• 한국문화재보존과학회:학술대회논문집
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• 2001.11a
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• pp.27-34
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• 2001

Following the recommendations made by the cultural authorities the wooden cultural properties (WCP) had been treated with fire-retardants for fire protection. However, visual inspections of some of the WCPs treated with fire-retardants showed microbial decay. The work was extended to examine the micromorphological characteristics of the WCPs in a Buddhist temple which had been treated with fire-retardant. Microscopic examination showed the presence of typical soft rot cavities along the length of microfibrils in the secondary wall. Bacterial attack was also observed by scanning and transmission electron microscopy. It is interesting that the decay patterns observed in the Buddhist temple were very similar to those observed in the waterlogged woods. Presumably chemicals in the fire-retardants used rendered the wood susceptible to attack by soft-rot and bacterial decay by causing an increase in the moisture content of wood. Further studies are needed to investigate the effect of fire-retardants used currently on the hygroscopicity and the strength of wood materials in the WCPs. Microbial attacks caused degradation of the secondary cell walls and in some cases also of the middle lamella. In addition, the cell walls in the outer parts of wood were also degraded due to weathering, and cell separation occurred from total disintegration of the middle lamella.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.52-52
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• 2012

Poly(phenylene sulfide)(PPS)는 내열성 및 내화학성이 뛰어난 고분자 소재로, 대표적인 엔지니어링 플라스틱 중 하나이다. PPS는 벤젠 링에 황원자가 파라 치환 형태로 교대로 존재하는 결정성 고분자이며, 다른 대부분의 고성능 섬유고분자가 용융되지 않는 것과는 달리 용융되는 열가소성 소재이다. PPS는 높은 내약품성과 열에 대한 장기적인 안정성을 나타내고, 방염제 첨가 없이도 방염화가 가능하며, 전기 절연성이 뛰어나고, 형태안정성도 우수하다. 또한 $200^{\circ}C$ 이하에서는 어떤 용매에도 용해되지 않으며, $200^{\circ}C$ 이상에서도 몇 가지 방향족 화합물에만 제한된 범위 내에서 용해되는 우수한 내약품성을 나타낸다. PPS의 내열성을 더욱 우수하게 하기 위해 고분자 사슬을 가교할 수 있다. 가교에는 열처리 또는 감마선, 전자선, 자외선 조사를 이용할 수 있는데 열에 의한 가교는 균일한 열전달과 고온이 필요하며 감마선 및 전자선 조사는 설비의 고비용과 방사선 노출 위험으로 인해 비친환경적이다. 반면에 자외선 조사법은 다루기 쉽고 비용이 적게 들고 친환경적인 장점을 가진다. 본 연구에서는 PPS film의 열안정성을 향상시키기 위해 자외선 조사를 이용하여 PPS film의 광가교를 수행하였다.

• Journal of the Korean Applied Science and Technology
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• v.11 no.1
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• pp.45-52
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• 1994

For the purpose of producing emulsified fire proofing agent for synthetic fibers, 2,3-dibromopropylmonoamido orthophosphate[DP-AOP] and bis(2,3-dibromopropyl)monoamidoorthophosphate[$(DP)_{2}AOP$] were synthesized, and their structures were identified by instrumental analysis, respectively. Using three kinds of emulsifiers, O/W emulsified fire proofing agents, DPF and DPDPF, were obtained corresponding to DP-AOP and $(DP)_{2}-AOP$, respectively. Various synthetic textiles were fire-retardant treated by prepared DPF and DPDPF, and fire retardancy and tearing strength of the resulting products were tested. The results showed that as the concentration of fire proofing agents increased, fire retardancy increased, but the tearing strength much decreased, where the tendencies of DPDPF were deeper than those of DPF. But, since the fire retardancy appeared favorable in the range of $10{\sim}20wt%$ of DPDPF, DPDPF is proven to be a fire proofing agent useful for various synthetic textiles.

• Journal of the Korean Society of Clothing and Textiles
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• v.29 no.9_10 s.146
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• pp.1274-1284
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• 2005

Effect of fixation methods and relaxation treatment on the dimensional stability and physical properties of MDPPA/HMM treated cotton knitted fabrics were studied. Combination of four different fixation methods - relaxation, swelling agent treatment, pad dry cure fixation, and wet fixation - were applied to flame retardant finish of 4 kinds of cotton knitted fabric with MDPPA/HMM. Then these fabrics were washed 10 times. As a result, In swelling treatment on 10G showed relatively higher value of length shrinkage than 14G. Length and width shrinkage were increased by initial washing treatment and no further change was shown after 6 washing cycles. After 10 washing cycles, length and width shrinkage decreased. The KES standardized basic value of B/W, 2HB/W and bursting strength of interlock were relatively larger than those of single jersey. The values of B/W and 2HB/W of cotton knitted fabrics were increased by relaxation and washing treatment but were decreased by swelling treatment. In addition, the bursting strength of the cotton knitted fabrics was decreased after fusing, washing and relaxation treatment.

• Proceedings of the KAIS Fall Conference
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• 2008.05a
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• pp.336-338
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• 2008

본 연구에서는 EU에서 발효되는 6대 규제유해물질(Pb, Hg, Cd, $C^{6+}$, PBB/PBDE)과 환경부 규제유해물질에 의해 도료의 유해조성물질을 제한하게 됨에 따라 VOC(휘발성유기화합물) 배출이 적고, 브롬계/할로겐계를 탈피하여 인체안전성 확보 및 환경오염을 최소화하며, 방염제 형식승인 및 검정기술기준 (KOFEIS 0201)에 부합하는 수용성 유 무기계 난연도료를 개발하였다. 친환경적인 난연도료 제조에 대한 최적조건으로 Mg(OH)$_2$, $Sb_2O_3$, 붕산아연을 1:2:2로 혼합한 난연제 그리고 바인더(마이셸 2%)와 물의 비율을 1:1로 제조한 후, 난연제:(바인더+물)을 1:1로 제조한 난연도료 3의 성능이 가장 우수하였다.

• Applied Biological Chemistry
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• v.47 no.3
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• pp.325-331
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• 2004

In order to study the effect of formulation type on the burning characteristics of smoke generator, fenarimol smoke generators containing the powdered rice chaff as a combustible carrier were prepared by molding the kneaded mixtures into various shapes. Smoke generators containing wood flour as a combustible carrier were also prepared and compared with smoke generators containing rice chaff. All the fenarimol smoke generators moulded into powders, granules, and rods continuously burned out when the sodium chlorate content exceeded 11%. Regardless of their types, the highest smoking rate of fenarimol was observed with more than 13% of sodium chlorate. The smoking rate of active ingredient followed with the increasing order of powder (64.5%) < granule (78.4%) < rod (90.9%). The smoke rod was robust, easy to ignite, and showed the highest smoking rate among the tested formulations. When the mixture of wood flour and anti-flame agent was used as a combustible carrier, the burning rate was so slow that wood flour formulation seemed to be more suitable to a slow-burning fumigant rather than smoke generator.

• Journal of the Korean Wood Science and Technology
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• v.48 no.4
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• pp.417-430
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• 2020

The flame retardancy, such as carbonized length and area, of four plank type wood products by the spreading concentration and impregnation time of flame retardant were measured according to standard of the Nation Fire Agency in Republic of Korea. To measure the flame retardancy, Korean pine plywood, Japanese larch plywood, Japanese cypress planks, and perforated birch plywood boards were treated with self-development flame retardant by 300 and 500 g/㎡ spreading concentration and those were compared with control specimen. In general, the flame retardant performance of wood products improved as the spreading concentration of flame retardant increased. Except for Japanese larch plywood, there was no significant difference in the flame retardant performance by the spreading concentration. The flame retardant performance of perforated birch plywood board was positively correlated up to 60 minutes of impregnation time, but then gradually decreased. These results about the flame retardancy of wood products by spreading concentration and impregnation time were expected to be basic data for improving flame-retardant treated wood.

• Fire Science and Engineering
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• v.31 no.4
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• pp.12-19
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• 2017

The present paper is a study on the performance characteristics of organic-inorganic hybrid flame retardants. MDF plywood has been used, that are being used for the interior decoration of building structures, to make the samples for experiment according to the existing or non-existing treatment of organic-inorganic hybrid flame resistants. Later, the experiment on the measurement of flame retardant performance using a $45^{\circ}$ flammability tester and the experiment on the measurement of combustion characteristic using a cone calorimeter have been proceeded to confirm the performance characteristic of organic-inorganic hybrid flame retardants. From the result of experiments, it has been confirmed that both organic-inorganic hybrid flame retardants have merits of inorganic and organic substances, and that heat resistance, durability and adhesiveness have been largely improved. The performance on the flame retardant has also appeared with excellent effect such as the reduced generation of combustion gas and the decreased generation of smoke.

• Journal of the Korean Wood Science and Technology
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• v.44 no.5
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• pp.785-808
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• 2016

The objective of this study was to investigate the effect of the short-term weathering on the flame retardant performance of wood coated with Dancheong. Flame retardants were applied on the Dancheong coated Korean red pine. Flame retardants applied panels were layed at the two conditions of outdoor exposure and artificial aging to assess the reliability of artificial aging. Flame retardants used were commercial products developed for historical wooden buildings. Scanning electron micrographs revealed the forming of carbonized membrane by melting of flame retardant on wood surface. These carbonized membranes may help delay the further combustion of wood. Flame retardant performance was assessed by measuring heat release rate (HRR) and total heat release (THR) by cone calorimetry. There was no difference in flame retardant performance between before and after 6-month outdoor exposure tests. And also no difference in flame retardant performance between before and after 2-week artificial aging which corresponds to 6-month outdoor exposure. Both tests showed the similar results of combustion characteristics.

• Fire Science and Engineering
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• v.30 no.4
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• pp.65-72
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• 2016

This study examined the generation of combustion toxic gases of pinus rigida specimens processed with bis-(dimethylaminomethyl) phosphinic acid (DMDAP), bis-(diethylaminomethyl) phosphinic acid (DEDAP), and bis-(dibutylaminomethyl) phosphinic acid (DBDAP). Each pinus rigida plate was coated three times with 15 wt.% flame retardants in an aqueous solution. The specimens were then dried at room temperature. The production of combustion toxic gases was investigated using a cone calorimeter (ISO 5660-1). The first time to peak mass loss rate ($1^{st}-TMLR_{peak}$) processed with the chemical additives decreased to 5.9 from 41.2% compared with the unprocessed specimen. The second time to the peak mass loss rate ($2^{nd}-TMLR_{peak}$) for the processed specimens was decreased 1.8% for DMDAP and 5.3% for DBDAP and increased 1.8% for DEDAP. The peak carbon monoxide ($CO_{peak}$) production was 1.5 to 2.0 times higher than that of the unprocessed plate. The peak carbon dioxide ($CO_{2peak}$) production was reduced 0.01 times for DMDAP and increased 1.15 to 1.19 times for DEDAP and DBDAP compared with the unprocessed specimens. In particular, the oxygen concentration was much higher than 15%, which can be fatal to humans and the resulting hazard can be eliminated. Overall, the combustion toxicity of flammable gas were increased partially by the chemical additives compared with those of the unprocessed plate.