• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.275-275
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• 2020

홍수빈도분석의 실용적 측면의 목적은 특정 재현기간에 대하여 발생 가능한 홍수량을 설계홍수량(design flood)으로 설정함으로써 댐, 제방, 배수시설, 하수관거 등의 치수기능을 가진 치수시설물이 설계홍수량 내에서 홍수로 인한 피해를 발생시키지 않도록 그 규모와 기능을 설계함에 있다. 이와 같은 중요한 기능을 담고 있는 홍수빈도분석의 기술적 절차는 해외 및 국내의 기존 연구자들에 의해 많은 연구가 진행된 바 있으나, 보다 적절한 설계홍수량 산정절차 및 설계홍수량의 최종 결정을 위한 기술적 수단의 제공을 위한 연구가 많은 연구자들에 의해 지금도 진행 중에 있다. 그러나 이와 같이 결정된 설계홍수량이 특정유역에서 발생될 수 있는 피해규모에 대해 얼마나 적정한 지의 여부를 과학적으로 판단하기 위한 연구는 많지 않다. 따라서 본 연구에서는 홍수빈도분석을 통해 산정된 설계홍수량의 적정성 여부를 과학적으로 판단하기 위해 비용-편익분석 기법을 이용하여 최적설계홍수량을 결정하였다. 특히 본 연구에서는 불확실성으로 발생되는 범위를 고려한 최적설계홍수량을 산정하기 위하여 Metropolis-Hastings 알고리즘을 사용하였으며, 자료의 종류에 따른 홍수량의 변화를 분석하기 위하여 년최대계열 및 부분시계열 자료를 각각 적용하였다. 한강유역에서 가평대성, 여주 및 한강대교 수위표 지점에서 측정된 자동관측유량장치에 의한 홍수량 자료를 활용하였으며, 최적설계홍수량이 기존 설계홍수량에 비해 크게 산정됨을 알 수 있었다.

• Fire Science and Engineering
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• v.30 no.1
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• pp.31-36
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• 2016

This study investigates the characteristics of thermal decomposition of an epoxy-based intumescent paint using thermogravimetric analysis (TGA) and numerical simulation. A mathematical and numerical model is introduced to describe mass loss profiles of the epoxy-based intumescent coating induced by the thermal decomposition process. The decomposition scheme covers a range of complexity by employing simplified 4-step sequential reactions to describe the simultaneous thermal decomposition processes. The reaction rates are expressed by the Arrhenius law, and reaction parameters are optimized to fit the degradation behavior seen during thermogravimetric (TG) experiments. The experimental results show a major 2-step degradation under nitrogen and a 3-step degradation in an air environment. The experiment also shows that oxygen takes part in the stabilization of the intumescent coating between 200 and $500^{\circ}C$. The simulation results show that the proposed model effectively predicts the experimental mass loss as a function of time except for temperatures above $800^{\circ}C$, which were intentionally not included in the model. The maximum error in the simulation was less than 3%.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.843-849
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• 2012

When we use NiO based particle as an oxygen carrier in a chemical looping combustion system, the fuel conversion and the $CO_2$ selectivity decreased with increasing reaction temperature within high temperature range (> $900^{\circ}C$) due to the increment of exhaust CO concentration from reduction reactor. To improve reduction reactivity at high temperature, the applicable metal oxide component was selected by calculation of the equilibrium CO concentration of metal oxide components. After that, feasibility of reduction reactivity improvement at high temperature was checked by using solid mixture of the selected metal oxide particle and NiO based oxygen carrier. The reactivity was measured and investigated using batch type fluidized bed. The solid mixture of $Co_3O_4/CoAl_2O_4$(10%) and OCN706-1100(90%) showed higher fuel conversion, higher $CO_2$ selectivity and lower CO concentration than OCN706-1100(100%) cases. Consequently, we could conclude that improvement of reduction reactivity at high temperature range by adding some $Co_3O_4$ based oxygen carrier was feasible.

• 대한공업교육학회지
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• v.33 no.1
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• pp.1-22
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• 2008

The purpose of this research is to clarify the elements of the function of the role of industrial high schools that its experts perceived. The content of this research is verify the function element required for the performance of the role of specialized education through content validity ratio(CVR). This research adopted the method of literature research and Delphi method, which is to collect and come to an agreement of the opinions of the 26 research panels. The first round is constructed by the semi-constructed questionnaire for the analysis of the opinions of the panels by inductive method. The second round is to categorize the result of the first one into 7 domains, and asked each category by Likert's 5 scale checklists, and statistically analyzed mean, medium, standard deviation, and quartile. The third round is to statistically analyze Mean, standard deviation, medium, and validity ratio(CVR) to reassure the opinions of the panels on the basis of the result of the first one. The categorized contents of the function required for the performance of the specialized education in this research is 'in-service visit and in-service training', 'licence acquiring education', 'employment counseling and job employment information', 'custom-made education connected with industry', 'career education' and 'enhancement of basic career competency'. The panels are divided into professors, teachers, professionals, and policy administrators, and they verified the validity rate of the function role and priority of emphasis. The result showed that the tendency of the education is converting from physical function-centered education to education of emotional attitude and competence of thought.

• Journal of Applied Biological Chemistry
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• v.64 no.2
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• pp.177-184
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• 2021

While veterinary antibiotics are used only in a part of the dose administered, the rest are excreted as urine or feces. Residual antibiotics enter the adjacent agricultural environments by spraying manure-based composts on farmlands and lead to secondary pollution. Therefore, it is necessary to develop the technique for post management such as regulatory levels of antibiotics in the agricultural environments. This study was conducted to compare by different matrices the amount of residual antibiotics such as tetracyclines and sulfonamides, which are known to be frequently used in Korea and to practice risk assessment by different antibiotics in soils before and after application of composts. Pre-treatment with modified typical method using buffer and solid phase extraction showed the recovery of composts and soils was more than 70% at ppb level and the limits of detection were 0.13-0.46 and 0.05-0.25 ㎍/kg, respectively. Analysis of manure-based composts revealed concentrations from 5.38 to 196.0 ㎍/kg for tetracyclines, from below the detection of limit (BDL) to 259.0 ㎍/kg for sulfonamides. In case of agricultural soils, residual concentrations of selected veterinary antibiotics were ranged 0.30-53.3 ㎍/kg, BDL-4.16 ㎍/kg respectively and the concentration level of tetracyclines, which had higher soil distribution coefficient (Kd) values, was higher than that of sulfonamides. There was a difference in human risk assessment by different antibiotics in soil before and after application of composts. But, it was indicated that detection values of all of 5 antibiotics were very safe on the basis that Hazard Quotient was safe below 1.

• Economic and Environmental Geology
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• v.40 no.1 s.182
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• pp.1-14
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• 2007

The Guemseong mine is located near the southern margin of the Jurassic Jecheon granitoids collectively with the Cambro-Ordovician mixed dolostone-limestone series of the Yeongweol Group, Choseon Supergroup. Here, two spatially distinct types of skarn formation have been observed. The upper transitional skarn is the calcic Mo skarn which has the mineral assemblage of $garnet+hedenbergite+epidote{\pm}wollastonite{\pm}magnetite{\pm}hematite{\pm}amphibole{\pm}chlorite{\pm}vesuvianite$ within the calcite marble. On the other hand, the lower proximal skarn occurs as a discordant magnesian Fe skarn at the contact of Mo-bearing aplitic cupolas with unidirectional solidification texture(UST) within the dolomitic marble. The magnesian Fe skarn has the mineral assemlage $olivine+diopside+magnetite+tremolite+serpentine+talc+chlorite{\pm}phlogopite$. The formation of two different types of skarn and ore mineralization in Geumseong mine have been attributed to multistage and complex metasomatic replacements that ultimately resulted in silicate-oxide-sulfide sequence of metasomatism. An early prograde stage with anhydrous skarn minerals such as olivine, clinopyroxene and/or garnet with magnetite, formed from high temperature (about $500^{\circ}\;to\;400^{\circ}C$) at an environmental condition of low $CO_2$ fugacity ($XCO_2<0.1$) and 0.5 kbar. The later retrograde stage with hydrous silicates such as amphibole, serpentine, phlogopite, epidote and chlorite with molybdenite or hematite, termed from relatively lower temperature (about $400^{\circ}\;to\;300^{\circ}C$).

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.110-110
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• 2016

도시 유역의 강우-유출 모의에는 지표 투수율 및 하수관거 영향 등 인위적 배수계통의 영향을 고려할 수 있는 도시유출모형이 널리 이용되고 있으며, 모형 검증을 통해 모의 성능을 평가한다. 도시유출모형의 검증은 일반적인 강우-유출 모형과 같이 강우사상별 유량의 관측시계열과 모의시계열의 목적함수가 최소가 되는 최적 매개변수를 탐색하는 과정이다. 도시유출모형의 검증에서 발생하는 문제점은 크게 다음과 같다. 첫째, 대규모 도시 유역의 복잡하고 다양한 하수관거에 대한 최적매개변수를 관거별로 구하는 것은 물리적으로 불가능하다. 따라서 동일 배수분구내 하수관거의 매개변수 값은 동일하다고 가정하거나, 모형 단순화 과정을 통해 매개변수의 물리적 범위 내에서 최적해를 탐색해야 하는 단순화에서 기인한 불확실성이 있다. 둘째, 다양한 매개변수들의 물리적 범위를 고려하기 위해서는 전역최적화기법이 유효하다. 그러나 전역최적화 종류, 목적함수, 모의횟수, 목표성능별 최적 매개변수 결과가 각각 다르므로 추정된 최적 매개변수의 범위에 대한 불확실성이 있다. 이에 본 연구에서는 Bayesian 모형과 EPA SWMM(Storm Water Management Model)을 연계하여 도시유출모형의 매개변수 불확실성을 정량적으로 분석할 수 있는 모형을 제안하고자 한다. 이를 위해 서울 우이천 유역을 대상으로 SWMM 모형을 구축하고, 절단 정규분포(truncated Gaussian distribution)를 사전분포(prior)로 가정하여 매개변수의 물리적 범위를 고려하였다. 최종적으로 결합확률분포로 계산된 각 매개변수간 사후분포를 통해 모의된 유출량의 불확실성을 정량적으로 분석하였다. 본 연구에서 제안된 모형은 대규모 도시 유역의 도시유출모형 구축 시 다양한 매개변수의 물리적 범위를 고려한 최적화와 동시에 내재된 불확실성을 정량적으로 분석할 수 있으므로, 침수예측 및 홍수예경보 등의 문제에서 상당한 신뢰성을 확보할 수 있을 것으로 판단된다.

• Journal of the Mineralogical Society of Korea
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• v.25 no.1
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• pp.41-50
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• 2012

페루 남동부 지역에 위치한 꾸스코 동-금을 포함한 다중금속 광상 지역의 지질은 고생대 페름기-중생대 삼첩기 변성퇴적암인 미투(Mitu)층군과 이를 관입한 동시기 관입암으로 구성되어 있다. 조사지역은 페름기-삼첩기 관입암과 관련된 U-W-Sn-Mo, Au-Cu-Pb-Zn, REE 광화작용과 관련된 금속광화 대로 알려져 있다. 특히 해당 관입암은 대자율 측정 결과 S-type, 티탄철석계열과 관련이 있는 것으로 보인다. 꾸스코 지역은 깔까 북쪽과 시꾸아니 부근에 주요 광화대가 발달하고 있다. 조사대상 광상은 아줄 동, 올미오 동, 빅토리아 금, 빠딴자 동, 나우챠피-초차까나 동, 체카 금광상이다. 아줄 광상의 모암은 안산암질암이며 광석광물로는 반동석 및 황동석이 산출하며, 동은 7.81~15.3%의 범위를 가지고 평균 10.7%이다. 올미오 광상의 모암은 흑색편암이며 엽리를 따라 산화동이 충진되어 있고, 동은 0.61~2.60%의 범위를 가지고 평균 1.74%이다. 빅토리아 광상의 모암은 변성퇴적암이며, 석영맥 충진형 광상으로 금함량은 < 0.1 g/t, 은함량은 < 0.1~< 0.3 g/t이다. 빠딴자 광상에서는 이암 또는 실트암의 층리를 따라 충진하고 있는 산화동이 산출하며, 동은 3.74~9.21%의 범위를 보이며 평균 6.21%이다. 나우챠피-초차까나 광상은 적색사암의 층리를 교대충진하고 있는 산화동 광체이며, 동은 1.62~10.5%의 범위를 가지며 평균 6.39%이다. 체카 광상은 모암인 규암이 각력화작용을 받은 부분에서 금이 산출되고 있는 것으로 보고되어있으나 분석결과 금이 탐지되지는 않았다.

• The Journal of the Acoustical Society of Korea
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• v.31 no.8
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• pp.514-522
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• 2012

The temperature dependence of the characteristics in a PZT-5 piezoelectric ceramic vibrator with the transverse mode was investigated in the range of $-100^{\circ}C$ to $90^{\circ}C$ using a thermal vacuum chamber to utilize the vibrator in aerospace industries. As the results, at room temperature, the resonant and anti-resonant frequencies had the minimum value, whereas, the dielectric constant increased linearly from about 2500 to 7500 in the given temperature range. The mechanical loss decreased linearly from 0.08 to 0.03. Through the regression analysis, the temperature dependence functions of the characteristics were derived to linear and square regression functions. Applying the functions, the input admittance characteristics of the piezoelectric vibrator were calculated, and the results showed good agreement with measured ones. It can be confirmed that this method is useful to estimate the characteristics change of the piezoelectric vibrator caused by the temperature change under the space environment.

• Fire Science and Engineering
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• v.16 no.3
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• pp.26-31
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• 2002

Bromotrifluoromethane(halon-1301) and bromochlorodifluoromethane(halon-1211) have been widely used as a clean fire extinguishing agents due to their outstanding properties. However, production and use of halon are currently being phased out under an international agreements Montreal Protocol because of global environmental concerns and HFCs have been considered as promising alter-natives for the replacement of halon since their ozone depletion potentials are low. The vapor-liquid equilibrium data are required as important basic information in evaluating the solubility of clean fire extinguishing agents and determining their optimal compositions. In this work, we chose HFCs such as HFC-22 HFC-125, and HFC-l34a for gaseous fire extinguishing agents and nitrogen as a pressurization gas for a proper jet velocity of these agents. Phase equilibria for binary mixtures of nitrogen/HFC-22, nitrogen/HFC-125, and nitrogen/HFC-l34a were measured in the temperature range from 283.15K to 303.15K. For equilibrium measurement, we used a circulation type apparatus in which both vapor and liquid phases were continuously recirculated. The experimental data were relatively well correlated with the Peng-Robinson equation of state with Wong-Sandier mixing rules.