• Title/Summary/Keyword: 반응 동특성

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Multi-scale Simulation Approach on Lithiation of Silicon Electrodes

  • Jeong, Hyeon;Ju, Jae-Yong;Jo, Jun-Hyeong;Lee, Gwang-Ryeol;Han, Sang-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.186.2-186.2
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    • 2014
  • 최근 친환경 에너지에 대한 관심이 증폭되면서 리튬이차전지에 대한 연구가 활발히 진행되고 있다. 특히 음극(anode) 물질의 경우 기존의 흑연(graphite)보다 이론적 용량이 약 10배 이상 높은 실리콘(Silicon)에 대한 관심이 매우 높다. 하지만 Si의 경우 리튬 충전거동 시 400% 이상의 부피팽창으로 몇 번의 충전/방전 싸이클(cycle)에 전극이 파괴되는 문제점을 지니고 있다. 이를 극복하기 위해 Si 나노선이 고려되고 있다. 우수한 전극특성을 갖는 Si 소재를 개발하기 위해서는 원자단위에서 Si 나노선의 리튬 충전 메커니즘을 살펴보는 것이 매우 중요하다. 하지만 기존의 시뮬레이션 기법으로는 Si 나노선의 볼륨팽창에 관한 메커니즘과 리튬 충전과정에서의 상변화(결정질에서 비정질) 과정을 설명하기는 기술적으로 매우 힘들다. 고전적인 분자동역학 방법의 경우 실제 나노스케일을 고려할 수 있지만, empirical potential로는 원자들간의 화학반응을 제대로 묘사할 수 없다. 한편 양자역학에 기반을 둔 제일원리방법의 경우 계산의 복잡성으로 현재의 컴퓨터 환경에서는 나노스케일에서 원자들의 동역학적인 거동을 연구하기 매우 힘들다. 우리는 이러한 문제를 해결하기 위해 실제 나노스케일에서 원자간 화학반응을 예측할 수 있는 Si-Li 시스템의 Reactive force field를 개발하였고, 분자동역학 계산방법을 이용하여 Si 나노선의 Li 충전 메커니즘을 규명하였다.

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The Research of Zincate Properties with Pre-treatment of AZ31 Magnesium Plate (AZ31 마그네슘 판재의 전처리에 따른 아연치환도금 특성 조사)

  • Park, Sang-Eon;Gang, Yong-Seok;Heo, Se-Jin;Choe, Ju-Won
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.77-78
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    • 2007
  • AZ31 마그네슘 판재의 장식 도금을 공정 개발을 적용하기 위한 기초 연구로서 전처리 특성에 따른 마그네슘 AZ31 판재의 아연치환도금의 특성을 연구하였다. AZ31 판재는 다이캐스팅으로 사용되는 AZ91 소재에 비해 산세에 대해 민감한 반응을 나타내었다. 소재의 균일화는 시편 E와 F에서 균일하고 광택 있는 표면을 얻었고, 질산은 표면 에칭효과만을 가진다는 것을 알 수 있었다. 아연치환도금을 위한 전처리에 있어서는 시편 E에서 우수한 밀착력을 나타내었다. 이후 청화동 도금과 황산동 도금, 니켈도금 3가 크롬도금을 실시하여, X-cutting 테이핑 테스트에서 양호한 밀착성과 내식성 72시간, 열탕시험을 만족하였다.

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A Study on the Recovery of Shape-controlled Copper Oxide from the Waste etchant of PCB Industry (PCB 産業에서 배출되는 산성 염화동 폐액으로부터 입자형상이 제어된 산화동 회수에 관한 연구)

  • 김영희;류도형;김수룡;어용선
    • Resources Recycling
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    • v.10 no.6
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    • pp.15-21
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    • 2001
  • Shape-controlled copper oxides have been recovered from copper-containing waste etchant by neutralization with alkalihydroxide. Large amount of copper-containing waste etchant is generated from Printed Circuit Board industry. In an environmental and economic point of view, retrieve of the valuable natural resource from the waste is important. In recycling process of copper oxide from the waste etchant, reaction temperature controls shapes and sizes of the products. Copper oxide recovered below reaction temperature $40^{\circ}C$ was of a needle shape, while copper oxide comes in a platy shape above $40 ^{\circ}C$ . Physical properties of samples have been characterized using SEM, XRD, TGA and Atomic absorption spectroscopy.

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Cation Exchange Capacities, Swelling, and Solubility of Clay Minerals in Acidic Solutions : A Literature Review

  • Park, Won Choon
    • Economic and Environmental Geology
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    • v.12 no.1
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    • pp.41-49
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    • 1979
  • A literature review is made on the physical and chemical characteristics of clay minerals in acidic solutions from the mineralogical and hydrometallurgical viewpoints. Some of the important characteristics of clays are their ability to cation exchange, swelling, and incongruent dissolution in acidic solutions. Various clay minerals can take up metallic ions from solution via cation exchange mechanism. Generally, cation exchange capacity increases in the following order : kaolinite, halloysite, illite, vermiculite, and montmorillonite. In acidic solutions, the cation uptake such as copper by clay minerals is strongly inhibited by hydrogen and aluminum ions and thus is not economically significant factor for recovery of metals such as uranium and copper. In acidic solutions, the cation uptake is substial. Swelling is minimal at lower pH, possibly due to lattice collapse. Swelling may be controllable with montmorillonite type clays by exchanging interlayer sodium with lithium and/or hydroxylated aluminum species. The effect of add on clay minerals are : 1. Division of aggregates into smaller plates with increase in surface area and porosity. 2. Clay-acid reactions occur in the following order: (i) $H^+$ replacement of interlayer cations, (ii) removal of octahedral cations, such as Al, Fe, and Mg, and (iii) removal of tetrahedral Al ions. Acid attack initiates, around the edges of the clay particles and continued inward, leaving hydrated silica gel residue around the edges. 3. Reaction rates of (ii) and (iii) are pseudo-1st order and proportional to acid concentration. Rate doubles for every temperature increment of $10^{\circ}C$. Implications in in-situ leaching of copper or uranium with acid are : 1. Over the life span of the operation for a year or more, clays attacked by acid will leave silica gel. If such gel covers the surface of valuable mineral surfaces being leached, recovery could be substantially delayed. 2. For a copper deposit containing 0.5% each of clay minerals and recoverable copper, the added cost due to clay-acid reaction is about 1.5c/lb of copper (or 0.93 lbs of $H_2SO_4/1b$ of copper). This acid consumption by clay may be a factor for economic evaluation of in-situ leaching of an oxide copper deposit.

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A Study on the Factors Influencing the Acceptance of K-pop Short-form Video Created by Chinese Influencers - Focusing on Chinese TikTok Users (중국 인플루언서들의 K-pop 짧은 동영상 수용에 영향을 미치는 요인에 관한 연구 - 중국 '틱톡' 사용자를 중심으로)

  • Liu, QuanQuan;Yu, Sae-Kyung
    • The Journal of the Korea Contents Association
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    • v.22 no.4
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    • pp.28-36
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    • 2022
  • This study analyzed 284 K-pop song and dance cover short-form videos recreated by Chinese influencers uploaded on TikTok, to explore which reform factors of image similarity, language similarity, the extent of audience participation leading, the extent of lyrics or subtitles translated into Chinese, PPL disclosure, the length of video and the reputation of influencer affected Chinese TikTok audiences' reactions - number of "Likes," "Comments" and "Shares." The results showed that only the "reputation of influencer" was significantly affected the number of "Likes" which estimated as a relatively passive response, but the other factors affected the number of "Comments" and "Shares" significantly which estimated as more active responses. The more an influencer is perceived as not similar to the singer in terms of image the more comments were posted. And the videos expressed in Korean archived more comments and shares than those lyrics or subtitles translated into Chinese. This study is meaningful in that it confirmed the necessity of influencers in the globe diffusion of K-pop, by specifically analyzing the audience's reactions according to the characteristics of UCCs created by local influencers using short-form video platforms.

Reduction Characteristics of Hexavalent Chromium in Cement/Fe(II) Systems

  • 강희석;서진권;황인성;박주양
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.233-236
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    • 2002
  • 다양한 산업활동에 의하여 발생하는 6가 크롬 (Cr(Ⅵ))은 대표적인 토양 및 지하수 오염물질이다. Cr(Ⅵ)은 3가크롬(Cr(III))로의 환원에 의한 침전반응으로 이동성이 저하된다고 알려져 있다. 본 연구에서는 기존의 고형화/안정화 공정에 환원.분해 반응을 추가한 2가철 기반 분해성 고형화/안정화(Degradative Solidification/Stabilization)공정에 의한 Cr(Ⅵ) 처리 특성을 고찰하였다. 회분식 실험결과 cemen/Fe(II) system내에 Cr(Ⅵ)은 환원반응 뿐만 아니라 cement에 의한 침전에 의해서도 제거됨이 밝혀졌다. Cr(Ⅵ)의 제거속도는 Fe(II)의 반응당량에 비례하는 것으로 보여진 반면, cement/solution ratio에 따른 Cr(Ⅵ) 제거동역학의 차이는 그다지 크지 않았다

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A study on the driver training simulator for train (전동차 모의운전 시뮬레이터에 관한 연구)

  • Kim, Bong-Taek;Choi, Sung
    • Proceedings of the Korea Technology Innovation Society Conference
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    • 1999.05a
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    • pp.11-20
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    • 1999
  • 전동차 시뮬레이터는 제한된 공간상에서 영상 및 음향, 운동, 운전석에 있는 각종 계기와 모니터 시스템들을 이용해 운전자에게 실제 주행하고 있다는 현실감을 제공하는 일종의 가상현실 장비이다. 시뮬레이터의 유효성은 각종 차량 특성과 운전조건 변화에 대해 CAB 상의 승무원에게 실제에서 경험할 수 있는 각종 주행환경을 제공하는 데 있다. 주행 현실감을 확보하기 위해서는 CAB 승무원에게 소리, 영상, 운동, 촉각 신호 등과 같은 큐(Cue)를 현실적으로 제공해야 한다. 대부분의 큐는 운전자의 조작 명령에 반응하는 차량의 동특성 해석을 통해 결정되어 시각, 음향, 모니터 등에 제공된다. 그러므로, 시뮬레이터 운용에 있어서 핵심적인 위치를 차지하고 있는 실시간 전동차 시뮬레이션 시스템의 전동차 모델은 차량의 운동을 현실적으로 모사할 수 있어야 하며, 실시간으로 시뮬레이션 되어야 하는 서로 상충되는 조건을 만족시켜야 한다. 실시간 전동차 시뮬레이션을 수행하기 위해서 특히 공학적으로 검토되어야 할 요소는 전동차 모델의 적절성, 적분기법, 운용 소프트웨어 및 실시간 시뮬레이션용 컴퓨터 등에 관하여 연구하였다.

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Derivation of benchmark dose lower limit of lead for ADHD based on a longitudinal cohort data set (동집단 자료의 주의력 결핍 과잉행동 장애를 종점으로 한 납의 벤치마크 용량 하한 도출)

  • Kim, Byung Soo;Kim, Daehee;Ha, Mina;Kwon, Ho-Jang
    • Journal of the Korean Data and Information Science Society
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    • v.25 no.5
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    • pp.987-998
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    • 2014
  • The primary purpose of this paper is to derive a benchmark dose lower limit (BMDL) of lead for the attention deficit/hyperactive disorder (ADHD) based on a longitudinal cohort data set which is referred to as CHEER data set. The CHEER data were recently recruited from the Ministry of Environment of S. Korea to investigate the effect of environment on children's health We first confirm the correlation of ADHD with the blood lead level using a linear mixed effect model. We report from the longitudinal characteristic of CHEER data that ADHD scores tend to have "regression to the mean". A dose-response curve of blood lead level with ADHD being the end point is derived and from this dose-response curve a few BMDLs are derived based on corresponding assumptions on the benchmark region.

Study on the Deactivation Trends of Liquid Fuel According to the Types of Endothermic Catalyst in Flow Reactor (흐름형 반응기 내에서 액체연료의 흡열반응촉매 종류에 따른 비활성화 정도에 대한 연구)

  • Lee, Tae Ho;Jeon, Sunbin;Kim, Sung Hyun;Jeong, Byung Hun;Han, Jeong Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.5
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    • pp.81-87
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    • 2018
  • In hypersonic aircraft, increase of aerodynamic and engine heat lead thermal load in airframe. It could lead structural change of aircraft's component and malfunctioning. Endothermic fuels are liquid hydrocarbon fuels which absorb the heat load by undergoing endothermic reactions. In this study, we investigated the relationship between product, coke formation and catalytic properites of endothermic catalysts by using exo-tetrahydrodicyclopentadiene as a fuel in a fixed bed flow reactor similar to the actual reaction conditions.

Content Analysis on the Characteristics of News-related Videos and Users' Reactions in the Local Broadcasting YouTube News Channels (지역 방송사 유튜브 뉴스 콘텐츠 특성과 이용자 반응에 관한 내용분석)

  • Joo, Eunsin
    • The Journal of the Korea Contents Association
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    • v.20 no.9
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    • pp.169-186
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    • 2020
  • This study aims to examine the characteristics of news content and users' reactions in local broadcasting Youtube news' channel, and explore how the local media should response in the new online video environment. YouTube Open API sampled 3,950 news-related videos uploaded over a month on 31 YouTube news channels nationwide. The content analysis was performed on the basis of the analysis of individual videos, such as characteristics of each content and users' reactions. As a result, a few news channels have produced digital-only content, but the ratio has been very low, most were broadcast replay videos with titles and formats uploaded as they were. In some cases, it still operates as a comprehensive channel, which failed to show its expertise as an independent digital news platform. This shows that theses YouTube channels lacks differentiation from TV or its own web page, and is still skewed to the auxiliary role or online archive function of TV platform. Nevertheless, digital-only content, which can be a national issue based on regional expertise, has led to a higher number of views and users reactions, suggesting that is a realistic and effective strategy with expandability in online space in the future.