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http://dx.doi.org/10.4491/KSEE.2017.39.12.689

Optimizing Coagulation Conditions of Magnetic based Ballast Using Response Surface Methodology  

Lee, Jinsil (Department of Civil and Environmental Engineering, Hanyang University)
Park, Seongjun (Department of Civil and Environmental Engineering, Hanyang University)
Kim, Jong-Oh (Department of Civil and Environmental Engineering, Hanyang University)
Publication Information
Abstract
As a fundamental study to apply the new flocculation method using ballast in water treatment process, the optimal conditions for general and ballast coagulant dosage, and pH, which are known to have a significant influence, were derived by response surface methodology. Poly aluminum chloride (PAC) and magnetite ballast were used as a general coagulant and ballast, respectively. Coagulation experiments were performed by jar-tester using the kaolin based synthetic water. The effects of three independent variables (pH, PAC, and ballast) on response variables (turbidity removal rate and average settling velocity of flocs) and the optimum condition of independent variables to induce the optimum flocculation were obtained by 17 experimental conditions designed by Box-Behnken procedure. After performing experiments, the quadratic regression model was derived for each of response variables, and the response surface analysis was conducted to explore the correlation between independent variables and response variables. The $R^2$ values for the turbidity removal rate and the average settling velocity were 0.9909 and 0.8295, respectively. The optimal conditions of independent variables were 7.4 of pH, 38 mg/L of PAC and 1,000 mg/L of ballast. Under these conditions, the turbidity removal rate was more than 97% and the average settling velocity exceeded 35 m/h.
Keywords
Coagulation; Ballast Material; Turbidity Removal; Settling Velocity; Response Surface Methodology (RSM);
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Times Cited By KSCI : 4  (Citation Analysis)
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1 Jeong, S. U., Lee, J. H., Park, T. W. and Kim, Y. M., "Utilization of response surface methodology to optimize a coagulation- flocculation process for tunnel wastewater treatment," J. Korean Soc. Water Wastewater, 28(5), 601-608(2014).   DOI
2 Lee, K. E., Morad, N., Teng, T. T. and Poh, B. T., "Development, characterization and the application of hybrid materials in coagulation/flocculation of wastewater: A review," Chem. Eng. J., 203, 370-386(2012)   DOI
3 Zhu, T., Heo, H. J. and Row, K. H., "Optimization of crude polysaccharides extraction from Hizikia fusiformis using response surface methodology," Carbohydrate Polym., 82(1), 106-110(2010)   DOI
4 Watson, M. A., Tubic, A., Agbaba, J., Nikic, J., Maletic, S., Jazic, J. M. and Dalmacija, B., "Response surface methodology investigation into the interactions between arsenic and humic acid in water during the coagulation process," J. Hazard. Mater., 312, 150-158(2016).   DOI
5 Kim, Y. and Oh, J., "Optimization of coagulant dosage using response surface methodology with central composite design," J. Korean Soc. Water Wastewater, 29(2), 193-202(2015).   DOI
6 Trinh, T. K. and Kang, L. S., "Response surface methodological approach to optimize the coagulation-flocculation process in drinking water treatment," Chem. Eng. Res. Des., 89(7), 1126-1135(2011).   DOI
7 Ghafari, S., Aziz, H. A., Isa, M. H. and Zinatizadeh, A. A., "Application of response surface methodology (RSM) to optimize coagulation-flocculation treatment of leachate using poly-aluminum chloride (PAC) and alum," J. Hazard. Mater., 163(2), 650-656(2009).   DOI
8 Nourani, M., Baghdadi, M., Javan, M. and Bidhendi, G. N., "Production of a biodegradable flocculant from cotton and evaluation of its performance in coagulation-flocculation of kaolin clay suspension: optimization through response surface methodology (RSM)," J. Environ. Chem. Eng., 4(2), 1996-2003(2016)   DOI
9 Yoon, C. H., Bok, H. S., Choi, D. K. and Row, K. H., "Optimization condition of astaxanthin extract from shrimp waste using response surface methodology," Korean Chem. Eng. Res., 50(3), 545-550(2012).   DOI
10 Krupa, A. N. D., Abigail, M. E. A., Santhosh, C., Grace, A. N. and Vimala, R., "Optimization of process parameters for the microbial synthesis of silver nanoparticles using 3-level Box-Behnken Design," Ecol. Eng., 87, 168-174(2016).   DOI
11 Lomax, Richard G., "Statistical Concepts: A Second Course," p.10. ISBN 0-8058-5850-4(2007).
12 Freitas, T. K. F. S., Oliveira, V. M., De Souza, M. T. F., Geraldino, H. C. L., Almeida, V. C., Favaro, S. L. and Garcia, J. C., "Optimization of coagulation-flocculation process for treatment of industrial textile wastewater using okra (A. esculentus) mucilage as natural coagulant," Ind. Crops Prod., 76, 538-544(2015).   DOI
13 Han, S. W. and Kang, L. S., "Comparison of Al(III) and Fe(III) Coagulants for Improving Coagulation Effectiveness in Water Treatment," J. Korean Soc. Environ. Eng., 37(6), 325-331(2015).   DOI
14 Ha, S. R. and Lee, S. C., "An Evaluation of Solid Removal Efficiency in Coagulation System for Treating Combined Sewer Overflows by Return Sludge," J. Korean Soc. Environ. Eng., 35(3), 171-178(2013).   DOI
15 Boo, K. O., Kwon, W. T. and Baek, H. J., "Change of extreme events of temperature and precipitation over Korea using regional projection of future climate change," Geophys. Res. Lett., 33(1), L01701 (2006).   DOI
16 Zhang, M., Xiao, F., Wang, D., Xu, X. and Zhou, Q., "Comparison of novel magnetic polyaluminum chlorides involved coagulation with traditional magnetic seeding coagulation: Coagulant characteristics, treating effects, magnetic sedimentation efficiency and floc properties," Sep. Purif. Technol., 182, 118-127(2017).   DOI
17 Desjardins, C., Koudjonou, B. and Desjardins, R., "Laboratory study of ballasted flocculation," Water Res., 36(3), 744-754(2002).   DOI
18 Lapointe, M., Brosseau, C., Comeau, Y. and Barbeau, B. "Assessing Alternative Media for Ballasted Flocculation," J. Environ. Eng., 143(11), 04017071(2017).   DOI
19 Cirak, M. and Hosten, C., "Optimization of coagulation-flocculation process for treatment of a colloidal suspension containing dolomite/clay/borax," Int. J. Miner. Process, 159, 30-41(2017).   DOI
20 Lee, Y. J., Lim, J. L., Lee, K. H. and Heo, T. Y., "Optimization of coagulation conditions for the drinking water treatment using a response surface method," J. Korean Soc. Water Sci. Technol., 20(5), 81-89(2012).
21 Bache, D. H. and Gregory, R., "Flocs in water treatment," IWA Publishing, (2007).
22 Lee, B. H., Park, S. B. and Kim, M. G., "Optimization of coagulant dosage in Eel farm using response surface methodology," Jour. Wat. Treat., 24(4), 119-129(2016).   DOI