• Title/Summary/Keyword: 반응 조건 최적화

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The Study of Statistical Optimization of MTBE Removal by Photolysis(UV/H2O2) (광분해반응을 통한 MTBE 제거에 대한 통계적 최적화 연구)

  • Chun, Sukyoung;Chang, Soonwoong
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.9
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    • pp.55-61
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    • 2011
  • This study investigate the use of ultraviolet(UV) light with hydrogen peroxide($H_2O_2$) for Methyl Tert Butyl Ether(MTBE) degradation in photolysis reactor. The process in general demands the generation of OH radicals in solution at the presence of UV light. These radicals can then attack the MTBE molecule and it is finally destroyed or converted into a simple harmless compound. The MTBE removal by photolysis were mathematically described as the independent variables such as irradiation intensity, initial concentration of MTBE and $H_2O_2$/MTBE ratio, and these were modeled by the use of response surface methodology(RSM). These experiments were carried out as a Box-Behnken Design(BBD) consisting of 15 experiments. Regression analysis term of Analysis of Variance(ANOVA) shows significantly p-value(p<0.05) and high coefficients for determination values($R^2$=94.60%) that allow satisfactory prediction of second-order regression model. And Canonical analysis yields the stationery point for response, with the estimate ridge of maximum responses and optimal conditions for Y(MTBE removal efficiency, %) are $x_1$=25.75 W of irradiation intensity, $x_2$=7.69 mg/L of MTBE concentration and $x_3$=11.04 of $H_2O_2$/MTBE molecular ratio, respectively. This study clearly shows that RSM is available tool for optimizing the operating conditions to maximize MTBE removal.

Chromaticity Analysis of Curcumin Extracted from Curcuma and Turmeric: Optimization Using Response Surface Methodology (강황과 울금으로부터 추출된 커큐민의 색도분석 : 반응표면분석법을 이용한 최적화)

  • Yoo, Bong-Ho;Jang, Hyun Sik;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.30 no.4
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    • pp.421-428
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    • 2019
  • This paper describes a methode to extract yellow pigment from curcuma and turmeric containing natural color curcumin whose target color indexes of L, a, and b were 87.0 7.43, and 88.2, respectively. The pH range and extraction temperature used for the reaction surface analysis method were from pH 3 to pH 7 and between 40 and $70^{\circ}C$, respectively for both natural products. A central synthesis planning model combined with the method was used to obtain optimal extraction conditions to produce the color close to target. Results and regression equations show that the color space and difference of curcuma and turmeric have the greatest influence on the value. In the case of curcuma, the optimum conditions to satisfy all of the response theoretical values of color coordinates of L (74.67), a (5.69), and b (70.08) were at the pH and temperature of 3.43 and $54.8^{\circ}C$, respectively. The experimentally obtained L, a, and b, values under optimal conditions were 72.92, 5.32, and 72.17, respectively. For the case of turmeric, theoretical numerical color coordinates of L, a, and b, under the pH of 5.22 and temperature of $50.4^{\circ}C$ were 82.02, 7.43, and 72.86 respectively. Whereas, the experiment results were L (81.85), a (5.39), and b (71.58). Both cases showed an error range within 1%. Therefore, it is possible to obtain a low error rate when applying the central synthesis planning model to the reaction surface analysis method as an optimization process of the dye extraction of natural raw materials.

Aerodynamic Design Optimization of Airfoils for WIG Craft Using Response Surface Method (반응표면법을 이용한 지면효과익기 익형의 공력 설계최적화)

  • Kim, Yang-Joon;Joh, Chang-Yeol
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.5
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    • pp.18-27
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    • 2005
  • Airfoils with improved longitudinal static stability were designed for a WIG craft through aerodynamic design optimization. The response surface method is coupled with NURBS-based shape functions and Navier-Stokes flow analysis. The procedure runs in the network-distributed design framework of commercial-code based automated design capability to enhance computational efficiency and robustness.Lift maximization design maintaining similar static margin to a DHMTU airfoil successfully produced a new airfoil shape characterized by pronounced front-loading and the well-known reflexed aft-camber line. Another airfoil design of lower variation in pitching moment during take-off showed weakened front-loaded characteristics and hence decreased lift slightly. Investigations using the present design methodology on an existing optimization result based on potential flow analysis and NACA-type geometry generation demonstrated significance of carrying various geometry generations and more realistic flow analysis with optimization.

Production of Levulinic Acid from Chitosan by Acidic-Hydrothermal Reaction (산성 수열반응을 통한 키토산으로부터 레불린산의 생산)

  • Jeong, Gwi-Taek
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.355-359
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    • 2014
  • Recently, many chemicals produced from renewable resources such as lignocellulosics, micro-algae and marine macro-algae, were introduced to chemical industry. Chitin/chitosan is secondly abundant feedstock on Earth. It is easily obtained from crusraceans' shells such as crab, shrimp and insects. In this work, we performed the acidic-hydrothermal hydrolysis to produce levulinic acid from chitosan using statistical approach. By design of response surface methodology, the effect of reaction temperature, catalyst amount, and reaction time and their reciprocal interactions were investigated. As a result, higher reaction temperature and catalyst amount increased the higher concentration of levulinic acid. However, reaction time did not caused large increase of levulinic acid after some reaction period. Levulinic acid of 2.7 g/L produced from chitosan in the optimized condition of reaction temperature of $175^{\circ}C$, sulfuric acid of 2.4% and reaction time of 40.7 min.

A Study on the Convergence Characteristics Analysis of Chaotic Dynamic Neuron (동적 카오틱 뉴런의 수렴 특성에 관한 연구)

  • Won-Woo Park
    • Journal of the Institute of Convergence Signal Processing
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    • v.5 no.1
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    • pp.32-39
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    • 2004
  • Biological neurons generally have chaotic characteristics for permanent or transient period. The effects of chaotic response of biological neuron have not yet been verified by using analytical methods. Even though the transient chaos of neuron could be beneficial to overcoming the local minimum problem, the permanent chaotic response gives adverse effect on optimization problems in general. To solve optimization problems, which are needed in almost all neural network applications such as pattern recognition, identification or prediction, and control, the neuron should have one stable fixed point. In this paper, the dynamic characteristics of the chaotic dynamic neuron and the condition that produces the chaotic response are analyzed, and the convergence conditions are presented.

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Optimal Supersonic Diffuser Design of Integrated Rocket Ramjet Engine (IRR형 Ramjet Intake 초음속 확산부 형상 최적설계)

  • 민병영;이재우;변영환
    • Journal of the Korean Society of Propulsion Engineers
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    • v.6 no.2
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    • pp.65-74
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    • 2002
  • Optimal supersonic diffuser shape of integrated rocket ramjet engine was derived which maximizes the total pressure recovery. Mass flux is considered as a design constraint and the second oblique shock angle of the external ramp, the cowl-lip angle and the throat area are selected as design variables. Refined response surface method through design space transformation technique was developed and employed, and high confidence level of the regression model could be obtained. Genetic algorithm was implemented for both system optimizer and subspace regression model optimization. Virtual nozzle was located at the end of throat to adjust the back pressure. With only 20 aerodynamic analyses, optimal supersonic diffuser shape which has 14% improved total pressure recovery characteristics was successfully designed.

Optimization of the Vinegar Fermentation Using Concentrated Apple Juice (농축 사과주스를 이용한 식초 발효조건의 최적화)

  • 서지형;이기동;정용진
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.3
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    • pp.460-465
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    • 2001
  • To prepare vinegar using concentration apple juice, response surface methodology (RSM) was applied to optimize and monitor the vinegar fermentation properties by two stage fermentation. In the first stage, the optimum conditions for maximum alcohol contents were 18.56。Brix of initial sugar concentration, 61.96 rpm of agitation rate and 67.32 hr of fermentation time. The optimum condition for maximum acidity in the second stage (vinegar fermentation) were 201.53 rpm of agitation rate and 179.42 hr of fermentation time. Malic acid content was the highest and its content little changed during acetic acid fermentation. Lactic acid content increased a little during alcohol fermentation. Acetic acid content apparently increased during acetic acid fermentation.

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Optimization of Extraction Conditions for Lyophyllum ulmarium by Response Surface Methodology (반응표면분석에 의한 만가닥 버섯의 추출조건 최적화)

  • 김현구;최맑음;김미옥;김공환
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.4
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    • pp.574-580
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    • 2003
  • Optimal extraction conditions for yield, browning color, electron donating ability, nitrite scavenging effect, total polyphenol content and tyrosinase inhibitory activity of Lyophyllum ulmarium were determined by using response surface methodology (RSM) through the central composite design. The extraction yield of Lyophyllum ulmarium was effected by ethanol concentration and browning color was improved with the increase of ethanol concentration than microwave power. The nitrite scavenging effect was improved with the increase of ethanol concentration and decrease of microwave power The electron donating ability, browning color, tyrosinase inhibitory activity and total polyphenol content were improved with the increase in ethanol concentration and microwave power. The optimal ranges of extraction conditions for effective components of Lyophyllim ulmarium were predicted as 60.05~102.75 watt of microwave power, 53.20~64.01% of ethanol concentration and 7.77 min of extraction time.

Optimization of Roasting Process for Preparation of Water Extracts from Job's tears (Coicis lachryma-jobi) (고품질 율무추출액 제조를 위한 볶음공정의 최적화)

  • Chung Hun-Sik;Youn Kwang-Sup
    • Food Science and Preservation
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    • v.13 no.2
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    • pp.119-124
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    • 2006
  • This study was conducted to optimize roasting process of Job's tears for utilization as food Optimal condition for masting was investigated with changes in temperature and time by response surface methodology. The qualities of water extract such as browning degree, polyphenol and DPPH radical scavenging ability were affected more by roasting temperature than time. The values increased with temperature and time proportionally. The response variables were more significant with temperature than time and the established polynomial model was suitable (P>0.05) model by Lack-of-Fit analysis. Optimal roasting conditions with the limit of $0.2{\sim}0.3$ browning degree, $2.0{\sim}2.5{\mu}g/mL$ polyphenol, $30{\sim}40%$ scavenging ability and $0{\sim}100$ hue angle were $215^{\circ}C$ and 32 min.

Optimization of Electro-UV-Ultrasonic Complex Process for E. coli Disinfection using Box-Behnken Experiment (Box-Behnken법을 이용한 E. coli 소독에서 전기-UV-초음파 복합 공정의 최적화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.3
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    • pp.149-156
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    • 2011
  • This experimental design and response surface methodology (RSM) have been applied to the investigation of the electro-UV-ultrasonic complex process for the disinfection of E. coli in the water. The disinfection reactions of electro-UV-ultrasonic process were mathematically described as a function of parameters power of electrolysis ($X_1$), UV ($X_2$), and ultrasonic process ($X_3$) being modeled by use of the Box-Behnken technique, which was used for fitting 2nd order response surface model. The application of RSM yielded the following regression equation, which is empirical relationship between the residual E. coli number (Ln CFU) in water and test variables in coded unit: residual E. coli number (Ln CFU) = 23.69 - 3.75 Electrolysis - 0.67 UV - 0.26 Ultrasonic - 0.16 Electrolysis UV + 0.05 Electrolysis Ultrasonic + 0.27 $Electrolysis^2$ + 0.14 $UV^2$ - 0.01 $Ultrasonic^2$). The model predictions agreed well with the experimentally observed result ($R^2$ = 0.983). Graphical 2D contour and 3D response surface plots were used to locate the optimum range. The estimated ridge of maximum response and optimal conditions for residual E. coli number (Ln CFU) using 'numerical optimization' of Design-Expert software were 1.47 Ln CFU/L and 6.94 W of electrolysis, 6.72 W of UV and 14.23 W of ultrasonic process. This study clearly showed that response surface methodology was one of the suitable methods to optimize the operating conditions and minimize the residual E. coli number of the complex disinfection.