• Title/Summary/Keyword: 반응분석

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Optimization of Bleaching Conditions for Stain Removal in Japanese Hackberry (Celtis sinensis Persoon) Using Response Surface Methodology (반응표면분석법을 이용한 팽나무(Celtis sinensis Persoon)의 최적 변색제거조건 결정)

  • Kim, Sung-Hwan;Ra, Jong-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.3
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    • pp.191-198
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    • 2010
  • This research was performed to investigate the effect of hydrogen peroxide on the stain removal in japanese hackberry. Response surface method (RSM) was used to optimize the bleaching conditions such as reaction temperature, reaction time and the concentration of hydrogen peroxide. Fifteen different bleaching conditions were selected according to $2^3$ factorial central composite design (CCD). The bleaching effect were evaluated by lightness differences of wood surface before and after the bleaching. The RSM model was determined and its $R^2$ values were 0.93, showing it well represented the bleaching effect. The most affecting factor on the stain removal was the concentration of hydrogen peroxide, followed by reaction time and reaction temperature. Second degree of concentration was proved to have an effect on the bleaching. Bleaching rates above 3% concentrations of hydrogen peroxide were tended to be slightly decreased, and low bleaching effect was found at $20^{\circ}C$. The determined RSM model may offer very practical ways to obtain the desired levels of bleaching because it offers multiple solutions.

An Empirical Study on the Effects of e-Mail Marketing : A focus on e-Mail Campaign for Credit Card Consumers (이메일 마케팅 성과에 관한 연구: 신용카드 고객을 대상으로 한 캠페인을 중심으로)

  • Shin, Sung-Hoon;Chung, Soo-Yeon;Park, Cheol
    • Information Systems Review
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    • v.11 no.1
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    • pp.49-67
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    • 2009
  • E-mail marketing is the cheapest channel in target marketing. The channel works amazingly well for marketers who know how to use it. The e-mail marketers are able to integrate transactional and behavioral data to improve the targeting content of e-mail marketing campaigns. The cost in e-mail marketing is low and e-mail marketing makes no pollution. But, the e-mail response rate is lower than all the other channels. So, it is very hard for companies to increase their sales volumes, though the companies are ready to execute e-mail marketing campaigns on the side of computer systems. Marketers can send messages easily to target customers compared to other channels. But, the possibility to be read by the customers is low. Normal e-mails are continually devalued by spam mails. This study shows the influence of e-mail marketing to increase sales used by credit cards, on the basis of the real data promoted by A bank, in the Republic of Korea. The analysis on the traits of the respondent can help marketers to target customers. If additional studies on the response prediction model on the basis of traits of potential respondents are done, the targeting method to increase the effectiveness of e-mail marketing will be better structured and organized.

Hydrothermal Mechanism of Na-A Type Zeolite from Natural Siliceous Mudstone (규질 이암으로부터 Na-A형 제올라이트 수열합성 반응기구에 대한 연구)

  • Bae, In-Kook;Jang, Young-Nam;Chae, Soo-Chun;Kim, Byoung-Gon;Ryu, Kyoung-Won;Lee, Sung-Ki
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.3
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    • pp.223-229
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    • 2007
  • The mechanism of hydrothermally synthesizing Na-A zeolite from siliceous mudstone at a $Na_2O/SiO_2$ ratio of 0.6, a $SiO_2/Al_2O_3$ 2.0 and a $H_2O/Na_2O$ 119 has been observed by IR, DTA, XRD and SEM. This mudstone is a tertiary periodic sedimentary rock and widely spreads around the Pohang area. In the early hydrothermal synthesis at $80^{\circ}C$ in an autoclave, sodium silicate and sodium aluminate were found to be preferentially reacted to generate Na-A type zeolite. Gibbsite and bayerite were also formed due to the presence of extra aluminum oxide in the feedstock. As reaction time in-creased up to 50 h, residual sodium aluminatewas reacted with siliceous mudstone, causing the Na-A zeolite crystal to grow and the hydroxylsodalite to generate. Therefore, in the $14{\sim}50\;h$ synthetic time, Na-A zeolite and hydroxylsodalite were formed. Also, if reaction time passed over 50 h, a part of the Na-A zeolite was finally redissolved and reacted with hydroxylsodalite to synthesize Na-P zeolite, generating porous surface of Na-A zeolite and disappearing hydroxylsodalite.

액체 금속로의 가상 사고 해석

  • 석수동;한도희
    • Nuclear industry
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    • v.20 no.6 s.208
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    • pp.31-44
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    • 2000
  • 본 연구에서 액체금속로의 노심용융(core meltdown)으로 인한 초 즉발 임계(super-prompt critical)의 출력 폭주 사고시, 노심의 반응도 및 열수력 특성 변화와 에너지 방출량등을 계산하기 위하여, Bethe-Tait 방버론을 수정, 보완한 분석 모델이 개발되었다. 주요 보완 내용으로서는, 금속 연료 노심의 단상 액체 영역에서의 선형의(Linear) threshold 형태의 상태 방정식뿐만 아니라 포화 증기(saturated fuel vapor) 영역에서의 상태 방정식이 개발되었고, 이에 따른 노심 붕괴 반응도(disassembly reactivity)의 분석 모델이 개발되었다. 또한 도플러 반응도 효과를 고려하기 위한 분석모델도 아울러 개발되었다. 상기 보완 모델을 실행할 수 있는 수치 해석 프로그램이 개발되었고, 이를 활용하여 KALIMER에서 HCDA가 발생하였을 경우 노심에서의 에너지 방출량 계산이 수행되었다. 분석결과 도플러 효과와 포화 증기 영역에서의 압력 증가 및 노심팽창의 중요성이 확인되었다. 도플러 효과가 고려되지 않을 경우 HCDA는 분석된 모든 반응도 삽입률에 대하여 폭발적인 에너지 방출과 함께 사고가 종결되는 것으로 평가되었다. 그러나 도플러 상수가 최적 평가치인 -0.002인 경우 50$/s이하의 반응도 삽입률에서는 노심은 비등점(0.8KJ/g)에 도달치 않았으며, 설계 기준 사고인 100$/s의 경우에도 노심은 포화 증기 영역에 머물고 압력이 급격히 증가하는 단상(single phase)액체 영역의 threshold 값에 미치지 않기 때문에 사고는 핵연료 증기(vapor)의 점진적인 분산과 함께 종결되는 것으로 분석되며, 총 에너지 발생량은 약 1,800MJ로서 기계적 손상 에너지로 전환되는 분율을 고려할 때 KALIMER 원자로 용기의 구조 설계 기준치에 비해 상당한 여유도를 갖는 것으로 평가되었다.

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Evaluation of Concentration and Reaction Kinetics through Color Analyses (색상 분석법을 이용한 농도 및 촉매반응속도 측정)

  • Lee, Euna;Chang, Ji Woong
    • Applied Chemistry for Engineering
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    • v.33 no.3
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    • pp.279-283
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    • 2022
  • UV-vis spectroscopy is one of the powerful tools for measuring the concentrations of reactant and products during a chemical reaction. However, there is an limitation of using the technique when the reaction undergoes in high concentration and high temperature. Color analysis using camera images can provide the identical results with UV-vis analysis with regardless of the sample concentration and temperature. The catalytic reduction reaction of resazurin to resorufin was investigated using the color analysis with the color spaces such as CIE L*a*b*. Moreover, the color analysis enabled the independent analysis of two different material's concentrations without the deconvolution of overlapped wavelengths unlike the case of using UV-vis spectroscopy.

Comparative studies for the performance of a natural gas steam reforming in a membrane reactor (분리막 반응기를 이용한 천연가스 개질반응의 성능에 관한 비교 분석)

  • Lee, Boreum;Lim, Hankwon
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.95-101
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    • 2016
  • For a natural gas steam reforming, comparative studies of the performance in a conventional packed-bed reactor and a membrane reactor, a new conceptual reactor consisting of a reactor with series of hydrogen separation membranes, have been performed. Based on experimental kinetics reported by Xu and Froment, a process simulation model was developed with Aspen $HYSYS^{(R)}$, a commercial process simulator, and effects of various operating conditions like temperature, $H_2$ permeance, and Ar sweep gas flow rate on the performance in a membrane reactor were investigated in terms of reactant conversion and $H_2$ yield enhancement showing improved $H_2$ yield and methane conversion in a membrane reactor. In addition, a preliminary cost estimation focusing on natural gas consumption to supply heat required for the system was carried out and feasibility of possible cost savings in a membrane reactor was assessed with a cost saving of 10.94% in a membrane reactor.

계절·시간대별 차등요금에 대한 수용가의 반응성 분석 연구

  • Choe, Gi-Ryeon;Kim, Dong-Hyeon
    • Environmental and Resource Economics Review
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    • v.4 no.2
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    • pp.223-242
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    • 1995
  • 본 연구는 1977년 부터 한국에서 적용된 계절 시간대별 차등요금에 대한 반응성을 분석하기 위하여 각 요금적용시간대에 대한 전력소비의 탄력성을 1987년 1월부터 1992년 12월 까지의 자료를 이용하여 초월대수 비용 함수 (Translog Cost Function)을 이용하여 추정 분석하였다. 추정결과 낮 시간대, 저녁시간대, 밤 시간대에 대한 자기가격탄력성은 산업용(을) 고압 A 수용가의 경우 각각 -0.386, 0.351, -0.114이며, 고압 B 수용가는 각각 -0.095, -0.230, -0.192이었다. 일반적으로 대규모 수용가(고압 B)는 소규모 수용가(고압 A)에 비해 계시별 요금제에 대한 반응성이 더 낮은 것으로 나타났다. 한편 교차가격 탄력성 산출결과 상호 시간대간에 전력사용량의 대체성이 존재함을 알 수 있다. 즉, 산업용(을) 고압 A 수용가는 낮시간대와 저녁시간대간에 강한 대체성이 나타났으며, 산업용(을) 고압 B 수용가는 저녁시간대와 밤시간대간에 대체성이 높은 것으로 나타났다. 또한 계시별 요금제 구조의 변화에 따른 수용가의 반응성을 분석하기 위해 표본기간을 1987년 1월 부터 1989년 12월 까지(기간 I)와 1990년 1월 부터 1992년 12월 까지 (기간 II)로 분리하여 탄력성을 추정하였다. 기간 I에서는 계시별 요금제에 대한 수용가의 반응성이 아주 낮았으나, 기간 II에서는 현저하게 높아졌다. 이러한 결과로 보아 기간 II에서 시행된 1991. 6의 요금구조 개편은 수용가의 반응성을 증가시키는데 크게 기여하였으며, 이에 따라 계절 시간대별 차등 요금제가 부하관리를 위한 효율적인 방법임을 알 수 있었다.

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Molecular holographic QSPR analysis on the reactivity between glycine and ninhydrin analogues as latent fingerprints detector (잠재지문 검출제로서 Ninhydrin 유도체들과 Glycine과의 반응성에 관한 분자 홀로그래픽적인 QSPR 분석)

  • Kim, Se-Gon;Jang, Seok-Chan;Cho, Yun-Gi;Hwang, Tae-Yeon;Park, Sung-Woo;Sung, Nack-Do
    • Analytical Science and Technology
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    • v.20 no.4
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    • pp.339-346
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    • 2007
  • To search the ninhydrin derivatives that have high chromogenic and fluorogenic properties, molecular holographic quantitative structure property relationship (HQSPR) models on the reactivity between glycine and ninhydrin analogues as latent fingerprint detector were derived and investigated quantitatively. The ${\varepsilon}LUMO$ (e.v.) energy of ninhydrin molecule was an important factor to reactivity of ninhydrin. And, it is suggested that the nucleophilic reaction by orbital-controlled reaction from the frontier molecular orbital (FMO) interaction between glycine and ninhydrin derivatives was more superior than that of electrophilic reaction by charged controlled reaction. The analytical results in atomic contribution maps also shows that the reactivity of ninhydrin was increased by meta-substituents as strong electron withdrawing groups on the benzo ring. Therefore, it is sugested by HQSPR and QSPR model that the 5,6-dinitroninhydrin molecule would increase the reactivity as much as three times as compared to none substituted ninhydrin molecule.

Optimizing Coagulation Conditions of Magnetic based Ballast Using Response Surface Methodology (반응표면분석법을 이용한 자성기반 가중응집제의 응집조건 최적화)

  • Lee, Jinsil;Park, Seongjun;Kim, Jong-Oh
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.12
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    • pp.689-697
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    • 2017
  • As a fundamental study to apply the new flocculation method using ballast in water treatment process, the optimal conditions for general and ballast coagulant dosage, and pH, which are known to have a significant influence, were derived by response surface methodology. Poly aluminum chloride (PAC) and magnetite ballast were used as a general coagulant and ballast, respectively. Coagulation experiments were performed by jar-tester using the kaolin based synthetic water. The effects of three independent variables (pH, PAC, and ballast) on response variables (turbidity removal rate and average settling velocity of flocs) and the optimum condition of independent variables to induce the optimum flocculation were obtained by 17 experimental conditions designed by Box-Behnken procedure. After performing experiments, the quadratic regression model was derived for each of response variables, and the response surface analysis was conducted to explore the correlation between independent variables and response variables. The $R^2$ values for the turbidity removal rate and the average settling velocity were 0.9909 and 0.8295, respectively. The optimal conditions of independent variables were 7.4 of pH, 38 mg/L of PAC and 1,000 mg/L of ballast. Under these conditions, the turbidity removal rate was more than 97% and the average settling velocity exceeded 35 m/h.

Electrocephalographic Manifestations of Transient Stress Responses While Performing a Memory Task With Background White Noise (배경 백색소음하에서 기억과제를 수행할 때 겪는 단기 스트레스의 뇌파 특성)

  • ;Estate Sokhadze
    • Science of Emotion and Sensibility
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    • v.2 no.1
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    • pp.137-145
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    • 1999
  • 열 두 명의 피험자가 안정상태 일 때, 백색 소음에 노출되었을 때, 백색 소음 하에서 기억과제에 주의를 기울일 때, 백색 소음 하에서 기억 검사를 받을 때, 기록된 뇌파에 대해 relative power spectrum 분석을 하였다. 뇌파는 전두, 측두, 후두 영역에서 단극 유도법으로 기록되었다. 분석 결과, 백색 소음에만 노출되었을 때나, 백색 소음 하에서 기억과제에 주의를 기울일 때나 비슷한 전기피질(electrocortical) 반응이 나타났다. 즉, delta power의 증가, 알파 blocking, fast beta power의 증가, 스트레스를 일으킨다고 피험자들이 평정한 배색 소음 하에서 기억검사를 받을 때에도 동일한 뇌파 패턴이 나타났지만 그 크기가 유의하게 컸다. 정보를 지각할 때 전형적으로 나타나는 반응을 유발하는 스트레스원에 수동적으로 노출되었을 때("intaki"상황)의 생리 반응과 스트레스 상황에 적극적으로 대처할 때("rejection")의 생리 반응을 구분하는 이론 틀 아래서 데이터를 해석하였다. 스트레스 후 기간에 대부분의 뇌파 변수들이 기저선 수준으로 회복된 것으로 보아 사용한 스트레스 유발 모델은 단기적 스트레스 반응만을 유발한 것으로 보인다. 이는, 더 장기적으로 지속되는 스트레스원을 사용하게 되면, tonic상태의 전기피질 반응이 나타날 것을 시사한다.기피질 반응이 나타날 것을 시사한다.

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