• Title/Summary/Keyword: 반응 생성물

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Determination of Trace Impurities in High Purity Aluminum by Instrumental Neutron Activation Analysis (고순도알루미늄의 비파괴 중성자방사화분석)

  • Cho, Seung-Yeon;Kim, Young-Kuk;Chung, Yong-Sam
    • Nuclear Engineering and Technology
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    • v.24 no.2
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    • pp.163-167
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    • 1992
  • Nondestructive neutron activation analysis of copper in high purity Aluminum samples which can be used as a parameter of impurity is investigated and determined. Other 23 trace impurity elements in the samples are also determined. In the analysis of copper, the new irradiation method using thermal column was applied to reduce the interfering activity of 24Na produced by 27Al(n,$\alpha$)24Na reaction induced by fast neutron. As a result, the interference can be reduced to 100 times more than other activation methods. Also the influence by activity of 24Na is found in the range of 2~3 %. It has been observed that the copper contents in so-ratted“six nine”class standard aluminum samples are about 0.54 $\pm$ 0.08 ppm. By the comparison with other values re-ported, our results are reasonable and can be available as a improved routine analysis.

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The protective effect of berberine on Propionibacterium acnes-induced inflammatory response in human monocytes (여드름균에 의해 염증 반응이 유도된 인간 단핵구 세포에서 알칼로이드 화합물 berberine의 항염증 효과)

  • Kim, Hyun Pyo;Yoon, Young Geol
    • Journal of Applied Biological Chemistry
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    • v.61 no.2
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    • pp.181-186
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    • 2018
  • In this study, we investigated the anti-inflammatory activity of berberine using human monocytes. Infection of Propionibacterium acnes induced the production of nitric oxide (NO) and the pro-inflammatory cytokines such as, $TNF-{\alpha}$, IL-8 and $IL-1{\beta}$ in THP-1 monocytic cells. However, when berberine was supplemented in these P. acnes-induced THP-1 cells, the production of pro-inflammatory cytokines and NO was significantly reduced. We also analyzed signaling pathways of the antiinflammatory function of berberine and found that berberine suppressed the phosphorylation of ERK1/2, JNK and p38 and the expression and nuclear translocation of $NF-{\kappa}B$ p65 in the P. acnes-induced cells. From these results, we concluded that berberine can effectively exert the anti-inflammatory activity via suppressing the $NF-{\kappa}B$ and mitogen-activated protein kinases signaling pathways in human monocytes. Moreover, these results suggest the feasibility of developing natural therapeutics using berberine for the treatment of P. acnes-induced inflammatory diseases.

Disposal and Waste-to-Fuel of Infected Poultry with Avian Influenza(AI) Using Thermal Hydrolysis Reaction (열가수분해 반응을 이용한 조류인플루엔자(AI) 감염 가금류의 사체처리 및 연료화)

  • Song, Chul-Woo;Kim, Nam-Chan;Jeong, Guk;Ryu, Jae-Keun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.4
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    • pp.49-57
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    • 2016
  • In this study, a thermal hydrolysis technology was used to treat the poultry carcasses that were killed due to Avian Influenza (AI) occurrence, as well as to determine the possibility of fueling for the resultant products. Experimental results showed that the poultry carcasses were liquefied except for sand, and showed the optimum efficiency at $190^{\circ}C$ and operating time of 60 minutes. It has been shown that liquid products obtained after thermal hydrolysis has good conditions for fuel conversion since it had high carbon contents and calorific value, as well as low ash content. In addition, it was possible to operate the thermal hydrolysis facility by using only the waste heat generated in the combustion without injecting the auxiliary fuel, and the exhaust gas generated in the combustion has a small influence on the atmosphere.

Pulse-mode Response Characteristics of a Small LRE for the Precise 3-axes Control of Flight Attitude in SLV (우주발사체의 비행자세 3축 정밀제어를 위한 소형 액체로켓엔진의 펄스모드 응답특성)

  • Jung, Hun;Kim, Jong Hyun;Kim, Jeong Soo;Bae, Dae Seok
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.1
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    • pp.1-8
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    • 2013
  • A liquid-monopropellant hydrazine thruster has several outstanding advantages such as relatively-simple structure, long/stable propellant storability, clean exhaust products, and so on. Therefore hydrazine thruster has such a wide application as orbit and attitude control system (ACS) for space vehicles. A hydrazine thruster with the medium-level thrust to be used in the ACS of space launch vehicles (SLV) has been developed, and its ground firing test result is presented in terms of thrust, impulse bit, temperature, and chamber pressure. It is verified through the performance test that the response and repeatability of thrust are very excellent, and the thrust efficiencies compared to its ideal requirement are larger than 93%.

Synthesis and Spectroscopic Characterization of Vanadium-Incorporated V-AlMCM-48 Mesoporous Material (바나듐이 들어있는 Mesoporous V-AlMCM-48 분자체의 합성 및 분광학적 특성 조사)

  • Back, Gernho;Yu, Jong-Sung;Park, Sung-Kun;Lee, Chul Wee;Won, Taejin
    • Korean Chemical Engineering Research
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    • v.44 no.4
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    • pp.369-374
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    • 2006
  • A solid-state reaction of $V_2O_5$ with AlMCM-48 followed by calcination generated very weak paramagnetic $VO^{2+}$ species in the mesoporous material. Dehydration and subsequent reduction with CO result in the formation of vanadyl $VO^{2+}$ species that can be characterized by EPR. The chemical environment of vanadium centers in $VO^{2+}-AlMCM-48$ was investigated by XRD, EDX, DR-UV-Vis, EPR,$^{29}Si$ and $^{27}Al$ and $^{51}V$ NMR. Vanadium species in MCM-48 are existed as pseudotetrahedral $VO^{2+}$ state when they were dehydrated or reduced with CO. The coordination of water on vanadyl ions transformed their structure to distorted octahedral.

Preperation and Flavor Characteristics of Seasoning Oil for Chinese Dish (중화요리용 향미유의 제조 및 향미특성)

  • Koo, Bon-Soon
    • Journal of the Korean Society of Food Culture
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    • v.20 no.2
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    • pp.214-220
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    • 2005
  • Seasoning oil (SO) for Chinese dish was manufactured from the combination of Maillard reaction for methionine and xylose with autoclaving method. Volatile compounds were determined by GC, GC-MSD for this SO and 3 kinds of seasoning jajang samples which was obtained from restaurant. From this SO 61 kinds-404.92ppm volatile compounds were separated and identified. And from 3 samples of restaurant, 39 kinds-333.52ppm, 42 kinds-330.01ppm, 42 kinds-393.18ppm obtained respectively. Major volatile components of SO were diallyl disulfide, pentane, diallyl trisulfide, t,t-2,4-decadienal and zinngiberene. Those contents were 40.15ppm, 32.32ppm, 19.57ppm, 15.06ppm and 13.23ppm, respectively. Major volatile components in 3 kinds samples were pentane, propenal, hexanal, t-2-heptanal, 2,4-heptadienal, t,t-2,4-decadienal and unknown components. The volatile components of SO were very similar to 3 samples,

Crystallization and Magnetic Properties of Iron Doped ZnO Diluted Magnetic Semicondutor (철을 미량 치환한 ZnO 희박자성반도체의 결정학적 및 자기적 특성 연구)

  • Ahn, Geun-Young;Park, Seung-Iel;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.15 no.2
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    • pp.92-95
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    • 2005
  • $Zn_{1-x}\;^{57}Fe_xO(x=0.01, 0.02, 0.03)$ compounds were fabricated using the solid-state reaction method. In order to determine magnetic behavior and ionic state of the doped transition metal ($^{57}Fe$) in ZnO, we carried out $M\ddot{o}ssbauer$ measurements at various temperatures ranging from 13 to 295 K. $M\ddot{o}ssbauer$spectra for $Zn_{0.97}\;^{57}Fe_{0.03}O$ at 4.2 K have shown the ferromagnetic phase (sextet), but the only paramagnetic phase (doublet) is seen at 295 K. The hysteresis loop below 77 K for $Zn_{0.97}\;^{57}Fe_{0.03}O$ indicated the coexistence of ferromagnetic and paramagnetic phases.

Highly Sensitive and Selective Fluorescent Chemosensors Specific for Pd2+ Detection (Pd2+ 검출용 고감도 형광화학센서)

  • Wang, Jing;Ha, Chang-Sik
    • Journal of Adhesion and Interface
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    • v.14 no.1
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    • pp.13-20
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    • 2013
  • Palladium plays a pivotal role in the production of dental and medicinal devices, medicinal substances, jewellery, automobile and high-performance adhesives. Despite the frequent and fruitful use of such reactions, one major setback is the high level of palladium in the resultant compounds which can harm the human body. Among the palladium species, $PdCl_2$ is the most toxic. As a consequence it is desirable to detect the $Pd^{2+}$ cations by fluorescence spectra because it can provide an operationally simple and cost-effective detection method together with high sensitivity and selectivity. Herein, an ${\alpha}$-carbonyl substituted pyrene derivative, ${\gamma}$-oxo-1-pyrenebutyric acid (OPBA), was demonstrated to be a highly sensitive and selective fluorescent probe for $Pd^{2+}$ among the metal cations examined in aqueous solutions.

Effect of Acidic Leachate on the Cement-based Landfill Soil Liner System (고화토차수층에 대한 산성침출수의 영향과 대책방안 - 산업부산물(고로슬래그, 플라이애쉬) 재활용 방안 중심으로 -)

  • Cho, Jae-Beom;Hyun, Jae-Hyuk;Lee, Jong-Deuk;Park, Joung-Ku
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.265-269
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    • 2006
  • This study was to investigate the effect of acidic leachate on the landfill liner system and healing of cracks by using industrial by-products; BFS(Blast Furnace Slag) and FA(Fly Ash). From the results of pH measurement, for OPC(Ordinary Portland Cement) and DM(Dredged Mud) mixtures immersed acidic leachate, the initial pH($4.5{\sim}5.5$) was heavily increased to approximately 10 after 60 days experiment due to the production of 2 mole $OH^-$ which was occurred by hydrolysis of CaO and MgO etc.. Meanwhile, the initial pH of acidic leachate immersed DM mixtures with BFS and FA respectively was lasted for longer period as compared to the comparison. The reason was that production of low Ca C-S-H hydrates which stabilized in acidic liquid. The physical properties(compressive strength, hydraulic conductivity) of DM mixtures added BFS and FA was improved. It was concluded that the dissolution of hydrates was disturbed by high alkalinity of BFS and FA.

The Effect of Ginseng Saponin Fraction on Antioxidant Activity of $\alpha$-Tocopherol ($\alpha$-tocopherol의 항산화작용에 미치는 인삼사포닌분획의 영향)

  • 주충노;곽한식
    • Journal of Ginseng Research
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    • v.12 no.2
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    • pp.128-134
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    • 1988
  • The effect of the saponin fraction extracted from Panax ginseng C.A. Meyer on the antioxidant activity of $\alpha$-tocopherol was investigated in vitro as well as in vivo. Microsomal preparation of rat(Winter, 180-200g) liver was incubated in the mixture containing NADPH, $Fe^{3+}$, ATP, $\alpha$-tocopherol with and/or without ginseng saponin fraction for 30 minutes and the malondialdehyde formed was assayed and found that the saponin fraction stimulated the antioxidant activity of $\alpha$-tocopherol cooperatively. It was also realized that the cooperative stimulation of the antioxidant activity of $\alpha$-tocopherol was most eminent when the concentration of the saponin fraction was around $10^{-5}$% in the reaction mixture. Alcoholic suspension of $\alpha$-tocopherol with and f or without ginseng saponin fraction was administered orally to rats in which the lipid preoccupation was induced by ethanol administration and the lipid peroxide contents of the liver were assayed at certain periods of time after $\alpha$-tocopherol administration in this animal. From the previous work and present experimental results, it seemed that the saponin fraction accelerated the absorption of $\alpha$-tocopherol and therefore stimulated the antioxidant activity of $\alpha$-tocopherol more effectively in the animal body.

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