• Resources Recycling
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• v.4 no.4
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• pp.37-58
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• 1995

Whole tues were put uto cement kiln inlet where the tempmalures or gas and cemcnt-raw-materials were 1050 and 800- 850.C. respcclrvely. Tl~ck iln consisls of \ulcorner-stage suspension preheatel- and air quenching coolers The amount of wusle tlrcs added in lhc normal encrgy in lhc ce~ncnlk iln was 3, 5, 7% by volume Welght and steel contents of tiles. ulti~~iaalcn d elemental analysis, ash contents. ash hsion temperature. etc, wete detcnutned to inveshgate thc prnpcrlics a1 tires and ilreir ashes. Flucluat~ons of cement kiln placess, cement quality and an pollulton were invesligalerl during lhc burning tins. When the Ieeding ralio ol wasle lires to normal cncrgy was 50'0, there was nn wlde d~ffereilces m the cemmt quctlity and air pollutcon between operation with tiles and withoul tires. Tl~ch cal iccovcry was uhout 50% w~th5 % add~tionI n the nonndl energy. There was a little lxt fluctuation of cement quultty ncld an pollution at olher feeding ralios.

• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.492-500
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• 2019

In this study, the effect of chemical additives on the reduction of fine particles was identified in $9.2MW_e$ commercial scale circulating fluidized bed boiler firing bituminous coal. Futhermore, a simple and effective method of fine particle collection has been developed to collect the fine particles of the boiler during fossil fuel combustion. Chemical additives were used to reduce particles below 10 PM in the flue gas, and borax solution was used as a chemical additive. In order to identify the particle behavior of PM 10 or less among the collected fine particles, it was analyzed through particle size analyzer and SEM analysis. The Borax solution tends to absorb molten mineral in the flue gas and make fine particles grow. As a result, it was analyzed that particles smaller than $10{\mu}m$ were reduced by using borax solution.

• Journal of Digital Convergence
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• v.18 no.4
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• pp.419-424
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• 2020

The purpose of this study is to find out whether changed interactions due to reformatting has a significant effect on the play attribute of children's play from an instrumental point of view. Based on the study of Roser Caillois theory of play (Agon, Mimicry, Area, Ilinx) and previous studies, a questionnaire was written and experimental design was carried out through brick stack which are most preferred in the whole development of children. Brick stack were selected from physical and electronic spaces and the survey was conducted with children's experiences by dividing into experimental group and comparative group. Correlation and T-test results, the brick stack by reformating showed significant difference in the play attributes (Agon, Mimicry, Area, Ilinx) of Rose Caillois and we found that the effectiveness of play is doubled in the electronic space. Play properties evenly distributed in electronic space brick stacking suggest that pleasure and fun can double.

• Korean Chemical Engineering Research
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• v.53 no.5
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• pp.590-596
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• 2015

Estimating potential of $CO_2$ emission reduction of non-capture $CO_2$ utilization (NCCU) technology was evaluated. NCCU is sodium bicarbonate production technology through the carbonation reaction of $CO_2$ contained in the flue gas. For the estimating the $CO_2$ emission reduction, process simulation using process simulator (PRO/II) based on a chemical plant which could handle $CO_2$ of 100 tons per day was performed, Also for the estimation of the indirect $CO_2$ reduction, the solvay process which is a conventional technology for the production of sodium carbonate/sodium bicarbonate, was studied. The results of the analysis showed that in case of the solvay process, overall $CO_2$ emission was estimated as 48,862 ton per year based on the energy consumption for the production of $NaHCO_3$ ($7.4GJ/tNaHCO_3$). While for the NCCU technology, the direct $CO_2$ reduction through the $CO_2$ carbonation was estimated as 36,500 ton per year and the indirect $CO_2$ reduction through the lower energy consumption was 46,885 ton per year which lead to 83,385 ton per year in total. From these results, it could be concluded that sodium bicarbonate production technology through the carbonation reaction of $CO_2$ contained in the flue was energy efficient and could be one of the promising technology for the low $CO_2$ emission technology.

• Journal of Energy Engineering
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• v.14 no.4 s.44
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• pp.219-225
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• 2005

for the removal of carbon dioxide in flue gas, which is the main cause of the global warming, chemical absorption methods were widely used for years. Alkanolamines such as MEA, AMP, MDEA are mainly used as an absorbent. In this study, cyclic amines - Piperazine, Piperidine and Cyclohelylamine are investigated to compare the chemical solubilities, absorption capacities and rate ot reaction. In conclusion, Piperazine is the most effective absorbent of $CO_2$ and ran be the excellent alternative to the former absorbents. Experiments were performed at 5, 10, 15 weight percent, 30, 40, $50^{\circ}C$, and the gas solubilities are determined by back-titration method, and using Gas Chromatography the absorption rate was compared.

• Applied Chemistry for Engineering
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• v.31 no.5
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• pp.560-567
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• 2020

In this study, we investigated that the effect of alkali metals [Na(Sodium) and K(Potassium)], known as representative deactivating substances among exhaust gases of various industrial processes, on the NH₃-SCR (selective catalytic reduction) reaction of V/W/TiO₂ catalysts. NO, NH₃-TPD (temperature programmed desorption), DRIFT (diffuse reflectance infrared fourier transform spectroscopy analysis), and H₂-TPR analysis were performed to determine the cause of the decrease in activity. As a result, each alkali metal acts as a catalyst poisoning, reducing the amount of NH₃ adsorption, and Na and K reduce the SCR reaction by reducing the L and B acid points that contribute to the reaction activity of the catalyst. Through the H₂-TPR analysis, the alkali metal is considered to be the cause of the decrease in activity because the reduction temperature rises to a high temperature by affecting the reduction temperature of V-O-V (bridge oxygen bond) and V=O (terminal bond).

• New & Renewable Energy
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• v.7 no.3
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• pp.67-73
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• 2011

MGT fuelled by landfill gas was tested to asses feasibility of its exhaust gas application for $CO_2$ enrichment. The exhaust gas was analyzed during start-up and normal operation with different MGT load conditions. Due to the changes of air/fuel ratio and combustion mode, $O_2$, $CO_2$, CO and NOx concentration were varied within wide ranges during the MGT start-up. Especially, NOx emissioin level was increased up to 20.01 ppmv. Different tendencies of $O_2$, $CO_2$, CO and NOx concentrations were observed with MGT output changes. $O_2$ and CO concentrations were shown to be decreased and NOx and $CO_2$ concentrations were shown to have opposite trends. NOx emission level (0.8~1.88 ppmv) was very low compared to other types of combustion based power generation equipment. Unburned hydrocarbon emission level was substantially decreased with MGT load increase. Especially, $C_2H_4$ concentration was below the detection limit(0.2 ppmv) around the nominal load condition. The exhaust gas from landfill gas fuelled MGT system was shown to be feasible for $CO_2$ fertilization. Concentrations of major components were within or below the maximum allowable ranges.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.2
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• pp.211-216
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• 2012

The availability of thermal energy has been widely recognized recently, and the cascade usage of thermal energy from combustion has been encouraged. Within this framework, a 1-kW-class Stirling-engine.based cogeneration system has been proposed as a unit of a distributed energy system. The capacity has been designed to be adequate for domestic usage, which requires high compactness as well as low emissions and noise. To develop a highly efficient system satisfying these requirements, a premixed slot-type short-flame burner has been proposed, and a series of experiments has been performed to understand its combustion characteristics. Flame images have been captured to observe the dependence of the flame mode on the combustion load and air/fuel ratio. The exhaust gas has been sampled and analyzed to study the emission characteristics for each flame mode.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.739-744
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• 2011

Activated carbon SCR(CSCR) catalyst that is used to remove $NO_x$ in exhaust gas including boron discharged from the production process of liquid crystal display(LCD) shows deactivation when boron is deposited to block the pores within the catalyst or to cover its active sites. The spent carbon catalyst is regenerated by washing with various surfactants, drying and calcination. For comparison of the physical and chemical properties before and after the regeneration with the variables, type of surfactants and calcination condition, element analysis by ICP, $N_{2}$ adsorption were conducted. $DeNO_{x}$ in SCR with $NH_3$ was carried out in a fixed bed reactor at $120^{\circ}C$. The activated carbon catalyst regenerated through washing with a non-ionic surfactant in $H_{2}O$ at $90^{\circ}C$ and calcination under $N_{2}$ gas at $550^{\circ}C$ shows similar level of surface area and $NO_x$ removal efficiency with those of fresh catalyst.

• Journal of Soil and Groundwater Environment
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• v.6 no.3
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• pp.43-52
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• 2001

It is important that the gas collected from wells completed in waste landfill should be continuously and stably transported to pre-treatment stage through pipelines. The transport is generally affected by fluid flow characteristics of landfill, gas reserves, leachate moisture holdup in pipeline, structures and dimensions of pipeline network, etc. This paper analyzes the pipeline transport and collection mechanism for gas generated in a durable waste landfill. From the results, the optimal controlled scheme of blower inlet pressure is proposed for the prevention of trapped gas pocket zones.