• Title/Summary/Keyword: 반응성 상호작용

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Photocatalysis and Adsorption of Reactive Black 5(RB5) by HAP/TiO2 Media (HAP/TiO2 여재를 이용한 Reactive Black 5(RB5)의 광촉매 반응과 흡착)

  • Chun, Sukyoung;Chang, Soonwoong
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.11
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    • pp.31-37
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    • 2011
  • This study investigated on the adsorption and photocatalysis of Reactive Black 5(RB5) by the hydroxyapatite(HAP)/Titanium dioxide($TiO_{2}$) media. The adsorption of RB5 on $TiO_{2}$, HAP and $TiO_{2}$/HAP was investigated during a series of batch adsorption experiments. The amounts adsorbed at equilibrium were measured. Langmuir and Freundlich isotherm models were tested for their applicability. The result of equilibrium studies of $TiO_{2}$, HAP and $TiO_{2}$/HAP adsorbent were found to follow Langmuir isotherm model. The adsorbed amounts(Qmax) were found to be 5.28mg/g on single $TiO_{2}$, 12.45mg/g on single HAP and 9.03mg/g on $TiO_{2}$/HAP, respectively. The experimental data were analysed using the pseudo-first-order adsorption and photocatalysis kinetic models. According to these models, RB5 degradation by $TiO_{2}$/HAP was affected by interaction effect of photocatalysis and adsorption.

Hierarchical Porous 3D gel of the Co3O4/graphene with Enhanced Catalytic Performance for Green Catalysis (녹색 촉매반응을 위한 코발트 옥사이드/그래핀의 계층적 다공성 3D 젤)

  • Jeong, Jae-Min;Jang, Sukhyeun;Kim, Yunsu;Kim, Hyun Bin;Kim, Do Hyun
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.404-409
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    • 2018
  • The integration of organic and inorganic building blocks into hierarchical porous architectures makes potentially desirable catalytic material in many catalytic applications due to their combination of dissimilar components and well-constructed reactant transport path. In this study, we prepared the hierarchical porous $Co_3O_4@graphene$ 3D gel by hydrothermal method to achieve high catalytic performance in PET glycolysis reaction. Obtained $Co_3O_4@graphene$ 3D gel consisted of interconnected networks of $Co_3O_4$ and graphene sheets, providing large number of accessible active sites for efficient catalytic reaction. These structural merits from synergistic effect of $Co_3O_4$ and graphene gave a high performance in the PET degradation reaction giving high conversion yield of BHET, fast degradation rate of PET, and remarkable stability.

Insecticidal Activation Mechanism of m-Methylphenyl N-methylcarbamate Derivatives (m-Methylphenyl N-methylcarbamate 유도체들의 살충활성 메카니즘)

  • Park, Seung-Heui;Nam, Sang-Kil;Sung, Nack-Do
    • Korean Journal of Agricultural Science
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    • v.22 no.2
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    • pp.127-133
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    • 1995
  • A Series of meta and para-substituted phenyl N-methylcarbamate derivatives were synthesized and influence of substituents(X) on the molecular orbital(MO) quantities of carbonyl group, carbamylation reaction center, and insecticidal activities($pI_50$) were discussed quantitatively. From these findings, the most stable streo conformer(Z) shows that the planer phenyl group occupies vertical(${\theta}=90^{\circ}$) position on the plane of the N-methylcarbamyl group. The carbamylation mechanism was proposed that the carbamylation process of acetylcholinesterase(ACh.E) by m-methyl substituted phenyl N-methylcarbamate derivatives proceeds via hyperconjugation of m-methyl group and carbonyl oxygene protonation, theromodynamically control reaction with acidic site of ACh.E.

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Pyriproxyfen Inhibits Hemocytic Phagocytosis of the Beet Armyworm, Spodoptera exigua (파밤나방(Spodoptera exigua)의 혈구세포 식균반응에 대한 피리프록시펜의 억제효과 Nalini Madanagopal)

  • Madanagopal, Nalini;Lee, Yong-Joon;Kim, Yong-Gyun
    • The Korean Journal of Pesticide Science
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    • v.11 no.3
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    • pp.164-170
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    • 2007
  • The concept of innate immunity in insects which refers to the first line of host defense constitutes the humoral and cellular components which are involved in recognition and actively participate in the elimination of the intruding foreign micro- or macro-organisms. Several recent studies suggest that juvenile hormone (JH) modulates the cellular immune reactions in response to pathogen. In this study, pyriproxyfen (a JH agonist as an insect growth regulator) was tested in its any inhibitory effect on the immune reactions of the beet armyworm, Spodoptera exigua. To this end, five different hemocyte morphotypes of final instar S. exigua were identified by phase contrast microscopy. Plasmatocytes and granular cells, which constitute about 90% of the total hemocyte count, were prominently distinguished based on their basophilic/acidophilic nature using Giemsa stain. The role of pyriproxyfen on the functional ability of hemocytes was analyzed using FITC-labeled Providencia vermicola for the phagocytic potential of the hemocytes. Both granular cells and plasmatocytes exhibited phagocytosis behavior. Pyriproxyfen significantly inhibited the phagocytosis of both cell types, proposing its novel action as an immunosuppressant.

Separation of water-soluble egg yolk proteins using polysaccharide (다당류를 이용한 수용성 난황 단백질의 분리)

  • Moon, Tae-Wha;Lee, Hyun-Jong
    • Applied Biological Chemistry
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    • v.36 no.4
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    • pp.296-303
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    • 1993
  • Response surface methodology was employed to investigate the conditions for separating water-soluble proteins from egg yolk using sodium alginate, propylene glycol alginate (PGA), sodium carboxymethylcellulose (CMC) and pectin which are approved as food additives. Effects of plysaccharide concentration and pH of the reaction system on protein and lipid contents in the supernatant were evaluated at respectively five and three levels of concentration and pH using rotatable hexagon design. Statistical analysis showed that pH of the system was a more important factor than polysaccharide concentration as it significantly affected all two responses. Separating conditions established by a graphical optimization technique were $0.23{\sim}0.25%$ of sodium alginate at $pH\;5.9{\sim}6.0$, $0.15{\sim}0.17%$ of PGA at $pH\;4.3{\sim}4.5$, $0.30{\sim}0.25%$ of CMC at pH 3.0, and $0.09{\sim}0.10%$ of pectin at $pH\;5.6{\sim}5.8%$.

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Viewers' Psychophysiological and Self-report Responses to 3D Stereoscopic Display (3D 영상의 입체성이 콘텐츠 특성에 따라 이용자의 심리적 반응에 미치는 효과 - 콘텐츠의 유인가와 각성도를 중심으로 -)

  • Lim, So-Hei;Chung, Ji-In
    • The Journal of the Korea Contents Association
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    • v.12 no.6
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    • pp.211-222
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    • 2012
  • There has been growing academic interest in revealing the effect of 3D stereoscopic displays, mostly based on the assumption that 3D would enhance the media user's psychological experiences. A 2(Display: 2D, 3D) x 2(Arousal: High, Low) x2(Valence: Positive, Negative) within-between subject experimental design, including both psychophysiological and self-report measurements, was employed to investigate if valence and arousal of the media content interact with the 3D stereo display. The results confirmed that 3D stereo significantly enhances the viewer's skin conductance level, while no meaningful difference for HR was found across the experimental conditions. The viewer's recall memory did not differ depending on the display type either. However, the viewer experienced a greater level of presence and liking of the content when the negative content was displayed in 3D stereo in comparison with the positive content. The practical implications of the results are further discussed.

Characteristics of Teacher Help and Student Response in Small Group Thinking Science Activities (Thinking Science의 모둠별 활동에 나타나는 교사 도움과 학생 반응의 특성)

  • Ha, Eun-Jung;Choi, Byung-Soon;Shin, Ae-Kyung;Kang, Seong-Joo
    • Journal of The Korean Association For Science Education
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    • v.26 no.2
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    • pp.212-221
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    • 2006
  • The purposes of this study were to examine the characteristics of teacher help in small group Thinking Science(TS) activities and analyze the way students respond to teacher help. For this study, twenty-four 5th grade and twenty-four 7th grade students were selected, to undertake TS activities. Out of the 8 activities students participated in, the verbal interactions in activity 4 and 6, by students in four small groups, which incorporated relatively active argumentation was analyzed. Students' cognitive level was identified through a science reasoning task and the students were grouped heterogeneously according to their cognitive level. This study showed that teachers predominately used simple confirmation questions in preference to metacognitive question. Also, teacher help varied according to one's personal traits, work experience and degree of activity recognition. It was discovered that when the teacher provided student appropriate metacognitive questions and sufficient feedback, students actively engaged in argumentation. On the other hand, when the teacher asked simple confirmation questions and interfered in the activity, students did not participate in argumentation actively.

Thermodynamics of Ti in Liquid 409L Stainless Steel (409L 스테인레스 용강내 Ti의 열역학적 거동)

  • 유진태;정용수;태순재;서석민;박종진;김동식;이용득
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.45-45
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    • 2003
  • 409L 페라이트강은 스테인레스강내 Ti을 첨가함으로써 내식성이 우수한 자동차 배기계 부품용으로 개발된 강이다. 그러나 Ti 첨가시 용존산소 및 질소와의 반응 생성물에 의해 용강의 주조성, 표면품질, 등축정율 저하등 조업 및 품질문제를 발생시킨다. 한편 용강의 응고시 생성되는 미세 질화물은 주편의 등축정율을 높혀, 주편의 가공성 및 최종제품의 품질을 향상시키는 것으로 알려져있다. 따라서 스테인레스 용강중 Ti의 반응 생성물 제어는 매우 중요하며, 이를 위해서는 고 Cr 함유 스테인레스 용강내 Ti의 열역학적 거동과 타 원소와의 상호작용계수를 측정하여야 한다.

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Cognitive-Motor Interaction-Based Instrument Playing for Improving Early Social Skills of Children With Autism Spectrum Disorder (ASD 아동의 초기 사회기술 향상을 위한 인지-운동 통합 기반 악기연주 중재)

  • Yu, Hyun Kyung
    • Journal of Music and Human Behavior
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    • v.20 no.1
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    • pp.75-97
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    • 2023
  • This study aimed to investigate the effect of cognitive-motor interaction-based instrument playing on the early social skills of children with autism spectrum disorder (ASD). Nine children with ASD, averaging 5.6 years of age, participated in twelve individual sessions lasting 30 minutes each. The intervention comprised five stages: self-regulation, motivation to engage in social interaction, acceptance of a partner in co-playing activities, interpersonal coordination with a partner, and engagement in joint music playing. To evaluate changes in early social skills, joint attention and social interaction behaviors were observed, and the Social Responsiveness Scale (SRS-2) was administered pre- and post-intervention. Social synchronization was measured through a dyadic drum task, measuring synchronization accuracy, duration, and timing. Following the intervention, all nine children demonstrated increased early social behaviors, although there were no significant differences in SRS scores. Moreover, synchronized movement improved significantly in accuracy and maintained duration but not in reaction time. This study highlights the significance of recognizing the cognitive-motor interplay as crucial element in facilitating early social skills development in children with ASD.

Congestion Control Method of Area of Interest in Distributed Virtual Environment (분산가상환경에서 참여자 관심영역의 혼잡도 조절기법)

  • 유석종
    • Journal of Korea Multimedia Society
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    • v.7 no.4
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    • pp.550-558
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    • 2004
  • Previous researches on scalability problem of distributed virtual environment (DVE) have been mainly focused on spatial partitioning of area of interest (AOI). Congestion phenomena by avatar groups in AOI have been neglected relatively However, AOI congestion is highly related to scalability of DVE because it exhausts system resources such as network bandwidth and rendering time, and could be a bar to perform collaboration among participants. In this paper, this will be defined as the problem that must be solved for the realization of the scalable DVE, and a model will be proposed to measure and control congestion situation in AOI. The purposes of the proposed model are to prevent high density of participants in AOI, and to protect stable collaboration in DVE. For evaluation of the performance it is compared with a previous method by defining the resource cost model which is dynamically activated to AOI congestion.

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