• Title/Summary/Keyword: 반응 생성물

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Reforming of Hydrocarbon Fuel Using Water Jet Plasma (Water Jet 플라즈마를 이용한 탄화수소 연료 개질)

  • Kim, Seong-Cheon;Chun, Young-Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.9
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    • pp.949-954
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    • 2006
  • The purpose of this paper is to develop water jet plasma reactor and investigate the optimal condition of the syngas production by reforming of hydrocarbon fuel. Fuel used was propane and plasma was generated by arc discharge on water jet surface. Discharge slipping over the water surface has a number of advantages such as a source of short-wave and UV radiation, and it can be used for biological and chemical purification of water. Parametric screening studies were conducted, in which there were the variations of power ($0.18{\sim}0.74$ kW), water jet flow rate($38.4{\sim}65.6$ mL/min), electrode gap($5{\sim}15$ mm) and treatment time($2{\sim}20$ min). When the variations were 0.4 kW, 53.9 mL/min, 10 mm and 20 min respectively, result of maximum $H_2$ concentration was 61.6%, intermediates concentration were 6.1% and propane conversion rate was 99.8%.

Preparation and Application of CSA Expansive Additives Using Industrial Wastes (산업폐기물을 이용한 CSA계 팽창재 제조 및 응용)

  • Yoon Sung-Won;Rho Jae-Seong
    • Journal of the Korea Concrete Institute
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    • v.16 no.3 s.81
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    • pp.369-374
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    • 2004
  • Calcium sulfoalumiante(CSA) was prepared for using natural calcite($CaCO_3$) and industrial by-products and wastes, such as $Al(OH)_3,\;CaSO_4{\cdot}2H_2O$. The mixture of raw materials was fired at 20, 400, 600, $1200^{\circ}C$ for 1h and cooled rapidly in air. The cement replaced by 10 wt% $C_4A_3S$ expansive additives was investigated by the measurement of the hydration products and compressive strength, setting time, expansion at wet curing condition. $C_4A_3S$ was found in x-ray diffraction pattern over the temperature $1200^{\circ}C$. The setting time or the cement pastes added clinkers fired at different temperature was shorter than ordinary portland cement. The compressive strength was higher than the ordinary portland cement about 20~30%. The mainly hydration products were ettringite, and $Ca(OH)_2$. The expansion due to the formation of ettringite during hydration decreased the drying shrinkage of hardened cement rather than the ordinary portland cement.

Analysis of Internal Structure in Alkali-Activated Fire Protection Materials Using Fly ash (플라이애시를 활용한 알칼리 활성화 내화성 마감재의 내부구조 분석)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.104-112
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    • 2012
  • This study involves investigating the correlation between variation of internal structure and heating temperature of alkali-activated fire protection materials using fly ash. Dehydration and micro crack thermal expansion occur in cement hydrates of cementitious materials heated by fire. Internal structure difference due to both the dehydration of cement hydrates and pore solution causes and influences changes in the properties of materials. Also, this study is concerned with change in microstructure and dehydration of the alkali-activated fire protection materials at high temperatures. The testing methods of alkali-activated fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. The study results show that the alkali-activated fire resistant finishing material composed of potassium hydroxide, sodium silicate and fly ash has the high temperature thermal stability. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction.

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Study on the Development of Accelerator for Early Strength of Concrete using Industrial by-product (산업부산물을 활용한 조기강도 촉진제 기술 개발을 위한 연구)

  • Lee, Ji-Hwan;Lee, Jin-Woo;Lee, Jae-Sam;Lee, Kang-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.1-10
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    • 2013
  • In this study utilize industry product for OPC(ordinary portland cement) and BFS(blast furnace slag) mixing concrete early age compressive strength elevation and executed study for high strength binder. Association ratio of industry product for high strength binder manufacture is Titanogypsum (4) : Limestone (3) : Waterworks Sludge by ratio of (3) as it is proper move. high strength binder mixing rate appeared that (7~9) % are proper via preliminary test. Could confirm that display high compressive strength incidence rate in early age than plain harmony according as mix high strength binder mixing concrete compressive strength high strength binder. Also, high strength binder generality that give function than high strength binder used in existing displayed more excellent intensity, and compressive strength displayed result that multiply single breadth according as high strength binder substitute that give function increases.

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Fabrication and Stability of Pd Coated Ta/YSZ Cermet Membrane for Hydrogen Separation (Pd 코팅된 Ta/YSZ 수소분리막의 제조 및 안정성)

  • Lee, Sang-Jin;Jeon, Sung-Il;Park, Jung-Hoon
    • Membrane Journal
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    • v.20 no.1
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    • pp.69-75
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    • 2010
  • Cermet membrane was fabricated with tantalum as hydrogen-permeable metal and $Y_2O_3$-stabilized $ZrO_2$ (YSZ) as ceramic supporter. Ta/YSZ cermet membrane was prepared through pre-sintering in He atmosphere and then main sintering under high vacuum and the impurities to originate from sintering and brazing could be removed by mechanical polishing. As-prepared membrane showed dense structure with continuous channel of tantalum. Hydrogen permeation experiment was conducted in the region of $200{\sim}350^{\circ}C$ using Ta/YSZ membrane coated with Pd for hydrogen dissociation. The crack in membrane was formed at $300^{\circ}C$ and the Pd coating layer has flaked off in spots. XRD results showed that tantalum reacted with hydrogen to form $Ta_2H$. The lattice expansion by $Ta_2H$ caused deterioration for membrane.

Thin Layer Chromatographic Determination of ${\alpha}-Solanine$ (Thin Layer Chromatography 법(法)에 의한 ${\alpha}-Solanine$의 정량(定量))

  • Choe, Eun-Ok;Ahn, Seung-Yo
    • Applied Biological Chemistry
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    • v.24 no.4
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    • pp.238-244
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    • 1981
  • The thin Layer chromatographic determination of ${\alpha}-solanine $ in potato tuber was investigated. The solanine was extracted with methanol-chloroform mixture (2 : 1, v/v) and precipitated as the crude glycoalkaloid by the addition of ammonium hydroxide. The solanine in the crude precipitate was separated by TLC using a solvent system of 1% $NH_4OH-absolute$ ethanol-chloroform (1:2:2, v/v). The purity of ${\alpha}-solanine $ was confirmed by infrared spectrophotometry. The ${\alpha}-solanine $ separated by TLC was determined at the wavelength of 310nm after coloration with concentrated sulfuric acid-1% paraformaldehyde, with the molar absorptivity of 2,090.

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Phases and phase Equilibria of the Pt-Sb System (백금-안티모니 계의 식평구 및 화합흉에 대한 연구)

  • 김원사
    • Korean Journal of Crystallography
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    • v.4 no.1
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    • pp.18-24
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    • 1993
  • The phase diagram of the Pt-Sb system was reinvestigated, using the conventional sealedcapsule technique. The identification of phases present in the reaction products was made by reflected light microscopy, X-ray diffraction and electron microprobe analysis. The existence of compounds, Pt5Sb, Pt3Sb, Pt3Sb2, PtSb and PtSb5 was confirmed. A new phase, Pt5Sb with a composition of 83at% Pt and tetragonal structure of the lattice parameters a=3.948(3), c=16.85(1)A, was found. The X-ray powder data of Ptsb may be indexable on a tetragonal cell with a=3.9455(7), c=16.959(5)A. PtSb is stoichiometric up to 800t and becomes Pt-deficient as much as lat% at 1000t. Solid solubility limits of Sb in Pt were determined to be 7.5,10.0 and 6.1at% at 1000˚,800˚ and 600˚ , respectively. The earlier reported Pts Sbf was not found in this study. The liquidus curve between the Ptsb2 and Sb phases was revised.

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Determination of Trace Impurities in High Purity Aluminum by Instrumental Neutron Activation Analysis (고순도알루미늄의 비파괴 중성자방사화분석)

  • Cho, Seung-Yeon;Kim, Young-Kuk;Chung, Yong-Sam
    • Nuclear Engineering and Technology
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    • v.24 no.2
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    • pp.163-167
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    • 1992
  • Nondestructive neutron activation analysis of copper in high purity Aluminum samples which can be used as a parameter of impurity is investigated and determined. Other 23 trace impurity elements in the samples are also determined. In the analysis of copper, the new irradiation method using thermal column was applied to reduce the interfering activity of 24Na produced by 27Al(n,$\alpha$)24Na reaction induced by fast neutron. As a result, the interference can be reduced to 100 times more than other activation methods. Also the influence by activity of 24Na is found in the range of 2~3 %. It has been observed that the copper contents in so-ratted“six nine”class standard aluminum samples are about 0.54 $\pm$ 0.08 ppm. By the comparison with other values re-ported, our results are reasonable and can be available as a improved routine analysis.

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The protective effect of berberine on Propionibacterium acnes-induced inflammatory response in human monocytes (여드름균에 의해 염증 반응이 유도된 인간 단핵구 세포에서 알칼로이드 화합물 berberine의 항염증 효과)

  • Kim, Hyun Pyo;Yoon, Young Geol
    • Journal of Applied Biological Chemistry
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    • v.61 no.2
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    • pp.181-186
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    • 2018
  • In this study, we investigated the anti-inflammatory activity of berberine using human monocytes. Infection of Propionibacterium acnes induced the production of nitric oxide (NO) and the pro-inflammatory cytokines such as, $TNF-{\alpha}$, IL-8 and $IL-1{\beta}$ in THP-1 monocytic cells. However, when berberine was supplemented in these P. acnes-induced THP-1 cells, the production of pro-inflammatory cytokines and NO was significantly reduced. We also analyzed signaling pathways of the antiinflammatory function of berberine and found that berberine suppressed the phosphorylation of ERK1/2, JNK and p38 and the expression and nuclear translocation of $NF-{\kappa}B$ p65 in the P. acnes-induced cells. From these results, we concluded that berberine can effectively exert the anti-inflammatory activity via suppressing the $NF-{\kappa}B$ and mitogen-activated protein kinases signaling pathways in human monocytes. Moreover, these results suggest the feasibility of developing natural therapeutics using berberine for the treatment of P. acnes-induced inflammatory diseases.

Disposal and Waste-to-Fuel of Infected Poultry with Avian Influenza(AI) Using Thermal Hydrolysis Reaction (열가수분해 반응을 이용한 조류인플루엔자(AI) 감염 가금류의 사체처리 및 연료화)

  • Song, Chul-Woo;Kim, Nam-Chan;Jeong, Guk;Ryu, Jae-Keun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.4
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    • pp.49-57
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    • 2016
  • In this study, a thermal hydrolysis technology was used to treat the poultry carcasses that were killed due to Avian Influenza (AI) occurrence, as well as to determine the possibility of fueling for the resultant products. Experimental results showed that the poultry carcasses were liquefied except for sand, and showed the optimum efficiency at $190^{\circ}C$ and operating time of 60 minutes. It has been shown that liquid products obtained after thermal hydrolysis has good conditions for fuel conversion since it had high carbon contents and calorific value, as well as low ash content. In addition, it was possible to operate the thermal hydrolysis facility by using only the waste heat generated in the combustion without injecting the auxiliary fuel, and the exhaust gas generated in the combustion has a small influence on the atmosphere.