• Proceedings of the Korea Water Resources Association Conference
• /
• 2017.05a
• /
• pp.119-119
• /
• 2017

기후 온난화로 인하여 빙하의 해빙과 해수의 팽창으로 해수면의 상승 속도는 나날이 증가하고 있다. 우리나라는 2.48mm/yr로 상승하고 있으며, 특히 남해는 2.89mm/yr로 가장 크게 상승하고 있다. 해수면의 상승과 더불어 해수침투 영역 확장을 방지할 수 있는 지하수위 또한 낮아지고 있어 해수침투에 대한 피해를 점차 늘어나고 있다. 해수침투로 인한 피해는 연안지역에서부터 시작하여 점점 영역을 넓혀가고 있다. 해수침투 피해는 직접적으로 토지의 염수화로 지하수의 오염, 농작물의 염수 피해, 주변 생태계의 교란 등으로 나타나고 한 번 염수화가 진행된 지역을 되돌리는 것은 많은 노력과 재화가 들어가게 된다. 이를 방지하기 위해서 많은 연구가 진행되고 있다. 해수침투 범위가 증가하는 것이 해수면의 상승도 큰 영향을 미치지만, 해수침투 쐐기를 구성하는 담수 지하수위가 낮아지면 더욱 가속화된다. 이에 본 연구에서는 남해안의 여수지역을 SEAWAT으로 구성하여, 현재의 상황을 나타내고 지하수위, 해수면, 지하수 이용량, 함양량 등을 대상으로 선형적인 상승 혹은 하강으로 미래의 상황을 나타내었다. 적용된 시나리오에 지하수위 관리 방안을 적용하여 해수침투 영역 저감 효과에 대해서 분석하였다. 지하수위 관리 방안으로는 지하수위 하강 시기에 지하수 이용량 규제, 도심지에서 LID(Low Impact Development) 시설물 중 침투 증진 시설 보강 등을 이용하였으며, 각각의 시나리오를 통해 해수침투 영역 저감 효과 분석을 실시하였다. 지하수위의 관리는 해수침투에 대한 피해 방지와 더불어 지속가능한 지하수 이용을 위한 정책을 마련하기 위한 기초자료로 활용할 수 있을 것으로 보여진다.

• Journal of the Korean Chemical Society
• /
• v.52 no.2
• /
• pp.124-132
• /
• 2008

effect of some furfural hydrazone derivatives (I -V) as corrosion inhibitors for C-steel in 3M H3PO4 solution in which M indicates mol/l has been studied using weight-loss and galvanostatic polarization techniques. A significant decrease in the corrosion rate of C-steel was observed in the presence of the investigated compounds. This study revealed that, the inhibition efficiency increases with increasing the inhibitor concentration, and the addition of iodide and thiocynate ions enhances it to a considerable extent. The effect of temperature on the corrosion behavior of C-steel was studied in the range from 30-60oC with and without 510-6 M investigated compounds using weight-loss method. Apparent activation corrosion energy (Ea*) and other thermodynamic parameters for the corrosion process were calculated and discussed. The polarization measurements show that the investigated compounds act as mixed-type inhibitors, but the cathode is more polarized when an external current was applied. The adsorption of these compounds on the surface of C-steel in 3M H3PO4 obeys Frumkins adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the investigated compounds.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2011.05a
• /
• pp.32.2-32.2
• /
• 2011

반도체 생산공정에서 CMP (Chemical-mechanical planarization) 공정은 우수한 전기전도성 재료인 Cu의 사용과 다층구조의 소자를 형성하기 위해서 도입되었으며, 최근 소자의 집적도가 증가함에 따라 CMP 공정 비중은 점점 높아지고 있다. Cu CMP 공정에서 연마제인 슬러리는 금속 표면과의 물리적 화학적 반응을 동시에 사용하여 표면을 연마하게 되며, 연마특성을 향상시키기 위해 산화제, 부식방지제, 분산제 및 다양한 계면활성제가 첨가된다. 하지만 슬러리는 Cu 표면을 평탄화하는 동시에 오염입자, 유기오염물, 스크레치, 표면부식 등을 발생시키며 결과적으로 소자의 결함을 야기시킨다. 특히 부식방지제로 사용되는 BTA (Benzotriazole)은 Cu CMP 공정 중 Cu-BTA 형태로 표면에 흡착되어 오염원으로 작용하며 입자오염을 증가시시고 건조공정에서 물반점 등의 표면 결함을 발생시킨다. 이러한 문제점을 해결하기 위해 Cu 표면에서 식각과 부식반응을 최소화하며, 오염입자 제거 및 유기오염물을 효과적으로 제거하기 위한 Post-CMP 세정 공정과 세정액 개발이 요구된다. 본 연구에서는 오염입자 및 유기물 제거와 동시에 표면 거칠기와 부식현상을 제어할 수 있는 post Cu CMP 세정액을 개발 평가하였다. 오염입자 및 유기오염물을 제거하기 위해서 염기성 용액인 TMAH 사용하였으며, Cu 이온을 용해할 수 있는 Chelating agent와 표면 부식을 억제하는 부식 방지제를 사용하여 세정액을 합성하였다. 접촉각 측정과 FESEM(field Emission Scanning Electron Microscope) 분석을 통하여 CMP 공정에서 발생하는 유기오염물과 오염입자의 흡착과 제거를 확인하였으며 Cu 웨이퍼 세정 전후의 표면 거칠기의 변화와 식각량을 AFM(Atomic Force Microscope)과 4-point probe를 사용하여 각각 평가하였다. 또한 세정액 내에서의 연마입자의 zeta-potential을 측정 및 조절하여 세정력을 향상시켰다. 개발된 세정액과 Cu 표면에서의 화학반응 및 부식방지력은 potentiostat를 이용한 전기화학 분석법을 통해서 chelating agent와 부식방지제의 농도를 최적화 시켰다. 개발된 세정액을 적용함으로써 Cu-BTA 형태의 유기오염물과 오염입자들이 효과적으로 제거됨을 확인하였다.

• Journal of the Korea Institute of Building Construction
• /
• v.16 no.5
• /
• pp.397-403
• /
• 2016

As a building energy saving standard strengthened, The number of building installed external thermal insulation composite system(ETICS) using EPS insulation increased. But frequent fire accident in the buildings installed EIFS using EPS led to strengthening of building fire safety regulation. This study is for fire property of EPS ETICS reinforced with noncombustible calcium silicate-based mineral insulation as a fire spread prevention structure(FSPS). Fire test for large scale wall by ISO 13785-2 was applied and results showed EPS EIFS with FSPS got 3~8 times superior fire safety than normal EIFS by visual investigation. Temperature and heat flux measurement results, which data of upside of specimen were lower than downside, also supported fire safety of EIFS with FSPS.

• The Journal of Engineering Geology
• /
• v.32 no.4
• /
• pp.499-511
• /
• 2022

In this study, a vertical drop test was carried out to identify the performance of flexible wire rope rockfall protection fence by 100 kJ rockfall energy according to ETAG 027. The flexible wire rope, which consists of wire rope and spring. is especially enhanced the elasticity and flexibility so that it can be longer elongated when the rope is impacted by rockfall compared to original wire rope, and that results longer increase of contact time between rockfall and wire rope and increase rockfall energy absorption capability and decreases rockfall impact force. The test results shows that the plastic deformation occurred in middle post and the final deflection of the middle post was 1.15 m, which is lower than 2.0 m determined by ETAG 027. This vertical test verified the flexible wire rope rockfall protection fence can successfully absorb 102.9 kJ rockfall energy.

• Korean Journal of Food Science and Technology
• /
• v.48 no.6
• /
• pp.574-581
• /
• 2016

Glasswort (Salicornia herbacea L.) is an edible halophyte that grows in salt marshes. In the present study, anti- and pro-oxidant activities and cytotoxic properties of glasswort were investigated. Solvent fractions, including fractions of hexane, ethylether (Fr.E), ethylacetate (Fr.EA), butanol and water, were prepared from a 70% methanol extract of glasswort aerial parts. Fr.EA contained the highest levels of total polyphenols and flavonoids, showing the strongest scavenging activities against DPPH and ABTS radicals, and nitrite. In addition Fr.EA showed the most potent cytotoxic effects on HCT-116 colon cancer cells and INT-407 normal intestinal cells, followed by Fr.E. Most fractions also decreased the level of reactive oxygen species in the treated cells, but generated $H_2O_2$ in the medium. The cytotoxic activity of Fr.EA was more pronounced in the presence of ascorbic acid or N-acetylcysteine. These results indicate that the fractions from aerial parts of glasswort exhibit both anti- and pro-oxidant activities, and these activities modulate cytotoxic properties.

• KSBB Journal
• /
• v.28 no.5
• /
• pp.287-294
• /
• 2013

Stained and discolored hair will be damaged by the shampooing, daily UV disposal, and the use of hair dryer. Thus many studies about the effect of various natural substances on the re-secure the skin and scalp are recently reported. This study was carried out to investigate the effect of green tea (Camelloia sinensis) seed oil on colored (dyed) and decolored (bleached) hair. The beneficial effects of green tea seed oil are already well known, but little research has been done about the hair treatment and fade-resistant effect. Dyed and bleached hair was pretreated with green tea seed oil to determine the tensile strength and elongation of the hair, to analyze the hair surface using SEM, and to compare the color fade using spectrocolormeter. The results showed that the tensile strength increased with green tea seed oil pretreatment samples for virgin, dyed, and bleached hairs. Elongation showed the reverse results showing the presence of hair treatment effect. The results of the surface pre-treatment in all groups analyzed by SEM, the hair cuticle became sharper, so coating effect were identified with all samples. The value of the $L^*$, $a^*$, $b^*$ decreased with washed hairs damaged by UV irradiation and the values were decreased also in dyed and bleached hair. In summary, green tea seed oil prevent reinjury to the heat and UV rays for colored and decolored hairs. Cosmetic practice effects of the oil were identified in the field to be appropriate to the customer's skin and scalp that natural cosmetic oils would like to offer.

• Korean Journal of Food Science and Technology
• /
• v.48 no.6
• /
• pp.610-617
• /
• 2016

Melatonin, known as a powerful wide-spectrum antioxidant, is consumed as a food supplement in some countries, but its applicability as an antioxidant additive was not yet studied. Therefore, we evaluated the antioxidant activity of melatonin by DPPH, ABTS, FRAP and ORAC assays as well as its ability to inhibit perilla oil oxidation. The activities of four other related indoles were also compared. Melatonin showed the highest antioxidant activity (mmol trolox equivalent per mol indole, mmol TE) in ORAC (2,159) assay, but a low antioxidant activity in DPPH (0.63), ABTS (91), and FRAP (764) assays, whereas serotonin showed an opposite result. Addition of 1% (w/w) melatonin to perilla oil extended the induction period of oxidation up to about 2 times ($2.93{\pm}0.47h$) compared to that of control ($1.43{\pm}0.26h$) in the Rancimat assay, corresponding to almost 50% of the ability of butylated hydroxyl toluene (BHT). Tryptamine was the most effective indole that inhibited perilla oil oxidation ($9.53{\pm}1.43h$).

• Korean Journal of Food Science and Technology
• /
• v.29 no.2
• /
• pp.379-382
• /
• 1997

The effects of different concentrations of ${\alpha}-tocopherol,\;{\delta}-tocopherol$, BHA, BHT and TBHQ on the oxidative stability of perilla oils undergoing autoxidation during storage at $50^{\circ}C$ were studied. ${\alpha}-\;and,\;{\delta}-tocopherols$ were added as concentrations of 100, 200, 300 and 400 ppm to the perilla oils from the unroasted seeds or the roasted seeds at $190^{\circ}C$ for 20 min. BHA, BHT and TBHQ were also added to the perilla oils described above as concentrations of 50, 100, 150 and 200 ppm, respectively. The oxidative stability of perilla oils was estimated by the antioxidative index (AI: the induction periods of oils with antioxidants/the induction periods of oils without antioxidants) on the basis of the peroxide values. The roasted perilla seed oil was more stable than the unroasted seed oil in autoxidation. The addition of ${\alpha}-\;and,\;{\delta}-tocopherols$ accelerated the autoxidation of perilla oils. BHA did not show antioxidant effects, but BHT showed very weak antioxidant effects. The autoxidation of perilla oils, however, was effectively prevented by the addition of TBHQ. TBHQ showed activity in preventing 5 times on the autoxidation of perilla oils. Therefore, the oxidation stability of perilla oils seemed to be depend both on the roasting process and the kind of antioxidants.

• Korean Journal of Food Science and Technology
• /
• v.17 no.2
• /
• pp.55-59
• /
• 1985

Antioxidant activity of gingerol, a component of ginger, was studied in ${\beta}-carotene-linoleic$ acid-water emulsion system. Crude gingerol extracted from ginger was separated and purified by thin-layer chromatography (TLC) into two bands. The two bands were identified as 6- and 10-gingerol by color reactions on TLC plate, acid dehydration reaction, infrared and nuclear magnetic resonance spectrometry. The antioxidant activity of gingerols (mixture of 6- and 10-gingerol) separated from ginger was remarkable, but lower than that of BHA or BHT.