, Seong-Won
    • Journal of Korean Tunnelling and Underground Space Association
    • /
    • v.24 no.6
    • /
    • pp.483-494
    • /
    • 2022
  • Owing to the saturation of ground spaces in downtown areas, underground spaces are being developed increasingly. Underground spaces are utilized for transportation, water supply and sewerage, communication zones, electric power zones, and various cultural complexes. In Korea, for excavating underground spaces, blasting methods using gunpowder such as the New Austrian Tunneling Method (NATM) are mainly used. However, the blasting method causes vibration and noise during tunnel excavation, generating many complaints from residents in the vicinity of the excavation site. To address this problem, various methods have been developed, and recently, vibration and noise have been reduced using deep excavation. This study predicts blast vibration changes according to the depth, under the same blasting and tunnel conditions, using numerical analysis based on the blast vibration measurement data of the GTX-A route, the tunnel cross-section drawings, and ground investigation reports. Furthermore, the necessary separation distance from densely populated areas such as residential areas is suggested by analyzing the trend of decreasing blast vibration according to the distance from ground surface directly above the blasting location.

A Study on Remediation of Explosives-Contaminated Soil/Ground Water using Modified Fenton Reaction and Fenton-like Reaction (Modified Fenton Reaction과 Fenton-like Reaction을 이용한 화약류 오염 토양/지하수의 처리에 관한 연구)

  • Hur, Jung-Wook;Seo, Seung-Won;Kim, Min-Kyoung;Kong, Sung-Ho
    • Korean Chemical Engineering Research
    • /
    • v.43 no.1
    • /
    • pp.153-160
    • /
    • 2005
  • There have been large areas of soil contaminated with high levels of explosives. For this experimental work, 2,4,6-trinitrotoluene (TNT) was tested as a representative explosive contaminant of concern in both aqueous and soil samples and its removal was evaluated using three different chemical treatment methods: 1) the classical Fenton reaction which utilizes hydrogen peroxide ($H_2O_2$) and soluble iron at pH less than 3; 2) a modified Fenton reaction which utilizes chelating agents, $H_2O_2$, and soluble iron at pH 7; and 3) a Fenton-like process which utilizes iron minerals instead of soluble iron and $H_2O_2$, generating a hydroxyl radical. Using classic Fenton reaction, 93% of TNT was removed in 20 h at pH 3 (soil spiked with 300 mg/L of TNT, 3% $H_2O_2$ and 1mM Fe(III)), whereas 21% removed at pH 7. The modified Fenton reaction, using nitrilotriacetic acid (NTA), oxalate, ethylenediaminetetraacetic acid (EDTA), acetate and citrate as representative chelating agents, was tested with 3% $H_2O_2$ at pH 7 for 24 h. Results showed the TNT removal in the order of NTA, EDTA, oxalate, citrate and acetate, with the removal efficiency of 87%, 71%, 64%, 46%, and 37%, respectively, suggesting NTA as the most effective chelating agent. The Fenton-like reaction was performed with water contaminated with 100 mg/L TNT and soil contaminated with 300 mg/L TNT, respectively, using 3% $H_2O_2$ and such iron minerals as goethite, magnetite, and hematite. In the goethite-water system, 33% of TNT was removed at pH 3 whereas 28% removed at pH 7. In the magnetite-water system, 40% of TNT was removed at pH 3 whereas 36% removed at pH 7. In the hematite-water system, 40% of TNT was removed at pH 3 whereas 34% removed at pH 7. For further experiments combining the modified Fenton reaction with the Fenton-like reaction, NTA, EDTA, and oxalate were selected with the natural iron minerals, magnetite and hematite at pH 7, based on the results from the modified Fenton reaction. As results, in case magnetite was used, 79%, 59%, and 14% of TNT was removed when NTA, oxalate, and EDTA used, respectively, whereas 73%, 25%, and 19% removed in case of hematite, when NTA, oxalate, and EDTA used, respectively.