• Fire Science and Engineering
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• v.30 no.3
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• pp.1-6
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• 2016

More than five thousands transportation fires occurannually in Korea and the resulting destruction of property and loss of life is huge and results in traffic and environmental pollution. The recent development of automobile technology such as the hybrid concept and use of bio fuels makes fire protection even more difficult due to a lack of understanding of the new adapted system including vehicle engines. In this study, a numerical simulation was performed on a PSR (perfectly Stirred Reactor) to simulate an automobile engine and to clarify the effect of gasoline/ethanol surrogates as a fuel. The temperature, NOx and soot emissions were predicted to decrease with increasing ethanol content, but that of unburned hydrocarbons was found to increase dramatically. The result will provide not only the basic thermal characteristics for engines and their after-treatment systems, but also make it possible to assess the potential for fire events in these systems when an ethanol mixed fuel is used in gasoline vehicles.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2002.11a
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• pp.63-63
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• 2002

현재 기계적 합금화법에서는 주로 합금을 구성하는 성분원소 분말을 불활성분위기에서 볼밀처리 함으로써 함금화를 시키거나 모합금에 산화물을 분산시켜 복합화시키는 공정을 통하여 각종 화합물, 비정질상 및 과포화고용체등의 준안정상의 합성 뿐만이 아니라 초미세조직의 생성에 관한 폭 넓은 분야의 연구가 행하여지고 있다. 한편 MA에서는 볼멀처리중 기계적 에너지의 투여에 의하여 실제 반응온도보다 낮은 온도에서 발생하는 특이한 화학반응 즉 Mechanochemical 반응을 일으키 기도 한다. 본 연구에서는 헤마타이트($Fe_20_3$)와 금속윈소인 Ti의 MA처리에 의하여 고상환원반응 을 유기시켜 $Fe-TiO_2$계 nanocomposite 분말재료를 제조하고자 한다. 특히 MA 공정에 있어서 자기 물성의 변화와 X선 회절을 통하여 고상환원반응에 의한 복합분말의 생성과정을 조사하였다. 출발원료는 $Fe_20_3$(고순도화학제,99.9%, 평균입경 0.1$\mu\textrm{m}$)와 금속원소인 Ti(99.9%, 명균업경 150$\mu\textrm{m}$)을 몰비 2:3의 조성이 되도록 하여 MA를 실시하였다. 볼멀은 고에너지 유성형 볼밀장치(독일 제, Fritsch P-5)를 이용하였으며 진공치환형 용기에 원료분말을 장입하여 2회정도 진공배기한 후 아르곤 가스를 충전하여 볼밀을 행하였다. 얻어진 분말시료에 대하여 x-선 회절장치, 전자현미경 (SEM) 및 진동시료형자력계(VSM)를 통하여 결정구조, 미셰조직 빛 자기특성을 조사하였다. $Fe_2O_3-Ti$ 혼합분말의 MA처리 에 의하여 초기단계부터 환원반응과 함께 $Fe_3TIO_{lO}$ 중간상이 관찰 되었으나 30hrs의 MA처리 후 Fe와 산화물 $TiO_2$로 모두 환원되어 $Fe-TiO_2$계 나노복합분말이 얻어짐을 알 수 있었다. 이 때 X션 회절피크의 line broadening으로부터 복합분말의 Fe 명균 결정립 크기는 24nm로 초미세 결정럽의 분말합금이었다. 포화자화값은 볼밀처리에 따라 점점 증가하여 MA 30시간에는 20.3emu/g로 포화됨을 알 수 있었다. 또한 보자력 Hc는 MA초기단계에 350e로 매우 낮으나 30시간 후에는 Hc값이 2600e로 매우 큰 값을 나타내었다. 이것은 환원반응결과 초기에 생성된 Fe의 결정립이 비교적 크고 결정결함이 적으나 볼밀처리를 30시간까지 행하면 Fe 결정렵의 미세화 빛 strain 증가로 magnetic hardening이 일어나기 때문인 것으로 사료된다.

• Clean Technology
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• v.16 no.4
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• pp.284-291
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• 2010

Nitrous oxide ($N_2O$) is a greenhouse material which is hard to remove. Even with a catalytic process it requires a reaction temperature, at least, higher than 670 K. This study has been performed to see the effects of Ce addition to the mixed oxide catalyst which shows the highest activity in decomposing $N_2O$ completely at temperature as low as 473 K when CO is used as a reducing agent. Mixed metal oxide(MMO) catalyst was made through co-precipitation process with small amount of Ce added to the base components of Co, Al and Rh or Pd. Consequently, the surface area of the catalyst decreased with the contents of Ce, and the catalytic activity of direct decomposition of $N_2O$ also decreased. However, in the presence of CO, the activity was found high enough to compensate the portion of activity decrease by Ce addition, so that it can be ascertained that the catalytic activity and stability can be maintained in the CO involved $N_2O$ reduction system when Ce is added for the physical stability of the catalyst.

• Journal of the Korean Applied Science and Technology
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• v.34 no.4
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• pp.962-973
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• 2017

Concerns about an air pollution are gradually increasing at home and abroad. The automotive and fuel researchers are trying to reduce emissions and greenhouse gases of vehicles through a research on new engine designs and innovative after-treatment systems using clean fuels (eco-alternative fuel) and fuel quality improvements. In this paper, we stduy the emission characteristics of greenhouse gases on seven vehicles using gasoline, diesel, and LPG by legal test mode in domestic and abroad.(Urban mode, Highway mode, rapidly acceleration and deceleration, using air conditioner, low temperature condition) Regardless of fuels, most of the greenhouse gases tend to show the worst results in cold FTP-75 mode. In the case of A vehicles (2.0 MPI) and B vehicles (2.4 GDI) using a gasoline fuel, the factors that increase greenhouse gases are in order of a rapidly acceleration and deceleration, using air conditioner, low temperature condition. But G vehicles(LPLi) have different emission characteristics from another vehicles. In the case of A vehicles (2.0 w/o DPF) and B vehicles (2.2 with DPF) using a diesel fuel, the factors that increase greenhouse gases are in order of a rapidly acceleration and deceleration, using air conditioner, low temperature condition. However, the factor of F vehicles are in order of low temperature condition, using air conditioner, rapidly acceleration and deceleration. In conclusion, it will be an effective method to apply different technologies of emission reduction for each fuel.

• Journal of the Korean Chemical Society
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• v.39 no.7
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• pp.513-523
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• 1995

Polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) are the most concerned toxic organic pollutants to human. Because of their extremely high toxicity and uncertain genotoxic potential, their determination in environmental and biological samples is of great interest. Municipal solid waste incinerator facilities have been reported as the major contributors of dioxins and furans to the environment, and their formation from combustion is a universal phenomenon, everywhere. In this study dioxins and furans were analyzed from the bottom ash produced during combustion in an municipal waste incinerator located in Seoul. The EPA method was modified for sample pretreatment: the soxhlet method was used for extraction and clean-up procedures were performed by using silica and basic alumina, excluding active-carbon. The extract was then analyzed by HRGC/HRMS. A general trend of increase in the amounts of 6∼7 chlorine-substituted dioxins and furans was observed. Total dioxins, furans and 2,3,7,8-TCDD were determined as 8.05 ng/g, 4.75 ng/g, and 6.93 pg/g, respectively.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.2
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• pp.161-168
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• 2013

Nowadays, one of the most interested area of automobile industry is the production of vehicle which has collision safety and ability to produce less amount of $CO_2$. The achievement of such a dual performance is done by choosing the materials like dual phase steel, ferrite bainite steel, etc. These steels have been used in automotive chassis and body parts, and also used to be formed by hole flanging to meet the goal of strength and design requirement. The formability of sheet material was experimented by hole expansion test and the judgement relies on human eye and his experience. This manual judgement involves many errors and large deviation. This paper develops the automatic crack recognition system which finds a crack based on CCD image to complement the problem of the current method depending on human's sense.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.7 no.3
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• pp.278-284
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• 2006

The popularity of the diesel engine revolves around its fuel efficiency, reliability, and durability compared to the gasoline engine. However, the main disadvantage of diesel engine is the emission of particulate matter (PM) which is known as carcinogenic substance. Therefore recent progress in engine management and after-treatment systems has led to great improvement to satisfy strict emission regulations. To comply with powerful environment regulations, this study is focused on the decrease of PM(soot) as to increase significantly exhaust temperature. Therefore, HC injection is used as the method to go to the PM regeneration temperature in front of filters composed of diesel oxidation catalyst(DOC) and diesel particulate filter(DPF). And especially, LPG is used because it has good chemical reactions with exhaust. In this study, we could manufacture the test bench thought LPG injection - with which soot can be decreased-, construct 3 kinds of database(DB) according to quantity of temperature to decide the LPG injection quantity and develop DPF ECU algorithm.

• Journal of Navigation and Port Research
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• v.43 no.6
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• pp.335-343
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• 2019

As the regulations of ship exhaust gas have been strengthened recently, many measures are under consideration to reduce fuel consumption. Among them, research has been performed actively to develop a machine-learning model that predicts fuel consumption by using data collected from ships. However, many studies have not considered the methodology of the main parameter selection for the model or the processing of the collected data sufficiently, and the reckless use of data may cause problems such as multicollinearity between variables. In this study, we propose a method to predict the fuel consumption of the ship by using the principal component analysis to solve these problems. The principal component analysis was performed on the operational data of the 13K TEU container ship and the fuel consumption prediction model was implemented by regression analysis with extracted components. As the R-squared value of the model for the test data was 82.99%, this model would be expected to support the decision-making of operators in the voyage planning and contribute to the monitoring of energy-efficient operation of ships during voyages.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.1
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• pp.1-7
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• 2016

A Urea-SCR(Selective Catalytic Reactor) system, which converts nitrogen oxides into nitrogen and water in the presence of a reducing agent, creates a major exhaust gas aftertreatment system for NOx reduction among other compounds. With regard to vehicle applications, a urea solution was chosen based on its eutectic composition of a 32.5wt% urea-water solution. An important advantage of this eutectic composition is that its melting point of $-11.7^{\circ}C$ is sufficiently low to avoid solidification in cold environments. However, the storage tanks must be heated separately in case of low ambient temperature levels to ensure a sufficient amount of liquid is available during scheduled start ups. In this study, therefore, a numerical investigation of three-dimensional unsteady heating problems analyzed to understand the melting processes and heat transfer characteristics including liquid volume fraction, temperature distributions, and temperature profiles. The investigations were performed using Fluent 6.3 commercial software that modeled coolant and electric heater models based on a urea solution. It is shown that the melting performance with the electric heater is higher than a coolant heater and is more efficient.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.97-97
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• 2010

많은 플라즈마 공정 중에 건식 식각은 복잡하고 표면반응이 잘 알려지지 않은 등의 이유로 가장 어려운 분야 중의 하나이다. 이러한 이유로 식각 장치 디자인뿐만 아니라 플라즈마를 이용한 건식 식각의 공정 조건은 수많은 시행착오를 통해 시도되어 왔다. 이런 문제들을 극복하기 위해 많은 연구자들에 의해서 다양한 방법과 tool을 이용해 모델링이 시도되고 있다. 본 연구에서는 $CF_4$ 가스를 이용한 유도결합 플라즈마에 의해 Si와 $SiO_2$를 식각하는 것을 상용 프로그램인 전산모사 유체역학 시뮬레이터인 CFD-ACE+를 이용하여 모델링했다. 150 mm 직경의 웨이퍼에 대한 모델은 식각 속도 실험결과와 비교 하였다. Ar의 경우 20 mTorr에서 13.56 MHz, 500 W인가 시 2.0 eV의 전자온도와 $7.3{\times}10^{11}\;cm^{-3}$의 전자밀도가 계산결과와 상당히 일치하게 측정되었고, $CF_4$를 이용한 $SiO_2$ 식각에서도 식각 속도가 평균 190 nm/min로 일치했고 식각 균일도는 3% 였다. 450 mm 웨이퍼 공정용 장치의 모델 계산 결과에서는 안테나와 기판의 거리, 챔버의 단면적, 기판 지지대와 배기구와의 높이 등 기하학적인 구조와 각 안테나 턴의 위치 및 전류비가 플라즈마 균일도에 많은 영향을 주었으며, 안쪽부터 4 turn이 있는 경우 2번째, 4번째 turn에만 1:4의 전류비를 인가했을 때, 수십%의 전자밀도의 불균일도를 4.7%까지 낮출 수 있었다. 또한, Si 식각에서는 식각 속도의 분포가 F radical의 분포와 같은 경향을 보임을 확인했고, $SiO_2$ 식각에서는 전자 밀도의 분포와 일치함을 확인함으로써 균일한 식각을 위해서 두 물질의 식각 공정에서는 다른 접근의 시도가 필요함을 확인했다. 플라즈마의 준중성 조건을 이용해서 Poisson 방정식을 풀지 않고 sheath를 해석적 모델로 처리하는 방법과, Poisson 식으로 정전기장을 푸는 방법을 통해서 입사 이온의 에너지 분포를 비교하였다. 에너지 범위는 80~120 eV로 같지만, 실험에서는 IED가 낮은 에너지 쪽이 더 높게 측정됐고, 계산 결과에서는 높은 에너지 쪽이 높았다.