• Title/Summary/Keyword: 발광곡선

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The Measurement and Analysis of LiF:Mg, Cu, Na, Si TL Material by Thermoluminescence Spectrum (LiF:Mg, Cu, Na, Si TL 물질의 열자극발광스펙트럼 측정 및 분석)

  • Lee, J.I.;Moon, J.H.;Kim, D.H.
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.1
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    • pp.149-153
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    • 2001
  • Three-dimensional thermoluminescence(TL) spectra of LiF: Mg, Cu, Na, Si TL material based on temperature, wavelength and intensity were measured and analyzed. The glow curves were obtained by integration of luminescence intensity for wavelength at each temperature, and various trapping parameters related to the trap formation were determined by analyzing these curves. Computerized glow curve deconvolution(CGCD) method which based on general order kinetics(GOK) model were used for the glow curve analysis. The glow curves of LiF:Mg, Cu, Na, Si TL material were deconvoluted to six isolated glow curves which have peak temperature at 333 K, 374 K, 426 K, 466 K, 483 K and 516 K, respectively. The 466 K main glow peak had an activation energy of 2.06 eV and a kinetic order of 1.05. This TL material was also found to have three recombination centers, 1.80 eV, 2.88 eV and 3.27 eV by TL spectra analysis based on Franck-Condon model. It showed that 2.88 eV is the dominant center, followed by 3.27 eV level, and 1.80 eV center is ascertained as emission center of this material even though its very weak emission intensity.

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A Measurement and Analysis of Thermoluminescence Spectra of LaAlO3 (LaAlO3에 대한 열자극발광 스펙트럼의 광학적 분석)

  • Lee, J.I.;Moon, J.H.;Kim, D.H.
    • Journal of Korean Ophthalmic Optics Society
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    • v.4 no.2
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    • pp.141-146
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    • 1999
  • We measured and analyzed thermoluminescence spectra of $LaAlO_3$, single crystal by 3 dimensional data for temperature, wavelength and luminescence intensity. $LaAlO_3$, has used as the substrates of YBCO(superconductor) or semiconductors. We could determined the energy of recombination center, that is impossible through analysis of glow curve data. We could obtained the energy through analysis of the spectrum data at peak temperature by Franck-Condon model. The total glow curve was deconvoluted to three glow curves by curve fitting method. The activation energies were 0.54eV, 0.91eV and 1.02eV respectively. The energies of recombination centers were determined with 2.04eV and 2.75eV from the analysis of luminescence intensity data for wavelength.

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Identification of Bulgogi Sauce Added with Low Quantity of Electron Beam-Irradiated Garlic Powders by Thermoluminescence Analysis: An Inter-Laboratory Study (전자선 조사 처리한 마늘분말 첨가 불고기소스의 혼합비와 살균처리에 따른 열발광 판별특성: 실험실 교차 검증시험)

  • Ahn, Jae-Jun;Lee, Jeongeun;Baek, Ji-Yeong;Jeong, Il-Yun;Kwon, Joong-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.11
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    • pp.1857-1863
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    • 2013
  • Bulgogi sauces containing electron beam-irradiated garlic powder (1%, 3%, and 5%) were used to compare their irradiation status before and after pasteurization ($85^{\circ}C$, 30 min), using a thermoluminescence (TL) analysis by two different laboratories. The sauces with non-irradiated ingredient only provided a background TL glow curve with a maximum peak after $300^{\circ}C$. However, the presence of irradiated ingredient (1 and 10 kGy) was evident through the typical TL glow curves in a temperature range of 150 to $250^{\circ}C$. The concentration of irradiated ingredients showed a greater impact on identification characteristics than their radiation doses. TL ratios ($TL_1/TL_2$) were not able to confirm the results showing evidence of irradiation through the TL glow curve shapes. Pasteurization showed a negligible effect on the key identification parameters and did not change the shape or temperature range of radiation-specific TL glow peak, but reduced TL glow curve intensity. TL glow curve shape with the maximum peak in a temperature range of $150{\sim}250^{\circ}C$ was the most useful characteristic providing information required for confirming the irradiation status.

Computerized Analysis of Thermoluminescence from ${\gamma}$-Ray Irradiated $\alpha$-$Al_2$$O_3$ (감마선 조사된 $\alpha$-$Al_2$$O_3$의 열자극에 관한 수치해석적인 분석)

  • 김태규;이병용;김성규;박영우;추성실
    • Progress in Medical Physics
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    • v.4 no.2
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    • pp.49-58
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    • 1993
  • The complex glow curves were split into isolated glow curves to be calculated the values of kinetic order, activation energy, escape frequency and density of initial trap from the independent glow curves using the mathematical method of thermally stimulated processes. The minimization of the intensity difference between measured and theoretical glow curve was done by the nonlinear least-square program. The results of the fitted curves were almost equal to the actual values of the parameters. Thermoluminescence from gamma ray irradiated ${\alpha}$-Al$_2$ $O_3$ over the range of 300K to 600K was split into six glow curves. The kinetic order, activation energy and escape frequency of first glow curve were obtained as 1, 1.12eV and 6.79X10$\^$12/sec$\^$-1/, respectively, which were similar to the results of other method. Also the parameters of the second and the third glow curve and so forth were calculated.

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Supralinearity of UV Irradiated Magnesium Aluminum Spinel (자외선 조사된 Magnesium Aluminum Spinel의 Supralinearity)

  • Kim, Tae-Kyu
    • Progress in Medical Physics
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    • v.16 no.4
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    • pp.202-206
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    • 2005
  • Three-dimensional thermoluminescence (TL) spectra from $MgAl_2O_4$ irradiated with UV light were measured over 300${\~}$600 K and 300${\~}$800 nm. The peak positions of TL glow curves were shifted to lower temperature with increasing the exposure time of UV light. The 476 K TL glow curve is due to the second kinetics and its activation energy and escape frequency factor are calculated to be 0.85 eV and $1.92{\times}10^6 sec^{-1}$, respectively The TL spectra were split into 530 nm and 700 nm emission bands which were associated with $V^{2+}$ and $Cr^{2+}$, respectively. The linearity range of 700 nm omission band is smaller than that of 530 nm emission band, but the saturation time of 700 nm emission band is longer than that of 530 nm omission band.

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불순물을 첨가한 호스트 발광층을 가진 청색 유기발광소자의 발광효율 증진

  • Bang, Hyeon-Seong;Chu, Dong-Cheol;Kim, Tae-Hwan;Seo, Ji-Hyeon;Kim, Yeong-Gwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.421-421
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    • 2010
  • 적색과 녹색 유기발광소자 보다 청색 유기발광소자는 상대적으로 발광 효율이 낮고 색 순도가 낮으며 수명이 짧은 이유로 유기발광소자를 이용한 전색 디스플레이 패널 구현에 많은 어려움이 있다. 이 문제를 해결하기 위하여 청색 유기발광 소자의 발광 효율을 향상하기 위한 방법으로 기존의 제작되는 불순물이 첨가된 단일 발광 호스트층을 이용한 유기발광소자와는 다르게 불순물이 첨가된 혼합된 발광 호스트층으로 구성된 발광 기능층을 가진 유기발광소자의 전기적 성질과 광학적 성질에 대한 연구를 하였다. 본 연구에서는 1.3-Bis(carbazol-9-yl)benzene 인광 호스트 유기화합물과 5%의 3-Tert-butyl-9,10-di(naphtha-2-yl)anthracene 형광 호스트 유기화합물을 혼합된 발광 기능층으로 적용하고 8%의 bis(3,5-difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl-l) iridiumIII 인광 불순물을 첨가한 청색 유기발광소자와 5%의 4,4'-Bis[4-(diphenylamino)styryl] biphenyl (BDAVBi) 형광 불순물을 첨가한 청색 유기발광소자를 제작하여 전기적 성질과 광학적 성질을 비교하였다. 형광 불순물인 BDAVBi를 첨가하여 제작된 청색 유기발광소자는 전류밀도 $20\;mA/cm^2$에서 5.78 cd/A의 발광 효율을 구현하였다. 대역폭이 큰 인광 호스트 물질에서 형성된 엑시톤이 효율적으로 대역폭이 상대적으로 작은 형광 호스트로의 에너지 전달이 일어나고 형광 호스트에서 형성된 엑시톤이 대역폭이 더 작은 형광 불순물로의 에너지 전달이 효율적으로 전달 됨을 알 수 있다. 인광 호스트에서 형성된 엑시톤이 중간 과정을 거치지 않고 바로 형광 불순물로의 에너지 전달이 형성되어 주입된 캐리어가 기존의 소자보다 에너지 전달 과정을 거쳐 다수의 엑시톤이 소멸하지 않고 발광에 기여하여 상대적으로 전류가 작게 흐르고 다량의 엑시톤이 외부로 추출되어 효율이 증가하였다. 전계 발광 스펙트럼 분석에서 메인 피크가 467 nm 영역에서 형성되지만 불순물에 의한 부 피크가 491 nm 영역에서 형성되어 시각계 곡선과 중첩되는 영역을 추가로 형성하여 효율이 증가하게 되는 것을 알 수 있었다. 그러므로 불순물이 첨가된 혼합된 호스트 발광층을 적용한 유기발광소자는 높은 발광 효율을 가지는 청색 유기발 광소자 디스플레이 패널 제작 가능성을 제공하고 있다.

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Evaluation of Relative Emission of Image Plate by Using Relative Sensitivity in Computed Radiography System (컴퓨터 방사선영상시스템에서 비감도를 이용한 영상판의 상대적 발광량 평가)

  • Seoung, Youl-Hun
    • The Journal of the Korea Contents Association
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    • v.14 no.11
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    • pp.355-361
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    • 2014
  • The aim of the present study was to evaluate a relative emission of image plate (IP) in computed radiography (CR) system by using relative sensitivity in film/screen methods. The characteristic curve was obtained by using the uniform aluminum 11-step wedge penetrometer. X-ray exposure factors on radiographic digital image were 50 kVp, 10 mAs. We adjusted zero of all parameter of algorithms (MUSICA) so proximate to raw data and applied to 200 of exposure class. Modeling on relative emission of IP are used IP without fading time and IP after 4 hours, 8 hours, 12 hours, 24 hours in the respective storage after X-ray exposure. The results of this study showed that the sensitivity point density at the measuring of relative sensitivity in CR was suited pixel values of the 2000 easy to relatively measure the characteristic curve and when relative sensitivity is decreased, the amount of light emitted from the image signal for generating was also decreased. In conclusion, the proposed method of measurement of relative sensitivity can be utilized to evaluate the quantity of relative emission of IP in CR system.

Monitoring of Commercial Red Pepper Powders for Their Irradiation Status (물리적 확인시험법을 이용한 시판 유통 중인 고춧가루의 방사선 조사여부 판별 모니터링)

  • Jeong, Mi-Seon;Ahn, Jae-Jun;Akram, Kashif;Kim, Gui-Ran;Kim, Hyun-Ku;Kwon, Joong-Ho
    • Korean Journal of Food Science and Technology
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    • v.44 no.6
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    • pp.673-679
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    • 2012
  • Ten commercially available red pepper powders were investigated using photostimulated-luminescence (PSL), thermoluminescence (TL) and electron spin resonance (ESR) analyses to confirm their irradiation status. The application of PSL, TL, and ESR analyses was also confirmed by in-house irradiation. In PSL-based screening, all samples gave negative photon counts (<700 PCs). The PSL calibration dose (1 kGy) showed a low sensitivity of 4 samples, while the others provided reliable screening results. TL glow curves demonstrated maximum peaks after $250^{\circ}C$ for the 6 samples; however 4 samples gave complex TL glow curves with maximum peaks in the range of $185-260^{\circ}C$ (radiation-specific), which could be the effect of an irradiated component in low concentration as the TL ratios of all samples were <0.1. Radiation-specific ESR features were absent in the all commercial samples. Variable irradiation detection properties were found; where the TL analysis showed the possible presence of an irradiated component in 4 samples requiring further monitoring and investigation.