• Title/Summary/Keyword: 반응면

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A Study of Carbon Monoxide Oxidation on ZnO Single Crystal Surface (산화아연 단결정 면에서 일산화탄소의 산화반응에 대한 연구)

  • Jin Jun;Chong Soo Han
    • Journal of the Korean Chemical Society
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    • v.37 no.2
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    • pp.183-190
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    • 1993
  • The properties of oxidation reactions of carbon monoxide on ZnO (1010) were studied at the temperature range of 298∼573 K by measuring the capacitance and conductance in the insulating layer of two contacting crystal faces which vary with ZnO-gas interaction mechanisms. Exposure of the sample to CO resulted in an increase in the layer depth at 298∼373 K, while it decreased above 473 K. But the variation of the layer depth was very small in all measurements. When CO was admitted to the sample previously treated with $O_2$ at the same temperature, we observed the different features compared with the case of CO adsorption. From these results we discussed the mechanisms of CO oxidation in connection with the adsorbed oxygen species at each temperature.

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Design Optimization of An Axial-Flow Compressor Rotor Using Response Surface Method (반응면 기법을 이용한 천음속 축류압축기의 삼차원 형상 최적설계)

  • Ahn, Chan-Sol;Kim, Kwang-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.2
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    • pp.155-162
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    • 2003
  • Design optimization of a transonic compressor rotor (NASA rotor 37) using response surface method and three-dimensional Navier-Stokes analysis has been carried out in this work. Baldwin-Lomax turbulence model was used in the flow analysis. Three design variables were selected to optimize the stacking line of the blade. Data points for response evaluations were selected by D-optimal design, and linear programming method was used for the optimization on the response surface. As a main result of the optimization, adiabatic efficiency was successfully improved. It is also found that the design process provides reliable design of a turbomachinery blade with reasonable computing time.

Aerodynamic Design Optimization of An Axial Flow Compressor Rotor (반응면 기법을 이용한 천음속 축류압축기의 3차원 형상 최적설계)

  • Ahn, Chan-Sol;Kim, Kwang-Yong
    • 유체기계공업학회:학술대회논문집
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    • 2001.11a
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    • pp.135-142
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    • 2001
  • Design optimization of a transonic compressor rotor (NASA rotor 37) using response surface method and three-dimensional Navier-Stokes analysis has been carried out in this work. Baldwin-Lomax turbulence model was used in the flow analysis. Three design variables were selected to optimize the stacking line of the blade. Data points for response evaluations were selected by D-optimal design, and linear programming method was used for the optimization on the response surface. As a main result of the optimization, adiabatic efficiency was successfully improved. Ana, it is found that the design process provides reliable design of a turbomachinery blade with reasonable computing time.

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Aerodynamic Design Optimization of an Jet Fan using the Response Sruface Method (반응면 기법을 이용한 제트송풍기의 공력학적 수치최적설계)

  • Seo Seoung-Jin;Kim Kwang-Yong
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.635-638
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    • 2002
  • In this study, three-dimensional imcompressible viscous flow analysis and optimization using response surface method are presented for the design of a jet fan. Steady, imcompressible, three-dimensional Reynolds averaged Wavier-Stokes equations are used as governing equations, and standard $k-{\varepsilon}$ turbulence model is chosen as a turbulence model. Governimg equations are discretized using finite volume method. Sweep angles are used as design variables for the shape optimization of the impeller in response surface method. The experimental points which are needed to construct response surface are obtained from the D-optimal design and finally the shape of impeller Is achieved from using a numerical optimization for the response surface which is obtained from CFD.

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Shape Optimization of Sedimentation Tank Using Response Surface Method (반응면기법을 이용한 침전조의 형상최적설계)

  • Kim, Hong-Min;Choi, Seung-Man;Kim, Kwang-Yong
    • The KSFM Journal of Fluid Machinery
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    • v.7 no.6 s.27
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    • pp.55-61
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    • 2004
  • A numerical procedure for optimizing the shape of three-dimensional sedimentation tank is presented to maximize its sedimentation efficiency. The response surface based optimization is used as an optimization technique with Reynolds-averaged Navier-Stokes analysis for multi-phase flow. Standard $k-{\epsilon}$ model is used as a turbulence closure. Three design variables such as, tank height to center feed wall diameter ratio, blockage ratio of center feed wall and angle of distributor are chosen as design variables. Sedimentation efficiency is defined as an objective function. Full-factorial method is used to determine the training points as a means of design of experiment. Sensitivity of each design variable on the objective function has been evaluated. And, optimal values of the design variables have been obtained.

Chemical Fixation of Carbon Dioxide with Methane (메탄에 의한 이산화탄소의 화학적 고정화)

  • 조영복;김상채;서성규;유의연
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.389-390
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    • 2000
  • 최근 지구 온난화의 55% 이상을 차지하고 있는 이산화탄소를 유용한 화합물로 전환하고자 메탄을 환원제로 사용한 이산화탄소 개질반응으로부터 합성가스 생성에 관한 연구가 활발히 진행되고 있다. 메탄의 이산화탄소 개질반응은 수증기 개질반응보다 낮은 합성 가스비의 생성, 온실효과를 유발하는 이산화탄소의 저감, 반응의 높은 흡열도를 이용한 화학에너지 전송 시스템의 응용 면에서 그 의의가 있다. (중략)

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Sonolysis of Trichloroethylene in the Multi Ultrasound Irradiation Reactor (다중 초음파 조사 반응조에서의 TCE의 초음파 분해)

  • Lee, Min-Ju;Oh, Je-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.10
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    • pp.873-882
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    • 2009
  • Sonolysis of TCE (Trichloroethylene) was performed in 584 kHz rectangular reactor. At first, the effect of acoustic power and aqueous temperature which are both important factors to operate ultrasound system on sonolysis of TCE were examined under one side irradiation condition. First degradation rate constants of TCE and chloride yields were increased with increasing acoustic power from 100 to 300 W. And increasing the aqeuous temperature resulted in the increase of first degradation rate constants of TCE and the decrease of chloride yield. Sonolysis of TCE was performed under multi ultrasound irradiation conditions that total acoustic power of 300 W was distributed according to the number of irradiation sides. First degradation rate constants of TCE followed the order 4 sides > 3 sides > 1 side > 2 sides (parallel) > 2 sides (orthogonal). When comparing the experimental results under parallel and orthogonal irradiation conditions of 2 sides with 300 and 450 W, first degradation rate constants of TCE were similar, while production rate constants of hydrogen peroxide were more higher at parallel conditions compared to orthogonal conditions.

Effect of Light on Growth of Chlorella sp. HA-1 in Large-scale Photobioreactors for Biological $CO_2$ Fixation (생물학적 $CO_2$ 고정화를 위한 스케일-업된 광생물반응기에서 Chlorella sp. HA-1의 성장에 미치는 빛의 영향)

  • 이재영;권태순;김호정;양지원
    • KSBB Journal
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    • v.18 no.4
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    • pp.340-345
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    • 2003
  • Feasibility of large-scale photobioreactors for biological CO$_2$ fixation was investigated using Chlorella sp. HA-1. Generally, as the volume of photobioreactor increased, the CO$_2$ fixation rate decreased because of a lower illumination efficiency in large-scale than in small-scale photobioreactors. Though controlling the arrangement and the number of light source, the maximum CO$_2$ fixation rates that could be achieved were 530 and 357 gCO$_2$/㎡day for 40 L and 188 L photobioreactor, respectively, which was higher than the CO$_2$ fixation rate of lab-scale photobioreactor.

Properties of Methane Steam Reforming in Micro Channel Reactor (미세유로 반응기를 이용한 메탄 스팀 개질 반응 특성)

  • Lee, Sung-Wook;Lee, Chun-Boo;Kim, Kwang-Ho;Park, Jin-Woo;Hwang, Kyung-Ran;Park, Jong-Soo;Kim, Sung Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.114.2-114.2
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    • 2010
  • 마이크로 반응기술은 작은 반응기 부피, 높은 열전달, 넓은 반응 면적/부피 및 정확한 반응시간 조절이 가능하기 때문에 화학공정의 고집적화, 반응 선택도의 향상 및 안전도 향상을 꾀할 수 있는 장점이 있다. 이러한 마이크로 반응 기술을 중소형 천연가스 및 국내에서 소규모로 국지적으로 발생하는 메탄의 활용 방안으로서 개발함은 청정 합성유를 제조함으로서 석유 자원의 고갈과 고유가에 대비하여 에너지 자원의 다변화 및 자립을 확보 할 수 있다. 본 연구에서는 마이크로 반응기술을 적용한 미세 유로 반응기(Micro Channel Reactor)를 사용하여 메탄 스팀 개질 반응 특성을 연구하였다. 미세유로 반응기는 내부 홀이 존재하는 plate를 적층함으로 반응기내에 반응가스가 이동할 수 있는 미세유로가 존재하게 하였다. 이러한 미세유로는 반응기의 크기가 작음에도 반응기내에서 반응가스가 충분히 반응할 수 있는 시간과 높은 열전달 효율을 가질 수 있게 한다. 메탄 스팀 개질 반응에 사용된 촉매는 Ni 촉매를 사용하였고, 반응에 필요한 열원으로는 수소 연소에서 발생한 열을 사용하여 반응을 유도하였다. 본 반응기는 외부의 열원을 사용하지 않고, 반응기 내부의 수소 연소에서 발생한 열을 사용함으로 적은 발생 열만으로 메탄 스팀 개질 반응에 필요한 에너지를 얻을 수 있고, 열의 손실이 적다. 또한 메탄 스팀 개질 반응으로 발생한 일부의 수소를 열원으로 이용하여 에너지 사용면에서도 효율적인 반응 공정이다.

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Neutral Network에 의한 기계운활면의 마멸분 해석

  • 박흥식
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1995.06a
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    • pp.65-71
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    • 1995
  • 기계 윤활면내에 포함된 마멸입자는 기계시스템의 상태를 잘 대변하여 주므로 마멸입자의 크기분포, 단위체적당 입자수, 구성성분 및 형상 등의 정확한 규명은 기계시스템의 상태진단을 위한 여러 정보를 제공한다. 특히 마멸입자의 형상과 그 크기는 미시적 파괴현상인 마멸과정의 기구를 반영해 주고 있으며, 또한 마멸입자의 표면은 그것이 마찰면 혹은 파단면의 미시적인 형상과 반응 생성물을 포함하고 있는 표본이 된다. 본 연구에서는 마멸분의 형상, 크기, 표면광택 등과 그것이 발생하는 작동조건과의 관계를 인공 신경회로망 해석을 이용하여 기계 윤활면의 마멸분 형태인식에 적용하는 것을 목적으로 하였다.

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