• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.798-803
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• 2018

In order to use Si as an anode material for lithium-ion battery, the particle size was controlled to less than $0.5{\mu}m$ and carbon was coated on the surface with the thickness less than 10 nm. The carbon fiber was grown on the Si surface with 50~150 wt%, and the carbon coating was carried out once again. The Si composite material was mixed with dissimilar metals to increase the conductivity, and graphite was mixed to improve cyclic life characteristics. The physical and electrochemical characteristics of composite materials were measured with XRD, SEM, TEM and coin cell. The discharge capacity of Si/PC/CNF/PC was lower than that of Si/PC (Pyrolytic Carbon)/CNF (Carbon Nano Fiber). However, the cyclic life of Si/PC/CNF/PC was higher. Initial discharge capacity of 1512 mA h g-1 at 0.2 C rate and initial efficiency of 78% were shown. It also showed a capacity retention of 94% in 10 cycles.

• Korean Chemical Engineering Research
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• v.43 no.3
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• pp.425-431
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• 2005

New type of supercapacitor using high surface area activated carbons mixed with high conductivity polypyrrole (Ppy) has been prepared in order to achieve low impedance and high energy density. Mixed carbons of BP-20 and MSP-20 were used as the active electrode material, and polypyrrole doped with 2-naphthalenesulfonic acid (2-NSA) and carbon black (Super P) as conducting agents were added to activated carbons in order to enhance good electric conductivity. Electrodes prepared with the activated electrode materials and the conducting agents were added to a solution of organic binder [P(VdF-co-HFP) / NMP]. The ratio of optimum electrode composition was 78 : 17 : 5 wt.％ of (MSP20 : BP-20=1 : 1), (Super P : Ppy=10 : 7) and P(VdF-co-HFP) respectively. The performance of unit cell with addition of 7 wt％ Ppy have shown specific capacitance of 28.02 F/g, DC-ESR of $1.34{\Omega}$, AC-ESR of $0.36{\Omega}$, specific energy of 19.87 Wh/kg and specific power of 9.77 kW/kg. With addition of Ppy, quick charge-discharge of unit cell was possible because of low ESR, low charge transfer resistance and quick reaction rate. And good stability up to 500 chargedischarge cycles were retained about 80％ of their original capacity. It was concluded that the specific capacitance originated highly from compound phenomena of the pseudocapacitance by oxidation-reduction of polypyrrole and the nonfaradaic capacitance by adsorption-desorption of activated carbons.

• Journal of the Korean Electrochemical Society
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• v.2 no.2
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• pp.81-87
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• 1999

Poly-acrylonitrile (PAN) based carbon fibers were stabilized under various tensions in the presence of air at about $200^{\circ}C$ and sequentially carbonized under some different gas environments in the range of 700 to $1500^{\circ}C$. The prepared carbon fibers were used for rechargeable lithium ion battery anode to investigate preparation parameters effects on electrochemical characteristics. It was found that the tension during stabilization, carbonization temperature and gas atmospheres affect the carbon fiber properties such as conductivity, mechanical strength, surface morphology and diffusion coefficient of lithium ion, which are closely related to the on electrolchemical properties as well as the charge/discharge characteristics.

• Clean Technology
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• v.20 no.4
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• pp.433-438
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• 2014

There is an increasing interest in the development of rechargeable batteries suitable for use in both hybrid electric vehicles and energy storage systems that require higher charge & discharge rates, bigger battery sizes and increased safety of the batteries. Spinel-type lithium titanium oxide ($Li_4Ti_5O_{12}$) as a potential anode for lithium ion batteries has many advantages. It is a zero-strain materials and it experiences no structural change during the charge/discharge precess. Thus, it has long cycle life due to its structural integrity. It also offers a stable operation voltage of approximately 1.55 V versus $Li^+/Li$, above the reduction potential of most organic electrolyte. In this study, Ru added $Li_4Ti_5O_{12}$ composites were synthesized by solid state process. The characteristics of active material were investigated with TGA-DTA, XRD, SEM and charge/discharge test. The capacity was reduced when Ru was added, however, the polarization decreased. The capacity rate of $Li_4Ti_5O_{12}$ with Ru (3%, 4%) addition was reduced during the charge/discharge precess with 10 C-rate as a high current density.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.196.2-196.2
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• 2012

본 논문은 달착륙선의 개념설계를 위하여 고려한 전력시스템의 설계와 달착륙선의 지상시험모델용 추력기 밸브구동 전원장치 개발에 대해 기술하였다. 달착륙선의 임무특성을 고려하여 전력시스템의 구조를 검토하고, 극한의 온도환경에서 달착륙선의 임무수행을 위하여 필요한 전력에너지를 충분히 공급할 수 있도록 태양전지 배열기와 배터리의 용량, 그리고 전장품의 용량을 설계하였다. 특히 경량의 달착륙선 개발을 위하여 고효율의 태양전지를 이용한 태양전지 배열기와 리튬-이온 배터리를 검토하였다. 극한의 우주환경에서 태양전지배열기의 동작특성을 검토하고 생성될 수 있는 최대 전력을 분석하여 최적의 태양전지 배열기의 면적을 분석하고, 장시간의 월식을 고려하여 배터리의 방전특성에 따른 배터리의 전압특성을 검토하였다. 그리고 달착륙선의 전력시스템 개념설계의 타당성 검토를 위하여 유럽에서 개념설계 중인 달착륙선의 전력시스템 사양과 용량에 대해 비교검토를 수행하였다. 현재 개발중인 지상검증모델용 달착륙선의 전력시스템 설계와 추력기 밸브구동 전원장치의 개발에 관해 기술하였다. 지상검증용 전력시스템은 태양전지배열기의 장착 없이 배터리의 전력만을 사용하여 지상검증모델용 달착륙선의 부하에 전력을 공급할 수 있도록 설계되었다. 달착륙선 지상시험모델의 비행시간과 임무에 따른 부하특성을 고려하여 상용 리튬-이온 배터리의 용량을 선정하였으며, 부하의 전력을 고려하여 간단한 보호회로를 설계하였다. 그리고 지상검증용 전원시스템은 추력기의 밸브구동을 위한 추력기 밸브구동 전원장치, DC/DC 컨버터 전원 모듈, 모니터링 모듈, 그리고 위급상황에서 전원을 차단하기 위한 "Emergency STOP" 모듈로 구성되어 있다.

• Journal of Sensor Science and Technology
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• v.5 no.6
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• pp.35-42
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• 1996

In this paper, a development of model based battery SOC indicator is described. The proposed method is independent upon initial SOC, is reliable on the sudden change of load, and could estimate the available driving distance. The mathematical model of battery which has relation of the current, voltage and SOC estimates the SOC by least square estimation to minimize the error between measured voltage and estimated voltage. For experiment, the charging and discharging system using computer was designed to acquire the current and voltage data for model. The feasibility in electric vehicle was confirmed by variable load testing using the developed SOC indicator by stand-alone type microcontroller.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.7 no.6
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• pp.34-41
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• 1993

This paper describes an effort to develop a microcomputer-based parameter identification system for three phase and two phase brushless DC motor. Back EMF equation is derived from back EMF waveform of three phase and two phase brushless DC motor. In this paper, a new identification algorithm for the brushless DC motor parameters by Pasek's technique is de veloped. It is found that Pasek's equation is valid for the brushless DC motor, too. The results obtained clearly shows that it is possible to implement the identification system for the determination of the brushless DC motor parameters. To minimize errors due to the ripple component in the measured armature current, dlgital averaging filter is employed. The whole identification process of signal generation, measuring, parameter determination is fully automated. The use of the pmpased method in the parameter identification system shows that the averaged current curve is in excellent agreement with the estimated current curve. Therefore, this close agreement conf i i the validity of this technique.

• Proceedings of the KIPE Conference
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• 2013.11a
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• pp.35-36
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• 2013

본 논문은 EV(Electric Vehicle)에 사용되는 배터리의 충/방전 전류에 따른 SOC(State of Charge) 및 전압특성을 Matlab Simulink로 구현하였으며, 검증을 위해 양방향 DC-DC 컨버터를 설계하여 실험을 하였다. 배터리 모델에 사용된 파라미터는 Randles등가회로를 기반으로 펄스방전을 통해 추출하였고, 단자전압 계산부에 3D Look-up 테이블을 이용해 적용하였다. SOC계산부는 전류에 따른 용량변화를 보상하기 위해 Peukert Effect를 적용하였으며, FTP-75 전류패턴으로 온도($0^{\circ}C$, $25^{\circ}C$, $40^{\circ}C$)에 따라 실험한 결과 시뮬레이션의 오차율은 5%로 높은 정확도를 갖는 것을 확인을 통해 검증 하였다.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.4
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• pp.52-59
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• 2005

When a micro hole is machined by EDM with a cylindrical electrode, the hole diameter is different at the inlet and the outlet of the micro hole. The taper shape of the micro hole is caused by not only wear of the electrode but the eroded particles. The eroded particles cause secondary discharge during machining the micro hole. As a result, the diameter of the inlet becomes larger than that of the outlet. In this paper, a new method is proposed to reduce the difference in diameter between the inlet and the outlet of the hole. Observed was that the feed depth and machining time affect the formation of taper shape On this experimental basis, ultrasonic vibration was applied to reduce machining time, and capacitance was changed during machining to use the difference in discharging energy of different capacitances. Using the proposed method, a straight micro-hole was fabricated.

• Journal of the Korean Ceramic Society
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• v.38 no.8
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• pp.755-760
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• 2001

본 연구에서는 카본전극의 표면개질에 따른 리튬이온 전지의 전지특성 변화에 대해서 연구하였다. 즉, mesocarbon microbeads(MCMB) 카본에 에폭시 수지(resin)를 코팅시킴으로서 카본전극 표면에 개질시켰으며, 이에 따른 전극의 전기화학적 특성을 고찰하였다. 에폭시 수지에 의한 카본의 표면코팅은 30%의 H$_2$SO$_4$용액에서 2시간 동안 refluxing한 MCMB를 에폭시 수지를 용해시킨 THF(tetrahydrofuran) 용액에 넣어 혼합함으로써 MCMB 표면에 에폭시 수지가 코팅되도록 하였다. 이렇게 에폭시 수지가 코팅된 MCMB를 약 1000-130$0^{\circ}C$로 열처리하여 고분해능 투과전자현미경으로 관찰한 결과, 코팅층은 비정질 카본 구조를 갖게됨을 알 수 있었다. 또한, 에폭시 수지에 의하여 코팅된 MCMB는 코팅되지 않은 MCMB보다 더 높은 BET 비표면적을 나타내었다. Li/MCMB 전지 cell을 만들어 충방전시험을 수행한 결과, 에폭시 수지에 의하여 코팅된 MCMB로 만든 전극이 더 우수한 충방전 용량과 싸이클 특성을 나타내었다. 에폭시 수지 코팅으로 전극 표면을 개질시킴으로서 전지특성이 개선된 원인에 관하여 에폭시 코팅의 결정구조와 전극계면에서의 부동태 피막(passivation film) 형성과 연계하여 논의하였다.