• Title/Summary/Keyword: 반응 조건 최적화

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A Study on the Calcium Ion Extraction for PCC Production (PCC 제조를 위한 칼슘이온 추출 조건에 관한 연구)

  • Lee, Ye-Hwan;Lee, Sang Hyun;Hwang, In-Hyuck;Choi, Sung-Yeol;Lee, Sang Moon;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.43-48
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    • 2018
  • In this study, we performed various extraction condition experiments such as types and concentrations of extractants, amounts of extraction sources, pretreatment processes, to optimize the calcium ion extraction for precipitated calcium carbonate (PCC) production. CaO was used as a calcium extraction source, The extraction amount of calcium ions and the particle size of CaO were determined by ICP and SEM results. As a result, 100% calcium ion was extracted when 2 M hydrochloric acid was used as an extractant, and the optimum amount of the extraction source was 6 g. On the other hand, it was confirmed that the reaction time, reaction temperature, particle milling and heat treatment process had no significant effect on the calcium ion extraction amount.

Preparation of Cadmium-free Buffer Layers for CIGS Solar Cells (CIGS 태양전지용 Cd-Free 버퍼층 제조)

  • Moon, Jee Hyun;Kim, Ji Hyeon;Yoo, In Sang;Park, Sang Joon
    • Applied Chemistry for Engineering
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    • v.25 no.6
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    • pp.577-580
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    • 2014
  • Indium hydroxy sulfide ($In(OH)_xS_y$) as a cadmium (Cd)-free buffer layer for $CuInGaSe_2$ (CIGS) solar cells was prepared by the chemical bath deposition (CBD) and the reaction time was optimized. The band gap energy and transmittance data alongside the thickness results from the direct observation with focused ion beam system (FIB) could be a powerful tool for optimizing the conditions. In addition, X-ray diffractometer (XRD), X-ray photoelectron microscopy (XPS), and scanning electron microscope (SEM) were also employed for the layer characterization. The results indicated that the optimum reaction time for $In(OH)_xS_y$ buffer layer deposition by CBD was 20 min at $70^{\circ}C$ under the conditions employed. At the optimum conditions, the buffer layer thickness was near 57 nm and the band gap energy was 2.7 eV. In addition, it was found that there was no XPS peak shift in between the buffer layers deposited on molybdenum (Mo)/glass and that on CIGS layer.

Carotenoids pigment extraction from a wasted persimmon peel (폐기 감 과피를 이용한 Carotenoids색소의 추출)

  • 오상룡;차원섭;박준희;조영제;홍주헌;이원영
    • Food Science and Preservation
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    • v.8 no.4
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    • pp.456-461
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    • 2001
  • To develop the use of natural pigment for food, carotenoids from wasted persimmon peel were extracted with seven organic solvents. Among the solvents, acetone was a high yielding solvent of carotenoids. Extraction trends depending on process variables(temperature, time, solvent ratio to persimmon peel) were explained through response surface which was made by central composite experimental design. Carotenoid contents were increased with the extraction time and solvent ratio but it decreaed in the higher experimental design. Carotenoid contents were increased with the extraction time and solvent ratio but it decreased in the higher extraction temperature. The optimum conditions of extraction process variables were predicted as 29$\^{C}$, 93min. at fixed solvent ratio(1:27).

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Recovery and Characterization of Lactic Acid from Fermentation Broth Using Chemical Precipitation (화학침전을 이용한 발효액의 젖산 회수 및 유기물 특성분석)

  • Lee, Wontae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.1
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    • pp.47-53
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    • 2018
  • Recovery of lactic acid from fermentation broth using chemical precipitation was investigated with various chemicals. Effects of chemical types, mixing speeds, settling duration, and solvent addition were evaluated to improve the recovery rates of lactic acid. Overall, recovery efficiencies increased as the dosage of chemicals increased. Recovery rate of lactic acid by CaO was higher than those of $Ca(OH)_2$ and $CaCO_3$. Recovery of lactic acid increased by 48% under the optimized reaction conditions which included a mixing speed at 180 rpm, a settling duration of 24 h, and addition of ethanol at 25%(v/v). Practical application needs to consider types and concentrations of other organic acids as well as lactic acid. Based upon the results of fluorescence excitation emission matrix (FEEM), size exclusion chromatography (SEC), characteristics of recovered lactic acid were same as that in the fermentation broth.

A Study on the Optimal Welding Condition for Root-Pass in Horizontal Butt-Joint TIG Welding (수평자세 맞대기 TIG 초층용접에서 최적용접조건의 선정에 관한 연구)

  • Jung, Sung Hun;Kim, Jae-Woong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.4
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    • pp.321-327
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    • 2017
  • In this study, to investigate the shape of the back bead as a weld quality parameter and to select the optimal condition of the root-pass TIG welding of a horizontal butt-joint, an experimental design and the response surface method (RSM) have been employed. Three parameters are used as input variables, which include the base current, peak current, and welding speed. The back bead width is selected as an output variable representing the weld quality, the target value of the width is 5.4 mm. Conducting the experiments according to the Box-Behnken experimental design, a $2^{nd}$ regression model for the back bead width was made, and the validation of the model was confirmed by using the F-test. The desirability function was designed through the nominal-the-best formula for the appropriate back bead width. Finally, the following optimal condition for welding was selected using the RSM: base current of 0.9204, peak current of 0.8676, and welding speed of 0.3776 in coded values. For verification, a test welding process under the optimal condition was executed and the result showed the back bead width of 5.38 mm that matched the target value well.

Performance Improvement of Cooperating Agents through Balance between Intensification and Diversification (강화와 다양화의 조화를 통한 협력 에이전트 성능 개선에 관한 연구)

  • 이승관;정태충
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.40 no.6
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    • pp.87-94
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    • 2003
  • One of the important fields for heuristic algorithm is how to balance between Intensification and Diversification. Ant Colony Optimization(ACO) is a new meta heuristic algorithm to solve hard combinatorial optimization problem. It is a population based approach that uses exploitation of positive feedback as well as Breedy search It was first Proposed for tackling the well known Traveling Salesman Problem(TSP). In this paper, we deal with the performance improvement techniques through balance the Intensification and Diversification in Ant Colony System(ACS). First State Transition considering the number of times that agents visit about each edge makes agents search more variously and widen search area. After setting up criteria which divide elite tour that receive Positive Intensification about each tour, we propose a method to do addition Intensification by the criteria. Implemetation of the algorithm to solve TSP and the performance results under various conditions are conducted, and the comparision between the original An and the proposed method is shown. It turns out that our proposed method can compete with the original ACS in terms of solution quality and computation speed to these problem.

Premixture Composition Optimization for the Ram Accelerator Performance Enhancement (램 가속기 성능 향상을 위한 예 혼합기 조성비 최적화에 관한 연구)

  • 전용희;이재우;변영환
    • Journal of the Korean Society of Propulsion Engineers
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    • v.4 no.2
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    • pp.21-30
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    • 2000
  • Numerical design optimization techniques are implemented for the improvement of the ram accelerator performance. The design object is to find the minimum ram tube length required to accelerate projectile from initial velocity $V_o$ to target velocity $V_e$. The premixture is composed of $H_2$, $O_2$, $N_2$ and the mole numbers of these species are selected as design variables. The objective function and the constraints are linearized during the optimization process and gradient-based Simplex method and SLP(Sequential Linear Programming) have been employed. With the assumption of two dimensional inviscid flow for internal flow field, the analyses of the nonequilibrium chemical reactions for 8 steps 7 species have been performed. To determined the tube length, ram tube internal flow field is assumed to be in a quasi-steady state and the flow velocity is divided into several subregions with equal interval. Hence the thrust coefficients and accelerations for corresponding subregions are obtained and integrated for the whole velocity region. With the proposed design optimization techniques, the total ram tube length had been reduced 19% within 7 design iterations. This optimization procedure can be directly applied to the multi-stage, multi-premixture ram accelerator design optimization problems.

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Optimization of Processing Conditions for the Production of Puffed Rice (팽화미 제조 공정조건의 최적화)

  • Cheon, Hee Soon;Cho, Won Il;Jhin, Changho;Back, Kyeong Hwan;Ryu, Kyung Heon;Lim, Su Youn;Chung, Myong Soo;Choi, Jun Bong;Lim, Taehwan;Hwang, Keum Taek
    • Culinary science and hospitality research
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    • v.21 no.1
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    • pp.77-89
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    • 2015
  • The objective of this study was to optimize processing conditions for the production of an instant puffed rice product using response surface methodology (RSM) and contour analysis. Sensory and texture qualities, and physical properties of the puffed rice were analyzed with various processing conditions related to drying and puffing temperature, and moisture content. Preference, color intensity, cohesiveness, rehydration ratio, density and lightness of the puffed rice product significantly varied depending on the processing conditions. The responses showed high $R^2$ values (0.623, 0.852, 0.735, 0.688, and 0.790) and lack-of-fit. Rehydration ratio was found to have a negative correlation with density in the condition of drying and puffing temperature. Lightness and preference scores of the puffed rice increased as the moisture content increased. According to RSM, the preference scores were very highly related to the moisture content, and the optimum processing conditions of the puffed rice product were at $40^{\circ}C$ of drying temperature, with 11.0% of moisture content, and at $232.7^{\circ}C$ of puffing temperature.

Prediction of Homogenization Efficiency using Response Surface Methodology (반응표면분석을 활용한 균질 효율 예측)

  • Kang, Ho Jin;Kang, Shin Ho;Shin, Yong Kook
    • Journal of Dairy Science and Biotechnology
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    • v.35 no.3
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    • pp.202-207
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    • 2017
  • The objective of this study was to analyze the effects of homogenization, storage temperature, and storage period on the creaming of milk fat and changes in fat contents in the upper and lower layers and to predict the conditions for optimal homogenization efficiency using response surface methodology (RSM). The homogenization pressure, storage temperature, and storage period were set as independent variables of RSM, and the dependent variables were creaming, US Public Health Service (USPHS) code, and volume weighted mean diameter ($D_{4,3}$) in the upper and lower layers. Based on the results of RSM and regression analysis, the correlation coefficient ($R^2$) between experimental data and predicted values by RSM for homogenized milk was estimated to be more than 0.8. The RSM analysis indicated that optimal homogenization pressures of 14 MPa or more and 17 MPa or more were required to maintain the creaming layer of 3 mm or less during the storage for 15 days at $10^{\circ}C$ and $20^{\circ}C$, respectively. To keep the USPHS code at less than 10% for 15 days at $10^{\circ}C$ and $20^{\circ}C$, milk should be homogenized with a pressure of 16.8 MPa or more and 17 MPa or more, respectively.

Optimization of Peptide Production from Leg Meat of Yeonsan Ogae by High Hydrostatic Pressure and Protein Hydrolytic Enzyme and Its Characteristic Analysis (고압처리와 단백질 분해효소를 이용한 연산오계 다리육 펩타이드 생산 최적화 및 특성 분석)

  • Ha, Yoo-jin;Kim, A-Yeon;Yoo, Sun-Kyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.7
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    • pp.182-191
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    • 2016
  • The purpose of this research was the optimization of protein hydrolysate production using a commercial enzyme bromelain 1200 derived from the leg of Yeonsan Ogae by response surface methodology. Yeonsan Ogae has long been known as supporting health and high efficacy treatment. In recent days, as the efficacy of functional peptides becomes more known, optimization of oligopeptide production and its characteristics from Ogae leg meat has been performed. Response surface methodology was performed for optimization of enzyme hydrolysis. The process was varied in pressure (30 to 100 MPa), time (1 to 3 h), and substrate concentration (10 to 30%). The degree of hydrolysis, amino acids, and molecular weight of products were analyzed. The optimum conditions were determined to be a pressure of 100 Mpa, time of 3 h, and substrate concentration of 20%. Under optimized conditions, degree of hydrolysis was 34.10%. The average molecular weight of protein hydrolysates was less than 1,000 Da. Major amino acids were leucine, lysine, alanine, glutamic acid, and phenylalanine.