• Title/Summary/Keyword: 반응성 유동 분리

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Influence of Reaction Temperature on Bio-oil Production from Rice Straw by the Pyrolysis (볏짚으로부터 바이오오일 생산에 대한 열분해 반응온도의 영향)

  • Kang Bo-Sung;Park Young-Kwon;Kim Joo-Sik
    • Resources Recycling
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    • v.15 no.1 s.69
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    • pp.12-19
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    • 2006
  • Rice straw is one or the main renewable energy sources in Korea. Bio-oil is produced from rice straw with a lab-scale equipment mainly with a fluidized bed and a char removal system. It was investigated how the reaction temperature affected the production of bio-oil and the efficiency of a char removal system. To elucidate how the temperature depended on the production of bio-oil, experiments were conducted at $466^{\circ}C,\;504^{\circ}C\;and\;579^{\circ}C$, respectively. The mass balance was established in each experiment, and the produced gas and oil were analyzed with the aid of GCs and a GC-MS system. The char removal system is composed of a cyclone and a hot filter. Tn the experiments, we observed that the production of bio-oil was decreased with temperature, and the bio-oil contained very useful chemicals.

Numerical Modeling of Turbulent Open Channel Flow Downstream of a Drop Structure (하상단차 하류부 난류흐름 거동 수치모의)

  • Kim, Byung Joo;Paik, Joong Cheol
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.244-244
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    • 2021
  • 난류흐름 거동은 지형이나 수공구조물과 같은 고체 경계면의 변화에 민감하게 반응하며 특징 또한 다양하다. 보나 여수로 등과 같은 단차 구조물을 통과하는 흐름은 구조물의 모서리 같은 흐름 경계면이 급변하는 지점에서는 흐름분리(flow separation)가 발생하는 것이 특징이다. 이러한 흐름분리로 인해 전단층이 발생하며 흐름 재순환(recirculation)이 구조물 하류부에 형성된다. 이 연구에서는 낙차공 형식의 단차 구조물 하류부에서의 흐름 거동을 이해하기 위해 CFD모델링을 통하여 계산된 3차원 유동장을 분석한다. 난류 모의는 하이브리드 LES(large-eddy simulation)/RANS 계산 기법인 IDDES(improved delayed detached-eddy simulation)기법을 적용한다. IDDES의 기본 모형으로는 k-ω SST모형과 Spalart-Allmaras모형을 이용하여 두 모형의 성능을 평가한다. 자유수면의 변동은 VoF(volume of fluid)기법을 이용하여 계산하며, 각 지배방정식은 최소의 수치분산을 유지하면서 수치해의 안정성을 확보할 수 있는 2차 정확도의 유한체적법을 이용하여 이산화하였다. 수치해석 결과는 레이놀즈수 23,400과 후르드수 0.22의 조건에서 기존에 계측된 자료와 비교하여 수치모형의 정확도를 평가하고 하상 단차 하류부에서의 흐름 거동 특성을 분석한다. 계산 결과는 공학적으로 널리 사용되는 RANS 수치모의에서 볼 수 없는 전단층과 난류구조의 동적 거동 특성과 이에 따른 레이놀즈 응력분포의 특성을 설명해준다.

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Recent Progress in the Catalytic Decomposition of Methane in a Fluidized Bed for Hydrogen and Carbon Material Production (수소 및 탄소소재 생산을 위한 메탄 유동층 촉매분해 기술의 최근 동향)

  • Keon Bae;Kang Seok Go;Woohyun Kim;Doyeon Lee
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.175-188
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    • 2023
  • Global interest in hydrogen energy is increasing as an eco-friendly future energy that can replace fossil fuels. Accordingly, a next-generation hydrogen production technology using microorganisms, nuclear power, etc. is being developed, while a lot of time and effort are still required to overcome the cost of hydrogen production based on fossil fuels. As a way to minimize greenhouse gas emissions in the hydrocarbon-based hydrogen production process, methane direct decomposition technology has recently attracted attention. In order to improve the economic feasibility of the process, the simultaneous production of value-added carbon materials with hydrogen can be one of the most essential aspects. For that purpose, various studies on catalysis related to the quality and yield of high-value carbon materials such as carbon nanotubes (CNTs). In terms of process technology, a number of the research and development of fluidized-bed reactors capable of continuous production and improved gas-solid contact efficiency has been attempted. Recently, methane direct decomposition technology using a fluidized bed has been developed to the extent that it can produce 270 kg/day of hydrogen and 1000 kg/day of carbon. Plus, with the development of catalyst regeneration, separation and recirculation technologies, the process efficiency can be further improved. This review paper investigates the recent development of catalysts and fluidized bed reactor for methane direct pyrolysis to identify the key challenges and opportunities.

Applicability Estimation of Ballast Non-exchange-type Quick-hardening Track Using a Layer Separation Pouring Method (층 분리주입을 이용한 도상자갈 무교환방식 급속경화궤도의 적용성 평가)

  • Lee, Il Wha;Jung, Young Ho;Lee, Min Soo
    • Journal of the Korean Society for Railway
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    • v.18 no.6
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    • pp.543-551
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    • 2015
  • Quick-hardening track (QHT) is a construction method which is used to change from old ballast track to concrete track. Sufficient time for construction is important, as the construction should be done during operational breaks at night. Most of the time is spent on exchanging the ballast layer. If it is possible to apply the ballast non-exchange type of quick-hardening track, it would be more effective to reduce the construction time and costs. In this paper, pouring materials with high permeability are suggested and a construction method involving a layer separation pouring process considering the void condition is introduced in order to develop ballast non-exchange type of QHT. The separate pouring method can secure the required strength because optimized materials are poured into the upper layer and the lower layer for each void ratio condition. To ensure this process, a rheology analysis was conducted on the design of the pouring materials according to aggregate size, the aggregate distribution, the void ratio, the void size, the tortuosity and the permeability. A polymer series was used as the pouring material of the lower layer to secure the void filling capacity and for adhesion to the fine-grained layer. In addition, magnesium-phosphate ceramic (MPC) was used as the pouring material of the upper layer to secure the void-filling capacity and for adhesion of the coarse-grained layer. As a result of a mechanics test of the materials, satisfactory performance corresponding to existing quick-hardening track was noted.

Treatment of Spent ion-Exchange Resins from NPP by Supercritical Water Oxidation(SCWO) Process (초임계수 산화공정에 의한 원전 폐수지 처리기술)

  • Kim, Kyeong-Sook;Son, Soon-Hwan;Song, Kyu-Min;Han, Joo-Hee;Han, Kee-Do;Do, Seung-Hoe
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.3
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    • pp.175-182
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    • 2009
  • The spent cationic exchange resins and anionic exchange resins were separated from mixed spent exchange resins by a fluidized bed gravimetric separator. The separated resins were identified by an elemental analysis and thermogravimetric analysis. The each test sample was prepared by diluting the slurry made by wet ball milling the cationic exchange resins and the anionic exchange resins separated as a spherical granular form for 24 hours. The resulting test samples showed a slurry form of less than $75{\mu}m$ of particle size and 25,000ppm of $COD_{cr}$. The decomposition conditions of each test samples from a thermal power plant were obtained with a lab-scale(reactor volume : 220mL) supercritical water oxidation(SCWO) facility. Then pilot plant(reactor volume : 24 L) tests were performed with the test samples from a thermal power plant and a nuclear power plant successively. Based on the optimal decomposition conditions and the operation experiences by lab-scale facility and the pilot plant, a commercial plant(capacity : 150kg/h) can be installed in a nuclear power plant was designed.

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Influence of Reaction Temperature on the Pyrolytic Product of Rice Straw by Fast Pyrolysis using a Fluidized Bed (볏짚의 급속 열분해 생성물에 대한 반응온도의 영향)

  • Kang, Bo-Sung;Park, Young-Kwon;Kim, Joo-Sik
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.47-58
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    • 2005
  • Rice straw is one of the main renewable energy sources in Korea, and bio-oil is produced from rice straw with a lab. scale plant equipped mainly with a fluidized bed and a char removal system. We investigated how the reaction temperature affected the production of bio-oil and the efficiency of a char removal system. To elucidate how the temperature depended on the production of bio-oil, experiment were conducted between $450^{\circ}C\;and\;600^{\circ}C$ with a feed rate of about 300g/h. The mass balance was established in each experiment, and the produced gas and oil were analyzed with the aid of GCs and a GC-MS system. The char removal system is composed of a cyclone and a hot filter. In the experiments, we observed that the optimum reaction temperature range for the production of bio-oil is between $450^{\circ}C\;and\;500^{\circ}C$.

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Modeling and Characteristics of Ethanol Fermentation Process Combined with Pervaporation (투과증발과 결합된 에탄올 발효 공정의 모델링 및 특성)

  • 최은수;김진현;유영제
    • Microbiology and Biotechnology Letters
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    • v.20 no.4
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    • pp.451-458
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    • 1992
  • Pervaporation which is capable of removing ethanol selectively was adopted to reduce the ethanol inhibition and in situ recovery of ethanol in ethanol fermentation, The composite membrane made of silicone and polysulfone was used to separate the ethanol selectively. The ethanol selectivity of the membrane was about 4 and the total flux was 300 g/m2 h at 301:: and 10 mmHg for 25 g/l of feed concentration. Saccharomyces cerevisiae entrapped within Ca-alginate gels was employed for ethanol fermentations in a fluidized-bed bioreactor. The pervaporation membrane unit and fluidized-bed bioreactor were combined into one system. The proposed model equations for the combined system showed good accordances with the experimental results. It was found from the simulation results that the ethanol concentration in the broth for the combined system was lower than that for the continuous fermentation system without a membrane unit. Ethanol productivity can be thus increased by employing the combined system.

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Treatment of dyeing wastewater using Moving Bed Bioractor (부유메디아 생물막 공정을 이용한 염색폐수처리)

  • Shin, Dong-Hoon;Lee, Sang-Hun;Ryu, Seung-Han;Park, Jun-Hyung;Jo, Seog-Jin
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.110-110
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    • 2011
  • 염색공업 폐수는 그 성분이 일반적으로 매우 복잡하며, 작업공정의 가동 사항에 따라 수질 변동이 큰것이 특징으로, 각 공정에서 배출되는 염료, 보조화학물질, PVA(Polyvinyl alchol), 전분, wax 등이 포함되어 있으며 pH가 높고, 색도로 인해 하천에 방류될 경우 확산성이 높아 미생물에 의한 자정작용을 방해하여 하천의 수중생태계를 파괴할 우려가 있다. 이러한 염색산업에서 발생하는 폐수는 일반적으로 응집침전, 부상분리법 등의 전처리한 후 활성오니공정으로 처리하는 방법이 널리 이용되고 있으나, 이들 처리공정으로는 폐수 속에 포함되어 있는 다양한화학적 구조의 색소성분 및 유해물질을 완벽하게 제거하는 것이 어려운 실정이다. 유기물 함량이 높은 염색폐수를 처리하기 위해 제안된 기술로는 산소활성슬러지법, 유동상 및 고정상 생물막법, 포괄고정화법 등이 있다. 이러한 기술들중 기존의 처리공정을 증축없이도 처리효율을 높일 수 있는 방법으로 담체를 이용한 부유메디아 생물막공정(Moving-Bed BioReactor, MBBR)이 있다. 이공정은 미생물이 부착, 성장할 수 있는 공극율과 비표면적이 큰 담체를 이용하므로 반응조내의 부유 미생물 뿐만 아니라 담체에 고농도로 부착된 부착 미생물에 의해서도 유기물을 제거하기 때문에 다른 공정들에 비해 처리효율이 뛰어나고 기존의 활성슬러지 공정에 비해 갑작스러운 부하변동 및 유독성 폐수유입에 대해서도 안정적으로 운전이 가능한 장점이 있다. 본연구에서는 부유메디아 생물반응기(Moving-Bed BioReactor, MBBR)을 이용하여 염색폐수내 $COD_{Mn}$, 색도 및 난분해성 물질인 PVA 저감에 대한 Lab-scale test 수행하였다. 실험에 사용된 염색폐수의 수질은 평균 pH 13, $COD_{Mn}$ 900 mg/L, SS 135 mg/L, 색도 1,134 [C.U.], PVA 593 mg/L였으며, 2L의 반응기를 사용하여 회분식 실험을 수행였다. 본 실험에서는 호기성 미생물에 의한 염색폐수의 생분해가 유지되는데 필요한 최적의 용존산소 농도와 이에 필요한 공기 폭기량을 결정하기 위하여 i) DO uptake rate측정과 ii) 담체의 충진율, iii) COD/N ratio, iv) Air 유량, v) 담체내 흡착제의 종류, vi) $Ca^{2+}$ 첨가가 염색폐수의 생분해에 미치는 영향을 살펴보았다. 운전시간을 7일로 하여 COD, 색도, PVA 등을 측정한 결과 담체를 첨가한 경우가 담체를 첨가하지 않은 경우 보다 제거효율이 뛰어났다. 특히 충진율 30%(C/N 3)의 경우에서 COD, 색도, PVA의 제거율이 각각 평균 65%, 70%, 60%로 가장 높은 제거효율을 나타내었다.

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Hydro-ecological characterizations in groundwater dependent ecosystem (지하수 종속 생태환경에서 수문-생태학적 특성 조사 및 분석)

  • Kim, Hee-Jung;Hyun, Yun-Jung;Lee, Kang-Kun
    • Journal of Wetlands Research
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    • v.11 no.3
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    • pp.1-8
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    • 2009
  • The groundwater dependent ecosystem associated with a natural stream is the area where mixing and exchange of surface water and groundwater occurs due to large chemical and hydraulic gradients. Surface-groundwater interactions play an important role in biogeochemical processes in groundwater dependent ecosystems and make this area a hydro-ecological hot spot. The objective of this study is to characterize the groundwater dependent ecosystem in a natural stream where nitrate contamination of stream water is observed by means of hydrogeological, chemical, and biological methods. In this study, vertical flow exchange(hyporheic flow) rates between stream and groundwater were estimated based on vertical hydraulic gradients measured at mini-piezometers of various depths. To investigate the biological natural attenuation potential, biological analyses using polymerase chain reaction(PCR)-cloning methods were performed in this study. Results show that the veritical hyporheic water fluxes affect nitrate concentrations and bacterial densities in groundwater dependent ecosystems to some degree. Also, denitrifying bacteria were identified in hyporheic soils, which may support the biodegradation potential of the groundwater dependent ecosystems under certain conditions.

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A Monitoring System based on Layered Architecture (계층형 구조를 기반으로 한 모니터링 시스템)

  • Kwon Sung-Ju;Choi Jae-Young;Lee Ji-Soo
    • Journal of KIISE:Computer Systems and Theory
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    • v.33 no.7
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    • pp.440-447
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    • 2006
  • Grid computing is the complex deployments of various hardware and software components. The Grid environment should provide a mechanism for real-time monitoring and notification. It is very important to implement a monitoring mechanism in the Grid environment. Most existing monitoring systems only focus on their own requirements. With the development of Grid computing technology, the extensible monitoring systems become more and more feasible and popular. In this paper, we describe our research and development works on M-Mon, a novel framework for the flexible and adaptive Grid monitoring system. M-Mon system focuses on some critical issues like scalability, reusability, runtime extensibility, protocol transparency and uniform data representation. To provide interoperability with other monitoring systems and to reuse legacy facilities with a minimum effort, our monitoring system has been developed using service-oriented architecture.