• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.348-352
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• 2011

In this research, we have synthesized new pendant-type polyurethane polymers by introducing various chromophores with stilbene derivatives in the side-chain of the polymer backbone. The Stilbene monomers, N,N-bis(2-hydroxyethyl) amino-4'-cyanostilbene, N,N-bis(2-hydroxyethyl)amino-4'-methoxy stilbene, N,N-bis(2-hydroxyethyl)amino-4'-acetylstilbene, and N,N-bis(2-hydroxyethyl) amino stilbene, were synthesized by Wittig reaction. Another stilbene monomer, N,N-bis(2-hydroxyethyl)amino-4'-nitrostilbene, was synthesized by Knoevenagel condensation. By the measurement of UV-Vis absorption and Photoluminescence (PL) spectrum, we found that introduction of the electron-withdrawing group as a substituent shifts both UV-Vis and PL spectra to longer wavelength, and the introduction of the electron-donating group results in blue-shift of the spectrum. In case of polymer with $NO_2$ group as a substituent, PL is quenched.

• The Journal of the Korea Contents Association
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• v.8 no.2
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• pp.182-194
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• 2008

Corporate managers look at IT outsourcing as long-term strategic choices not as short-term tactical ones, and maximizing the effect that IT outsourcing brings about is the main concern to them. Emerging different types of IT outsourcing and their effects on the corporate business decisions necessitate the research on this subject. According to previous researches, the Intent for IT outsourcing is categorized as IS Improvement, Business Impact, and Commercial Exploitation. The decison factors for these IT outsourcing include corporate strategy types, IT role, and interaction between these two. Firm size and IT maturity are selected as moderating factors to add the credibility to the research of the effect of IT outsourcing decision making. Analyzing collected data revealed that corporate strategy rather than IT role is more significant factor affecting the intent for IT outsourcing decision. Defenders(as in corporate strategy types) tend to use IT outsourcing more as a means to improve information systems, compared to analyzers and reactors. Prospectors tend to use IT outsourcing more as a commercial exploitation, compared to analyzers and reactors. These outcomes prove that corporate strategy characteristics reflect outsourcing intent. There were previous researches that showed outsourcing decision depends on IT role, however the hypothesis was rejected that IT role determines outsourcing intent. It was also rejected that the interaction between corporate strategy types and IT role determines outsourcing intent. Corporate decision makers should first analyze corporate strategy, and reflect it on the outsourcing intent when they make IT outsourcing decisions. Only the precise defining of IT outsourcing intent will lower the risk and increase the possibility of success.

• Korean Journal of Comparative Education
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• v.28 no.2
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• pp.77-95
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• 2018

This study introduces the Classroom Assessment Scoring System (CLASS) and explores the characteristics of CLASS for observing classroom. The CLASS is a standardized observation instrument that was largely developed for use in the USA. The CLASS attempts to provide a conceptual framework for categorizing classroom interactions and consists of three broad domains of quality (emotional supports, classroom organization, instructional supports). We simulated this method to the elementary school classes. The professional-teacher makes the best use of student's initiation behaviors, and the novice teacher focused on the leading the contents of subject. The novice teacher tyr to make more positive climate and to present more frequent feedback to students than professional teacher's classroom. The professional teacher would like to reveal the student's opinions, questions and subtle emotional state. The CLASS can be used to collect data on a wide range of specific aspects of the teaching and learning process at any given time.

• Polymer(Korea)
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• v.28 no.2
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• pp.177-184
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• 2004

Polymer-clay nanocomposite containing the low amounts of clay shows improved physical, mechanical properties. In this study, allyl ester prepolymer was synthesised by reactions of the diallyl terephthalate monomers and the 1,3-butanediol monomers. Nanocomposites of allyl ester prepolymer and the two kinds of the organically layered silicate were prepared by using the intercalation method as well as the in-situ polymerization method using. By varying the amount of clay content, curing conditions, and feeding conditions. the nanocomposite was studied using X-ray diffraction. From XRD results, allyl ester-Cloisite 30 B nanocomposite made by the in-situ polymerization method shows better exfoliation behavior compared with the intercalation method. It can be said that the transesterification reaction between functional groups (-OH) of intercalant and monomers results in the increased gallery distance. Also mechanical and thermal properties indicate that the dispersity of clay is an important factor for improving physical properties of the nanocomposite.

• Korean Journal of Microbiology
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• v.46 no.2
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• pp.122-126
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• 2010

RAD53 functions as an effector kinase of checkpoint pathways in Saccharomyces cerevisiae, which plays a central role to regulate many downstream cellular processes in response to DNA damage. It also involves in transcriptional activation of various genes including RNR genes which encode the key enzyme required for dNTP synthesis. In this study, we identified CYC8 as a suppressor for the hydroxyurea sensitivity of $rad53{\Delta}$ mutation. $Rad53{\Delta}$ mutant transformed with a multi-copy plasmid containing CYC8 showed increased hydroxyurea resistance. In contrast, TUP1 which forms a complex with CYC8 did not function as a suppressor. In the case of mutations, both $cyc8{\Delta}$ and $tup1{\Delta}$ suppressed hydroxyurea sensitivity of $rad53{\Delta}$. Since CYC8 can propagate as a prion in yeast, overexpression of CYC8 induced misfolding of the normal CYC8 proteins, resulting in dominant cyc8-phenotype. Therefore, it is suggested that CYC8 can act as a multi-copy suppressor due to its prion property. It was observed that the levels of RNR transcription were increased in the yeast strains containing either multi-copies of CYC8 gene or $cyc8{\Delta}$ mutation, suggesting that the increased level of RNR will elevate the intracellular pools of dNTPs, which, in turn, suppress the phenotype of $rad53{\Delta}$ mutation.

• Polymer(Korea)
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• v.30 no.6
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• pp.512-518
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• 2006

A biodegradable polymer poly((R) -3-hydroxybutyric acid) (PHB) was conjugated with a hydrophilic polymer poly(ethylene glycol) (PEG) by the ttansesterification reaction to form the amphiphilic block copolymer. PHB with low molecular weight ($3000{\sim}30000$) was appropriated for the drug delivery materials. High molecular weight PHB was hydrolyzed by an acid-catalyst to produce the low molecular weight one. Amphiphilic block copolymer was formed the self-assembled polymeric micelle system in the aqueous solution that the hydrophillic PEG was wraped the hydrophobic PHB. Generally, polymeric micelle forms the small particle between $10{\sim}200nm$. These polymeric micelle systems have been widely used for the drug delivery systems because they were biodegradable, biocompatible, non-toxic and patient compliant. The hydroxyl group of PEG was substituted with carboxyl group which has the reactivity to the ester group of PHB. Amphiphilic block copolymer was conjugated between PHB, and modified PEG at $176^{\circ}C$ which was higher than the melting point of PHB. Transesterification reaction was verified with DSC, FTIR, $^1H-NMR$. In the aqueous solution, critical micelle concentration (CMC) of the mPEG-co-PHB copolymer measured by the fluororescence scanning spectrometer was $5{\times}10^{-5}g/L$. The shape and size of the nanoparticle was taken by dynamic light scattering and atomic force microscopy. The size of the nanoparticle was about 130 nm and the shape was spherical. Our polymeric micelle system can be used as the passive targeting drug delivery system.

• Polymer(Korea)
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• v.38 no.2
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• pp.180-187
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• 2014

Nanocomposites including graphene oxide (GO) and conducting polymers (PPy, PANI and PEDOT) were prepared via an in-situ chemical polymerization process, and their characteristic properties depending upon the change of conducting polymer (CP) content were analyzed. A confirmation was made on not only the functional groups formed in GO but also the presence of CP existent in the nanocomposites. The molecular interaction between GO and poly(4-styrene sulfonic acid) (PSSA) or CP in the nanocomposites was proposed. With the increase of PEDOT content in the GOPSS/PEDOT nanocomposite, the estimated value of $I_D/I_G$ regarding the Raman analysis of them was decreased and a major change of their Raman spectra characteristic peaks was observed. In the GO-PSS/PEDOT nanocomposite, PEDOT molecules made an exfoliation of GO-PSSA layers and thus they were intercalated among layers. Such a unique molecular morphology induced the highest electrical conductivity for the GO-PSS/PEDOT nanocomposite among three kinds of nanocomposites prepared in this study. It is also noted that the uniform morphology confirmed in this study helped a thermal stability improvement in the nanocomposite due to the presence of GO or GO-PSSA acting as a thermal barrier.

• Polymer(Korea)
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• v.28 no.1
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• pp.35-40
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• 2004

The formation mechanism of void defect which deteriorate composite's property is various according to each composite process. In this paper, void formation and growth mechanism is analyzed by thermal analysis and GC/MS. We made a vacuum chamber for observing pressure effect. Thermal analysis has been done in various condition. Elements of volatiles during resin curing were turned out by GC/MS. The most of volatiles of polyester were composed of styrene (over 80%) and a small quantity of toluene. In case epoxy resin, butyl glycidyl ether was the main element of volatiles (over 90%). We concluded that the original sites of void growth existed in resin and they were eliminated by vacuum and heating process. And the growth of void was influenced by water, diluents, solvent, and reactants in resin.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.296-300
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• 2007

우리나라에 내리는 대부분의 강수량은 6월${\sim}$8월의 장마기간 혹은 태풍의 영향으로 인해 발생한다. 특히 국지적으로 발생하는 집중호우로 인해 많은 인명, 재산 피해 등이 발생한다. 우리나라에서 집중호우로 인한 피해는 거의 매년 발생하고 있으며, 집중호우의 발생 지역은 특정 지역에 국한되어 있지 않다. 따라서 집중호우 발생으로 인한 피해 방지를 위해 사전에 충분한 준비를 해야 한다. 2006년 7월 8일부터 10일까지 3일 동안 진주지역 306.5mm, 합천지역 259.5mm, 산청지역 366.0mm의 집중호우가 발생하였으며, 이 기간 동안 이들 지역 외에도 전국적으로 태풍 에위니아(EWINIAR)의 영향으로 많은 호우가 발생하였다. 본 연구에서는 2006년 7월 진주지역 집중호우 특성 연구를 위해 진주지역 시강우 자료를 이용하여 자료를 분석하였다. 시강우 자료를 이용하여 진주지역 재현기간별 확률강우량을 산정하였고 2006년 7월 8일부터 10일까지의 강우분포형태를 설계강우분포형과 비교하였다. 또한 2006년 7월 발생했던 진주지역 집중호우의 무차원 누가곡선을 작성하여 분석을 실시하였다. 분석 결과 일최대 강우량의 경우 그 크기가 50년 혹은 80년 이내였으며, 강우분포형의 경우 하천정비기본계획의 경우 Mononobe 중앙집중형이였지만, 지난 호우의 경우 후방위의 강우가 연속적으로 발생한 형태였다. 또한 대부분의 강우가 6시간 이내에 내려 첨두홍수 발생에 많은 영향을 미쳤을 것으로 판단된다. 앞으로 이상기후와 같은 자연 현상에 대비하기 위해서는 단시간 호우에 대한 정확한 분석과 강우분포에 대한 연구가 더욱 필요할 것으로 생각된다.적자색의 미려한 결정이 석출되므로 이 결정을 여과하여 ethanol로 세척하고 진공 desiccator중에서 건조시켰다. 수득량 1.2~1.3g.)와의 조환가는 11.9565의 상인연소현상을 보였다. 삭과색(Y) 경색(R) 유전자간에는 어느것이나 연소현상이 보이지 않았다. 4. 단일반응성의 변이는 연소적이며 우성은 거의 인정되지 않았고 인자간의 상호작용도 인정되지 않았으며 상가적 유전을 보였다. 광의와 협의의 유전력은 각각 89.50%로서 실용적으로 대단히 높은 것으로 생각되었으며 단일반응성에 관여하는 유전자수는 2대의 인자로 추정하였고 다시 양친의 유전자형을 aabb AABB라고 측정하여 각인자의 작용가는 11.136일로 산출되었고 분해법에 의한 유전분석결과 유전자형의 관찰빈도분포와 이론빈도분포는 서로 잘 적합되었다. 단일반응성에 있어서 유전력이 대단히 높았으므로 비교적 초기세대에서 본 형질의 선발이 가능할 것 같았다. 5. 단일반응성과 엽형 및 엽병색 유전자와의 사이에 $F_2$, $BC_1$ 및 $BC_2$에서 각각 유의적인 상관관계를 볼 수 있었으므로 이들 형질간에 연소가 있는 것으로 인정되었다. 더욱 엽형과 엽병색과의 연소가 있는 것으로 인정되는 이상단일반응성 유전자와의 사이에 연소군이 인정된다. 6. 섬유중 유전자와 엽병색 및 엽형유전자와의 사이에 $F_2$$BC_1$ 및 $BC_2$에서 각각 유의적 상관관계를 볼 수 있었으므로 이를 형질간에 연소가 있는 것으로 인정되었다. 더욱 엽형과 엽병색과의 연소가 있는 것으로 인정되는 이상 섬유중 유전

• Polymer(Korea)
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• v.38 no.6
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• pp.801-808
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• 2014

Ion diffusion and chemical binding to acrylic polymer were investigated in a solid film. The composition of acrylic monomers containing amino group and carboxylic acid was adjusted for rapid ion migration in the film. p-Methylred (PMR) and phenolphthalein derivatives were optically sensitive to the concentration of proton and hydroxyl anion, respectively and verified the ion migration through the film layers. A rapid proton migration was observed in the film of a high amino content. On the other hand, $OH^-$ migration occurred rapidly in a high content of carboxylic acid group. The proton migration occurred through the internal layer as well as surface layer of a film and was reversible during 50 repetition examination. Copper(II) ion migration was examined with a Rhodamine-containing polymer film. The light absorption and emission spectra of a Rhodamine-Cu complex showed the key contribution of carboxylic acid group to the Cu(II) migration in a film.